CN103614024B - A kind of antibiotic waterproof coating - Google Patents
A kind of antibiotic waterproof coating Download PDFInfo
- Publication number
- CN103614024B CN103614024B CN201310517161.3A CN201310517161A CN103614024B CN 103614024 B CN103614024 B CN 103614024B CN 201310517161 A CN201310517161 A CN 201310517161A CN 103614024 B CN103614024 B CN 103614024B
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- Prior art keywords
- add
- raw material
- waterproof coating
- adhesive aid
- minute
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- Expired - Fee Related
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- 239000011248 coating agent Substances 0.000 title claims abstract description 15
- 238000000576 coating method Methods 0.000 title claims abstract description 15
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 14
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000853 adhesive Substances 0.000 claims abstract description 13
- 230000001070 adhesive effect Effects 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 7
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 7
- 239000010455 vermiculite Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 4
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 claims abstract description 4
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims abstract description 4
- 239000004317 sodium nitrate Substances 0.000 claims abstract description 4
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 4
- 229940070527 tourmaline Drugs 0.000 claims abstract description 4
- 239000011032 tourmaline Substances 0.000 claims abstract description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000003242 anti bacterial agent Substances 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 5
- 239000005871 repellent Substances 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 2
- 241000195493 Cryptophyta Species 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 235000015170 shellfish Nutrition 0.000 abstract description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of antibiotic waterproof coating, it is made up of the raw material of following weight parts: aqueous acrylic emulsion 70-80, dipropylene glycol 1-2, SA 1-2, MEA 1-2, sodium nitrate 1-2, dimethyl methyl phosphonate 2-3, tourmaline powder 1-2, lithium carbonate 1-2, cupric oxide 1-2, zinc oxide 1-2, vermiculite power 15-20, phenethyl phenol polyethenoxy ether 0.6-1, adhesive aid 6-10, deionized water 5-20, water-repellent paint bacteria resistance of the present invention is good, can stop marine organisms as shellfish, algae adheres to, therefore go for harbour or nearly water material, good waterproof performance, biological resistance is strong.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of antibiotic waterproof coating.
Background technology
Brushing, on building surface, forms thin film through the volatilization of solvent or moisture or the chemical reaction of two kinds of components, makes building surface and water isolated, thereby plays the effect of waterproof, sealing, and the thick liquid of these brushings is called water-repellent paint. The waterproofing membrane that water-repellent paint forms after solidifying has certain extensibility, elastoplasticity, crack resistance, impermeability and weatherability, can play waterproof, prevent blending protective effect. Water-repellent paint has good thermal adaptability, easy and simple to handle, for ease of maintenaince with maintenance.
Summary of the invention
The object of the invention is just to provide a kind of antibiotic waterproof coating.
The present invention is achieved by the following technical solutions:
A kind of antibiotic waterproof coating, it is made up of the raw material of following weight parts:
Aqueous acrylic emulsion 70-80, dipropylene glycol 1-2, SA 1-2, MEA 1-2, sodium nitrate 1-2, dimethyl methyl phosphonate 2-3, tourmaline powder 1-2, lithium carbonate 1-2, cupric oxide 1-2, zinc oxide 1-2, vermiculite power 15-20, phenethyl phenol polyethenoxy ether 0.6-1, adhesive aid 6-10, deionized water 5-20;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-45, aluminium isopropoxide 3-5, polyamide wax micropowder 3-4, silane resin acceptor kh-550 1-2, stearic acid monoglyceride 2-4, urea 2-3, nano-sized carbon 0.1-1;
Above-mentioned aluminium isopropoxide is heated to 130-135 DEG C, add polyamide wax micropowder, granulation after ball milling, mixes urea with stearic acid monoglyceride, stirring reaction 10-15 minute at 100-120 DEG C, be cooled to normal temperature, add silane resin acceptor kh-550, nano-sized carbon, 200-300 rev/min of dispersed with stirring 3-4 minute, mixes with particle obtained above and the each raw material of residue, fully ball milling, obtains described adhesive aid.
A preparation method for antibiotic waterproof coating, comprises the following steps:
Above-mentioned cupric oxide, zinc oxide, vermiculite power are mixed, add the deionized water of dipropylene glycol and above-mentioned weight 50-60%, 200-300 rev/min of dispersed with stirring 4-6 minute, add adhesive aid, fully mix and add the each raw material of residue, high-speed stirred, to mixing, obtains described antibiotic waterproof coating.
Advantage of the present invention is:
Water-repellent paint bacteria resistance of the present invention is good, can stop marine organisms as shellfish, algae adhere to, and therefore goes for harbour or nearly water material, good waterproof performance, and biological resistance is strong.
Detailed description of the invention
Embodiment 1
A kind of antibiotic waterproof coating, it by following weight parts (kilogram) raw material form:
Aqueous acrylic emulsion 80, dipropylene glycol 2, SA 2, MEA 2, sodium nitrate 1, dimethyl methyl phosphonate 2, tourmaline powder 2, lithium carbonate 2, cupric oxide 1, zinc oxide 1, vermiculite power 20, phenethyl phenol polyethenoxy ether 0.6, adhesive aid 6-10, deionized water 5-20;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 45, aluminium isopropoxide 5, polyamide wax micropowder 4, silane resin acceptor kh-550 1, stearic acid monoglyceride 2-4, urea 2, nano-sized carbon 0.1;
Above-mentioned aluminium isopropoxide is heated to 135 DEG C, add polyamide wax micropowder, granulation after ball milling, mixes urea with stearic acid monoglyceride, stirring reaction 15 minutes at 120 DEG C, be cooled to normal temperature, add silane resin acceptor kh-550, nano-sized carbon, 300 revs/min of dispersed with stirring 4 minutes, mix with particle obtained above and the each raw material of residue, fully ball milling, obtains described adhesive aid.
