CN103184688B - A kind of antifouling textile product and application thereof - Google Patents
A kind of antifouling textile product and application thereof Download PDFInfo
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- CN103184688B CN103184688B CN201110454976.2A CN201110454976A CN103184688B CN 103184688 B CN103184688 B CN 103184688B CN 201110454976 A CN201110454976 A CN 201110454976A CN 103184688 B CN103184688 B CN 103184688B
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- water
- antifouling
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- 239000004753 textile Substances 0.000 title claims abstract description 44
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 77
- 239000000835 fiber Substances 0.000 claims abstract description 51
- 239000011347 resin Substances 0.000 claims abstract description 46
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 229920000742 Cotton Polymers 0.000 claims abstract description 36
- 239000005871 repellent Substances 0.000 claims abstract description 27
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 22
- 239000011737 fluorine Substances 0.000 claims abstract description 22
- 229920000728 polyester Polymers 0.000 claims abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 18
- 230000002940 repellent Effects 0.000 claims abstract description 17
- 238000005213 imbibition Methods 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims description 24
- 230000015572 biosynthetic process Effects 0.000 claims description 17
- 239000012948 isocyanate Substances 0.000 claims description 9
- 150000002513 isocyanates Chemical class 0.000 claims description 9
- 239000004814 polyurethane Substances 0.000 claims description 7
- 229920006306 polyurethane fiber Polymers 0.000 claims description 4
- 239000002689 soil Substances 0.000 abstract description 22
- 239000007788 liquid Substances 0.000 abstract description 11
- 239000007787 solid Substances 0.000 abstract description 9
- 239000004519 grease Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 description 76
- 239000004744 fabric Substances 0.000 description 42
- 238000000034 method Methods 0.000 description 37
- 239000012530 fluid Substances 0.000 description 27
- 239000003921 oil Substances 0.000 description 26
- 230000006641 stabilisation Effects 0.000 description 17
- 238000011105 stabilization Methods 0.000 description 17
- 238000012360 testing method Methods 0.000 description 15
- 239000004615 ingredient Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 230000000740 bleeding effect Effects 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- 239000004900 Hydrophilic Finishing Agent Substances 0.000 description 11
- 238000004513 sizing Methods 0.000 description 11
- 230000000699 topical effect Effects 0.000 description 9
- 229920004933 Terylene® Polymers 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 229920006359 Fluoroplast Polymers 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- NNTWKXKLHMTGBU-UHFFFAOYSA-N 4,5-dihydroxyimidazolidin-2-one Chemical compound OC1NC(=O)NC1O NNTWKXKLHMTGBU-UHFFFAOYSA-N 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 210000004243 sweat Anatomy 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000008601 oleoresin Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 1
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of antifouling textile product and application thereof.This textiles formed by the polyester staple fibers of cotton short fiber and 70 ~ 10 % by weight of 30 ~ 90 % by weight, wherein the filament surface coverage of polyester staple fibers has the resin bed of carbon containing-fluorine segment and polyester segment, and the filament surface coverage of cotton short fiber has the resin bed of carbon containing-fluorine segment.The cotton textiles that contain of the present invention have both water imbibition and oil repellent simultaneously, have superior antifouling and soil release performance energy to liquid greasy dirt; And also have superior antifouling property to solid shape oily dirts such as neck dirt, grease soils, can be applicable to shirt, T-shirt, underwear, sportswear.
Description
Technical field
The present invention relates to a kind of antifouling textile product and the application thereof with water suction and oil repellent energy simultaneously.
Background technology
Antifouling processing containing cotton textiles is generally arranged by fluoroplast, makes textiles have oil repellent energy, thus prevents greasy dirt from staiing fabric face or stop greasy dirt to penetrate into fabric, to ensure to prevent dirt from staiing fabric face in wearing process.But also have WATER REPELLENCY because common fluoroplast has oil repellent, then have higher requirements to hydrophily as when wearing next to the skin containing cotton textiles, thus fluoroplast is processed and is not suitable for this type of purposes simultaneously.
