CN100482652C - 生产烯烃氧化物的方法 - Google Patents
生产烯烃氧化物的方法 Download PDFInfo
- Publication number
- CN100482652C CN100482652C CNB2004800114702A CN200480011470A CN100482652C CN 100482652 C CN100482652 C CN 100482652C CN B2004800114702 A CNB2004800114702 A CN B2004800114702A CN 200480011470 A CN200480011470 A CN 200480011470A CN 100482652 C CN100482652 C CN 100482652C
- Authority
- CN
- China
- Prior art keywords
- olefin
- catalyst
- alkene
- feed
- scope
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US46090103P | 2003-04-07 | 2003-04-07 | |
| US60/460,901 | 2003-04-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1791586A CN1791586A (zh) | 2006-06-21 |
| CN100482652C true CN100482652C (zh) | 2009-04-29 |
Family
ID=33299733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004800114702A Expired - Fee Related CN100482652C (zh) | 2003-04-07 | 2004-04-05 | 生产烯烃氧化物的方法 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7348444B2 (2) |
| EP (1) | EP1620414B2 (2) |
| JP (1) | JP5227513B2 (2) |
| KR (1) | KR101107477B1 (2) |
| CN (1) | CN100482652C (2) |
| CA (1) | CA2525520C (2) |
| DE (1) | DE602004029247D1 (2) |
| IN (1) | IN246332B (2) |
| MX (1) | MX261656B (2) |
| RU (1) | RU2345073C2 (2) |
| TW (1) | TWI374773B (2) |
| WO (1) | WO2004092148A2 (2) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2003243757A1 (en) | 2002-06-28 | 2004-01-19 | Shell Oil Company | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
| US8357812B2 (en) * | 2005-12-22 | 2013-01-22 | Shell Oil Company | Process for preparing a rejuvenated epoxidation catalyst |
| GB2433705A (en) * | 2005-12-22 | 2007-07-04 | Shell Int Research | A method of installing an epoxidation catalyst |
| US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| US7932408B2 (en) * | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
| JP5542659B2 (ja) | 2007-05-09 | 2014-07-09 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | エポキシ化触媒、触媒を調製する方法、および酸化オレフィン、1,2−ジオール、1,2−ジオールエーテル、1,2−カーボネートまたはアルカノールアミンの製造方法 |
| AR066469A1 (es) * | 2007-05-09 | 2009-08-19 | Shell Int Research | Un proceso de produccion de oxido de olefina , 1,2- diol, 1,2- diol eter, 1,2- carbonato o alcanolamina |
| RU2452564C2 (ru) | 2007-05-11 | 2012-06-10 | Барри Дж. БИЛЛИГ | Активация высокоселективных катализаторов в установках синтеза оксидов олефинов |
| US8569527B2 (en) * | 2007-05-18 | 2013-10-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| US9144765B2 (en) | 2007-05-18 | 2015-09-29 | Shell Oil Company | Reactor system, an absorbent and a process for reacting a feed |
| US20090292132A1 (en) * | 2007-05-18 | 2009-11-26 | Wayne Errol Evans | Reactor system and process for reacting a feed |
| AR066574A1 (es) * | 2007-05-18 | 2009-08-26 | Shell Int Research | Un sistema reactor, un proceso de produccion de oxido de olefina 1,2-diol 1,2-diol eter , 1,2-carbonato o alcanolamina |
| US8290626B2 (en) * | 2007-09-10 | 2012-10-16 | SD Lizenzverwertungsgesellschadt mbH & Co KG | Chemical process optimization method that considers chemical process plant safety |
| KR101629037B1 (ko) | 2008-05-07 | 2016-06-09 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 에폭시화 방법의 스타트업 방법, 산화에틸렌, 1,2-디올, 1,2-디올 에테르, 1,2-카보네이트 또는 알칸올아민의 생산방법 |
| CA2723592C (en) | 2008-05-07 | 2016-08-16 | Shell Internationale Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CA2724084A1 (en) | 2008-05-15 | 2009-11-19 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of an alkylene carbonate and an alkylene glycol |
| EP2285795B1 (en) | 2008-05-15 | 2017-03-22 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of alkylene carbonate and/or alkylene glycol |
| US20110152547A1 (en) * | 2009-12-17 | 2011-06-23 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| US8845975B2 (en) | 2009-12-28 | 2014-09-30 | Dow Technology Investments Llc | Method of controlling the production of silver chloride on a silver catalyst in the production of alkylene oxides |
| US8546592B2 (en) | 2010-09-29 | 2013-10-01 | Shell Oil Company | Olefin epoxidation process |
| US8742147B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| US8742146B2 (en) | 2010-12-08 | 2014-06-03 | Shell Oil Company | Process for improving the selectivity of an EO catalyst |
