CN1032019A - Adhesive for shoe soles - Google Patents
Adhesive for shoe soles Download PDFInfo
- Publication number
- CN1032019A CN1032019A CN87106339A CN87106339A CN1032019A CN 1032019 A CN1032019 A CN 1032019A CN 87106339 A CN87106339 A CN 87106339A CN 87106339 A CN87106339 A CN 87106339A CN 1032019 A CN1032019 A CN 1032019A
- Authority
- CN
- China
- Prior art keywords
- sbs
- adhesive
- primer
- add
- butadiene block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 9
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims 1
- 238000012661 block copolymerization Methods 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- 239000003208 petroleum Substances 0.000 claims 1
- 239000011115 styrene butadiene Substances 0.000 claims 1
- 239000010985 leather Substances 0.000 abstract description 6
- 239000004677 Nylon Substances 0.000 abstract description 5
- 229920001778 nylon Polymers 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 229920001084 poly(chloroprene) Polymers 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 239000004636 vulcanized rubber Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- -1 azo isobutyronitrile Chemical compound 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005012 oleoresinous Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- AZIQALWHRUQPHV-UHFFFAOYSA-N prop-2-eneperoxoic acid Chemical class OOC(=O)C=C AZIQALWHRUQPHV-UHFFFAOYSA-N 0.000 description 1
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229920000428 triblock copolymer Polymers 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a kind of prescription and synthesis technique of adhesive for shoe soles.This primer is mainly used in the SBS sole surface and handles, and also is applicable to the surface treatment of EVA section, nylon fabrics, vulcanized rubber, and this primer mainly utilizes styrene-butadiene block copolymer (SBS) and methyl methacrylate-grafted copolyreaction to make.The SBS sole surface is dried and is adopted the graft type chloroprene rubber adhesive agent after this primer is handled, can acquisition with jails such as foamed leather, leather, nylon adhesive substance tie bonding.
Description
The invention provides a kind of prescription and synthesis technique of adhesive for shoe soles.This factory's glue is mainly used in the SBS sole surface and handles, and also is adapted to the surface treatment of EVA section, nylon fabrics, vulcanized rubber.
U.S. Pat 3459700(1969) introduces: if with 20～60% ABA triblock copolymer such as SBS, be dissolved in 80～40% the vinylbenzene (including 5～40% hydroxy acrylates), mixture cushioning to 20～200 ℃, the reaction times is 0.1～24 hour.By radical initiator (as hydrogen peroxide, Potassium Persulphate, benzoyl peroxide or azo isobutyronitrile etc.); can obtain thermoset graft crosslinking transparent copolymer; this uncommon invention is that aluminum alloy surface need not anticipated the bond strength that ， And acquisition had not been estimated.
Provided by the present invention is a kind of adhesive for shoe soles, mainly utilizes styrene-butadiene block copolymer (SBS) and methyl methacrylate-grafted copolyreaction system.The SBS sole surface is dried and is adopted the graft type chloroprene rubber adhesive agent after this primer is handled, can acquisition and firm bonding such as foamed leather, leather, nylon fabrics.Known to the documents and materials that contrast is consulted, mainly as tackiness agent, the grafted monomer that is adopted is vinylbenzene or butyl acrylate or other compounds to the product of introducing in the data.
Total prescription of the present invention:
100 parts of styrene-butadiene block copolymers (homemade YH-802 or YH-792)
50～100 parts of methyl methacrylates
900～1200 parts of the total consumptions of solvent (toluene is used ester acetoacetic ester or gasoline during dilution)
Initiator (dibenzoyl peroxide or Diisopropyl azodicarboxylate) is an amount of
Tackifying resin (rosin or ester gum or modified phenolic resins, terpine resin, stone
Oleo-resinous) 0～100 part
Synthetic basic technology of the present invention is as follows: in the reactor that has backflow and whipping appts, add styrene-butadiene block copolymer SBS and solvent toluene by weight ratio listed in the prescription; The weight ratio of toluene and SBS is 1: 3～3.5, treat SBS dissolving after, it is cured to add methyl methacrylate and initiator dibenzoyl peroxide or azo two isobutyls, 60～110 ℃ of reactions 0.5～8 hour down.Add an amount of tackifying resin according to different purposes then and alkene is released the solvent vinyl acetic monomer or gasoline is made primer.
