CN102995403A - Method for solidifying high-performance chitosan on fabric - Google Patents
Method for solidifying high-performance chitosan on fabric Download PDFInfo
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- CN102995403A CN102995403A CN 201210525242 CN201210525242A CN102995403A CN 102995403 A CN102995403 A CN 102995403A CN 201210525242 CN201210525242 CN 201210525242 CN 201210525242 A CN201210525242 A CN 201210525242A CN 102995403 A CN102995403 A CN 102995403A
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- fabric
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- bletilla polysaccharide
- agent
- chitosan
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- 239000004744 fabric Substances 0.000 title claims abstract description 44
- 229920001661 Chitosan Polymers 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 20
- 150000004676 glycans Chemical class 0.000 claims abstract description 36
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 36
- 239000005017 polysaccharide Substances 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 241001313855 Bletilla Species 0.000 claims description 31
- 230000002421 anti-septic effect Effects 0.000 claims description 7
- 229920002413 Polyhexanide Polymers 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 3
- 241001313857 Bletilla striata Species 0.000 abstract 4
- 239000003242 anti bacterial agent Substances 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 2
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 229920002101 Chitin Polymers 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 230000036541 health Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000003110 anti-inflammatory effect Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
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- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- MBLBDJOUHNCFQT-LXGUWJNJSA-N aldehydo-N-acetyl-D-glucosamine Chemical compound CC(=O)N[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO MBLBDJOUHNCFQT-LXGUWJNJSA-N 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
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- 239000001913 cellulose Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 210000004051 gastric juice Anatomy 0.000 description 1
- 238000010353 genetic engineering Methods 0.000 description 1
- 230000036449 good health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000003053 immunization Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 210000002751 lymph Anatomy 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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- 102000004169 proteins and genes Human genes 0.000 description 1
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- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000392 somatic effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
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- 229940088594 vitamin Drugs 0.000 description 1
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- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a method for solidifying high-performance chitosan on a fabric. The method comprises the following steps of: mixing and uniformly stirring water, granular water-soluble chitosan and a granular antibacterial agent at a normal temperature, thus obtaining a high-performance chitosan finishing agent, wherein the concentration of the chitosan ranges from 1% to 3%, and the concentration of the antibacterial agent ranges from 1%-2%; finishing the fabric in the high-performance chitosan finishing agent, wherein the weight ratio of the high-performance chitosan finishing agent to the fabric is equal to 2:1; dehydrating and drying the finished fabric; mixing and uniformly stirring water and granular water-soluble bletilla striata polysaccharide, thus obtaining a bletilla striata polysaccharide solution with the concentration of 0.5% to 1.5%; solidifying the finished and dried fabric in the bletilla striata polysaccharide solution, wherein the weight ratio of the bletilla striata polysaccharide solution to the fabric is equal to 4:1; and then dehydrating and drying the solidified fabric. The method is simple and flexible in process and low in cost, and can effectively improve the antimicrobial durability and washability of the fabric.
Description
Technical field
The invention belongs to the fabric treating technical field, be specifically related to a kind ofly with high-performance chitosan finishing fabric, and make the high-performance shitosan be solidificated in method on the fabric, make fabric have health care.
Background technology
Development and progress along with society, and improving constantly with environmental pollution of people's living standard increased the weight of day by day, people strengthen gradually to the consciousness of self health, up to the present, health care's theory has been not only to rest on to stress pollution-free food, balanced in nutrition and eat the aspect such as health products, people are more and more stronger to passing healthy consciousness, therefore, " magnetic force fiber sock " appearred in recent years, products such as " Taka Magnetotherapeutic pants ", what these products adopted is physical technique, the magnetic force fiber sock is that magnetic etc. processes in conjunction with polypropylene fiber, and price is higher, is difficult to form the scale seriation.
Chitin is to use the animality high molecular cellulose that genetic engineering is extracted from crab, shrimp shell, and shitosan is again chitosan, chitosamine, deacetylated chitin and chitin etc.1996.12.21 " healthy newspaper " once reported " chitosan-very important " vital principle " ", the report chitosan is at sugar, protein, fat, after vitamin and the mineral matter, obligato the 6th vital principle of the human body that scientists is recognized, has the effect that strengthens Cellular Immunity, scientist also confirms, chitosan can be dissolved in hydrochloric acid in gastric juice, the blood that can be present in the people, lymph, in each internal organs and the bone, has the human body compatibility, bactericidal properties and row's cholesterol, chlorion, the heavy metal performance, and the blocking-up cancer cell, the somatic function of activation equipment.
