CN1018624B - 结晶磷酸铝组合物的制备方法 - Google Patents

结晶磷酸铝组合物的制备方法

Info

Publication number: CN1018624B
Authority: CN; China
Prior art keywords: aluminum; water; masterbatch; reaction mixture; composition
Prior art date: 1987-08-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CN88107057A

Other languages

English (en)

Chinese (zh)

Other versions

CN1036376A (zh

Inventor

马克·E·戴维斯

马丽亚·德尔孔苏埃洛蒙特斯·迪科雷亚

胡安·M·加尔塞斯

卡洛斯·H·萨尔达里亚加

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-08-28

Filing date

1988-08-28

Publication date

1992-10-14

1988-06-15 Priority claimed from US07/207,850 external-priority patent/US5374411A/en

1988-08-28 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1989-10-18 Publication of CN1036376A publication Critical patent/CN1036376A/zh

1992-10-14 Publication of CN1018624B publication Critical patent/CN1018624B/zh

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 75
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 title claims abstract description 38
238000000034 method Methods 0.000 title claims abstract description 32
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 59
229910001868 water Inorganic materials 0.000 claims abstract description 44
239000011541 reaction mixture Substances 0.000 claims abstract description 35
239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 30
229910052782 aluminium Inorganic materials 0.000 claims abstract description 29
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 27
239000003795 chemical substances by application Substances 0.000 claims abstract description 27
229910052751 metal Inorganic materials 0.000 claims abstract description 25
239000002184 metal Substances 0.000 claims abstract description 25
239000013078 crystal Substances 0.000 claims abstract description 19
239000000126 substance Substances 0.000 claims abstract description 18
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 12
229910052710 silicon Inorganic materials 0.000 claims abstract description 12
239000010703 silicon Substances 0.000 claims abstract description 12
238000002441 X-ray diffraction Methods 0.000 claims abstract description 11
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 8
150000004706 metal oxides Chemical class 0.000 claims abstract description 8
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
239000011574 phosphorus Substances 0.000 claims abstract description 7
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 4
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 4
239000010941 cobalt Substances 0.000 claims abstract description 4
229910017052 cobalt Inorganic materials 0.000 claims abstract description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 4
239000011777 magnesium Substances 0.000 claims abstract description 4
229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
239000010936 titanium Substances 0.000 claims abstract description 4
229910052719 titanium Inorganic materials 0.000 claims abstract description 4
229910052725 zinc Inorganic materials 0.000 claims abstract description 4
239000011701 zinc Substances 0.000 claims abstract description 4
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 3
239000011135 tin Substances 0.000 claims abstract description 3
229910052718 tin Inorganic materials 0.000 claims abstract description 3
229910052726 zirconium Inorganic materials 0.000 claims abstract description 3
229910052593 corundum Inorganic materials 0.000 claims abstract 3
229910001845 yogo sapphire Inorganic materials 0.000 claims abstract 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 38
239000007787 solid Substances 0.000 claims description 29
239000000243 solution Substances 0.000 claims description 25
239000000463 material Substances 0.000 claims description 24
235000011007 phosphoric acid Nutrition 0.000 claims description 19
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 17
VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 16
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical group CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims description 11
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 10
-1 aluminum alkoxides Chemical class 0.000 claims description 9
239000008367 deionised water Substances 0.000 claims description 9
229910021641 deionized water Inorganic materials 0.000 claims description 9
238000006243 chemical reaction Methods 0.000 claims description 8
239000000377 silicon dioxide Substances 0.000 claims description 8
239000002253 acid Substances 0.000 claims description 6
UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 6
238000002156 mixing Methods 0.000 claims description 6
JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims description 5
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
229940043279 diisopropylamine Drugs 0.000 claims description 2
OOHAUGDGCWURIT-UHFFFAOYSA-N n,n-dipentylpentan-1-amine Chemical compound CCCCCN(CCCCC)CCCCC OOHAUGDGCWURIT-UHFFFAOYSA-N 0.000 claims description 2
239000003960 organic solvent Substances 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
235000012239 silicon dioxide Nutrition 0.000 claims description 2
VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims description 2
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 2
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 2
229910018072 Al 2 O 3 Inorganic materials 0.000 claims 3
XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical class O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 claims 1
239000000416 hydrocolloid Substances 0.000 claims 1
239000002243 precursor Substances 0.000 claims 1
239000012266 salt solution Substances 0.000 claims 1
239000002808 molecular sieve Substances 0.000 abstract description 14
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 14
239000011148 porous material Substances 0.000 abstract description 9
238000002360 preparation method Methods 0.000 abstract description 9
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 8
229910052802 copper Inorganic materials 0.000 abstract description 8
239000010949 copper Substances 0.000 abstract description 8
230000005855 radiation Effects 0.000 abstract description 8
238000001179 sorption measurement Methods 0.000 abstract description 6
150000002739 metals Chemical group 0.000 abstract description 5
