ZA201400863B - Process for the preparation of formic acid by reacting carbon dioxide with hydrogen - Google Patents
Process for the preparation of formic acid by reacting carbon dioxide with hydrogenInfo
- Publication number
- ZA201400863B ZA201400863B ZA2014/00863A ZA201400863A ZA201400863B ZA 201400863 B ZA201400863 B ZA 201400863B ZA 2014/00863 A ZA2014/00863 A ZA 2014/00863A ZA 201400863 A ZA201400863 A ZA 201400863A ZA 201400863 B ZA201400863 B ZA 201400863B
- Authority
- ZA
- South Africa
- Prior art keywords
- hydrogen
- preparation
- carbon dioxide
- formic acid
- reacting carbon
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 title 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 239000001569 carbon dioxide Substances 0.000 title 1
- 229910002092 carbon dioxide Inorganic materials 0.000 title 1
- 235000019253 formic acid Nutrition 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 title 1
- 239000001257 hydrogen Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
- B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/96—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11173130 | 2011-07-07 | ||
| PCT/EP2012/062518 WO2013004577A1 (de) | 2011-07-07 | 2012-06-27 | Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA201400863B true ZA201400863B (en) | 2015-12-23 |
Family
ID=46397263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA2014/00863A ZA201400863B (en) | 2011-07-07 | 2014-02-05 | Process for the preparation of formic acid by reacting carbon dioxide with hydrogen |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP2729438A1 (de) |
| JP (1) | JP2014522823A (de) |
| KR (1) | KR20140044891A (de) |
| CN (1) | CN103649036A (de) |
| BR (1) | BR112013033528A2 (de) |
| CA (1) | CA2838907A1 (de) |
| RU (1) | RU2014104137A (de) |
| WO (1) | WO2013004577A1 (de) |
| ZA (1) | ZA201400863B (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8946462B2 (en) | 2011-11-10 | 2015-02-03 | Basf Se | Process for preparing formic acid by reaction of carbon dioxide with hydrogen |
| US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
| CN111315716B (zh) * | 2017-11-15 | 2023-04-14 | 索尔维公司 | 用于生产甲酸的方法 |
| EP4089177A1 (de) | 2021-05-14 | 2022-11-16 | Cebal - Centro De Biotecnologia Agrícola E Agro-Alimentar Do Alentejo | Verfahren zur herstellung von ameisensäure unter verwendung von e.-coli-stämmen |
| CN117138775B (zh) * | 2023-07-24 | 2024-04-30 | 昆明贵金属研究所 | 一种无碱条件下催化二氧化碳加氢制甲酸的催化体系 |
| WO2026052664A1 (en) * | 2024-09-03 | 2026-03-12 | Basf Se | A process for the inhibition of alcohol dehydrogenation to aldehydes |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4474959A (en) | 1982-05-22 | 1984-10-02 | Bp Chemicals Limited | Production of formate salts from carbon dioxide, hydrogen and amines |
| GB8307611D0 (en) | 1983-03-18 | 1983-04-27 | Bp Chem Int Ltd | Formic acid |
| GB8401005D0 (en) | 1984-01-14 | 1984-02-15 | Bp Chem Int Ltd | Formate salts |
| GB8424672D0 (en) * | 1984-09-29 | 1984-11-07 | Bp Chem Int Ltd | Production of formic acid |
| NZ227890A (en) * | 1988-02-17 | 1992-02-25 | Bp Chemical Ltd | Production of formic acid from a nitrogenous base, carbon dioxide and hydrogen |
| DE68920933T2 (de) * | 1988-08-20 | 1995-05-24 | Bp Chem Int Ltd | Produktion von Formiat-Salzen von Stickstoffbasen. |
| DE102004040789A1 (de) | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
| CA2681508A1 (en) * | 2007-03-23 | 2008-10-02 | Basf Se | Process for preparing formic acid |
| UA104324C2 (ru) * | 2009-06-26 | 2014-01-27 | Басф Се | Способ получения муравьиной кислоты |
| CN102574762B (zh) | 2009-06-26 | 2014-08-13 | 巴斯夫欧洲公司 | 生产甲酸的方法 |
-
2012
- 2012-06-27 KR KR1020147002909A patent/KR20140044891A/ko not_active Withdrawn
- 2012-06-27 CA CA2838907A patent/CA2838907A1/en not_active Abandoned
- 2012-06-27 EP EP12730532.4A patent/EP2729438A1/de not_active Withdrawn
- 2012-06-27 BR BR112013033528A patent/BR112013033528A2/pt not_active IP Right Cessation
- 2012-06-27 RU RU2014104137/04A patent/RU2014104137A/ru not_active Application Discontinuation
- 2012-06-27 CN CN201280033657.7A patent/CN103649036A/zh active Pending
- 2012-06-27 JP JP2014517690A patent/JP2014522823A/ja active Pending
- 2012-06-27 WO PCT/EP2012/062518 patent/WO2013004577A1/de not_active Ceased
-
2014
- 2014-02-05 ZA ZA2014/00863A patent/ZA201400863B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2838907A1 (en) | 2013-01-10 |
| RU2014104137A (ru) | 2015-08-20 |
| KR20140044891A (ko) | 2014-04-15 |
| CN103649036A (zh) | 2014-03-19 |
| EP2729438A1 (de) | 2014-05-14 |
| WO2013004577A1 (de) | 2013-01-10 |
| BR112013033528A2 (pt) | 2017-02-07 |
| JP2014522823A (ja) | 2014-09-08 |
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