As in China Patent Publication No. CN101258284 through fluoroplast finishing agent process fabric to give grease proofness, water proofing property and soil release performance, when the solid shape oily dirts such as neck dirt, grease soils are stain fiber surface and are expressed between fiber by this kind of antifouling textile product under external force, fluoroplast layer near dirt can hinder cleaning solution to arrive greasy dirt their location, thus makes solid shape oily dirt more difficult removals in washing process such as neck dirt, grease soils.
And for example obtain one side by double-layered structure's design in China Patent Publication No. CN102031622 and refuse the hydrophilic fabric of water decontamination, one side, the solid shape oily dirt such as neck dirt, grease soils is extruded to and refuses between water and hydrophilic layer equally under external force, and the fluoroplast layer near dirt can hinder cleaning solution to arrive greasy dirt their location; Dirt can be pushed near fluoroplast layer by hydrophilic layer under the effect of washing simultaneously, thus it is poorer to solid shape oily dirt antifouling property, and this type of face weave cost is also higher simultaneously, is not suitable for the purposes such as shirt, T-shirt, underwear.
In antifouling field, the problem that water imbibition and oil repellent containing cotton textiles coexist fails to solve always, causes the blank in this field.
Summary of the invention
The object of the present invention is to provide one to have both water imbibition and oil repellent simultaneously, have superior antifouling and soil release performance energy to liquid greasy dirt; To the solid shape oily dirts such as neck dirt, grease soils also have superior antifouling property containing cotton textiles and application thereof.
Technical solution of the present invention is:
A kind of antifouling textile product, this textiles formed by the polyester staple fibers of cotton short fiber and 70 ~ 10 % by weight of 30 ~ 90 % by weight, wherein the filament surface coverage of polyester staple fibers has the resin bed of carbon containing-fluorine segment and polyester segment, and the filament surface coverage of cotton short fiber has the resin bed of carbon containing-fluorine segment.
The inner compound containing, for example lower structure of filament of above-mentioned cotton short fiber:
。
Above-claimed cpd by reacting thus making the crease resistance of cotton fiber significantly improve, can reach wrinkle resistant more than 3 grades.
Observed by high magnification SEM, resin bed of the present invention is have the micropore shape resin bed of aperture between 1 ~ 100 micron.The top layer of this resin bed be uniformly distributed promising level micropore, carbon containing-fluorine segment refuse oleoresin layer, nexine is hydrophilic resin layers, the hydrophilic radical of nexine resin can touch water or the aqueous substance on top layer through micropore, thus make the sweat of clothes inside, steam etc. absorb hydrophilic resin layers, derived by the micropore in film again, reach excellent absorbing sweat and lead sweat performance.When dirt is solid greasy dirt, common antifouling be dirt cannot be prevented to be stained with arrive between textile surface or fiber, if now there is no hydrophilic resin layers, in washing process solid greasy dirt can washing agent dispersion effect under, to textiles diffusion inside, more not easily remove.Film surface of the present invention has again oil repellent energy, the attachment of greasy dirt can be prevented, even if after the obstinate greasy dirt attachment of part, due to the existence of hydrophilic resin layers, during washing, washing agent (or clear water) can arrive hydrophilic resin layers rapidly, be wrapped in by greasy dirt in washing agent (or clear water), in washing process, wrapped greasy dirt is extruded by micropore; Can very light wipe oil.Because hydrophily and oil repellent act on down simultaneously, when not adding washing powder, also can have excellent soil release performance; And can wash time be shortened, thus can the energy that reduces the wastage be played, protection of the environment.
Be covered in fiber surface after the bridge formation group that above-mentioned resin bed is contained by isocyanates or polyurethane and cotton fiber react, the washing resistance of gained textiles can be improved.
This textiles initial stage crease resistance more than 3 grades, water absorbing properties less than 1 second, oil repellent more than 4 grades, soil release performance (sump oil drip method) more than 4 grades; After JISL0217103 method home washings 20 times, the crease resistance of this textiles more than 3 grades, water imbibition below 1 second, oil repellent more than 3 grades, soil release performance (sump oil drip method) more than 4 grades.