| SG190901A1 (en) | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| BR112013027585B1 (pt) | 2011-04-29 | 2020-09-29 | Shell Internationale Research Maatschappij B.V | Método para melhorar a seletividade de um catalisador de alta seletividade suportado usado na epoxidação de etileno e método para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina |
| WO2013062791A1 (en) * | 2011-10-24 | 2013-05-02 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| CA2858551C (en) | 2011-12-09 | 2021-10-26 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| US11801493B2 (en) | 2016-12-02 | 2023-10-31 | Shell Usa, Inc. | Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1191983A (en) * | 1968-04-11 | 1970-05-13 | Sir Soc Italiana Resine Spa | Preparation of Ethylene Oxide |
| US4766105A (en) * | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
Family Cites Families (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2219575A (en) | 1939-06-16 | 1940-10-29 | Carbide & Carbon Chem Corp | Catalyst and process for making olefin oxides |
| GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| GB1491447A (en) | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| GB1489335A (en) | 1973-10-26 | 1977-10-19 | Shell Int Research | Catalyst for the production of ethylene oxide |
| EP0003642B1 (en) | 1978-02-10 | 1984-07-18 | Imperial Chemical Industries Plc | Production of olefine oxides |
| JPS57107240A (en) | 1980-12-26 | 1982-07-03 | Nippon Shokubai Kagaku Kogyo Co Ltd | Production of silver catalyst for producing ethylene oxide |
| US4400559A (en) | 1982-06-14 | 1983-08-23 | The Halcon Sd Group, Inc. | Process for preparing ethylene glycol |
| US4845296A (en) | 1983-12-13 | 1989-07-04 | Union Carbide Corporation | Process for preparing alkanolamines |
| GB8423044D0 (en) | 1984-09-12 | 1984-10-17 | Ici Plc | Production of ethylene oxide |
| EP0211521B1 (en) | 1985-07-31 | 1990-03-21 | Imperial Chemical Industries Plc | Process of promoting catalysts for the production of alkylene oxides |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4950773A (en) | 1988-01-28 | 1990-08-21 | Eastman Kodak Company | Selective epoxidation of olefins |
| US5081259A (en) * | 1988-06-15 | 1992-01-14 | Abbott Laboratories | Novel amino acid substituted 4-aminophenazones for measuring enzyme activity |
| CA1339317C (en) | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| US4874879A (en) | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| GB9005814D0 (en) | 1990-03-15 | 1990-05-09 | Shell Int Research | A two-step monoethylene glycol preparation process |
| US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| AU656537B2 (en) | 1990-10-12 | 1995-02-09 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5100859A (en) | 1991-01-22 | 1992-03-31 | Norton Company | Catalyst carrier |
| US5155242A (en) | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA2089510C (en) | 1992-02-27 | 1998-09-01 | Shinichi Nagase | Silver catalyst for production of ethylene oxide and method for production of the catalyst |
| CA2078480A1 (en) | 1992-04-20 | 1993-10-21 | Bennie Albert Horrell Jr. | Improved process for ethylene epoxidation |
| US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| DE4241942A1 (de) * | 1992-12-11 | 1994-06-16 | Basf Ag | Verfahren zur Herstellung von 3,4-Epoxy-1-buten |
| US6184175B1 (en) | 1993-03-01 | 2001-02-06 | Scientic Design Company, Inc. | Process for preparing silver catalyst |
| EP0724479B1 (en) | 1993-08-23 | 2001-06-13 | Shell Internationale Researchmaatschappij B.V. | Ethylene oxide catalyst |
| US5380697A (en) | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5418202A (en) | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| WO1996004989A1 (en) | 1994-08-09 | 1996-02-22 | Scientific Design Company, Inc. | Process for preparing silver catalyst |
| US5504052A (en) | 1994-12-02 | 1996-04-02 | Scientific Design Company, Inc. | Silver catalyst preparation |
| EP0716884B2 (en) | 1994-12-15 | 2009-09-23 | Shell Internationale Researchmaatschappij B.V. | Process for preparing ethylene oxide catalysts |
| US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| US5801259A (en) | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5736483A (en) | 1996-10-25 | 1998-04-07 | Scientific Design Co., Inc. | Niobium or tantalum promoted silver catalyst |
