CN103498271B - Pineapple fiber and anti-pilling acrylic fiber blended fabric - Google Patents

Pineapple fiber and anti-pilling acrylic fiber blended fabric Download PDF

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CN103498271B
CN103498271B CN201310425893.XA CN201310425893A CN103498271B CN 103498271 B CN103498271 B CN 103498271B CN 201310425893 A CN201310425893 A CN 201310425893A CN 103498271 B CN103498271 B CN 103498271B
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fiber
pineapple
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pilling acrylic
antibacterial
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CN103498271A (en
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袁娟
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Dongguan Rui Xin Garments Co Ltd
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Shanghai Wanjing Textile Technology Co Ltd
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Abstract

The invention discloses a blended fabric of pineapple fibers and anti-pilling acrylic fibers, which is formed by blending and weaving 20-40wt% of pineapple fibers and 60-80wt% of anti-pilling acrylic fibers. The invention mixes the pineapple fiber and the anti-pilling acrylic fiber with different properties together, makes up for the deficiencies of the two fibers, and has the advantages of soft and smooth fabric, bulkiness, easy dyeing, bright color, light resistance and moth resistance.

Description

菠萝纤维和抗起球腈纶混纺的面料Pineapple fiber and anti-pilling acrylic blend fabric

技术领域technical field

本发明涉及一种面料,尤其涉及一种菠萝纤维和抗起球腈纶混纺的面料。The invention relates to a fabric, in particular to a fabric blended with pineapple fiber and anti-pilling acrylic fiber.

背景技术Background technique

菠萝纤维即菠萝叶纤维,又称凤梨麻,是从菠萝叶片中提取的纤维,属于叶片麻类纤维。菠萝纤维由许多纤维束紧密结合而成,每个纤维束又由10-20根单纤维细胞集合组成。纤维表面粗糙,有纵向缝隙和孔洞,横向有枝节,无天然扭曲。单纤维细胞呈圆筒形,两端尖,表面光滑,有线状中腔。菠萝纤维外观洁白,柔软爽滑,手感如蚕丝,故又有菠萝丝的称谓。菠萝纤维经深加工处理后,外观洁白,柔软爽滑。具体原料可以是如祁门天安纺织服装有限公司提供的菠萝纤维。Pineapple fiber is pineapple leaf fiber, also known as pineapple hemp, which is a fiber extracted from pineapple leaves and belongs to leaf hemp fiber. Pineapple fiber is tightly combined by many fiber bundles, and each fiber bundle is composed of 10-20 single fiber cells. The fiber surface is rough, with longitudinal gaps and holes, and horizontal branches without natural distortion. The monofilament cells are cylindrical, with pointed ends, smooth surface, and a linear lumen. Pineapple fiber is white in appearance, soft and smooth, and feels like silk, so it is also called pineapple silk. After deep processing, the pineapple fiber has a white appearance, soft and smooth. The specific raw material can be the pineapple fiber provided by Qimen Tianan Textile and Garment Co., Ltd.

抗起球腈纶的性能极似羊毛,弹性较好,伸长20%时回弹率仍可保持65%,蓬松卷曲而柔软,保暖性比羊毛高15%,有合成羊毛之称。强度22.1-48.5cN/dtex,比羊毛高1-2.5倍,耐晒性能优良,露天曝晒一年,强度仅下降20%,具有柔软、膨松、易染、色泽鲜艳、耐光、抗菌、不怕虫蛀等优点。The performance of anti-pilling acrylic is very similar to that of wool. It has good elasticity. When it is stretched by 20%, the rebound rate can still maintain 65%. It is fluffy, curly and soft, and its warmth retention is 15% higher than that of wool. The strength is 22.1-48.5cN/dtex, which is 1-2.5 times higher than that of wool. It has excellent light fastness. After being exposed to the open air for one year, the strength will only decrease by 20%. moth and other advantages.

