CN100347327C - Glass sealing alloy - Google Patents
Glass sealing alloy Download PDFInfo
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- CN100347327C CN100347327C CNB02145146XA CN02145146A CN100347327C CN 100347327 C CN100347327 C CN 100347327C CN B02145146X A CNB02145146X A CN B02145146XA CN 02145146 A CN02145146 A CN 02145146A CN 100347327 C CN100347327 C CN 100347327C
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- Prior art keywords
- alloy
- sealing
- glass sealing
- present
- glass
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- 239000000956 alloy Substances 0.000 title claims abstract description 38
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 37
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 238000007789 sealing Methods 0.000 title claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 238000003723 Smelting Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 description 8
- 230000006698 induction Effects 0.000 description 7
- 241001062472 Stokellia anisodon Species 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 229910052755 nonmetal Inorganic materials 0.000 description 6
- 239000012535 impurity Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 241001417490 Sillaginidae Species 0.000 description 1
- 229910002064 alloy oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000013139 quantization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Glass Compositions (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The present invention discloses glass sealing alloy which is composed of the following components by weight percentage respectively: 15.0 to 22.0 wt% of Cr, 0.20 to 3.0 wt% of Nb, 0 to 0.06 wt% of C, 0.20 to 0.80 wt% of Mn, 0 to 0.80 wt% of Si, 0 to 0.04 wt% of P, 0 to 0.04 wt% of S, 0 to 0.50 wt% of Ni, 0 to 0.40 wt% of Al, 0 to 0.50 wt% of Mo, 0 to 0.50 wt% of Ti and Fe as the rest. The glass sealing alloy can also be composed of the following components by weight percentage respectively: 25.0 to 32.0 wt% of Cr, 0.2 to 3.0 wt% of Nb, 0 to 0.06 wt% of C, 0.20 to 0.80 wt% of Mn, 0 to 0.80 wt% of Si, 0 to 0.04 wt% of P, 0 to 0.04 wt% of Ni, 0 to 0.50 wt% of Al, 0 to 0.40 wt% of Mo, 0 to 0.50 wt% of Ti and Fe as the rest. The Nb whose content need not check with the association of the contents of the C and the N is added to the alloy of the present invention, so that the smelting is convenient, and the cost is reduced; in addition, when the glass sealing is carried out by the present invention, the sealing quality can be ensured, the oxidation process can be simplified, and the production cost can be reduced.
Description
Technical field
The present invention relates to a kind of glass sealing alloy, particularly a kind of is the alloy of matrix with Fe, Cr, Nb.
Background technology
At present, domestic and international widely used glass sealing alloy is the 430Ti alloy.It is year historical that the 430Ti alloy is used for surplus electron tube and the glass sealing material existing 30, the company standard of each company is similar, because different its compositions in each glass company used glass material ore place of production are slightly different, so the thermal expansivity of glass is also slightly different, but each glass company is the same to the basic demand of 430Ti alloy.Chemical Composition as the desired 430Ti alloy of world-renowned Corning Incorporated (Corning Glass Works) is as shown in table 1:
Table 1:(weight) %
C N Mn Ni Si Al P S Cr
≤0.06 ≤0.035 ≤0.60 ≤0.50 ≤0.60 ≤0.15 ≤0.04 ≤0.03 19.5～20.5
Maximum other impurity surpluses of 0.65 Fe+ of minimum A 6 * (C+N) Ti of Ti
Minimum B 8 * C
World-renowned Japan AGC company desired 430Ti alloy composition standard is as shown in table 2:
Table 2::(weight) %
C Si Mn P S Ni Cr
≤0.06 0.20～0.80 ≤0.60 ≤0.04 ≤0.03 0.25～0.35 17.5～19.5
Cu Al Ti other impurity of Ti N Fe+ that dissociate
0.05～0.15≤0.03 0.35～0.65 0.15～0.35≤0.01 surplus
From table 1 and table 2 as can be seen, 430Ti alloy standard has the requirement except that the content to metallic element, also non-metallic element such as N there is requirement, and the Ti of Corning Incorporated constituent content must connect examination with C or C and N content, Asahi Glass company is except that examination Ti (metallic state+state of oxidation) content, also must examine free (Free) Ti (metallic state) content, bring very big difficulty to smelting.
Summary of the invention
The objective of the invention is to overcome the defective of above-mentioned prior art, a kind of novel glass sealing alloy is provided.
