RO104858B1 - Crystalline-alluminophosthatic compositions and producing process - Google Patents

Crystalline-alluminophosthatic compositions and producing process Download PDF

Info

Publication number: RO104858B1
Authority: RO; Romania
Prior art keywords: compositions; mixture; water; oxide; aluminum
Prior art date: 1987-08-28

Application number

RO139461A

Other languages

English (en)

Romanian (ro)

Inventor

Mark E Garces Juan M Davis

Carlos H Saldarriaga

Del Consuelo Montes De C Maria

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-08-28

Filing date

1989-04-27

Publication date

1993-04-01

1988-06-15 Priority claimed from US07/207,850 external-priority patent/US5374411A/en

1989-04-27 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1993-04-01 Publication of RO104858B1 publication Critical patent/RO104858B1/ro

Links

239000000203 mixture Substances 0.000 title claims abstract description 137
238000000034 method Methods 0.000 title claims description 19
230000008569 process Effects 0.000 title claims description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 64
229910001868 water Inorganic materials 0.000 claims abstract description 48
239000003795 chemical substances by application Substances 0.000 claims abstract description 34
239000002243 precursor Substances 0.000 claims abstract description 34
239000011541 reaction mixture Substances 0.000 claims abstract description 34
229910052782 aluminium Inorganic materials 0.000 claims abstract description 28
229910052751 metal Inorganic materials 0.000 claims abstract description 28
239000002184 metal Substances 0.000 claims abstract description 27
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 27
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 25
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 20
239000011574 phosphorus Substances 0.000 claims abstract description 20
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
229910052710 silicon Inorganic materials 0.000 claims abstract description 11
230000005855 radiation Effects 0.000 claims abstract description 10
238000001179 sorption measurement Methods 0.000 claims abstract description 10
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
229910052802 copper Inorganic materials 0.000 claims abstract description 9
239000010949 copper Substances 0.000 claims abstract description 9
239000010703 silicon Substances 0.000 claims abstract description 9
238000006467 substitution reaction Methods 0.000 claims abstract description 5
229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
229910052719 titanium Inorganic materials 0.000 claims abstract description 4
229910052725 zinc Inorganic materials 0.000 claims abstract description 4
229910052726 zirconium Inorganic materials 0.000 claims abstract description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 32
239000000243 solution Substances 0.000 claims description 23
VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 claims description 20
238000010438 heat treatment Methods 0.000 claims description 16
235000011007 phosphoric acid Nutrition 0.000 claims description 16
230000015572 biosynthetic process Effects 0.000 claims description 12
238000002156 mixing Methods 0.000 claims description 12
230000008685 targeting Effects 0.000 claims description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
239000011159 matrix material Substances 0.000 claims description 11
238000003786 synthesis reaction Methods 0.000 claims description 10
239000008367 deionised water Substances 0.000 claims description 9
229910021641 deionized water Inorganic materials 0.000 claims description 9
UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 claims description 9
LGXAANYJEHLUEM-UHFFFAOYSA-N 1,2,3-tri(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC(C(C)C)=C1C(C)C LGXAANYJEHLUEM-UHFFFAOYSA-N 0.000 claims description 7
239000000470 constituent Substances 0.000 claims description 7
229910052799 carbon Inorganic materials 0.000 claims description 6
JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 claims description 5
239000000969 carrier Substances 0.000 claims description 4
150000002605 large molecules Chemical class 0.000 claims description 4
229920002521 macromolecule Polymers 0.000 claims description 4
230000003647 oxidation Effects 0.000 claims description 4
238000007254 oxidation reaction Methods 0.000 claims description 4
229940043279 diisopropylamine Drugs 0.000 claims description 3
OOHAUGDGCWURIT-UHFFFAOYSA-N n,n-dipentylpentan-1-amine Chemical compound CCCCCN(CCCCC)CCCCC OOHAUGDGCWURIT-UHFFFAOYSA-N 0.000 claims description 3
230000002441 reversible effect Effects 0.000 claims description 3
230000005070 ripening Effects 0.000 claims description 3
JVOPCCBEQRRLOJ-UHFFFAOYSA-M tetrapentylazanium;hydroxide Chemical compound [OH-].CCCCC[N+](CCCCC)(CCCCC)CCCCC JVOPCCBEQRRLOJ-UHFFFAOYSA-M 0.000 claims description 3
238000010521 absorption reaction Methods 0.000 claims description 2
150000004703 alkoxides Chemical class 0.000 claims description 2
239000008119 colloidal silica Substances 0.000 claims description 2
239000003960 organic solvent Substances 0.000 claims description 2
150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
229910001392 phosphorus oxide Inorganic materials 0.000 claims description 2
LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical class [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 claims description 2
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims 1
230000002378 acidificating effect Effects 0.000 claims 1
239000012670 alkaline solution Substances 0.000 claims 1
150000004677 hydrates Chemical class 0.000 claims 1
239000010413 mother solution Substances 0.000 claims 1
239000011863 silicon-based powder Substances 0.000 claims 1
238000002441 X-ray diffraction Methods 0.000 abstract description 10
239000002808 molecular sieve Substances 0.000 abstract description 10
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract description 9
238000002360 preparation method Methods 0.000 abstract description 5
239000000126 substance Substances 0.000 abstract description 5
239000011701 zinc Substances 0.000 abstract description 5
150000002739 metals Chemical class 0.000 abstract description 4
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 3
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
239000010941 cobalt Substances 0.000 abstract description 3
229910017052 cobalt Inorganic materials 0.000 abstract description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 3
239000013078 crystal Substances 0.000 abstract description 3
239000011777 magnesium Substances 0.000 abstract description 3
239000010936 titanium Substances 0.000 abstract description 3
