CN102485196A - Hair dye - Google Patents

Abstract

In the past, the hair dyes use the silver salts such as silver nitrate or silver sulfate. The hair dyes are mostly the monotonous brown-series colors, and can not be used for wide range of hair dying. In order to solve the above mentioned problem, in the invention, the water-solubility can be mixed in the silver nitrate or the silver sulfate, thereby the hair dyes with color in wide range can be achieved. By using the organic acid as the pH adjusting agent, the hair dying effect can be improved, and at the same time, the damage on hairs can be reduced, and the dyed hairs have good touch feelings. The invention provides a hair dye, which is characterized in that the hair dye contains the silver nitrate or the silver sulfate, and the water-solubility; and the hair dye also contains the organic acid serving as the pH adjusting agent.

Description

Hair dye

Technical field

The present invention relates to a kind ofly has in the hair dye of silver nitrate or silver sulfate the further painted hair dye (dying woolen cloth) that can carry out extensive tone of fusion water solublity iron salt in fusion.

Background technology

As the main method of hair dyeing, the method for using acid stain, the method for using oxidation dyes such as p-phenylenediamine (PPD) were arranged in the past.

Use the method for acid stain, owing under acidity, have hair dyed, therefore can not damage hair, need not to worry chafe in addition and carry out skin anaphylactic test ground and have hair dyed.But its shortcoming is to lack the hair dyeing fastness, can not dyes bright color.

Further, use the method for oxidation dye, the hair dyeing fastness is good, in addition, also can dye bright color, still, the allergy of generation or possibility of skin irritation is arranged, and considers existing problems from the viewpoint of safety.In addition, exist owing under alkaline state, have hair dyed and the problem of easy damaged hair.

Except these the hair dye that in the past used; The known hair dye (patent documentation 1-15) that has used silver salt such as silver nitrate or silver sulfate; For example; After in patent documentation 1,3,6,11,14 etc., disclosing a kind of aqueous solution and being coated on the hair, on hair, generate argent under daylight, the ultraviolet and carry out hair dyeing method through being exposed to silver salt such as silver nitrate.

The prior art document

Patent documentation

Patent documentation 1: special public clear 10-2593 communique

Patent documentation 2: the spy opens clear 48-18438 communique

Patent documentation 3: the spy opens clear 52-125638 communique

Patent documentation 4: the spy opens flat 4-187625 communique

Patent documentation 5: special fair 7-116016 communique

Patent documentation 6: the spy opens the 2002-348221 communique

Patent documentation 7: the spy opens the 2003-300840 communique

Patent documentation 8: the spy opens the 2004-99502 communique

Patent documentation 9: the spy opens the 2005-53889 communique

Patent documentation 10: the spy opens the 2005-60354 communique

Patent documentation 11: No. 3881688 communique of patent

Patent documentation 12: the spy opens the 2006-176486 communique

Patent documentation 13: the spy opens the 2008-69131 communique

Patent documentation 14: the spy opens the 2008-247842 communique

Patent documentation 15: the spy opens the 2010-13386 communique

Summary of the invention

These uses in the past the hair dye of silver salt such as silver nitrate or silver sulfate, mostly the hair dyeing tone is dull brown system, can not carry out the dyeing of extensive tone.As managing to dye the application of tone widely, in patent documentation 13 visible further in silver salt such as silver nitrate or silver sulfate fusion the application of acid stain, still, owing to use acid stain, therefore above-mentioned hair dyeing fastness is low.

In order to address the above problem; The present invention is fusion water solublity iron salt in silver nitrate or silver sulfate; Can access the hair dye of extensive tone, can improve hair dyeing effect through the organic acid that contains as the pH regulator agent simultaneously, damage and the sense of touch of hair after the hair dyeing of improving hair simultaneously are good.That is, the present invention relates to following content:

(1) a kind of hair dye is characterized in that, this hair dye contains silver nitrate and/or silver sulfate and water solublity iron salt.

(2) according to the hair dye described in (1), wherein, the water solublity iron salt is one or more the water solublity iron salt that is selected from ferrous sulfate, iron sulfate, ferrous chloride, the iron chloride.

(3) according to above-mentioned (1) or (2) described hair dye, it is characterized in that this hair dye contains the organic acid as the pH regulator agent.

(4) according to above-mentioned (3) described hair dye, wherein, organic acid is one or more the organic acid that is selected from malic acid, lactic acid, glycolic, tartaric acid, the benzoic acid.

The hair dye of the application of the invention is compared with the hair dye in the past that has used silver salt, becomes to carry out the more extensively hair dyeing of tone.In addition since with pH regulator to from neutrality to the acidic region, having hair dyed, therefore, have and improve hair dyeing effect, further can not damage the good effect of sense of touch of hair, the hair after having hair dyed.

The specific embodiment

In the present invention, as silver salt, can use silver nitrate or silver sulfate.These silver salt can use separately or and use.

The content of these silver salt is 0.01-10.0 quality %, is preferably 0.5-3.0 quality %.The situation that is less than 0.01 quality % can not be given full play to hair dyeing effect; In addition, even surpass 10.0 quality %, can not expect and the content corresponding effects.

In addition, contain the water solublity iron salt in the present invention.As the water solublity iron salt, special preferably sulfuric acid is ferrous, iron sulfate, ferrous chloride, iron chloride.In the present invention, contain one or more of these water solublity iron salt.Through containing these water solublity iron salt, can access the hair dye of extensive tone.For example, shown in the embodiment 2 of table 12,, can make the hair dyeing tone become dark brown colour system from reddish brown colour system through combination benzoic acid and ferrous sulfate.

The content of these water solublity iron salt has no particular limits, and considers from the deliquescent aspect of hair dyeing color harmony, is 0.01-2.0 quality %.

Contain organic acid in the present invention.As organic acid, special preferably apple acid, lactic acid, glycolic, tartaric acid, benzoic acid, citric acid.In the present invention, contain these organic acids one or more.

These organic acid content so long as make the whole pH of system reach the amount from neutrality to tart zone, just have no particular limits.Remain on from neutrality to acidity through pH, can improve hair dyeing effect, further have the good effect of sense of touch of hair that can not damage after hair, the hair dyeing system.

In the present invention, can regulate pH through its buffering effect also with salts such as above-mentioned organic acid sodium, potassium, ammoniums.

Further, can also be in the scope of not damaging effect of the present invention in hair dye of the present invention sulphur compounds such as fusion Reducing agent, sulikol, mercaptan, disulphide; Oxidation dye intermediate such as p-phenylenediamine (PPD); Dyestuff such as oxybenzene compound, tar colorant; Pigment such as iron oxide black replenish hair dyeing effect.During these compositions of fusion, can also process the multiple medicines prescription according to its colour developing mechanism.

The dosage form of hair dye of the present invention is aqueous mediums such as aqueous, emulsion form, paste, gel, aerosol foam shape, solid-state, powder disperse system, so long as can be coated on the form on the hair, does not just have special qualification with not damaging hair dyeing effect.

Except above-mentioned necessary composition, usually in the scope of not damaging effect of the present invention, can also be in hair dye of the present invention fusion be used for other composition of cosmetics or medicine etc.As this other composition, illustration goes out following compositions.

As the oiliness composition, can enumerate following material.Oils such as olive oil, Camellia oil, macadimia nut oil, Oleum Ricini, American Avocado Tree oil, Semen Tritici aestivi germ oil, safflower oil, oil ben, Oleum Gossypii semen, soybean oil, Oleum Camelliae, Oleum Helianthi, Radix Oenotherae erythrosepalae oil, Oleum Cocois, Petiolus Trachycarpi oil, palm-kernel oil, Adeps Bovis seu Bubali, horse fat, cupu oil, haze tallow; Wax classes such as Brazil wax, candelilla wax, Jojoba oil, Cera Flava, agnolin; Hydrocarbon such as liquid paraffin, paraffin, vaseline, ceresine, microwax, three decanes; Higher fatty acids such as lauric acid, tetradecanoic acid, hexadecanoic acid, stearic acid, isostearic acid, docosanoic acid, oleic acid, linoleic acid, linolenic acid; Higher alcohols such as hexadecanol, octadecanol, isooctadecane alcohol, 2-octyldodecanol, batilol, Simmondsia chinensis alcohol (ホ ホ バ ア Le コ one Le), lanolin alcohol, cholesterol, plant sterol; Esters such as isopropyl myristate, tetradecanoic acid 2-octyl group dodecyl ester, sad cetyl ester, 2 ethyl hexanoic acid cetyl ester, tetramethylolmethane four esters, malic acid two isooctadecane base esters, triethyl citrate, cholesteryl stearate, isostearic acid plant sterol ester (イ ソ ス テ ア リ ソ acid Off ィ ト ス テ ア リ Le), ethoxydiglycol behenate, ethoxydiglycol oleate, coco-nut oil fatty acid butanediol ester; Polysiloxanes such as methyl polysiloxane, methyl phenyl silicone, ring-type dimethicone, alkyl-modified polysiloxanes, amino modified polysiloxane, tridimensional network polysiloxanes, polysiloxane rubber.

As polyhydric alcohol, can enumerate following example.Glycerol, diglycerol, propylene glycol, dipropylene glycol, 1,3 butylene glycol, diethylene glycol, Polyethylene Glycol, ethoxydiglycol, pentanediol, heptandiol, ethohexadiol etc.

Can enumerate following example as saccharide.Sorbitol, mannitol, sucrose, lactose, xylitol, maltose alcohol, trehalose etc.

Can enumerate following example as macromolecular compound.Natural polymers such as guar gum 、 Fructus cydoniae oblongae (Network イ ソ ス Star one De), pectin, mannan, agar, chondrus ocellatus Holmes polysaccharide, xanthan gum, curdlan, gelatin, casein, collagen; Semi-synthetic macromolecules such as methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, alginate; Synthetic high polymers such as polyvinyl alcohol, polyvinyl pyrrolidone, CVP Carbopol ETD2050, sodium polyacrylate, POE-POP copolymer; Bentonite, Strese Hofmann's hectorite., sodium magnesium silicate etc. are inorganic to be thickening agent; Overlay films such as both sexes methacrylate copolymer, Poise C-80M, polychlorostyrene lupetidine, polyvinyl acetate, acrylate copolymer, polyvinyl acetate, NC Nitroncellulose, polyphosphazene polymer siloxanes, polyorganosiloxane resin formation property macromolecule.

Can enumerate following example as surfactant.Anionic surfactants such as higher fatty acids soap, alkylbenzenesulfonate, alkyl sulfate salt, POE alkyl ether sulfate, acyl group N-methylamino esilate, alkyl ether phosphate salt, N-acyl amino hydrochlorate, alpha-olefin sulfonate, POE alkyl ether carboxy acid salt; Mountain Yu base trimethyl ammonium chloride Dispute Resolution Mechanism of NAFTA Chapter Eleven salt ア Le キ Le ト リ メ チ Le ア Application モ ニ ウ system), cationic surfactant such as benzalkonium chloride dialkyl dimethyl ammonium chloride "-f " flag salt ジ ア Le キ Le ジ メ チ Le ア Application モ ニ ウ system); Alkyl-dimethyl glycine betanin (ア Le キ Le ジ メ チ Le ア ミ ノ jealous woman acid ベ タ イ Application), alkylamide propyl dimethylamino acetic acid betanin (ア Le キ Le ア ミ De プ ロ ピ Le ジ メ チ Le ア ミ ノ jealous woman acid ベ タ イ Application), 2-alkyl-N-carboxymethyl-amphoteric surfactantes such as N-hydroxyethyl imidazole betanin; Fatty acid glyceride, polyglyceryl fatty acid ester, POE fatty acid glyceride, sorbitan fatty acid ester, POE sorbitan fatty acid ester, POE Sorbitol fatty acid ester, POE Oleum Ricini solidify non-ionic surface active agents such as Oleum Ricini, POE alkyl ether, POEPOP alkyl ether, POE alkylamine fatty acid amide, PEG fatty acid ester, alkyl amine oxide.

Can enumerate following example as colorant and powder body, granule.Inorganic pigments such as iron oxide black, iron oxide red, iron oxide yellow, ultramarine, carbon black; Pigments such as pearlescent pigment, organic pigment, tar colorant, natural pigment; Inorganic particles such as Pulvis Talci, Kaolin, Muscovitum, Magnesiumaluminumsilicate, silicic acid anhydride, titanium oxide, mica titanium, zinc white, zeolite; Organic powders such as nylon powder, polyethylene powder, cellulose powder, silkworm silk powder; The granule that forms by nylon, polyethylene, cellulose, paraffin, fatty acid ester, natural materials.

Can enumerate following example as the animals and plants extract.Mucopolysaccharide such as hyaluronate sodium, sodium chondroitin sulfate; Animal extracts such as chitin first polysaccharide, collagen, elastin laminin, peptide; The Aloe extract; The Lignum cinnamomi camphorae extract; Herba Onopordi acanthii (オ オ ヒ レ ア ザ ミ); The Herba Urticae Cannabinae extract; The Flos Chrysanthemi extract; The Radix Glycyrrhizae extract; The seed extract of Semen Juglandis; The Radix Arnebiae (Radix Lithospermi) extract; The Betula platyphylla Suk. extract; The milfoil extract; The West Herba Menthae extract; The tea extract; The Radix Angelicae Sinensis extract; The Bulbus Allii extract; The Radix Dauci Sativae extract; The Radix Hamamelidis Mollis extract; Hinokitiol; The Folium Eriobotryae extract; The plumelet extract of Fagus sinensis Oliv. tree; The Fructus Luffae extract; The Flos Carthami extract; The willow herb extract; The Cortex Capparis Spinosae Radicis extract; Arillus Longan chrysanthemum extract; Semen Juglandis seed extract; The leaf of Fructus Persicae extract; The Eucalyptus extract; Rose water; Plant extracts such as thorn Asparagus toxiformis (Delile) Coll et Harv extract.

Can enumerate following example as the mineral extract.The extract of malachite, rhodochrosite, smithsonite stone, bloodstone etc.

Can enumerate following example as sterilization antiseptic.Benzoic acid, sodium benzoate, salicylic acid, sorbic acid, to Para Hydroxy Benzoic Acid ester (ethyl hydroxybenzoate, butyl hydroxybenzoate etc.), Amolden MCM 400, phenyl phenol, hexachlorophene, benzalkonium chloride, hibitane, ZPT, triclosan, methylchloroisothiazandnone, Methylisothiazolinone etc.

Can enumerate following example as antioxidant.Epicatechol gallate, sodium sulfite etc.Can enumerate following example as the antioxidation auxiliary agent.Phosphoric acid, citric acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, phytic acid, EDTA etc.

Can enumerate following example as metal-chelator.Edetate, etridronate, phosphoric acid, citric acid, succinic acid, phytic acid.

Can enumerate following example as UV absorbent.2-hydroxyl-4-methoxy benzophenone, 2-hydroxyl-4-methoxy benzophenone-benzophenone derivates such as 5-sulfonic acid; Para-amino benzoic acid derivants such as para-amino benzoic acid, p-(dimethylamino)-benzoic acid monooctyl ester; P-methoxycinnamic acid monooctyl ester, di-p-methoxy cinnamic acid list-methoxy cinnamic acid derivants such as 2 ethyl hexanoic acid glyceride; Salicyclic acid derivatives such as ethylhexyl salicylate; Urocanic acid etc.

Can enumerate following example as various medicaments.Brightening agents such as arbutin, kojic acid, vitamin c class; Hair growth promoting with medicament such as Swertia japonica extract, gamma oryzanol, capsicum tincture, benzyl nicotinate, estradiol, ethinylestradiol, pantothenic acid, sensitization plain 301; β-enoxolone, glycyrrhizin derivative, allantoin, EACA, zinc oxide, aluminum sulfate, tannin, lactic acid, Mentholum, adrenocortical hormone, hydryllin etc. prevent the pachylosis with medicament; Acne with medicament such as sulfur, salicylic acid, resorcinol, benzalkonium chloride, CF3; Aluminium chlorhydroxide,, antiperspirant such as aluminum chloride, zinc oxide; Vitamin A and derivant thereof; Pyridoxine hydrochloride, vitamin B6 cetylate, vitamin B6 dicaprylate, vitamin B2 and vitamin(e) B groups such as derivant, vitamin B12, VITAMIN B15 and derivant thereof thereof; Vitamin c class such as ascorbic acid, ascorbic acid phosphoric acid esters (salt), Vitamin C dipalmitate; Vitamin E classes such as alpha-tocopherol, β-vitamin E, γ-vitamin E, vitamin E acetate, vitamin E Nicotinate; The vitamin D class, vitaminss such as biotin, pantothenic acid, pantothenic acid ethamine; Aminoacid and their hydrochlorates such as glycine, alanine, valine, leucine, serine, threonine, phenylalanine, tyrosine, aspartic acid, agedoite, glutamine, taurine, arginine, histidine.

Hair dye of the present invention can prepare through these compositions of fusion and according to the method for routine, still, importantly, from each operation of putting into stirring, heating, cooling, filling of material composition, operation under the environment of lucifuge as far as possible.

Embodiment

Below enumerate embodiment (with reference to table 1-table 8) and comparative example (with reference to table 9-table 11), further the present invention is carried out bright specifically.In addition, the present invention is only for scheduling these embodiment.If do not specify that blended amount is represented with quality %.

Table 1

< embodiment 1>shampoo type hair dye (1)

(method for preparing)

Successively with malic acid, silver nitrate, iron sulfate, antiseptic, 1,3 butylene glycol, Simmondsia chinensis wax PEG-80 heating for dissolving in Purified Water.Through under agitation in this solution, adding the mixed liquor of squalane and spice, carry out emulsifying, obtain the hair dye of emulsion form.

Table 2

< embodiment 2>hair cream type hair dyes (1)

(method for preparing)

Successively with benzoic acid, silver nitrate, ferrous sulfate, antiseptic, 1,3 butylene glycol, glycerol heating for dissolving in Purified Water.Through the heating mixed liquor of annex solution paraffin body, dimethyl polysiloxane, thylhexoic acid cetyl ester, hexadecanol, tristerin, isostearic acid PEG-60 glyceride, spice in this solution under agitation; Carry out emulsifying, cooling, obtain the hair dye of paste.

Table 3

< embodiment 3>shampoo type hair dyes (2)

(method for preparing)

Successively with glycolic, silver sulfate, iron chloride, antiseptic, 1,3 butylene glycol, Simmondsia chinensis wax PEG-80 heating for dissolving in Purified Water.Through under agitation in this solution, adding the mixed liquor of Jojoba oil and spice, carry out emulsifying, obtain the hair dye of emulsion form.

Table 4

< embodiment 4>hair cream type hair dyes (2)

(method for preparing)

Successively with lactic acid, silver sulfate, iron sulfate, antiseptic, 1,3 butylene glycol, glycerol heating for dissolving in Purified Water.Through the heating mixed liquor of annex solution paraffin body, dimethyl polysiloxane, thylhexoic acid cetyl ester, hexadecanol, tristerin, isostearic acid PEG-60 glyceride, spice in this solution under agitation; Carry out emulsifying, cooling, obtain the hair dye of paste.

Table 5

< embodiment 5>gel-type hair dyes (1)

(method for preparing)

Carbomer and triethanolamine are dissolved in the part Purified Water.Malic acid, silver sulfate, ferrous sulfate, antiseptic are dissolved in the remaining Purified Water, in the carbomer before adding to and the aqueous solution of triethanolamine.(mixed liquor of copolymer, ethanol, spice of vinyl pyrrolidone/VA) obtains gelatinous hair dye through in this solution, adding.