After selecting terylene short fiber and cotton short fiber blending, carry out weaving formation grey cloth, then functional topical finishing is carried out to grey cloth, obtain antifouling textile product of the present invention.Here functional topical finishing can be 1 section of processing, also can be 2 sections of processing.
1 section of processing technology is: first refuse to pad in oily working fluid in water suction, heat treatment 1 ~ 20 minute or drying under the condition of temperature 80 ~ 150 DEG C under the condition of temperature 80 ~ 200 DEG C again, then carry out obtaining textiles of the present invention after sizing arranges process under the condition of 130 ~ 200 DEG C.
Water suction is refused oily working fluid and is made up of following ingredients:
Form stabilization agent 60 ~ 180g/L
Catalyst 10 ~ 30g/L
Water suction oil-repellent agent 10 ~ 50g/L
Bridging agent 10 ~ 20g/L
Softener 0 ~ 20g/L
Bleeding agent 0 ~ 3g/L
All the other are water.
2 sections of processing technologys are: to pad after process under the condition of temperature 80 ~ 200 DEG C heat treatment 1 ~ 20 minute or dry under the condition of temperature 80 ~ 150 DEG C in 1 section of hydrophilic form stable treatment liquid, carry out sizing arrangement process again under the condition of 130 ~ 200 DEG C after, refuse to pad in oily working fluid 2 sections of water suctions again, heat treatment 1 ~ 20 minute or drying under the condition of temperature 80 ~ 150 DEG C under the condition of temperature 80 ~ 200 DEG C again, then carry out obtaining textiles of the present invention after sizing arranges process under the condition of 130 ~ 200 DEG C;
Hydrophilic form stable treatment liquid is made up of following ingredients:
Hydrophilic finishing agent 5 ~ 30g/L
Form stabilization agent 60 ~ 180g/L
Catalyst 10 ~ 30g/L
Bleeding agent 0 ~ 3g/L
All the other are water;
Water suction is refused oily working fluid and is made up of following ingredients:
Water suction oil-repellent agent 10 ~ 50g/L
Bridging agent 10 ~ 20g/L
Softener 0 ~ 20g/L
Bleeding agent 0 ~ 3g/L
All the other are water.
Bridging agent in above-mentioned working fluid can be polyurethane, block one or both of isocyanates bridging agent; Form stabilization agent is the one of the N-methylol of modification, dihydroxy ethylene urea or multi-carboxylic acid compounds; Water suction oil-repellent agent is not containing the fluorine resin of PFOA, PFOS; Softener is not particularly limited; Bleeding agent is the common surfactant refusing water processing isopropyl alcohol or other environment-friendly type low surface tensions.
The selection of above-mentioned 1 section or 2 sections processing method can be selected according to the number of cotton content, and the adjustment of dosing is then carried out according to the difference of cotton content and tissue.
All the other auxiliary agents such as pigment or fluorescer can require according to color difference and suitably add, and adding the stability that should be noted that working fluid, solving problems as occurred that non-persistent situation can adopt 2 sections to process or add the liquid stabilization agent of disperse system.
It is blank that the present invention has filled up product, has superior water suction simultaneously, refuses oil, antifouling soil release performance.When clothes made by this product is worn, can sweat be absorbed, and prevent oily dirt from penetrating into fibrous inside, under hydrophobic ingredient and the coefficient condition of hydrophilic component, dirt can be removed simply.And this product is not add its dirt-removing power when washing agent washs also very good.Can be applicable to shirt, T-shirt, underwear, sportswear etc.
