CN103649036A - 通过使二氧化碳与氢气反应制备甲酸的方法 - Google Patents

通过使二氧化碳与氢气反应制备甲酸的方法 Download PDF

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Publication number
CN103649036A
CN103649036A CN201280033657.7A CN201280033657A CN103649036A CN 103649036 A CN103649036 A CN 103649036A CN 201280033657 A CN201280033657 A CN 201280033657A CN 103649036 A CN103649036 A CN 103649036A
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China
Prior art keywords
phase
formic acid
mixture
tertiary amine
lower phase
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Pending
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CN201280033657.7A
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English (en)
Chinese (zh)
Inventor
T·绍布
D·M·弗莱斯
R·帕切洛
P·巴斯勒
M·舍费尔
S·里廷格
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BASF SE
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BASF SE
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Publication of CN103649036A publication Critical patent/CN103649036A/zh
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201280033657.7A 2011-07-07 2012-06-27 通过使二氧化碳与氢气反应制备甲酸的方法 Pending CN103649036A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP11173130.3 2011-07-07
EP11173130 2011-07-07
PCT/EP2012/062518 WO2013004577A1 (de) 2011-07-07 2012-06-27 Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff

Publications (1)

Publication Number Publication Date
CN103649036A true CN103649036A (zh) 2014-03-19

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ID=46397263

Family Applications (1)

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CN201280033657.7A Pending CN103649036A (zh) 2011-07-07 2012-06-27 通过使二氧化碳与氢气反应制备甲酸的方法

Country Status (9)

Country Link
EP (1) EP2729438A1 (de)
JP (1) JP2014522823A (de)
KR (1) KR20140044891A (de)
CN (1) CN103649036A (de)
BR (1) BR112013033528A2 (de)
CA (1) CA2838907A1 (de)
RU (1) RU2014104137A (de)
WO (1) WO2013004577A1 (de)
ZA (1) ZA201400863B (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019096190A1 (en) * 2017-11-15 2019-05-23 Solvay Sa Process for producing formic acid
CN117138775A (zh) * 2023-07-24 2023-12-01 昆明贵金属研究所 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8946462B2 (en) 2011-11-10 2015-02-03 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US9428438B2 (en) 2012-11-27 2016-08-30 Basf Se Process for preparing formic acid
EP4089177A1 (de) 2021-05-14 2022-11-16 Cebal - Centro De Biotecnologia Agrícola E Agro-Alimentar Do Alentejo Verfahren zur herstellung von ameisensäure unter verwendung von e.-coli-stämmen
WO2026052664A1 (en) * 2024-09-03 2026-03-12 Basf Se A process for the inhibition of alcohol dehydrogenation to aldehydes

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0329337A2 (de) * 1988-02-17 1989-08-23 BP Chemicals Limited Herstellung von Ameisensäure aus einer Stickstoffbase, Kohlendioxyd und Wasserstoff
US20100331573A1 (en) * 2009-06-26 2010-12-30 Basf Se Process for preparing formic acid

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
GB8307611D0 (en) 1983-03-18 1983-04-27 Bp Chem Int Ltd Formic acid
GB8401005D0 (en) 1984-01-14 1984-02-15 Bp Chem Int Ltd Formate salts
GB8424672D0 (en) * 1984-09-29 1984-11-07 Bp Chem Int Ltd Production of formic acid
DE68920933T2 (de) * 1988-08-20 1995-05-24 Bp Chem Int Ltd Produktion von Formiat-Salzen von Stickstoffbasen.
DE102004040789A1 (de) 2004-08-23 2006-03-02 Basf Ag Verfahren zur Herstellung von Ameisensäure
CA2681508A1 (en) * 2007-03-23 2008-10-02 Basf Se Process for preparing formic acid
CN102574762B (zh) 2009-06-26 2014-08-13 巴斯夫欧洲公司 生产甲酸的方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0329337A2 (de) * 1988-02-17 1989-08-23 BP Chemicals Limited Herstellung von Ameisensäure aus einer Stickstoffbase, Kohlendioxyd und Wasserstoff
US20100331573A1 (en) * 2009-06-26 2010-12-30 Basf Se Process for preparing formic acid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019096190A1 (en) * 2017-11-15 2019-05-23 Solvay Sa Process for producing formic acid
CN117138775A (zh) * 2023-07-24 2023-12-01 昆明贵金属研究所 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系
CN117138775B (zh) * 2023-07-24 2024-04-30 昆明贵金属研究所 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系

Also Published As

Publication number Publication date
CA2838907A1 (en) 2013-01-10
ZA201400863B (en) 2015-12-23
RU2014104137A (ru) 2015-08-20
KR20140044891A (ko) 2014-04-15
EP2729438A1 (de) 2014-05-14
WO2013004577A1 (de) 2013-01-10
BR112013033528A2 (pt) 2017-02-07
JP2014522823A (ja) 2014-09-08

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