A preparation method for antibiotic waterproof coating, comprises the following steps:
Above-mentioned cupric oxide, zinc oxide, vermiculite power are mixed, add the deionized water of dipropylene glycol and above-mentioned weight 60%, 300 revs/min of dispersed with stirring 6 minutes, add adhesive aid, fully mix and add the each raw material of residue, high-speed stirred, to mixing, obtains described antibiotic waterproof coating.
Performance test:
Tensile strength: >=1.5MPa;
Percentage elongation: >=300%;
Not saturating: 0.3MPa (hour waterproof).
Claims (2)
1. an antibiotic waterproof coating, is characterized in that what it was made up of the raw material of following weight parts:
Aqueous acrylic emulsion 70-80, dipropylene glycol 1-2, SA 1-2, MEA 1-2, sodium nitrate 1-2, dimethyl methyl phosphonate 2-3, tourmaline powder 1-2, lithium carbonate 1-2, cupric oxide 1-2, zinc oxide 1-2, vermiculite power 15-20, phenethyl phenol polyethenoxy ether 0.6-1, adhesive aid 6-10, deionized water 5-20;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-45, aluminium isopropoxide 3-5, polyamide wax micropowder 3-4, silane resin acceptor kh-550 1-2, stearic acid monoglyceride 2-4, urea 2-3, nano-sized carbon 0.1-1;
Above-mentioned aluminium isopropoxide is heated to 130-135 DEG C, add polyamide wax micropowder, granulation after ball milling, mixes urea with stearic acid monoglyceride, stirring reaction 10-15 minute at 100-120 DEG C, be cooled to normal temperature, add silane resin acceptor kh-550, nano-sized carbon, 200-300 rev/min of dispersed with stirring 3-4 minute, mixes with particle obtained above and the each raw material of residue, fully ball milling, obtains described adhesive aid.
2. a preparation method for antibiotic waterproof coating as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned cupric oxide, zinc oxide, vermiculite power are mixed, add the deionized water of dipropylene glycol and above-mentioned weight 50-60%, 200-300 rev/min of dispersed with stirring 4-6 minute, add adhesive aid, fully mix and add the each raw material of residue, high-speed stirred, to mixing, obtains described antibiotic waterproof coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310517161.3A CN103614024B (en) | 2013-10-28 | 2013-10-28 | A kind of antibiotic waterproof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310517161.3A CN103614024B (en) | 2013-10-28 | 2013-10-28 | A kind of antibiotic waterproof coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103614024A CN103614024A (en) | 2014-03-05 |
| CN103614024B true CN103614024B (en) | 2016-05-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310517161.3A Expired - Fee Related CN103614024B (en) | 2013-10-28 | 2013-10-28 | A kind of antibiotic waterproof coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN103614024B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293038A (en) * | 2014-09-26 | 2015-01-21 | 锐展(铜陵)科技有限公司 | Hard-type acrylic waterproof coating for automotive |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1524909A (en) * | 2003-02-25 | 2004-09-01 | 四川省德圣科技发展有限公司 | Nanometer heat insulation reflecting coatings for grain-oil packhouse |
| CN1931936A (en) * | 2006-10-24 | 2007-03-21 | 栗忠原 | Fuctional paint composition and its production process |
| CN101709190A (en) * | 2009-12-07 | 2010-05-19 | 吴尚泉 | Far infrared interior wall painting |
| CN101974270A (en) * | 2010-11-03 | 2011-02-16 | 苏州中驰环境科技发展有限公司 | Antibiotic waterproof coating |
| CN102504662A (en) * | 2011-11-23 | 2012-06-20 | 杨震源 | Anion coating material and preparation method thereof |
-
2013
- 2013-10-28 CN CN201310517161.3A patent/CN103614024B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1524909A (en) * | 2003-02-25 | 2004-09-01 | 四川省德圣科技发展有限公司 | Nanometer heat insulation reflecting coatings for grain-oil packhouse |
| CN1931936A (en) * | 2006-10-24 | 2007-03-21 | 栗忠原 | Fuctional paint composition and its production process |
| CN101709190A (en) * | 2009-12-07 | 2010-05-19 | 吴尚泉 | Far infrared interior wall painting |
| CN101974270A (en) * | 2010-11-03 | 2011-02-16 | 苏州中驰环境科技发展有限公司 | Antibiotic waterproof coating |
| CN102504662A (en) * | 2011-11-23 | 2012-06-20 | 杨震源 | Anion coating material and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN103614024A (en) | 2014-03-05 |
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| Date | Code | Title | Description |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Jiang Hongbing Inventor before: Zhu Xingtang Inventor before: Zhu Liangliang Inventor before: Chen Junyan |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171214 Address after: Suining County in Jiangsu province 221200 Xuzhou peach chemical garden Zhu Guan Lu No. 58 Patentee after: Xuzhou East macro Chemical Co., Ltd. Address before: 233010 Bengbu high tech Development Zone, Anhui Province Road No. 555 Patentee before: Bengbu Times Electronics Co., Ltd. |
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| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160525 Termination date: 20181028 |
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| CF01 | Termination of patent right due to non-payment of annual fee |