The biologically active that shitosan has and security more and more obtain people's approval, and its application is also more and more extensive.According to " China Textile News ", chitin fiber is natural to possess five functional: nontoxic, mildew-resistant, antibiotic, fire-retardant, antistatic, in the textile garment field, chitin fiber moisture absorbing and sweat releasing, antistatic, bacteria mildew-proof etc. are functional, make it be particularly suitable for doing the directly product of contact skin such as bedding, underwear, socks, towel.Phase early 1990s, Japan utilizes the characteristic of chitin fiber at first, makes antibacterial deodourizing class underwear and panty hose with cotton blending, favored by the consumer.1999～2000, Donghua University developed chitin series blended yarn and fabric and has made various health-care underclothes, panty hose and articles for babies.
Chitin fiber directly contacts skin and has good health care, antibacterial action, but chitin fiber is harder, and its comfort level is poor, and the chitin fiber spinnability is poor in addition, and expensive, and the method for there is no satisfies popular needs.Therefore, many producers obtain the fabric that keeps healthy, but the pull-out capacity of degradation of chitosan liquid are low by directly fabric being padded rear arrangement with degradation of chitosan liquid, poor durability, and manufacturing process flow is complicated in addition, has increased manufacturing cost.
Summary of the invention
The above-mentioned technical problem that exists in order to overcome the prior art field the object of the invention is to, and a kind of method of solidifying the high-performance shitosan at fabric is provided, and technique is simple, and cost is low, improves the antibacterial durability of fabric and washability.
Method of solidifying the high-performance shitosan at fabric provided by the invention may further comprise the steps:
One, allotment high-performance chitosan finishing agent: at normal temperatures, water, granular water soluble shitosan and graininess antiseptic are mixed, and stir, make the agent of high-performance chitosan finishing; Wherein, antiseptic is polyhexamethylene guanide, and the concentration of shitosan is 1～3%, and the concentration of antiseptic is 1～2%;
Two, high-performance chitosan finishing: with deployed high-performance chitosan finishing agent immersion, the finish fabric of step 1, the weight ratio of the agent of high-performance chitosan finishing and fabric is 2: 1, first fabric being put into the agent of high-performance chitosan finishing stirred 20 minutes, soaked again 30 minutes, and dewatered afterwards, dry;
Three, allotment bletilla polysaccharide solution: at normal temperatures, water and granular water soluble bletilla polysaccharide are mixed, and stir, make bletilla polysaccharide solution, the concentration of bletilla polysaccharide is 0.5～1.5%;
Four, bletilla polysaccharide solidifies: the fabric that step 2 is put in order is put into the deployed bletilla polysaccharide solution immersion of step 3, solidified, the weight ratio of bletilla polysaccharide solution and fabric is 4: 1, first fabric is put into bletilla polysaccharide solution and stirred 10 minutes, soaked again 30 minutes, dewater afterwards, dry.
Method of solidifying the high-performance shitosan at fabric provided by the invention, its beneficial effect is, adopt the high-performance chitosan finishing agent of granular water soluble shitosan and graininess antiseptic mixed preparing, fabric is put in order, strengthened the functional of shitosan, after film forming on the fabric, improved the quality of fabric, give fabric and have antibacterial anti-inflammatory, ultraviolet radiation preventing, reduction content of formaldehyde, suppress pruitus, suppress inflammation, skin-friendly is good, the effect of deodorization and absorption peculiar smell, can reach more than 96% on the antibacterial bacteriostatic rate; In the method that fabric solidifies the high-performance shitosan, technique is simple, maneuverability, cost are low, fabric safety non-toxic, the immunizing health put in order through the agent of high-performance chitosan finishing; After bletilla polysaccharide solution solidified, the biological polyoses pull-out capacity was strong, Effective Raise antibacterial durability and the washability of fabric.
The specific embodiment
Below in conjunction with two embodiment, the method at fabric curing high-performance shitosan provided by the invention is described in detail.
Embodiment one
Present embodiment is put in order the finished product towel in the method that fabric solidifies the high-performance shitosan, may further comprise the steps:
One, allotment high-performance chitosan finishing agent: at normal temperatures, water, granular water soluble shitosan and graininess polyhexamethylene guanide are put into industrial rinsing maching to be mixed, the concentration of shitosan is 2%, the concentration of polyhexamethylene guanide is 1%, positive and negative rotation was stirred 30 minutes, made the agent of high-performance chitosan finishing;
Two, high-performance chitosan finishing: towel is put into the deployed high-performance chitosan finishing agent of step 1 soak, put in order, the weight ratio of the agent of high-performance chitosan finishing and towel is 2: 1, first towel being put into the positive and negative rotation of high-performance chitosan finishing agent stirred 20 minutes, soaked again 30 minutes, and dewatered afterwards, dry;
Three, allotment bletilla polysaccharide solution: at normal temperatures, water and granular water soluble bletilla polysaccharide are put into industrial rinsing maching mix, the concentration of bletilla polysaccharide is 0.5%, and positive and negative rotation was stirred 20 minutes, made bletilla polysaccharide solution;
Four, bletilla polysaccharide solidifies: the towel of step 2 oven dry is put into the deployed bletilla polysaccharide solution of step 3 soak, solidify, the weight ratio of bletilla polysaccharide solution and towel is 4: 1, first towel being put into the positive and negative rotation of bletilla polysaccharide solution stirred 10 minutes, soaked again 30 minutes, and dewatered afterwards, dry.
Embodiment two
One, allotment high-performance chitosan finishing agent: at normal temperatures, 100 kg of water, 1500 gram granular water soluble shitosans and 1000 gram graininess polyhexamethylene guanides are put into industrial rinsing maching simultaneously to be mixed, and positive and negative rotation stirred 30 minutes, made the agent of high-performance chitosan finishing;
Two, high-performance chitosan finishing: 50 kilograms of towels are put into the deployed high-performance chitosan finishing agent of step 1, and positive and negative rotation was stirred 20 minutes, soaked 30 minutes again, dewatered afterwards, dried;
Three, allotment bletilla polysaccharide solution: at normal temperatures, 200 kg of water and 1500 gram granular water soluble bletilla polysaccharides are put into industrial rinsing maching mix, and positive and negative rotation stirred 20 minutes, make bletilla polysaccharide solution;
Four, bletilla polysaccharide solidifies: 50 kilograms of towels of step 2 oven dry are put into the deployed bletilla polysaccharide solution of step 3, and positive and negative rotation was stirred 10 minutes, soaked 30 minutes again, dewatered afterwards, dried.
Practical proof: will solidify the towel of processing through the agent dip-coating of high-performance chitosan finishing and bletilla polysaccharide, soak sealing with unboiled water, 25-30 ℃, humidity greater than 80% environment in, carry out mildew test, afterwards unpacking in 8 days, free from extraneous odour still has the characteristics such as good antibacterial anti-inflammatory, moldproof, anti-odour.
Method of solidifying the high-performance shitosan at fabric of the present invention adopts natural polysaccharide, environment-friendly degradable, the whole process environmental friendliness, technology is clean, even the lean solution pH value of discharging also can reach 6-7, owing to contain the shitosan solvent in the lean solution, can also play the effect of flocculation mud.