Glass sealing alloy of the present invention, form by Cr, Nb, C, Mn, Si, P, S, Ni, Al, Mo, Ti and Fe, its weight percent is respectively 15.0～22.0%, 0.20～3.0%, 0～0.06%, 0.20～0.80%, 0～0.80%, 0～0.04%, 0～0.04%, 0～0.50%, 0～0.40%, 0～0.50% and 0～0.50%, and all the other are Fe.Certainly, the present invention also contains other elements (impurity) of some traces.
Best, this each weight percentages of components is respectively 18.5%, 0.80%, 0.05%, 0.60%, 0.40%, 0.02%, 0.02%, 0.15%, 0.25%, 0.20%, 0.20% and 78.81%.
Glass sealing alloy of the present invention, can also form by Cr, Nb, C, Mn, Si, P, S, Ni, Al, Mo, Ti and Fe, its weight percent is respectively 25.0～32.0%, 0.2～3.0%, 0～0.06%, 0.20～0.80%, 0～0.80%, 0～0.04%, 0～0.04%, 0～0.50%, 0～0.40%, 0～0.50% and 0～0.50%, and all the other are Fe.Certainly, the present invention also contains other elements (impurity) of some traces.
Best, this each weight percentages of components is respectively 28.5%, 0.80%, 0.06%, 0.06%, 0.40%, 0.02%, 0.02%, 0.25%, 0.15%, 0.20%, 0 and 69.54%.
Alloy of the present invention can adopt pure metal material or iron alloy intermediate raw material, according to existing processing condition, smelts and gets at vacuum induction furnace.
Alloy of the present invention is owing to add Nb, and its content does not need to connect examination, convenient smelting with C and N content, reduce cost, in addition, when using the present invention to carry out glass sealing, not only can guarantee the sealing-in quality, and can simplify oxidizing process, reduce production costs.
Embodiment
Embodiment 1
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(unit: kilogram) 15.0 0.2 0 0.2 0000000 84.6
Embodiment 2
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(Dan Li: kilogram) 22.0 3.0 0.06 0.80 0.80 0.04 0.04 0.50 0.40 0.50 0.50 71.36
Embodiment 3
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(unit: kilogram) 18.5 0.80 0.05 0.60 0.40 0.02 0.02 0.15 0.25 0.20 0.20 78.81
Embodiment 4
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(unit: kilogram) 25.0 0.2 0 0.20 0000000 74.6
Embodiment 5
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(unit: kilogram) 32.0 3.0 0.06 0.80 0.80 0.04 0.04 0.50 0.40 0.50 0.50 61.36
Embodiment 6
With following each elemental metals or the nonmetal vacuum induction furnace of putting into, smelt by existing processing condition, thereby make this alloy.
Cr Nb C Mn Si P S Ni Al Mo Ti Fe
(unit: kilogram) 28.5 0.80 0.06 0.60 0.40 0.02 0.02 0.25 0.15 0.20 0 69.54
Application Example 1 (demoulding test)
With embodiment 1～6 prepared alloy is example
Behind the sealing-in component test sample and glass sealing that is processed into this alloy, through the demoulding evidence, its sealing-in fastness is fine.Its situation is: glass fragmentation faced, and oxide film is excellent, and the alloy material surface is with more complete glass.
Application Example 2 (experiment of sealing-in element oxidation increment)
| Before the oxidizing thermal treatment | After the processing | Oxidation increment | The averaged oxygen quantizer input quantization increment | |
| The sealing-in element that embodiment 1 makes | 2.60414g | 2.61138g | 7.24mg | 7.25mg |
| The sealing-in element that embodiment 2 makes | 2.60631g | 2.61358g | 7.27mg | |
| The sealing-in element that embodiment 3 makes | 2.60213g | 2.60938g | 7.26mg | |
| The sealing-in element that the 430Ti alloy makes | 2.61280g | 2.61658g | 3.78mg | 3.77mg |
| 2.61321g | 2.61695g | 3.74mg | ||
| 2.61269g | 2.61648g | 3.79mg | ||
| The sealing-in element that embodiment 4 makes | 3.04028g | 3.04553g | 5.25mg | 5.27mg |
| The sealing-in element that embodiment 5 makes | 3.04027g | 3.04554g | 5.27mg | |
| The sealing-in element that embodiment 6 makes | 3.04029g | 3.04557g | 5.28mg | |
| The sealing-in element that the 430Ti alloy makes | 3.04031g | 3.04345g | 3.14mg | 3.15mg |
| 3.04027g | 3.04344g | 3.17mg | ||
| 3.04029g | 3.04342g | 3.15mg |
Above-mentioned experimental result all obtains under the same process condition.Can calculate from above data, alloy sealing element oxidation increment of the present invention is higher by 67～92% than prior art 430Ti alloy, so alloy oxide film of the present invention forms the also corresponding raising 67～92% of speed ratio 403Ti alloy.Therefore use alloy of the present invention can obviously reduce sealing-in element oxidizing thermal treatment energy, labour cost etc., and improved the utilising efficiency of equipment greatly.
Claims (4)
1. a glass sealing alloy contains Cr, Nb, Mn, Mo and Fe, and its weight percent is respectively 15.0～22.0% or 25.0～32.0%, 0.20～3.0%, 0.20～0.80% and 0.20～0.50%, and all the other are Fe.
2. glass sealing alloy according to claim 1, it is characterized in that also containing and be not more than 0.06% C, be not more than 0.80% Si, be not more than 0.04% P, be not more than 0.04% S, be not more than 0.50% Ni, be not more than 0.40% Al and be not more than 0.50% Ti, this per-cent all is weight percentage.
3. alloy according to claim 2 is characterized in that each weight percentages of components is respectively 18.5%, 0.80%, 0.05%, 0.60%, 0.40%, 0.02%, 0.02%, 0.15%, 0.25%, 0.20%, 0.20% and 78.81%.
4. alloy according to claim 2 is characterized in that each weight percentages of components is respectively 28.5%, 0.80%, 0.06%, 0.60%, 0.40%, 0.02%, 0.02%, 0.25%, 0.15%, 0.20%, 0 and 69.54%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02145146XA CN100347327C (en) | 2002-11-08 | 2002-11-08 | Glass sealing alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB02145146XA CN100347327C (en) | 2002-11-08 | 2002-11-08 | Glass sealing alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1498982A CN1498982A (en) | 2004-05-26 |
| CN100347327C true CN100347327C (en) | 2007-11-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB02145146XA Expired - Fee Related CN100347327C (en) | 2002-11-08 | 2002-11-08 | Glass sealing alloy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100347327C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105132803B (en) * | 2015-09-15 | 2017-06-20 | 重庆材料研究院有限公司 | High intensity controlled expansion alloy |
| CN105401083B (en) * | 2015-11-13 | 2017-09-19 | 北京有色金属研究总院 | High temperature solar vacuum heat-collecting pipe sealing alloy and its preparation and application |
| CN108330400A (en) * | 2018-01-19 | 2018-07-27 | 辽宁顺通机械科技有限公司 | Edge face sealing member material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5773169A (en) * | 1980-10-24 | 1982-05-07 | Central Glass Co Ltd | Sealed metallic wire rod for reinforcing glass |
| JPS62188753A (en) * | 1987-02-19 | 1987-08-18 | Sumitomo Special Metals Co Ltd | Soft glass sealing alloy |
| CN1094096A (en) * | 1993-04-13 | 1994-10-26 | 上海钢铁研究所 | With soft glass sealing-in non-corrosive metal |
| US5364588A (en) * | 1992-10-26 | 1994-11-15 | A. Finkl & Sons Co. | Double stabilized stainless-type steel die block |
-
2002
- 2002-11-08 CN CNB02145146XA patent/CN100347327C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5773169A (en) * | 1980-10-24 | 1982-05-07 | Central Glass Co Ltd | Sealed metallic wire rod for reinforcing glass |
| JPS62188753A (en) * | 1987-02-19 | 1987-08-18 | Sumitomo Special Metals Co Ltd | Soft glass sealing alloy |
| US5364588A (en) * | 1992-10-26 | 1994-11-15 | A. Finkl & Sons Co. | Double stabilized stainless-type steel die block |
| CN1094096A (en) * | 1993-04-13 | 1994-10-26 | 上海钢铁研究所 | With soft glass sealing-in non-corrosive metal |
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| Publication number | Publication date |
|---|---|
| CN1498982A (en) | 2004-05-26 |
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Granted publication date: 20071107 Termination date: 20091208 |