大多数合成纤维都存在着在使用过程中“起球”这一现象。由于腈纶的强力比天然纤维和再生纤维素纤维高得多,而且其制品表面上纤维球粒的形成速率大于脱落速率,因此在摩擦力无法消除纤维球粒的情况下,所形成的这些纤维球粒将会长期保留在织物表面,从而影响织物的外观和穿着舒适性。抗起球腈纶是运用物理改性方法,通过调整生产工艺来改变纤维结构性能,在确保良好的可纺性能前提下,使其织物达到了抗起球的效果。具体的抗起球腈纶可以选用中国石油天然气股份有限公司、吉林奇峰化纤股份有限公司、中国石化上海石油化工股份有限公司生产的抗起球腈纶,纤度0.8-2.2dtex,平均长度38mm,抗起球级数3.5-4。Most synthetic fibers suffer from the phenomenon of "pilling" during use. Since the strength of acrylic fiber is much higher than that of natural fibers and regenerated cellulose fibers, and the formation rate of fiber pellets on the surface of its products is greater than the rate of shedding, these fiber pellets formed when friction cannot eliminate the fiber pellets The particles will remain on the surface of the fabric for a long time, thus affecting the appearance and wearing comfort of the fabric. The anti-pilling acrylic fiber uses physical modification methods to change the fiber structure and properties by adjusting the production process. On the premise of ensuring good spinnability, the fabric achieves the effect of anti-pilling. The specific anti-pilling acrylic fibers can be selected from the anti-pilling acrylic fibers produced by China National Petroleum Corporation, Jilin Qifeng Chemical Fiber Co., Ltd., and Sinopec Shanghai Petrochemical Co., Ltd., with a fineness of 0.8-2.2dtex and an average length of 38mm. Series 3.5-4.

本发明试图通过提供一种新的混纺面料,将菠萝纤维与抗起球腈纶混纺。The present invention attempts to blend pineapple fiber with anti-pilling acrylic fibers by providing a new blended fabric.

发明内容Contents of the invention

针对现有技术的不足,本发明所要解决的技术问题是提供一种菠萝纤维和抗起球腈纶混纺的面料。Aiming at the deficiencies of the prior art, the technical problem to be solved by the present invention is to provide a fabric blended with pineapple fiber and anti-pilling acrylic fiber.

为解决上述技术问题,本发明通过以下技术方案来实现:In order to solve the problems of the technologies described above, the present invention is achieved through the following technical solutions:

一种菠萝纤维和抗起球腈纶混纺的面料,由20-40wt%菠萝纤维和60-80wt%抗起球腈纶混纺织造而成。The invention relates to a blended fabric of pineapple fiber and anti-pilling acrylic fiber, which is made of 20-40wt% pineapple fiber and 60-80wt% anti-pilling acrylic fiber blended fabric.

优选地,Preferably,

一种菠萝纤维和抗起球腈纶混纺的面料,由20-40wt%菠萝纤维和60-80wt%抗起球腈纶混纺织造而成,再经过抗菌后整理而成。The invention discloses a blended fabric of pineapple fiber and anti-pilling acrylic fiber, which is made of 20-40wt% pineapple fiber and 60-80wt% anti-pilling acrylic fiber, and then finished after antibacterial finishing.

所述抗菌后整理步骤为,常温下在抗菌整理液中浸渍10-30分钟,所述抗菌整理液中抗菌整理剂用量为0.5-1.5%o.w.f,浴比为1:15-1:25。The antibacterial finishing step is to immerse in the antibacterial finishing solution at room temperature for 10-30 minutes, the amount of antibacterial finishing agent in the antibacterial finishing solution is 0.5-1.5% o.w.f, and the bath ratio is 1:15-1:25.

