CN1023364C - 固态金属硫电池 - Google Patents

固态金属硫电池 Download PDF

Info

Publication number: CN1023364C
Authority: CN; China
Prior art keywords: battery; solid; anode; sulfur; cathode
Prior art date: 1989-10-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CN90109212A

Other languages

English (en)

Chinese (zh)

Other versions

CN1053324A (zh

Inventor

斯蒂芬·J·维斯科

刘美玲

卢特加德·C·德容格

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

CALIFORNIA SENATE

Original Assignee

CALIFORNIA SENATE

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-10-13

Filing date

1990-10-13

Publication date

1993-12-29

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23669134&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1023364(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-10-13 Application filed by CALIFORNIA SENATE filed Critical CALIFORNIA SENATE

1991-07-24 Publication of CN1053324A publication Critical patent/CN1053324A/zh

1993-12-29 Application granted granted Critical

1993-12-29 Publication of CN1023364C publication Critical patent/CN1023364C/zh

2005-10-13 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000007787 solid Substances 0.000 title claims abstract description 37
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 37
229910052751 metal Inorganic materials 0.000 title claims description 28
239000002184 metal Substances 0.000 title claims description 28
229910052717 sulfur Inorganic materials 0.000 title claims 13
239000011593 sulfur Substances 0.000 title claims 13
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 23
229910052744 lithium Inorganic materials 0.000 claims abstract description 23
229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 22
239000003792 electrolyte Substances 0.000 claims abstract description 21
239000011734 sodium Substances 0.000 claims abstract description 21
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 18
229910052708 sodium Inorganic materials 0.000 claims abstract description 18
MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 claims abstract description 4
125000001931 aliphatic group Chemical group 0.000 claims description 25
125000001741 organic sulfur group Chemical group 0.000 claims description 19
229920000642 polymer Polymers 0.000 claims description 19
150000003839 salts Chemical class 0.000 claims description 19
125000003118 aryl group Chemical group 0.000 claims description 16
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
229910052760 oxygen Inorganic materials 0.000 claims description 12
239000001301 oxygen Substances 0.000 claims description 12
229910021645 metal ion Inorganic materials 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
229920000570 polyether Polymers 0.000 claims description 8
125000001153 fluoro group Chemical group F* 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
239000007774 positive electrode material Substances 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 5
239000002245 particle Substances 0.000 claims description 5
229920002627 poly(phosphazenes) Polymers 0.000 claims description 4
239000005518 polymer electrolyte Substances 0.000 claims description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
150000002500 ions Chemical class 0.000 claims description 3
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
150000001342 alkaline earth metals Chemical class 0.000 claims description 2
229920000620 organic polymer Polymers 0.000 claims 6
125000004432 carbon atom Chemical group C* 0.000 claims 4
230000037427 ion transport Effects 0.000 claims 3
229920006295 polythiol Polymers 0.000 claims 2
125000001424 substituent group Chemical group 0.000 claims 2
229910052783 alkali metal Inorganic materials 0.000 claims 1
150000001340 alkali metals Chemical class 0.000 claims 1
-1 polyimines Polymers 0.000 claims 1
238000006467 substitution reaction Methods 0.000 claims 1
239000006229 carbon black Substances 0.000 abstract description 2
229920000867 polyelectrolyte Polymers 0.000 abstract 2
230000007613 environmental effect Effects 0.000 abstract 1
230000008018 melting Effects 0.000 abstract 1
238000002844 melting Methods 0.000 abstract 1
238000006116 polymerization reaction Methods 0.000 description 16
239000000463 material Substances 0.000 description 11
239000005864 Sulphur Substances 0.000 description 10
MAHNFPMIPQKPPI-UHFFFAOYSA-N disulfur Chemical compound S=S MAHNFPMIPQKPPI-UHFFFAOYSA-N 0.000 description 8
230000004087 circulation Effects 0.000 description 7
238000007600 charging Methods 0.000 description 6
239000010408 film Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 5
238000000034 method Methods 0.000 description 5
230000008569 process Effects 0.000 description 5
230000032258 transport Effects 0.000 description 5
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
239000004721 Polyphenylene oxide Substances 0.000 description 4
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
150000002898 organic sulfur compounds Chemical class 0.000 description 4
229910052698 phosphorus Inorganic materials 0.000 description 4
239000011574 phosphorus Substances 0.000 description 4
229910052710 silicon Inorganic materials 0.000 description 4
239000010703 silicon Substances 0.000 description 4
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
230000008901 benefit Effects 0.000 description 3
230000002829 reductive effect Effects 0.000 description 3
239000007784 solid electrolyte Substances 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
150000001721 carbon Chemical group 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000002131 composite material Substances 0.000 description 2
239000004020 conductor Substances 0.000 description 2
238000011161 development Methods 0.000 description 2
238000007599 discharging Methods 0.000 description 2
229910052731 fluorine Inorganic materials 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
239000000178 monomer Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000036647 reaction Effects 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
238000012360 testing method Methods 0.000 description 2
BIGYLAKFCGVRAN-UHFFFAOYSA-N 1,3,4-thiadiazolidine-2,5-dithione Chemical class S=C1NNC(=S)S1 BIGYLAKFCGVRAN-UHFFFAOYSA-N 0.000 description 1
229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
229910000528 Na alloy Inorganic materials 0.000 description 1
229910002640 NiOOH Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
230000008859 change Effects 0.000 description 1
239000012611 container material Substances 0.000 description 1
238000012937 correction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
239000000539 dimer Substances 0.000 description 1
239000011263 electroactive material Substances 0.000 description 1
239000007772 electrode material Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
150000002466 imines Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
230000002687 intercalation Effects 0.000 description 1
238000009830 intercalation Methods 0.000 description 1
238000011835 investigation Methods 0.000 description 1
238000009533 lab test Methods 0.000 description 1
239000008141 laxative Substances 0.000 description 1
230000002475 laxative effect Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011244 liquid electrolyte Substances 0.000 description 1
239000011344 liquid material Substances 0.000 description 1
MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
150000002891 organic anions Chemical class 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920000233 poly(alkylene oxides) Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000005077 polysulfide Substances 0.000 description 1
229920001021 polysulfide Polymers 0.000 description 1
150000008117 polysulfides Polymers 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000007717 redox polymerization reaction Methods 0.000 description 1
239000012925 reference material Substances 0.000 description 1
238000011160 research Methods 0.000 description 1
238000013341 scale-up Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000000935 solvent evaporation Methods 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
230000009897 systematic effect Effects 0.000 description 1
239000010409 thin film Substances 0.000 description 1
238000012876 topography Methods 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1

