CN103352374A - High-breathable fabrics for high-grade sports shoes and preparation method thereof - Google Patents
High-breathable fabrics for high-grade sports shoes and preparation method thereof Download PDFInfo
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- CN103352374A CN103352374A CN2013102767668A CN201310276766A CN103352374A CN 103352374 A CN103352374 A CN 103352374A CN 2013102767668 A CN2013102767668 A CN 2013102767668A CN 201310276766 A CN201310276766 A CN 201310276766A CN 103352374 A CN103352374 A CN 103352374A
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- China
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- parts
- minute
- morpholine
- resistant polystyrene
- synthetic leather
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- Granted
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- 239000004744 fabric Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims abstract description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000843 powder Substances 0.000 claims abstract description 17
- 239000004927 clay Substances 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 14
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940043276 diisopropanolamine Drugs 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000035699 permeability Effects 0.000 claims abstract description 12
- 239000004793 Polystyrene Substances 0.000 claims abstract description 9
- 229920002223 polystyrene Polymers 0.000 claims abstract description 9
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 claims abstract description 7
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 7
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 6
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 8
- 239000004800 polyvinyl chloride Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 7
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 claims description 6
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 229910017083 AlN Inorganic materials 0.000 claims description 3
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 3
- 235000011449 Rosa Nutrition 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 239000002390 adhesive tape Substances 0.000 claims description 3
- -1 alkenyl imidazoline Chemical compound 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000013638 trimer Substances 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 239000002649 leather substitute Substances 0.000 abstract description 9
- 239000010985 leather Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- DNUPYEDSAQDUSO-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl benzoate Chemical compound OCCOCCOC(=O)C1=CC=CC=C1 DNUPYEDSAQDUSO-UHFFFAOYSA-N 0.000 abstract 2
- SCNFOPZWAVWOEF-UHFFFAOYSA-N 1-(4,5-dihydroimidazol-1-yl)-N-ethylheptadec-1-en-2-amine Chemical compound C(C)NC(=CN1C=NCC1)CCCCCCCCCCCCCCC SCNFOPZWAVWOEF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- AVVSGTOJTRSKRL-UHFFFAOYSA-L hydrogen phosphate;lead(2+) Chemical compound [Pb+2].OP([O-])([O-])=O AVVSGTOJTRSKRL-UHFFFAOYSA-L 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
Provided are high-breathable fabrics for high-grade sports shoes and a preparation method thereof. The high-breathable fabrics are characterized in that the high-breathable fabrics are composed of two layers in a composite mode, wherein the base material is cloth, the upper layer is a PVC resin layer, and the upper layer is prepared by the following components in parts by weight: 70 to 80 parts of SG-4 type PVC resin, 1 to 2 parts of diisopropanolamine, 1 to 2 parts of morpholine, 4 to 5 parts of impact-resistant polystyrene, 2 to 3 parts of dibutyltin dilaurate, 2 to 3 parts of zinc oxide, 1 to 2 parts of magnesium oxide, 2 to 3 parts of alumina, 5 to 7 parts of barium sulfate, 2 to 3 parts of methyltriethoxysilane, 1 to 2 parts of vinyltriethoxysilane, 5 to 7 parts of triglycidyl isocyanurate, 1 to 2 parts of dibasic lead phosphate, 2 to 3 parts of diethylene glycol benzoate, 1 to 2 parts of coumarone, 1 to 2 parts of 2-ethylamino heptadecenyl imidazoline, 10 to 12 parts of protein powder, 2 to 3 parts of polyvinyl alcohol and 3 to 4 parts of modified clay powder. Through formula and technology improvements provided by the invention, protein enhances the permeability of synthetic leather; the impact-resistant polystyrene enhances the toughness and strength of the synthetic leather; the synthetic leather has natural and comfortable hand feel similar to that of natural leather and is not easily damaged or torn within 3 to 5 years, thereby being suitable to be used as the fabrics of sports shoes.
Description
Technical field
The invention belongs to a kind of chemical synthesis leather facing material processing technique field, specifically a kind of polyvinyl chloride synthetic leather and preparation method thereof.
Background technology
The hydrolysis that the polyvinyl chloride synthetic leather has, wear-resisting, scratch resistance, the advantage such as fire-retardant, be widely used in the aspects such as high-grade sport footwear, case and bag, sofa, but it still has many deficiencies at aspects such as flexibility, gas permeability, feel, anti-complications, need to improve with technique its prescription.
Summary of the invention
The object of the present invention is to provide high-grade sport footwear fabric and preparation method thereof of a kind of good permeability, the synthetic leather good product quality of production.