SBS sole surface after this primer is handled and foamed leather adopt graft type neoprene latex adherent stripping strength greater than 3Kg/Cm(2.94KN/m), with the stripping strength of leather bonds greater than 6Kg/Cm(5.88KN/m), with nylon fabrics adherent stripping strength greater than 3Kg/Cm(2.94KN/m).
After the preceding revisal of the capable revisal of file name page or leaf
Specification sheets 1
2 ... this factory's glue is mainly used in ... this primer is mainly used in
7 ... the mixture cushioning extremely ... mixture heating up extremely
14 ... dry the employing graft type ... dry the back and adopt graft type
14 ... can obtain and the foam people ... can obtain and PVC foam people
22 ester acetoacetic ester Methane Carboxylic Acids
Claims (3)
1, a kind of adhesive for shoe soles is characterized in that, in the reactor that has backflow and whipping appts; Add and styrene butadiene block copolymerization SBS and solvent toluene; after treating the SBS dissolving; it is cured to add methyl methacrylate MMA and an amount of initiator dibenzoyl peroxide or azo two isobutyls; there are 60～110 ℃ to react 0.5～8 hour down, add an amount of tackifying resin and alkene according to different purposes then and release solvent vinyl acetic monomer or gasoline.The weight ratio of total consumption of SBS and solvent and MMA is 10: 5～10: 90～120, and wherein the weight ratio of SBS and toluene is 1: 3～3.5.
2, according to right require 1, it is characterized in that styrene-butadiene block copolymer can select homemade YH-802 or YH-792 or homemade other models.
3,, it is characterized in that tackifying resin can select rosin or ester gum or modified phenolic resins, terpine resin, petroleum resin according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87106339A CN1032019A (en) | 1987-09-12 | 1987-09-12 | Adhesive for shoe soles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87106339A CN1032019A (en) | 1987-09-12 | 1987-09-12 | Adhesive for shoe soles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1032019A true CN1032019A (en) | 1989-03-29 |
Family
ID=4815659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87106339A Pending CN1032019A (en) | 1987-09-12 | 1987-09-12 | Adhesive for shoe soles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1032019A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116373C (en) * | 1998-03-31 | 2003-07-30 | 中国科学院福建物质结构研究所 | Surface treating agent for cold-adhering shoe-making |
| CN102295882A (en) * | 2010-06-25 | 2011-12-28 | 米申产品控股有限公司 | Athletic shoe sole coating for traction enhancement |
| CN103012691A (en) * | 2012-12-17 | 2013-04-03 | 青岛森淼实业有限公司 | Method for preparing acrylic ester-styrene butadiene styrene (SBS) copolymer |
| CN101684397B (en) * | 2008-09-28 | 2013-04-17 | 中山宝立得高分子材料有限公司 | Waterproof modified polyacrylate leather adhesive and manufacturing method thereof |
| CN103756230A (en) * | 2014-01-09 | 2014-04-30 | 杭州电子科技大学 | Preparation method of thermal plastic rubber (TPR) surface treating agent containing acrylamide |
| CN118702871A (en) * | 2024-06-30 | 2024-09-27 | 广西大学 | Modified styrene-butadiene block copolymer elastomer and preparation method and application thereof |
-
1987
- 1987-09-12 CN CN87106339A patent/CN1032019A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116373C (en) * | 1998-03-31 | 2003-07-30 | 中国科学院福建物质结构研究所 | Surface treating agent for cold-adhering shoe-making |
| CN101684397B (en) * | 2008-09-28 | 2013-04-17 | 中山宝立得高分子材料有限公司 | Waterproof modified polyacrylate leather adhesive and manufacturing method thereof |
| CN102295882A (en) * | 2010-06-25 | 2011-12-28 | 米申产品控股有限公司 | Athletic shoe sole coating for traction enhancement |
| CN102295882B (en) * | 2010-06-25 | 2016-08-17 | 米申产品控股有限公司 | For strengthening the sports shoes priming coat of attachment frictional force |
| CN103012691A (en) * | 2012-12-17 | 2013-04-03 | 青岛森淼实业有限公司 | Method for preparing acrylic ester-styrene butadiene styrene (SBS) copolymer |
| CN103756230A (en) * | 2014-01-09 | 2014-04-30 | 杭州电子科技大学 | Preparation method of thermal plastic rubber (TPR) surface treating agent containing acrylamide |
| CN118702871A (en) * | 2024-06-30 | 2024-09-27 | 广西大学 | Modified styrene-butadiene block copolymer elastomer and preparation method and application thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |