CN100410263C - 作为均相氢化催化剂的取代的二茂铁基二膦 - Google Patents

作为均相氢化催化剂的取代的二茂铁基二膦 Download PDF

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Publication number
CN100410263C
CN100410263C CNB2004800125336A CN200480012533A CN100410263C CN 100410263 C CN100410263 C CN 100410263C CN B2004800125336 A CNB2004800125336 A CN B2004800125336A CN 200480012533 A CN200480012533 A CN 200480012533A CN 100410263 C CN100410263 C CN 100410263C
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China
Prior art keywords
compound
formula
complex
metal
alkyl
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Expired - Lifetime
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CNB2004800125336A
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English (en)
Chinese (zh)
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CN1832953A (zh
Inventor
F·斯平德勒
M·罗茨
M·托门
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Umicore AG and Co KG
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Umicore AG and Co KG
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0286—Complexes comprising ligands or other components characterized by their function
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB2004800125336A 2003-05-09 2004-05-07 作为均相氢化催化剂的取代的二茂铁基二膦 Expired - Lifetime CN100410263C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH8142003 2003-05-09
CH814/03 2003-05-09

Publications (2)

Publication Number Publication Date
CN1832953A CN1832953A (zh) 2006-09-13
CN100410263C true CN100410263C (zh) 2008-08-13

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Family Applications (1)

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CNB2004800125336A Expired - Lifetime CN100410263C (zh) 2003-05-09 2004-05-07 作为均相氢化催化剂的取代的二茂铁基二膦

Country Status (12)

Country Link
US (1) US7244860B2 (fr)
EP (1) EP1622920B1 (fr)
JP (1) JP4633047B2 (fr)
CN (1) CN100410263C (fr)
AT (1) ATE337327T1 (fr)
CA (1) CA2524902C (fr)
DE (1) DE602004002114T2 (fr)
ES (1) ES2271886T3 (fr)
IL (1) IL171765A (fr)
MX (1) MXPA05011392A (fr)
RU (1) RU2352577C2 (fr)
WO (1) WO2004099226A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7435840B2 (en) * 2003-12-12 2008-10-14 Solvias Ag Method for producing orthometalated and orthosubstituted metallocenes
ES2493634T3 (es) * 2006-05-23 2014-09-12 Solvias Ag Ligandos quirales que se usan en catalizadores de metales de transición para reacciones por adición asimétricas, especialmente para una hidrogenación
CN100465181C (zh) * 2006-06-08 2009-03-04 上海交通大学 C2－对称的只具有面手性的二茂钌双膦配体的合成方法
US8507705B2 (en) * 2006-06-08 2013-08-13 Shanghai Jiaotong University C2-symmetrical ruthenocene diphosphine ligands only with surface chirality and their manufacture
RU2433131C2 (ru) 2007-02-01 2011-11-10 Интервет Интернэшнл Б.В. ЭНАНТИОСЕЛЕКТИВНЫЙ СИНТЕЗ 6-АМИНО-7-ГИДРОКСИ-4,5,6,7-ТЕТРАГИДРОИМИДАЗО[4,5,1-jk][1]БЕНЗАЗЕПИН-2[1H]-ОНА И ЗИЛПАТЕРОЛА
DE102007022389A1 (de) 2007-05-10 2008-11-13 Umicore Ag & Co. Kg Ruthenium-Komplexe mit (P-P)-koordinierten Ferrocenyl-diphosphinliganden, Verfahren zu ihrer Herstellung sowie ihre Anwendung in der homogenen Katalyse
EP2107065A1 (fr) 2008-04-01 2009-10-07 Umicore AG & Co. KG Complexe de ruthénium contenant des ligands donneurs de di-phosphore coordonnés (P-P) et leur procédé de fabrication
US8450496B2 (en) * 2009-03-24 2013-05-28 Hoffman-La Roche Inc. Process for the preparation of propionic acid derivatives
CN106607092B (zh) * 2015-10-22 2019-10-08 中国石油化工股份有限公司 催化剂组合物及其应用
CN106046065B (zh) * 2016-05-26 2018-07-13 河南省科学院化学研究所有限公司 一种合成c2-对称性手性二茂铁膦化合物的方法
CN112047856B (zh) * 2019-06-06 2023-01-10 上海交通大学 手性α-酰胺基醛及其制备方法
CN112480179B (zh) * 2020-11-24 2025-11-14 苏州鹏旭医药科技有限公司 一种取代二茂铁基二膦均相催化剂配体
CN116925156A (zh) * 2023-07-28 2023-10-24 瑞博(苏州)制药有限公司 一种手性二茂铁配体的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0967015A2 (fr) * 1998-06-19 1999-12-29 Degussa-Hüls Aktiengesellschaft Utilisation de ligands ferrocenyl pour l'hydrogénation catalytique énantioselective

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5446844A (en) * 1987-10-05 1995-08-29 Unisys Corporation Peripheral memory interface controller as a cache for a large data processing system
JPH0262886A (ja) * 1988-08-29 1990-03-02 Sumitomo Chem Co Ltd 光学活性なフェロセニルホスフィンおよびその製法
SG42936A1 (en) * 1992-04-02 1997-10-17 Ciba Geigy Ag Ferrocenyl diphosphines as ligands for homogeneous catalysts
EP0965574B1 (fr) * 1998-06-19 2004-10-13 Degussa AG Procédé d'hydrogénation énantiosélective

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0967015A2 (fr) * 1998-06-19 1999-12-29 Degussa-Hüls Aktiengesellschaft Utilisation de ligands ferrocenyl pour l'hydrogénation catalytique énantioselective

Also Published As

Publication number Publication date
IL171765A (en) 2010-04-15
CA2524902C (fr) 2012-07-10
EP1622920A1 (fr) 2006-02-08
CA2524902A1 (fr) 2004-11-18
CN1832953A (zh) 2006-09-13
MXPA05011392A (es) 2005-12-12
RU2005138144A (ru) 2006-07-10
JP4633047B2 (ja) 2011-02-16
ES2271886T3 (es) 2007-04-16
DE602004002114T2 (de) 2007-03-29
JP2006525978A (ja) 2006-11-16
EP1622920B1 (fr) 2006-08-23
DE602004002114D1 (de) 2006-10-05
RU2352577C2 (ru) 2009-04-20
US7244860B2 (en) 2007-07-17
WO2004099226A1 (fr) 2004-11-18
ATE337327T1 (de) 2006-09-15
US20060241315A1 (en) 2006-10-26

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Granted publication date: 20080813