Purpose of the present invention can be achieved through the following technical solutions:
A kind of high-grade sport footwear fabric of good permeability is characterized in that compoundly consisting of by two layers, and base material is cloth, and the upper strata is the polyvinyl chloride resin layer, and the upper strata is made by the raw material of following weight portion:
SG-4 type polyvinyl chloride resin 70-80, diisopropanolamine (DIPA) 1-2, morpholine 1-2, impact resistant polystyrene 4-5, dibutyl tin laurate 2-3, zinc oxide 2-3, magnesia 1-2, aluminium oxide 2-3, barium sulfate 5-7, MTES 2-3, vinyltriethoxysilane 1-2, triglycidyl isocyanurate 5-7, dibasic lead phosphite 1-2, diglycol benzoic ether 2-3, coumarone 1-2,2-ethylamino 17 alkenyl imidazoline 1-2, protein powder 10-12, polyvinyl alcohol 2-3, modified clay powder 3-4;
Described modified clay powder makes by the following method:
Clay is put into 460-480 ℃ of lower calcining 3-4 hour, take out cooling, pulverize; Add again the morpholine of Rosa Damascana, the 2-3% of sodium phosphate trimer, the 2-3% of the aluminium nitride be equivalent to clay powders weight 5-8%, 3-4%, the di-n-octyl of 3-4%-4-isothiazoline-3-ketone, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 that is equivalent to clay powders weight 3-5%, 13000-16000 rev/min of lower the stirring 60-70 minute, and get final product.
The high-grade sport footwear of the described good permeability preparation method of fabric is characterized in that may further comprise the steps:
A) with diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 135-150 ℃ of lower the stirring 10-15 minute, then, lower the temperature 100-105 ℃, add other surplus stock, mixed at high speed 5-8 minute, then, under expect that mill carries out fitting to adhesive tape machine after fully mixing, the upper strata is attached on the base material;
B) product is processed through surface effect;
C) finished product inspection is qualified, dispatches from the factory.
The present invention is by prescription and process modification, and protein increases the gas permeability of synthetic leather, and impact resistant polystyrene has increased toughness and the intensity of synthetic leather, has to be similar to the naturally comfortable feel that natural leather has; 3-5 is not easy breakage or tears damage, is suitable for as Fabric Used for Sport Shoes.
The specific embodiment
A kind of high-grade sport footwear fabric of good permeability compoundly consists of by two layers, and base material is cloth, and the upper strata is the polyvinyl chloride resin layer, and the upper strata is made by the raw material of following weight portion (kilogram):
SG-4 type polyvinyl chloride resin 70, diisopropanolamine (DIPA) 2, morpholine 1, impact resistant polystyrene 5, dibutyl tin laurate 2, zinc oxide 2, magnesia 1, aluminium oxide 2, barium sulfate 7, MTES 2, vinyltriethoxysilane 1, triglycidyl isocyanurate 5, dibasic lead phosphite 2, diglycol benzoic ether 3, coumarone 1,2-ethylamino 17 alkenyl imidazolines 1, protein powder 12, polyvinyl alcohol 2, modified clay powder 4;
The high-grade sport footwear of the described good permeability preparation method of fabric may further comprise the steps:
A) with diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 135-150 ℃ of lower the stirring 10-15 minute, then, lower the temperature 100-105 ℃, add other surplus stock, mixed at high speed 5-8 minute, then, under expect that mill carries out fitting to adhesive tape machine after fully mixing, the upper strata is attached on the base material;
B) product is processed through surface effect;
C) finished product inspection is qualified, dispatches from the factory.
Described modified clay powder makes by the following method:
Clay is put into 460-480 ℃ of lower calcining 4 hours, take out cooling, pulverize; Add again the aluminium nitride be equivalent to clay powders weight 5%, 3% sodium phosphate trimer, 2% Rosa Damascana, 3% morpholine, 3% di-n-octyl-4-isothiazoline-3-ketone, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 that is equivalent to clay powders weight 3%, 13000-16000 rev/min of lower the stirring 60-70 minute, and get final product.
Synthetic leather of the present invention detects: stretch breaking strength/broadwise stretch breaking strength radially〉435N/3CM, directly/and filling-tear resistance〉29N ,-10 ℃ of low temperature flexibility can reach anti-tortuous 30,000 times, and degradation does not ftracture.Good air permeability.