所述抗菌整理剂,由如下重量份的组分组成:硫酸鱼精蛋白5-15份、2,4,4’-三氯-2’-羟基二苯醚50-70份、甲基椰油酰基牛磺酸钠5-15份、聚六亚甲基双胍盐酸盐15-25份。将上述各组分搅拌混合均匀,即可制得所述抗菌整理剂。The antibacterial finishing agent is composed of the following components by weight: 5-15 parts of protamine sulfate, 50-70 parts of 2,4,4'-trichloro-2'-hydroxydiphenyl ether, methyl coconut oil 5-15 parts of sodium acyl taurate, 15-25 parts of polyhexamethylene biguanide hydrochloride. The antibacterial finishing agent can be prepared by stirring and mixing the above-mentioned components evenly.

具体的,在本发明中:Specifically, in the present invention:

硫酸鱼精蛋白,拼音名:Liusuan Yujingdanbai,英文名:ProtamineSulfate,书页号:中国药典2005年版二部-742,本品系自适宜的鱼类新鲜成熟精子中提取的一种碱性蛋白质的硫酸盐。按干燥品计,为白色或类白色粉末,无臭,有吸湿性,易溶于水,不溶于乙醇、氯仿或乙醚中。Protamine sulfate, pinyin name: Liusuan Yujingdanbai, English name: ProtamineSulfate, page number: Chinese Pharmacopoeia 2005 Edition II-742, this strain is a kind of basic protein sulfate extracted from fresh mature sperm of suitable fish . Calculated as dry product, it is white or off-white powder, odorless, hygroscopic, soluble in water, insoluble in ethanol, chloroform or ether.

2,4,4’-三氯-2’-羟基二苯醚,别名:玉洁新、三氯生,缩写DP300,英文名:5-chloro-2-(2,4-dichlorophenoxy),CAS号:3380-34-5。2,4,4'-Trichloro-2'-hydroxydiphenyl ether, alias: Yujiexin, Triclosan, abbreviated as DP300, English name: 5-chloro-2-(2,4-dichlorophenoxy), CAS number : 3380-34-5.

甲基椰油酰基牛磺酸钠,CAS号:12765-39-8。Sodium Methyl Cocoyl Taurate, CAS No.: 12765-39-8.

聚六亚甲基双胍盐酸盐,英文名:Poly(hexamethylenebiguanide)hydrochloride,CAS登录号:32289-58-0。Polyhexamethylenebiguanide hydrochloride, English name: Poly(hexamethylenebiguanide) hydrochloride, CAS accession number: 32289-58-0.

o.w.f,全称为On weight the fabric,纺织染整用语,纺织染整工艺中浓度以织物重量为基准,相对织物百分比。o.w.f, the full name is On weight the fabric, a term for textile dyeing and finishing. The concentration in the textile dyeing and finishing process is based on the weight of the fabric, relative to the percentage of the fabric.

浴比,liquor ratio,纺织染整用语,指浸渍方式中织物与染液的比值。Bath ratio, liquor ratio, a term used in textile dyeing and finishing, refers to the ratio of fabric to dye liquor in the dipping method.

需要说明的是,在本发明中如无特别解释说明,各原料均以含量100%计。It should be noted that, unless otherwise specified in the present invention, the content of each raw material is 100%.

在本发明中,突破性地将常用于医药、食品行业的原料硫酸鱼精蛋白应用于纺织抗菌处理,进一步的,本发明中首次将硫酸鱼精蛋白与抗菌剂2,4,4’-三氯-2’-羟基二苯醚、聚六亚甲基双胍盐酸盐复配使用,并在表面活性剂甲基椰油酰基牛磺酸钠的协同下,抗菌效果明显增效。In the present invention, protamine sulfate, a raw material commonly used in medicine and food industry, is applied to textile antibacterial treatment. Further, in the present invention, protamine sulfate and antibacterial agent 2, 4, 4'-tri Chloro-2'-hydroxydiphenyl ether and polyhexamethylene biguanide hydrochloride are used in combination, and under the synergy of the surfactant methyl cocoyl taurate sodium, the antibacterial effect is significantly enhanced.