Images

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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
- H01M10/3918—Sodium-sulfur cells characterised by the electrolyte
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01M10/052—Li-accumulators
- H—ELECTRICITY
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- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
- H—ELECTRICITY
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- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
- H—ELECTRICITY
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries

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Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Engineering & Computer Science (AREA)
Manufacturing & Machinery (AREA)
Composite Materials (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Physics & Mathematics (AREA)
Condensed Matter Physics & Semiconductors (AREA)
Dispersion Chemistry (AREA)
General Physics & Mathematics (AREA)
Secondary Cells (AREA)
Battery Electrode And Active Subsutance (AREA)
Hybrid Electric Vehicles (AREA)
Control Of Transmission Device (AREA)
Electric Propulsion And Braking For Vehicles (AREA)

CN90109212A 1989-10-13 1990-10-13 固态金属硫电池 Expired - Fee Related CN1023364C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US42109189A	1989-10-13	1989-10-13
US421,091		1989-10-13

Publications (2)

Publication Number	Publication Date
CN1053324A CN1053324A (zh)	1991-07-24
CN1023364C true CN1023364C (zh)	1993-12-29

Family

ID=23669134

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN90109212A Expired - Fee Related CN1023364C (zh)	1989-10-13	1990-10-13	固态金属硫电池

Country Status (9)

Country	Link
EP (1)	EP0495895A4 (fr)
JP (1)	JP3102880B2 (fr)
KR (1)	KR0137006B1 (fr)
CN (1)	CN1023364C (fr)
AU (1)	AU642676B2 (fr)
BR (1)	BR9007750A (fr)
CA (1)	CA2053887C (fr)
RU (1)	RU2099821C1 (fr)
WO (1)	WO1991006132A1 (fr)