Claims (2)
1. the high-grade sport footwear fabric of a good permeability is characterized in that compoundly consisting of by two layers, and base material is cloth, and the upper strata is the polyvinyl chloride resin layer, and the upper strata is made by the raw material of following weight portion:
SG-4 type polyvinyl chloride resin 70-80, diisopropanolamine (DIPA) 1-2, morpholine 1-2, impact resistant polystyrene 4-5, dibutyl tin laurate 2-3, zinc oxide 2-3, magnesia 1-2, aluminium oxide 2-3, barium sulfate 5-7, MTES 2-3, vinyltriethoxysilane 1-2, triglycidyl isocyanurate 5-7, dibasic lead phosphite 1-2, diglycol benzoic ether 2-3, coumarone 1-2,2-ethylamino 17 alkenyl imidazoline 1-2, protein powder 10-12, polyvinyl alcohol 2-3, modified clay powder 3-4;
Described modified clay powder makes by the following method:
Clay is put into 460-480 ℃ of lower calcining 3-4 hour, take out cooling, pulverize; Add again the morpholine of Rosa Damascana, the 2-3% of sodium phosphate trimer, the 2-3% of the aluminium nitride be equivalent to clay powders weight 5-8%, 3-4%, the di-n-octyl of 3-4%-4-isothiazoline-3-ketone, mix and blend 30-40 minute, and then spray into the Silane coupling agent KH550 that is equivalent to clay powders weight 3-5%, 13000-16000 rev/min of lower the stirring 60-70 minute, and get final product.
2. the high-grade sport footwear of good permeability according to claim 1 is characterized in that may further comprise the steps with the preparation method of fabric:
A) with diisopropanolamine (DIPA), morpholine, impact resistant polystyrene, dibutyl tin laurate, zinc oxide, magnesia, aluminium oxide, barium sulfate, MTES, vinyltriethoxysilane, triglycidyl isocyanurate, dibasic lead phosphite, 135-150 ℃ of lower the stirring 10-15 minute, then, lower the temperature 100-105 ℃, add other surplus stock, mixed at high speed 5-8 minute, then, under expect that mill carries out fitting to adhesive tape machine after fully mixing, the upper strata is attached on the base material;
B) product is processed through surface effect;
C) finished product inspection is qualified, dispatches from the factory.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310276766.8A CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310276766.8A CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103352374A true CN103352374A (en) | 2013-10-16 |
| CN103352374B CN103352374B (en) | 2015-12-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310276766.8A Active CN103352374B (en) | 2013-07-03 | 2013-07-03 | High-grade sport footwear fabric of good permeability and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN103352374B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542344A (en) * | 2016-01-21 | 2016-05-04 | 苏州市景荣科技有限公司 | Bending-resistant air-permeable polyvinyl chloride vamp material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04304242A (en) * | 1991-03-29 | 1992-10-27 | Ajinomoto Co Inc | Resin composition and molding made therefrom |
| CN102002864A (en) * | 2010-12-24 | 2011-04-06 | 揭阳市中诚化学工业有限公司 | PVC synthetic leather for vamp of high-grade sneaker and production method thereof |
| CN102219967A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Modified polyvinyl chloride composite material and preparation process of modified polyvinyl chloride composite material |
| CN102995454A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Polyvinyl chloride synthetic leather for sports shoes and manufacturing method of polyvinyl chloride synthetic leather |
-
2013
- 2013-07-03 CN CN201310276766.8A patent/CN103352374B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04304242A (en) * | 1991-03-29 | 1992-10-27 | Ajinomoto Co Inc | Resin composition and molding made therefrom |
| CN102002864A (en) * | 2010-12-24 | 2011-04-06 | 揭阳市中诚化学工业有限公司 | PVC synthetic leather for vamp of high-grade sneaker and production method thereof |
| CN102219967A (en) * | 2011-06-07 | 2011-10-19 | 刘立文 | Modified polyvinyl chloride composite material and preparation process of modified polyvinyl chloride composite material |
| CN102995454A (en) * | 2012-10-23 | 2013-03-27 | 合肥市安山涂层织物有限公司 | Polyvinyl chloride synthetic leather for sports shoes and manufacturing method of polyvinyl chloride synthetic leather |
Non-Patent Citations (1)
| Title |
|---|
| 徐桂玲: "合成革在体育用品中的应用", 《中国皮革》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105542344A (en) * | 2016-01-21 | 2016-05-04 | 苏州市景荣科技有限公司 | Bending-resistant air-permeable polyvinyl chloride vamp material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103352374B (en) | 2015-12-09 |
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Effective date of registration: 20200107 Address after: 366300 Changting Tengfei Economic Development Zone, Changting County, Longyan, Fujian Patentee after: Fujian sky textile new material Co., Ltd. Address before: 237161 Qianjin Road, Lu'an economic and Technological Development Zone, Anhui Patentee before: Liuan Sanxi Leather Products Co., Ltd. |
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