相对于现有技术,本发明技术方案的显著进步主要体现为:本发明将菠萝纤维和抗起球腈纶两种性能不同的纤维混合在一起,取长补短,面料柔软爽滑、膨松、易染、色泽鲜艳、耐光且不怕虫蛀。进一步的,通过抗菌后整理,面料抑菌率高,从而能够有效保护人体健康。Compared with the prior art, the significant progress of the technical solution of the present invention is mainly reflected in the following: the present invention mixes two fibers with different properties, pineapple fiber and anti-pilling acrylic fiber, learn from each other, and the fabric is soft, smooth, bulky, easy to dye, Bright color, light fast and not afraid of insects. Furthermore, through antibacterial finishing, the fabric has a high antibacterial rate, which can effectively protect human health.

具体实施方式Detailed ways

实施例1Example 1

选用市售的菠萝纤维和抗起球腈纶,质量比为30:70。Commercially available pineapple fiber and anti-pilling acrylic fiber are selected, and the mass ratio is 30:70.

将按上述配比称取的菠萝纤维开松预处理,在梳棉机上梳理成生条;将按上述配比称取的抗起球腈纶开松预处理,在梳棉机上梳理成生条;然后将菠萝纤维生条和抗起球腈纶生条在并条机上并合,制成熟条;在粗纱机上进行牵伸和加捻,最后在细纱机上进一步牵伸加捻,制成抗起球腈纶和菠萝纤维混纺纱。再将抗起球腈纶和菠萝纤维混纺纱采用大圆机纬编织造方法进行织造,最终制得菠萝纤维和抗起球腈纶混纺的面料。The pineapple fibers weighed according to the above ratio are opened and pretreated, and carded into raw sliver on the carding machine; the anti-pilling acrylic fibers weighed according to the above ratio are opened and pretreated, and carded into raw sliver on the carding machine; Then the pineapple fiber raw sliver and the anti-pilling acrylic raw sliver are combined on the drawing frame to make mature sliver; drafting and twisting are carried out on the roving frame, and finally further drafting and twisting are carried out on the spinning frame to make anti-pilling acrylic fiber and Pineapple fiber blend yarn. Then the anti-pilling acrylic fiber and pineapple fiber blended yarn is woven by a large circular machine weft knitting method, and finally the pineapple fiber and anti-pilling acrylic fiber blended fabric is obtained.

显然,上述的混纺纱及面料的制备工艺均为本行业的通用方法,为本领域普通技术人员所熟知。Obviously, the above-mentioned preparation techniques of blended yarns and fabrics are common methods in this industry and are well known to those skilled in the art.

实施例2Example 2

取部分实施例1所制得的菠萝纤维和抗起球腈纶混纺的面料,进一步进行抗菌后整理,具体步骤为:Get the fabric of pineapple fiber and the anti-pilling acrylic fiber blending that part embodiment 1 makes, further carry out antibacterial post-finishing, concrete steps are:

(1)抗菌整理剂的配置:(1) Configuration of antibacterial finishing agent:

按表1中实施例2对应的数据称取各原料,搅拌混合均匀,制得抗菌整理剂。According to the data corresponding to Example 2 in Table 1, each raw material was weighed, stirred and mixed evenly, and an antibacterial finishing agent was obtained.

(2)浸渍:(2) Dipping:

将抗菌整理剂溶解在水中,制得抗菌整理液;Dissolving the antibacterial finishing agent in water to prepare an antibacterial finishing solution;

再将菠萝纤维和抗起球腈纶混纺的面料常温(18-25℃)下在抗菌整理液中浸渍20分钟,所述抗菌整理液中抗菌整理剂用量为1.0%o.w.f,浴比为1:20。Then immerse the blended fabric of pineapple fiber and anti-pilling acrylic fiber in the antibacterial finishing solution for 20 minutes at room temperature (18-25°C). .

(3)脱水;(3) Dehydration;

(4)烘干:在100℃温度下将织物烘干。(4) Drying: Dry the fabric at 100°C.

即可制得本发明的抗菌后处理之后的菠萝纤维和抗起球腈纶混纺的面料。The fabric of pineapple fiber and anti-pilling acrylic fiber blended after the antibacterial post-treatment can be obtained.