229940009859 aluminum phosphate Drugs 0.000 description 27
229910021536 Zeolite Inorganic materials 0.000 description 23
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 23
239000010457 zeolite Substances 0.000 description 23
238000003756 stirring Methods 0.000 description 22
239000004411 aluminium Substances 0.000 description 20
230000015572 biosynthetic process Effects 0.000 description 14
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 14
239000004809 Teflon Substances 0.000 description 13
229920006362 Teflon® Polymers 0.000 description 13
239000002002 slurry Substances 0.000 description 13
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 13
150000001875 compounds Chemical class 0.000 description 11
239000000047 product Substances 0.000 description 9
238000000634 powder X-ray diffraction Methods 0.000 description 8
239000011734 sodium Substances 0.000 description 8
239000012153 distilled water Substances 0.000 description 7
229910001220 stainless steel Inorganic materials 0.000 description 7
239000010935 stainless steel Substances 0.000 description 7
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
238000007605 air drying Methods 0.000 description 5
229940001007 aluminium phosphate Drugs 0.000 description 5
150000002500 ions Chemical class 0.000 description 5
RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 4
238000006555 catalytic reaction Methods 0.000 description 4
238000003795 desorption Methods 0.000 description 4
238000001914 filtration Methods 0.000 description 4
239000002994 raw material Substances 0.000 description 4
239000000376 reactant Substances 0.000 description 4
238000011084 recovery Methods 0.000 description 4
LGXAANYJEHLUEM-UHFFFAOYSA-N 1,2,3-tri(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(C(C)C)=C1C(C)C LGXAANYJEHLUEM-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229910052786 argon Inorganic materials 0.000 description 3
239000000470 constituent Substances 0.000 description 3
239000000428 dust Substances 0.000 description 3
230000036571 hydration Effects 0.000 description 3
238000006703 hydration reaction Methods 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
239000012265 solid product Substances 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
239000000725 suspension Substances 0.000 description 3
229910017119 AlPO Inorganic materials 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
101100387348 Drosophila melanogaster DptA gene Proteins 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
230000000274 adsorptive effect Effects 0.000 description 2
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
238000004364 calculation method Methods 0.000 description 2
230000000536 complexating effect Effects 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
239000007788 liquid Substances 0.000 description 2
UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical class [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 2
235000011285 magnesium acetate Nutrition 0.000 description 2
239000012452 mother liquor Substances 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000007789 sealing Methods 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
238000003786 synthesis reaction Methods 0.000 description 2
238000005406 washing Methods 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
241000370738 Chlorion Species 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
208000035126 Facies Diseases 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
NLTSCOZQKALPGZ-UHFFFAOYSA-N acetic acid;dihydrate Chemical compound O.O.CC(O)=O NLTSCOZQKALPGZ-UHFFFAOYSA-N 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
230000001195 anabolic effect Effects 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
229910001680 bayerite Inorganic materials 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
JHECKPXUCKQCSH-UHFFFAOYSA-J calcium;disodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate;hydrate Chemical compound O.[Na+].[Na+].[Ca+2].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JHECKPXUCKQCSH-UHFFFAOYSA-J 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000003889 chemical engineering Methods 0.000 description 1
239000002734 clay mineral Substances 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
238000010908 decantation Methods 0.000 description 1
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Natural products CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
229960001484 edetic acid Drugs 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910001679 gibbsite Inorganic materials 0.000 description 1
230000005484 gravity Effects 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
238000001027 hydrothermal synthesis Methods 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910000765 intermetallic Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000011654 magnesium acetate Substances 0.000 description 1
229940069446 magnesium acetate Drugs 0.000 description 1
238000003760 magnetic stirring Methods 0.000 description 1
238000012423 maintenance Methods 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
239000007769 metal material Substances 0.000 description 1
229910052914 metal silicate Inorganic materials 0.000 description 1
229910052752 metalloid Inorganic materials 0.000 description 1
150000002738 metalloids Chemical class 0.000 description 1
239000011268 mixed slurry Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
238000013021 overheating Methods 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
239000003495 polar organic solvent Substances 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
238000005204 segregation Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229960001866 silicon dioxide Drugs 0.000 description 1
239000002210 silicon-based material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
230000002194 synthesizing effect Effects 0.000 description 1
229910052645 tectosilicate Inorganic materials 0.000 description 1
238000012360 testing method Methods 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
235000013904 zinc acetate Nutrition 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/04—Aluminophosphates [APO compounds]
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)