Table 6

< embodiment 6>gel-type hair dyes (2)

(method for preparing)

Xanthan gum is dissolved in the part Purified Water.Malic acid, silver sulfate, iron sulfate, antiseptic are dissolved in the remaining Purified Water, and the aqueous solution of the xanthan gum before adding further adds spice, obtains gelatinous hair dye.

Table 7

< embodiment 7>gel-type hair dyes (3)

(method for preparing)

Xanthan gum is dissolved in the part Purified Water.Tartaric acid, silver sulfate, ferrous chloride, antiseptic are dissolved in the remaining Purified Water aqueous solution of the xanthan gum before adding.(mixed liquor of copolymer, ethanol, spice of vinyl pyrrolidone/VA) obtains gelatinous hair dye through in this solution, adding.

Table 8

< embodiment 8>gel-type hair dyes (4)

(method for preparing)

Xanthan gum is dissolved in the part Purified Water.Benzoic acid, silver sulfate, iron sulfate, antiseptic are dissolved in the remaining Purified Water aqueous solution of the xanthan gum before adding.(mixed liquor of copolymer, ethanol, spice of vinyl pyrrolidone/VA) obtains gelatinous hair dye through in this solution, adding.

Table 9

< comparative example 1>shampoo type hair dye

(method for preparing)

Successively with silver nitrate, antiseptic, 1,3 butylene glycol, Simmondsia chinensis wax PEG-80 heating for dissolving in Purified Water.Through under agitation in this solution, adding the mixed liquor of Jojoba oil and spice, carry out emulsifying, obtain the hair dye of emulsion form.

Table 10

< comparative example 2>shampoo type hair dye

(method for preparing)

Successively with silver sulfate, antiseptic, 1,3 butylene glycol, Simmondsia chinensis wax PEG-80 heating for dissolving in Purified Water.Through under agitation in this solution, adding the mixed liquor of Jojoba oil and spice, carry out emulsifying, obtain the hair dye of emulsion form.

Table 11

< comparative example 3>shampoo type hair dye

(method for preparing)

Successively with malic acid, silver sulfate, antiseptic, 1,3 butylene glycol, Simmondsia chinensis wax PEG-80 heating for dissolving in Purified Water.Through under agitation in this solution, adding the mixed liquor of Jojoba oil and spice, carry out emulsifying, obtain the hair dye of emulsion form.

The hair dye that on the wool cloth of 5 * 5cm, obtains among coating the foregoing description 1-8 and the comparative example 1-3, Burdick lamp irradiation 1 hour.Afterwards, stamp shampoo, washing, air-dry.The result of the color of the wool cloth that visual judgement obtains is illustrated in the table 12.△, zero, ◎ represent painted intensity, and △ representes a little less than the dyeing that zero expression dyeing is better, and ◎ representes that dyeing is good.

Table 12

As showing in the table 12; The hair dye of the application of the invention; Can on the hair of nature, make painted hue table reveal nearly brown to pitchy; Can implement simultaneously hair dyeing until the extensive tone of the grayish green colour system that is known as the fashion hair dyeing, and, can access the good hair dye of hair dyeing fastness.

Industrial applicibility

According to the present invention, can be used to prepare the industry and the industry of utilizing hair dye of hair dye.

Claims (4)

1. a hair dye is characterized in that, this hair dye contains silver nitrate and/or silver sulfate and water solublity iron salt.

2. hair dye according to claim 1, wherein, said water solublity iron salt is one or more the water solublity iron salt that is selected from ferrous sulfate, iron sulfate, ferrous chloride, the iron chloride.

3. hair dye according to claim 1 and 2 is characterized in that this hair dye contains the organic acid as the pH regulator agent.

4. hair dye according to claim 3, wherein, said organic acid is one or more the organic acid that is selected from malic acid, lactic acid, glycolic, tartaric acid, the benzoic acid.