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Publication number	Priority date	Publication date	Assignee	Title
FR2711843B1 (fr) *	1993-10-21	1995-12-01	Alsthom Cge Alcatel	Matériau cathodique pour générateur électrochimique.
KR100486926B1 (ko)	2000-02-09	2005-05-03	히다치 막셀 가부시키가이샤	폴리황화카본, 그 제조방법 및 그것을 사용한 비수 전해질전지
US20050130043A1 (en) *	2003-07-29	2005-06-16	Yuan Gao	Lithium metal dispersion in electrodes
GB0713898D0 (en) *	2007-07-17	2007-08-29	Nexeon Ltd	A method of fabricating structured particles composed of silcon or a silicon-based material and their use in lithium rechargeable batteries
JP2014523094A (ja) *	2011-07-11	2014-09-08	ビーエーエスエフソシエタス・ヨーロピア	金属硫化物を含む電極材料
WO2013155038A1 (fr) *	2012-04-13	2013-10-17	Arkema Inc.	Batterie à base d'espèces organosulfurées
KR20180074701A (ko) *	2015-11-09	2018-07-03	로베르트 보쉬 게엠베하	전고체 리튬 재충전 전지
SG10202006657SA (en) *	2016-12-02	2020-08-28	Arkema Inc	Battery based on organosulfur species
WO2020152119A1 (fr)	2019-01-25	2020-07-30	Shell Internationale Research Maatschappij B.V.	Dispositif de stockage d'énergie électrique
JP2023522761A (ja) *	2020-04-27	2023-05-31	ハイドロ－ケベック	固体電気化学セル、その調製方法およびその使用

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8329906D0 (en) *	1983-11-09	1983-12-14	Friend R H	Composites
US4833048A (en) *	1988-03-31	1989-05-23	The United States Of America As Represented By The United States Department Of Energy	Metal-sulfur type cell having improved positive electrode
CA1341507C (fr) *	1989-09-01	2006-06-13	Michel Gauthier	Generateur a l'etat solide fonctionnant par polymerisation redox

1990
- 1990-10-09 WO PCT/US1990/005638 patent/WO1991006132A1/fr not_active Ceased
- 1990-10-09 AU AU66110/90A patent/AU642676B2/en not_active Ceased
- 1990-10-09 BR BR909007750A patent/BR9007750A/pt not_active IP Right Cessation
- 1990-10-09 EP EP19900915940 patent/EP0495895A4/en not_active Withdrawn
- 1990-10-09 CA CA002053887A patent/CA2053887C/fr not_active Expired - Fee Related
- 1990-10-09 RU SU5011317/07A patent/RU2099821C1/ru not_active IP Right Cessation
- 1990-10-09 JP JP02514987A patent/JP3102880B2/ja not_active Expired - Fee Related
- 1990-10-13 CN CN90109212A patent/CN1023364C/zh not_active Expired - Fee Related
1992
- 1992-04-13 KR KR1019920700853A patent/KR0137006B1/ko not_active Expired - Fee Related

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Publication number	Publication date
JPH05501937A (ja)	1993-04-08
JP3102880B2 (ja)	2000-10-23
AU642676B2 (en)	1993-10-28
EP0495895A1 (fr)	1992-07-29
KR0137006B1 (ko)	1998-06-15
CA2053887A1 (fr)	1991-04-14
EP0495895A4 (en)	1993-02-03
WO1991006132A1 (fr)	1991-05-02
RU2099821C1 (ru)	1997-12-20
BR9007750A (pt)	1992-09-01
CA2053887C (fr)	2001-12-11
AU6611090A (en)	1991-05-16
CN1053324A (zh)	1991-07-24

Legal Events

Date	Code	Title
1991-07-24	C06	Publication
1991-07-24	PB01	Publication
1993-01-20	C10	Entry into substantive examination
1993-01-20	SE01	Entry into force of request for substantive examination
1993-12-29	C14	Grant of patent or utility model
1993-12-29	GR01	Patent grant
2002-04-24	C15	Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
2002-04-24	OR01	Other related matters
2004-12-08	C19	Lapse of patent right due to non-payment of the annual fee
2004-12-08	CF01	Termination of patent right due to non-payment of annual fee

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