| US5780656A (en) | 1997-04-14 | 1998-07-14 | Scientific Design Company, Inc. | Ethylene oxide catalyst and process |
| DE19723950A1 (de) * | 1997-06-06 | 1998-12-10 | Basf Ag | Verfahren zur Oxidation einer mindestens eine C-C-Doppelbindung aufweisenden organischen Verbindung |
| US5770746A (en) | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
| US5854167A (en) | 1997-09-02 | 1998-12-29 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| DE19803890A1 (de) | 1998-01-31 | 1999-08-05 | Erdoelchemie Gmbh | Silberhaltige Trägerkatalysatoren und Katalysator-Zwischenprodukte, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP4698835B2 (ja) | 1998-09-14 | 2011-06-08 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒特性改良のため触媒表面からイオン化可能種を除去する方法 |
| TR200100749T2 (tr) | 1998-09-14 | 2001-10-22 | Shell Internationale Research Maatschappij B.V. | Epoksitleme katalizörü taşıyıcı, bunun hazırlanması ve kullanılması |
| US6455713B1 (en) | 1998-09-14 | 2002-09-24 | Eastman Chemical Company | Reactivation of Cs-promoted, Ag catalysts for the selective epoxidation of butadiene to 3,4-epoxy-1-butene |
| WO2000015334A1 (en) | 1998-09-14 | 2000-03-23 | Shell Internationale Research Maatschappij B.V. | Process for preparing catalysts with improved catalytic properties |
| EP1002575B1 (en) | 1998-11-17 | 2005-03-30 | Nippon Shokubai Co., Ltd. | Catalyst carrier for use in production of ethylene oxide |
| RU2278730C2 (ru) | 2000-05-01 | 2006-06-27 | Сайентифик Дизайн Компани, Инк. | Катализатор для окисления этилена и способ получения оксида этилена |
| US6372925B1 (en) * | 2000-06-09 | 2002-04-16 | Shell Oil Company | Process for operating the epoxidation of ethylene |
| US6750173B2 (en) | 2002-04-08 | 2004-06-15 | Scientific Design Company, Inc. | Ethylene oxide catalyst |
| DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
-
2004
- 2004-04-01 US US10/816,480 patent/US7348444B2/en not_active Expired - Fee Related
- 2004-04-05 DE DE602004029247T patent/DE602004029247D1/de not_active Expired - Lifetime
- 2004-04-05 MX MXPA05010735 patent/MX261656B/es active IP Right Grant
- 2004-04-05 RU RU2005134228/04A patent/RU2345073C2/ru active
- 2004-04-05 IN IN4524DE2005 patent/IN246332B/en unknown
- 2004-04-05 WO PCT/US2004/010457 patent/WO2004092148A2/en not_active Ceased
- 2004-04-05 CA CA2525520A patent/CA2525520C/en not_active Expired - Fee Related
- 2004-04-05 JP JP2006509711A patent/JP5227513B2/ja not_active Expired - Fee Related
- 2004-04-05 KR KR1020057018966A patent/KR101107477B1/ko not_active Expired - Fee Related
- 2004-04-05 EP EP04759125.0A patent/EP1620414B2/en not_active Expired - Lifetime
- 2004-04-05 CN CNB2004800114702A patent/CN100482652C/zh not_active Expired - Fee Related
- 2004-04-07 TW TW093109624A patent/TWI374773B/zh not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1191983A (en) * | 1968-04-11 | 1970-05-13 | Sir Soc Italiana Resine Spa | Preparation of Ethylene Oxide |
| US4766105A (en) * | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
Non-Patent Citations (2)
| Title |
|---|
| Polymerization under high pressure.. Howard W.J.Am.Chem.Soc.,Vol.56 No.9. 1934 |
| Polymerization under high pressure.. Howard W.J.Am.Chem.Soc.,Vol.56 No.9. 1934 * |
Also Published As
| Publication number | Publication date |
|---|---|
| IN2005DE04524A (2) | 2009-10-02 |
| WO2004092148A2 (en) | 2004-10-28 |
| EP1620414B1 (en) | 2010-09-22 |
| EP1620414B2 (en) | 2013-08-14 |
| JP2006522155A (ja) | 2006-09-28 |
| DE602004029247D1 (de) | 2010-11-04 |
| CN1791586A (zh) | 2006-06-21 |
| IN246332B (2) | 2011-03-04 |
| CA2525520C (en) | 2012-03-13 |
| TW200427508A (en) | 2004-12-16 |
| RU2345073C2 (ru) | 2009-01-27 |
| MXPA05010735A (es) | 2006-05-25 |
| KR101107477B1 (ko) | 2012-01-19 |
| RU2005134228A (ru) | 2006-06-10 |
| CA2525520A1 (en) | 2004-10-28 |
| WO2004092148A3 (en) | 2005-03-24 |
| KR20060028672A (ko) | 2006-03-31 |
| MX261656B (es) | 2008-10-24 |
| US20040236124A1 (en) | 2004-11-25 |
| US7348444B2 (en) | 2008-03-25 |
| TWI374773B (en) | 2012-10-21 |
| JP5227513B2 (ja) | 2013-07-03 |
| EP1620414A2 (en) | 2006-02-01 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090429 Termination date: 20160405 |