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 2
229910052718 tin Inorganic materials 0.000 abstract description 2
239000011135 tin Substances 0.000 abstract description 2
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 abstract 3
229940009859 aluminum phosphate Drugs 0.000 abstract 3
229910052593 corundum Inorganic materials 0.000 abstract 2
229910001845 yogo sapphire Inorganic materials 0.000 abstract 2
238000003756 stirring Methods 0.000 description 30
239000010457 zeolite Substances 0.000 description 23
239000007787 solid Substances 0.000 description 22
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 15
229910021536 Zeolite Inorganic materials 0.000 description 13
WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 13
239000000047 product Substances 0.000 description 13
239000011148 porous material Substances 0.000 description 12
229910052760 oxygen Inorganic materials 0.000 description 11
239000004809 Teflon Substances 0.000 description 10
229920006362 Teflon® Polymers 0.000 description 10
ARHKYYXTHCPOLC-UHFFFAOYSA-N dialuminum;oxygen(2-);dihydrate Chemical compound O.O.[O-2].[O-2].[O-2].[Al+3].[Al+3] ARHKYYXTHCPOLC-UHFFFAOYSA-N 0.000 description 10
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
238000007792 addition Methods 0.000 description 8
238000012360 testing method Methods 0.000 description 8
239000012153 distilled water Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
229910044991 metal oxide Inorganic materials 0.000 description 7
150000004706 metal oxides Chemical class 0.000 description 7
229910001220 stainless steel Inorganic materials 0.000 description 7
239000010935 stainless steel Substances 0.000 description 7
239000000725 suspension Substances 0.000 description 7
-1 aluminum phosphate argon Chemical compound 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
239000000843 powder Substances 0.000 description 6
238000000634 powder X-ray diffraction Methods 0.000 description 6
239000011734 sodium Substances 0.000 description 6
239000000463 material Substances 0.000 description 5
239000002002 slurry Substances 0.000 description 5
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000377 silicon dioxide Substances 0.000 description 4
239000012265 solid product Substances 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
239000003463 adsorbent Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
230000003197 catalytic effect Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
238000005755 formation reaction Methods 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
230000035800 maturation Effects 0.000 description 3
150000002736 metal compounds Chemical class 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
239000006228 supernatant Substances 0.000 description 3
229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
229910017119 AlPO Inorganic materials 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000002178 crystalline material Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000011049 filling Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
238000000265 homogenisation Methods 0.000 description 2
238000005259 measurement Methods 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
239000010452 phosphate Substances 0.000 description 2
239000002798 polar solvent Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
238000011282 treatment Methods 0.000 description 2
WYMDDFRYORANCC-UHFFFAOYSA-N 2-[[3-[bis(carboxymethyl)amino]-2-hydroxypropyl]-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)CN(CC(O)=O)CC(O)=O WYMDDFRYORANCC-UHFFFAOYSA-N 0.000 description 1
WONYMNWUJVKVII-UHFFFAOYSA-N 3,5-diiodothyropropionic acid Chemical compound IC1=CC(CCC(=O)O)=CC(I)=C1OC1=CC=C(O)C=C1 WONYMNWUJVKVII-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
229910004283 SiO 4 Inorganic materials 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
NLTSCOZQKALPGZ-UHFFFAOYSA-N acetic acid;dihydrate Chemical class O.O.CC(O)=O NLTSCOZQKALPGZ-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
125000005210 alkyl ammonium group Chemical group 0.000 description 1
XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical class O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
229910001680 bayerite Inorganic materials 0.000 description 1
229910001593 boehmite Inorganic materials 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
230000008859 change Effects 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
239000002734 clay mineral Substances 0.000 description 1
ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 1
238000003795 desorption Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
150000004683 dihydrates Chemical class 0.000 description 1
231100000741 direct peptid reactivity assay Toxicity 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012013 faujasite Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
230000005484 gravity Effects 0.000 description 1
239000010440 gypsum Substances 0.000 description 1
229910052602 gypsum Inorganic materials 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
238000001027 hydrothermal synthesis Methods 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000011068 loading method Methods 0.000 description 1
UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
239000011654 magnesium acetate Substances 0.000 description 1
229940069446 magnesium acetate Drugs 0.000 description 1
235000011285 magnesium acetate Nutrition 0.000 description 1
XKPKPGCRSHFTKM-UHFFFAOYSA-L magnesium;diacetate;tetrahydrate Chemical compound O.O.O.O.[Mg+2].CC([O-])=O.CC([O-])=O XKPKPGCRSHFTKM-UHFFFAOYSA-L 0.000 description 1
239000012452 mother liquor Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
239000002245 particle Substances 0.000 description 1
RVZRBWKZFJCCIB-UHFFFAOYSA-N perfluorotributylamine Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)N(C(F)(F)C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F RVZRBWKZFJCCIB-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000013049 sediment Substances 0.000 description 1
238000004062 sedimentation Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000010802 sludge Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
125000006850 spacer group Chemical group 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229910052645 tectosilicate Inorganic materials 0.000 description 1
DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
YZYKBQUWMPUVEN-UHFFFAOYSA-N zafuleptine Chemical compound OC(=O)CCCCCC(C(C)C)NCC1=CC=C(F)C=C1 YZYKBQUWMPUVEN-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/04—Aluminophosphates [APO compounds]
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
- C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)

RO139461A 1987-08-28 1989-04-27 Crystalline-alluminophosthatic compositions and producing process RO104858B1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US9080187A	1987-08-28	1987-08-28
US07/207,850 US5374411A (en)	1987-08-28	1988-06-15	Crystalline aluminumphosphate compositions

Publications (1)

Publication Number	Publication Date
RO104858B1 true RO104858B1 (en)	1993-04-01

Family

ID=26782637

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
RO139461A RO104858B1 (en)	1987-08-28	1989-04-27	Crystalline-alluminophosthatic compositions and producing process

Country Status (8)

Country	Link
EP (1)	EP0333816A4 (fr)
JP (1)	JPH03505720A (fr)
CN (1)	CN1018624B (fr)
FI (1)	FI89037C (fr)
HU (1)	HU208511B (fr)
IL (1)	IL87606A (fr)
RO (1)	RO104858B1 (fr)
WO (1)	WO1989001912A1 (fr)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU2924089A (en) *	1987-12-21	1989-07-19	Mobil Oil Corporation	Crystalline molecular sieve
NZ228425A (en) *	1988-04-08	1990-11-27	Mobil Oil Corp	Method of synthesising a crystalline molecular sieve comprising oxides of aluminium and phosphorus, and other elements
WO1989009748A1 (fr) *	1988-04-08	1989-10-19	Mobil Oil Corporation	Synthese d'un tamis moleculaire cristallin
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1988
- 1988-08-24 JP JP63507736A patent/JPH03505720A/ja active Granted
- 1988-08-24 HU HU885511A patent/HU208511B/hu not_active IP Right Cessation
- 1988-08-24 WO PCT/US1988/002910 patent/WO1989001912A1/fr not_active Ceased
- 1988-08-24 EP EP19880908535 patent/EP0333816A4/fr not_active Withdrawn
- 1988-08-28 CN CN88107057A patent/CN1018624B/zh not_active Expired
- 1988-08-30 IL IL87606A patent/IL87606A/xx unknown
1989
- 1989-04-25 FI FI891964A patent/FI89037C/fi not_active IP Right Cessation
- 1989-04-27 RO RO139461A patent/RO104858B1/ro unknown

Also Published As

Publication number	Publication date
CN1018624B (zh)	1992-10-14
FI89037C (fi)	1993-08-10
FI89037B (fi)	1993-04-30
HU885511D0 (en)	1990-02-28
IL87606A (en)	1992-06-21
HU208511B (en)	1993-11-29
IL87606A0 (en)	1989-01-31
WO1989001912A1 (fr)	1989-03-09
JPH0574523B2 (fr)	1993-10-18
EP0333816A4 (fr)	1989-12-13
CN1036376A (zh)	1989-10-18
FI891964A0 (fi)	1989-04-25
EP0333816A1 (fr)	1989-09-27
JPH03505720A (ja)	1991-12-12
HUT52003A (en)	1990-06-28
FI891964A7 (fi)	1989-04-25

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