实施例3Example 3

制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例3对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 3 in Table 1 was used to prepare the antibacterial finishing agent.

实施例4Example 4

制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例4对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 4 in Table 1 was used to prepare the antibacterial finishing agent.

实施例5Example 5

制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例5对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 5 in Table 1 was used to prepare the antibacterial finishing agent.

实施例6Example 6

制备方法与实施例2基本相同,唯一的区别在于选用的抗菌整理剂不同,抗菌整理剂用量相同均为1.0%o.w.f。本实施例采用表1中实施例6对应的数据来制备抗菌整理剂。The preparation method is basically the same as that of Example 2, the only difference is that the antibacterial finishing agent used is different, and the dosage of the antibacterial finishing agent is the same as 1.0% o.w.f. In this example, the data corresponding to Example 6 in Table 1 was used to prepare the antibacterial finishing agent.

表1:抗菌整理剂配方表单位:公斤Table 1: Antibacterial finishing agent formula table Unit: kg

实施例2Example 2 实施例3Example 3 实施例4Example 4 实施例5Example 5 实施例6Example 6 硫酸鱼精蛋白protamine sulfate 1010 // 2020 1010 1010 2,4,4’-三氯-2’-羟基二苯醚2,4,4'-Trichloro-2'-hydroxydiphenyl ether 6060 6060 6060 8080 // 甲基椰油酰基牛磺酸钠Sodium Methyl Cocoyl Taurate 1010 2020 // 1010 1010 聚六亚甲基双胍盐酸盐Polyhexamethylene biguanide hydrochloride 2020 2020 2020 // 8080

测试例1test case 1

采用国家标准GB/T20944.3-2008《纺织品抗菌性能的评价第3部分:振荡法》进行抗菌性定量测试,采用耐洗色牢度试验机洗涤方法,测试水洗30次后的织物,测试结果见表2。The national standard GB/T20944.3-2008 "Evaluation of Antibacterial Properties of Textiles Part 3: Oscillating Method" was used for quantitative testing of antibacterial properties, and the washing method of washing color fastness test machine was used to test the fabric after washing 30 times. The test results See Table 2.

表2:水洗30次后抑菌率测试表Table 2: Antibacterial rate test table after washing 30 times

洗涤次数,次times of washing 抑菌率(大肠杆菌),%Bacterial inhibition rate (Escherichia coli), % 抑菌率(白色念珠菌),%Bacterial inhibition rate (Candida albicans), % 实施例2Example 2 3030 8181 8080 实施例3Example 3 3030 7272 6969 实施例4Example 4 3030 7272 7070 实施例5Example 5 3030 5959 6161 实施例6Example 6 3030 6565 6868

Claims (1)

1. a fabric for pina fibre and Antipilling nitrilon blending, is characterized in that: formed by 20-40wt% pina fibre and 60-80wt% Antipilling nitrilon hybrid woven, then form through anti-bacterial finish;
Described anti-bacterial finish step is in antibiotic finishing solution, flood 10-30 minute under normal temperature, and in described antibiotic finishing solution, antibacterial finishing agent consumption is 0.5-1.5%o.w.f, and bath raio is 1:15-1:25;
Described antibacterial finishing agent, is made up of the component of following weight portion: protamine sulfate 5-15 part, Irgacare MP 50-70 part, sodium methyl cocoyl taurate 5-15 part, hexamethylene 15-25 part.
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CN105690903B (en) * 2015-12-30 2018-09-25 江阴市长泾花园毛纺织有限公司 A kind of soybean fiber blended yarn weaved fabric of antistatic wet-heat resisting
CN108914289A (en) * 2018-07-27 2018-11-30 苏州皖丰纺织有限公司 It is a kind of with the not mould acrylic item that do not eat into
CN120250345A (en) * 2025-04-24 2025-07-04 山东东浩纺织科技有限公司 Plant antibacterial and deodorizing fabric and preparation process thereof

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