Claims (1)
1. method of solidifying the high-performance shitosan at fabric is characterized in that it may further comprise the steps:
One, allotment high-performance chitosan finishing agent: at normal temperatures, water, granular water soluble shitosan and graininess antiseptic are mixed, and stir, make the agent of high-performance chitosan finishing; Wherein, antiseptic is polyhexamethylene guanide, and the concentration of shitosan is 1～3%, and the concentration of antiseptic is 1～2%;
Two, high-performance chitosan finishing: with deployed high-performance chitosan finishing agent immersion, the finish fabric of step 1, the weight ratio of the agent of high-performance chitosan finishing and fabric is 2: 1, first fabric being put into the agent of high-performance chitosan finishing stirred 20 minutes, soaked again 30 minutes, and dewatered afterwards, dry;
Three, allotment bletilla polysaccharide solution: at normal temperatures, water and granular water soluble bletilla polysaccharide are mixed, and stir, make bletilla polysaccharide solution, the concentration of bletilla polysaccharide is 0.5～1.5%;
Four, bletilla polysaccharide solidifies: the fabric that step 2 is put in order is put into the deployed bletilla polysaccharide solution immersion of step 3, solidified, the weight ratio of bletilla polysaccharide solution and fabric is 4: 1, first fabric is put into bletilla polysaccharide solution and stirred 10 minutes, soaked again 30 minutes, dewater afterwards, dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210525242.3A CN102995403B (en) | 2012-11-17 | 2012-11-17 | The method solidifying high-performance chitosan on fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210525242.3A CN102995403B (en) | 2012-11-17 | 2012-11-17 | The method solidifying high-performance chitosan on fabric |
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| Publication Number | Publication Date |
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| CN102995403A true CN102995403A (en) | 2013-03-27 |
| CN102995403B CN102995403B (en) | 2016-10-12 |
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| CN201210525242.3A Active CN102995403B (en) | 2012-11-17 | 2012-11-17 | The method solidifying high-performance chitosan on fabric |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938445A (en) * | 2014-02-25 | 2014-07-23 | 江志清 | Method for processing and finishing ecologic, oxygen permeable and antibiotic mouth mask by using chitosan oligosaccharide |
| CN105803776A (en) * | 2016-05-20 | 2016-07-27 | 青岛德喜哆瑭生物科技有限公司 | Isatis root polysaccharide modified fibers and preparation method thereof |
| CN119775570A (en) * | 2024-12-10 | 2025-04-08 | 苏州大学 | A multifunctional finishing liquid and its preparation method and application in silk products |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101028535A (en) * | 2006-02-27 | 2007-09-05 | 权力敏 | Chitose coating with medical biological material |
| KR20090121506A (en) * | 2008-05-22 | 2009-11-26 | 아이텍스플래닝 주식회사 | Antimicrobial Processing Method of Cellulose Fabric or Cotton Fabric |
| CN101781849B (en) * | 2010-01-25 | 2012-01-18 | 江志清 | Method for curing chitosan on fabrics |
| CN102296465B (en) * | 2010-12-30 | 2012-11-28 | 上海水星家用纺织品股份有限公司 | Cassia seed composite antibacterial finishing agent, preparation method, method for processing fiber and application |
-
2012
- 2012-11-17 CN CN201210525242.3A patent/CN102995403B/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103938445A (en) * | 2014-02-25 | 2014-07-23 | 江志清 | Method for processing and finishing ecologic, oxygen permeable and antibiotic mouth mask by using chitosan oligosaccharide |
| CN105803776A (en) * | 2016-05-20 | 2016-07-27 | 青岛德喜哆瑭生物科技有限公司 | Isatis root polysaccharide modified fibers and preparation method thereof |
| CN119775570A (en) * | 2024-12-10 | 2025-04-08 | 苏州大学 | A multifunctional finishing liquid and its preparation method and application in silk products |
| CN119775570B (en) * | 2024-12-10 | 2025-12-12 | 苏州大学 | Multifunctional finishing liquid, preparation method thereof and application thereof in silk products |
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| Publication number | Publication date |
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| CN102995403B (en) | 2016-10-12 |
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Effective date of registration: 20180817 Address after: 266200 No. 568 Taishan Road, Jimo District, Qingdao, Shandong. Patentee after: Hang Ni Zhi (Qingdao) Technology Co., Ltd. Address before: 266200 81 shopping mall street, Jimo, Shandong Patentee before: Jiang Zhiqing |
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Effective date of registration: 20190428 Address after: 266200 No. 568 Taishan Road, Jimo District, Qingdao, Shandong. Patentee after: Qingdao Hongni Clothes Manufacture Co., Ltd. Address before: 266200 No. 568 Taishan Road, Jimo District, Qingdao, Shandong. Patentee before: Hang Ni Zhi (Qingdao) Technology Co., Ltd. |
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