The following describes the assay method of indices of the present invention:
(1) wrinkle resistance is according to the crease resistance measurement of test method of JISL1059 fibre
(2) water imbibition is tested according to JISL1097 method of dripping
(3) refuse oil content to test according to AATCCTestMethod118 " OilRepellency:HydrocarbonResistance " method
(4) soil release performance (flap is dirty) is tested according to following method
A. the test specimens cloth of 12cm × more than 24cm is prepared
B. lipstick is got
C. greasepaint pen (short peak SH № 14; Pig hair; Capital of a country NAKASATO), rubber stopper (organosilicon, ASONE manufacture, No. 9) and lipstick (Shiseido, brick-red)
D. use greasepaint pen to be evenly coated on rubber stopper by lipstick, adhesion weight is 0.0050 ± 0.0005 (g/9 rubber stopper)
E. will smear uniform rubber stopper and be positioned over fabric face gently, and use hand fixed fabric, then parent pushes back and turns about 10 °, is transferred to by lipstick (every level repeats aforesaid operations 3 go back tos, N number=3) on fabric
F. the fabric staiing lipstick is positioned in the dryer of 40 DEG C and takes out after about 15 hours
G. in the sink of full-automatic or 2 slot types, putting into the water that 24L temperature is 40 ± 2 DEG C, and 24g flower king high activity washing powder, putting into test film and load cloth after the pollution of weight 480g altogether, undertaken washing for 10 minutes by the strong condition of rinsing maching
H.30 wash 2 minutes after dehydration second, repeatedly this operation 2 times
I. do not twist dry taking-up test film, anhydrate by signature gently with filter paper, air dry under level
J. the test film after washing and the pollution of (1) item judge, by the change color of code test sheet, to compare the grade distinguishing washability, represent with the mean value of 3 pieces with pollution gray scale.
(5) soil release performance (lipstick contamination method) is tested according to following method
A. the test specimens cloth of 12cm × more than 24cm is prepared
B. lipstick is got
C. greasepaint pen (short peak SH № 14; Pig hair; Capital of a country NAKASATO), rubber stopper (organosilicon, ASONE manufacture, No. 9) and greasy dirt (synthesis flap dirt)
Greasy dirt (synthesis flap dirt): solid hardened tallow (fusing point more than 58 DEG C), atoleine, bone black (recording in JISZ8901)
D. use greasepaint pen to be evenly coated on rubber stopper by lipstick, adhesion weight is 0.0050 ± 0.0005 (g/9 rubber stopper)
E. will smear uniform rubber stopper and be positioned over fabric face gently, and use hand fixed fabric, then parent pushes back and turns about 10 °, is transferred to by lipstick (every level repeats aforesaid operations 3 go back tos, N number=3) on fabric
F. the fabric staiing lipstick is positioned in the dryer of 40 DEG C and takes out after about 15 hours
G. in the sink of full-automatic or 2 slot types, putting into the water that 24L temperature is 40 ± 2 DEG C, and 24g flower king high activity washing powder, putting into test film and load cloth after the pollution of weight 480g altogether, undertaken washing for 10 minutes by the strong condition of rinsing maching
H.30 wash 2 minutes after dehydration second, repeatedly this operation 2 times
I. do not twist dry taking-up test film, anhydrate by signature gently with filter paper, air dry under level
J. the test film after washing and the pollution of (1) item judge, by the change color of code test sheet, to compare the grade distinguishing washability, represent with the mean value of 3 pieces with pollution gray scale.
(6) soil release performance (flap dirty--do not add washing powder) is tested according to following method
Step g. in the sink of full-automatic or 2 slot types, putting into the water that 24L temperature is 40 ± 2 DEG C, put into test film and load cloth after the pollution of weight 480g altogether, undertaken washing for 10 minutes by the strong condition of rinsing maching.
(7) soil release performance (lipstick stain method--do not add washing powder) is tested according to following method
Step g. automatically or in the sink of 2 slot types putting into the water that 24L temperature is 40 ± 2 DEG C, put into test film and load cloth after the pollution of weight 480g altogether, carry out washing in 10 minutes by the strong condition of rinsing maching, all the other are with the test of 5 soil release performances (lipstick contamination method).
(8) carrying out washing treatment washs 20 times tests according to JISL0217103 method.
Below in conjunction with embodiment and comparative example, the invention will be further described.