CN88107057A 1987-08-28 1988-08-28 结晶磷酸铝组合物的制备方法 Expired CN1018624B (zh)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
US9080187A	1987-08-28	1987-08-28
US090,801		1987-08-28
US07/207,850 US5374411A (en)	1987-08-28	1988-06-15	Crystalline aluminumphosphate compositions
US207,850		1988-06-15

Publications (2)

Publication Number	Publication Date
CN1036376A CN1036376A (zh)	1989-10-18
CN1018624B true CN1018624B (zh)	1992-10-14

Family

ID=26782637

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN88107057A Expired CN1018624B (zh)	1987-08-28	1988-08-28	结晶磷酸铝组合物的制备方法

Country Status (8)

Country	Link
EP (1)	EP0333816A4 (fr)
JP (1)	JPH03505720A (fr)
CN (1)	CN1018624B (fr)
FI (1)	FI89037C (fr)
HU (1)	HU208511B (fr)
IL (1)	IL87606A (fr)
RO (1)	RO104858B1 (fr)
WO (1)	WO1989001912A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU2924089A (en) *	1987-12-21	1989-07-19	Mobil Oil Corporation	Crystalline molecular sieve
NZ228425A (en) *	1988-04-08	1990-11-27	Mobil Oil Corp	Method of synthesising a crystalline molecular sieve comprising oxides of aluminium and phosphorus, and other elements
WO1989009748A1 (fr) *	1988-04-08	1989-10-19	Mobil Oil Corporation	Synthese d'un tamis moleculaire cristallin
US5013535A (en) *	1989-04-20	1991-05-07	Uop	Stabilized aluminophosphate compositions and process for preparing same
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EP0464249B1 (fr) *	1990-07-05	1994-01-05	VAW Aluminium AG	Procédé pour préparer des tamis moléculaires cristallins à grands pores
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1988
- 1988-08-24 JP JP63507736A patent/JPH03505720A/ja active Granted
- 1988-08-24 HU HU885511A patent/HU208511B/hu not_active IP Right Cessation
- 1988-08-24 WO PCT/US1988/002910 patent/WO1989001912A1/fr not_active Ceased
- 1988-08-24 EP EP19880908535 patent/EP0333816A4/fr not_active Withdrawn
- 1988-08-28 CN CN88107057A patent/CN1018624B/zh not_active Expired
- 1988-08-30 IL IL87606A patent/IL87606A/xx unknown
1989
- 1989-04-25 FI FI891964A patent/FI89037C/fi not_active IP Right Cessation
- 1989-04-27 RO RO139461A patent/RO104858B1/ro unknown

Also Published As

Publication number	Publication date
FI89037C (fi)	1993-08-10
FI89037B (fi)	1993-04-30
HU885511D0 (en)	1990-02-28
IL87606A (en)	1992-06-21
HU208511B (en)	1993-11-29
IL87606A0 (en)	1989-01-31
WO1989001912A1 (fr)	1989-03-09
RO104858B1 (en)	1993-04-01
JPH0574523B2 (fr)	1993-10-18
EP0333816A4 (fr)	1989-12-13
CN1036376A (zh)	1989-10-18
FI891964A0 (fi)	1989-04-25
EP0333816A1 (fr)	1989-09-27
JPH03505720A (ja)	1991-12-12
HUT52003A (en)	1990-06-28
FI891964A7 (fi)	1989-04-25

Legal Events

Date	Code	Title
1989-10-18	C06	Publication
1989-10-18	PB01	Publication
1990-11-21	C10	Entry into substantive examination
1990-11-21	SE01	Entry into force of request for substantive examination
1992-10-14	C13	Decision
1992-10-14	GR02	Examined patent application
1993-07-21	C14	Grant of patent or utility model
1993-07-21	GR01	Patent grant
1995-10-18	C19	Lapse of patent right due to non-payment of the annual fee
1995-10-18	CF01	Termination of patent right due to non-payment of annual fee

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