The resin used in following examples is as follows:
Form stabilization agent A (the low formaldehyde of N-methylol of modification, the graceful system of Hensel)
Form stabilization agent B (multi-carboxylic acid compounds formaldehydeless, the graceful system of Hensel)
Form stabilization agent C (dihydroxy ethylene urea low formaldehyde form finishing agent, DIC system)
Form stabilization agent D (dihydroxy ethylene urea low formaldehyde form finishing agent, three texture of wood developments)
Form stabilization agent E (dihydroxy ethylene urea low formaldehyde form finishing agent, BASF system)
Form stabilization agent F (RUCONFAN wash and wear finisher, Rudoiph's system)
Catalyst A (the graceful system of slaine, Hensel)
Catalyst B (the graceful system of slaine, Hensel)
Catalyst C (hydrated magnesium chloride, Shanghai chemical drug system)
Hydrophilic finishing agent A (modified poly ester hydrophilic finishing agent, Hensel graceful weaving Ran Hua Co., Ltd system)
Hydrophilic finishing agent B (modified poly ester hydrophilic finishing agent, Nicca Chemical Co., Ltd's system)
Hydrophilic finishing agent C (modification acrylate hydrophilic finishing agent, KCC of Xin Zhong village system)
Hydrophilic finishing agent D (modified polyurethane hydrophilic finishing agent, great Yuan KCC system)
Oil-treatment agent A (oil-treatment agent, Daikin Ind Ltd's system are refused in the water suction of fluorine element) is refused in water suction
Oil-treatment agent B (oil-treatment agent, great Yuan KCC system are refused in the water suction of fluorine element) is refused in water suction
Oil-treatment agent C (mixture that oil-treatment agent is refused in the water suction of fluorine element, oil-treatment agent A and B is refused in water suction) is refused in water suction
Absorb water easy detergent A (ULTRAPHILHDS, Hensel graceful weaving Ran Hua Co., Ltd system)
Water, oil and soil repellent agent A (NK ガ ー De SR-108, Nicca Chemical Co., Ltd's system)
Bridging agent A (aqueous polyurethane, capital thin,tough silk change into Co., Ltd.'s system)
Bridging agent B(polyfunctional group blocked isocyanate, great Yuan KCC system)
Bridging agent C(polyfunctional group blocked isocyanate, Nicca Chemical Co., Ltd's system)
Bridging agent D (メ イ カ ネ ー ト MF, Ming Cheng chemical industry Co., Ltd. system)
Softener A (C-BAYPRETNANOPU, bright Sheng chemistry system)
Softener B (RVO, great Yuan KCC system)
Bleeding agent A (KieralonCSA, BASF system)
Bleeding agent B (isopropyl alcohol, Shanghai chemical drug system).
Embodiment 1
After selecting terylene short fiber 10 % by weight and cotton short fiber 90 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
Water suction is refused oily working fluid and is made up of following ingredients:
Form stabilization agent A180g/L
Catalyst A 20g/L
Water suction oil-repellent agent A15g/L
Bridging agent A5g/L
Softener A 5g/L
Bleeding agent A3g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into water suction and refuse oily working fluid and pad, under the condition of temperature 130 DEG C, heat treatment is carried out obtaining antifouling textile product of the present invention after sizing in 45 seconds arranges process for 2 minutes again under the condition of 170 DEG C again, the filament surface coverage of the polyester staple fibers of gained textiles has the resin bed of carbon containing-fluorine segment and polyester segment, the filament surface coverage of cotton short fiber to have the resin bed of carbon containing-fluorine segment; Resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron; Be covered in fiber surface after the bridge formation group that resin bed is contained by polyurethane and cotton fiber react, performance parameter is in table 1.
Embodiment 2
After selecting terylene short fiber 30 % by weight and cotton short fiber 70 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
Water suction is refused oily working fluid and is made up of following ingredients:
Form stabilization agent B120g/L
Catalyst C18g/L
Water suction oil-repellent agent C25g/L
Bridging agent B10g/L
Softener B 5g/L
Bleeding agent A1g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into water suction and refuse oily working fluid and pad, under the condition of temperature 130 DEG C, heat treatment is carried out obtaining antifouling textile product of the present invention after sizing in 45 seconds arranges process for 2 minutes again under the condition of 170 DEG C again, the filament surface coverage of the polyester staple fibers of gained textiles has the resin bed of carbon containing-fluorine segment and polyester segment, the filament surface coverage of cotton short fiber to have the resin bed of carbon containing-fluorine segment; Resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron; Be covered in fiber surface after the bridge formation group that resin bed is contained by isocyanates and cotton fiber react, performance parameter is in table 1.
Embodiment 3
After selecting terylene short fiber 45 % by weight and cotton short fiber 55 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
Hydrophilic form stable treatment liquid is made up of following ingredients:
Form stabilization agent C100g/L
Catalyst B 16g/L
Hydrophilizing agent finishing agent A20g/L
Bleeding agent A1g/L
All the other are water;
Water suction is refused oily working fluid and is made up of following ingredients:
Water suction oil-repellent agent C18g/L
Bridging agent C10g/L
Softener B 5g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into 1 section of hydrophilic form stable treatment liquid and to pad after process under the condition of temperature 130 DEG C heat treatment 2 minutes, carry out 60s sizing arrangement process again under the condition of 170 DEG C after, refuse to pad in oily working fluid 2 sections of water suctions again, heat treatment 3 minutes under the condition of temperature 130 DEG C again, carry out again obtaining antifouling textile product of the present invention after 45s sizing arranges process under the condition of 175 DEG C, the filament surface coverage of the polyester staple fibers of gained textiles has the resin bed of carbon containing-fluorine segment and polyester segment, the filament surface coverage of cotton short fiber has the resin bed of carbon containing-fluorine segment, resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron, be covered in fiber surface after the bridge formation group that resin bed is contained by isocyanates and cotton fiber react, performance parameter is in table 1.
Embodiment 4
After selecting terylene short fiber 55 % by weight and cotton short fiber 45 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
Hydrophilic form stable treatment liquid is made up of following ingredients:
Form stabilization agent D80g/L
Catalyst C16g/L
Hydrophilizing agent finishing agent B20g/L
Bleeding agent A1g/L
All the other are water;
Water suction is refused oily working fluid and is made up of following ingredients:
Water suction oil-repellent agent A20g/L
Water suction oil-repellent agent B5g/L
Bridging agent B10g/L
Softener B 20g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into 1 section of hydrophilic form stable treatment liquid and to pad after process under the condition of temperature 150 DEG C heat treatment 2 minutes, refuse to pad in oily working fluid 2 sections of water suctions again, heat treatment 2 minutes under the condition of temperature 130 DEG C again, carry out again obtaining antifouling textile product of the present invention after 60s sizing arranges process under the condition of 175 DEG C, the filament surface coverage of the polyester staple fibers of gained textiles has the resin bed of carbon containing-fluorine segment and polyester segment, the filament surface coverage of cotton short fiber to have the resin bed of carbon containing-fluorine segment; Resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron; Be covered in fiber surface after the bridge formation group that resin bed is contained by isocyanates and cotton fiber react, performance parameter is in table 1.
Embodiment 5
After selecting terylene short fiber 70 % by weight and cotton short fiber 30 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
Hydrophilic form stable treatment liquid is made up of following ingredients:
Form stabilization agent E60g/L
Catalyst C16g/L
Hydrophilic finishing agent B15g/L
Hydrophilic finishing agent C5g/L
Bleeding agent A1g/L
All the other are water;
Water suction is refused oily working fluid and is made up of following ingredients:
Water suction oil-repellent agent A30g/L
Water suction oil-repellent agent B20g/L
Bridging agent B10g/L
Bridging agent C3g/L
Softener B 20g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into 1 section of hydrophilic form stable treatment liquid and to pad after process under the condition of temperature 130 DEG C heat treatment 2 minutes, and after the 60s that shapes in 170 DEG C, refuse to pad in oily working fluid 2 sections of water suctions again, heat treatment 2 minutes under the condition of temperature 130 DEG C again, carry out again obtaining antifouling textile product of the present invention after 60s sizing arranges process under the condition of 175 DEG C, the filament surface coverage of the polyester staple fibers of gained textiles has the resin bed of carbon containing-fluorine segment and polyester segment, the filament surface coverage of cotton short fiber has the resin bed of carbon containing-fluorine segment, resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron, be covered in fiber surface after the bridge formation group that resin bed is contained by isocyanates and polyurethane and cotton fiber react, performance parameter is in table 1.
The antifouling textile product of embodiment 1-5 are applied to shirt, T-shirt, underwear, sportswear, and the filament of its cotton short fiber is inner all containing, for example the compound of lower structure:
。
Comparative example 1
After selecting terylene short fiber 70 % by weight and cotton short fiber 30 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth,
The antifouling working fluid that absorbs water is made up of following ingredients:
Form stabilization agent F100g/L
Catalyst C16g/L
Water suction anti-fouling agent A50g/L
Bridging agent D10g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into the antifouling working fluid of water suction, under the condition of temperature 130 DEG C, heat treatment is carried out obtaining water suction antifouling textile product after sizing in 45 seconds arranges process for 1 minute again under the condition of 180 DEG C again, the filament surface of this textiles does not form water suction and refuses oleoresin film, and performance parameter is in table 1.
Comparative example 2
After selecting terylene short fiber 30 % by weight and cotton short fiber 70 % by weight to carry out blending, weave formation grey cloth, then adopt the working fluid of following composition to carry out functional topical finishing to grey cloth:
Water, oil and soil repellent working fluid is made up of following ingredients:
Form stabilization agent F60g/L
Catalyst C16g/L
Water, oil and soil repellent agent A50g/L
Bridging agent D10g/L
Bleeding agent B10g/L
All the other are water;
Concrete finishing technique is: first grey cloth is put into water, oil and soil repellent working fluid, under the condition of temperature 130 DEG C, heat treatment is carried out obtaining water, oil and soil repellent textiles after sizing in 45 seconds arranges process for 1 minute again under the condition of 180 DEG C again, the filament surface of this textiles does not form water suction and refuses oleoresin film, and performance parameter is in table 1.
Claims (4)
1. antifouling textile product, it is characterized in that: this textiles formed by the polyester staple fibers of cotton short fiber and 70 ~ 10 % by weight of 30 ~ 90 % by weight, the filament surface coverage of wherein said polyester staple fibers has the resin bed of carbon containing-fluorine segment and polyester segment, and the filament surface coverage of described cotton short fiber has the resin bed of carbon containing-fluorine segment; Described resin bed is have the micropore shape resin bed of aperture between 1 ~ 100 micron; The initial stage crease resistance of this textiles more than 3 grades, oil repellent more than 4 grades, the dirty performance of the anti-flap more than 4 grades, water imbibition is below 1 second.
2. antifouling textile product according to claim 1, is characterized in that: be covered in fiber surface after the bridge formation group that the resin bed of described carbon containing-fluorine segment is contained by isocyanates or polyurethane and cotton fiber react.
3. antifouling textile product according to claim 1 and 2, is characterized in that: after home washings 20 times, this textiles crease resistance more than 3 grades, oil repellent more than 3 grades, the dirty performance of the anti-flap more than 4 grades, water imbibition is below 1 second.
4. antifouling textile product according to claim 1 are applied to shirt, T-shirt, underwear, sportswear.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1782219A (en) * | 2004-12-01 | 2006-06-07 | 日清纺织株式会社 | Anti-pollution fiber structure and its processing method |
| CN101835816A (en) * | 2007-10-24 | 2010-09-15 | 纳幕尔杜邦公司 | Hydrophilic fluorinated soil resistant copolymers |
| CN102041685A (en) * | 2010-11-19 | 2011-05-04 | 鲁泰纺织股份有限公司 | Finishing method of fiber product free of cleaning by detergent |
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| JPS6123674A (en) * | 1984-07-13 | 1986-02-01 | Asahi Glass Co Ltd | Antifouling agent |
| JP2008163474A (en) * | 2006-12-27 | 2008-07-17 | Toray Ind Inc | Fiber structure |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1782219A (en) * | 2004-12-01 | 2006-06-07 | 日清纺织株式会社 | Anti-pollution fiber structure and its processing method |
| CN101835816A (en) * | 2007-10-24 | 2010-09-15 | 纳幕尔杜邦公司 | Hydrophilic fluorinated soil resistant copolymers |
| CN102041685A (en) * | 2010-11-19 | 2011-05-04 | 鲁泰纺织股份有限公司 | Finishing method of fiber product free of cleaning by detergent |
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