CN103805010B - A kind of release rust special anticorrosive coating - Google Patents
A kind of release rust special anticorrosive coating Download PDFInfo
- Publication number
- CN103805010B CN103805010B CN201410038629.5A CN201410038629A CN103805010B CN 103805010 B CN103805010 B CN 103805010B CN 201410038629 A CN201410038629 A CN 201410038629A CN 103805010 B CN103805010 B CN 103805010B
- Authority
- CN
- China
- Prior art keywords
- parts
- rust
- coating
- anticorrosive coating
- mixing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000011248 coating agent Substances 0.000 title claims abstract description 39
- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 238000002156 mixing Methods 0.000 claims abstract description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000000049 pigment Substances 0.000 claims abstract description 22
- 239000004593 Epoxy Substances 0.000 claims abstract description 17
- 239000012046 mixed solvent Substances 0.000 claims abstract description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000013530 defoamer Substances 0.000 claims abstract description 14
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 18
- 239000003921 oil Substances 0.000 claims description 14
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 12
- 238000003801 milling Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 6
- 229940106691 bisphenol a Drugs 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 6
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 5
- 238000011049 filling Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000002349 favourable effect Effects 0.000 abstract description 2
- 230000003405 preventing effect Effects 0.000 abstract description 2
- 239000003973 paint Substances 0.000 description 16
- 229960005191 ferric oxide Drugs 0.000 description 7
- 238000001514 detection method Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000011268 mixed slurry Substances 0.000 description 3
- 238000011017 operating method Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- -1 ion salt Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000001062 red colorant Substances 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of release rust special anticorrosive coating, this coating is mixed by the component of following weight portion: acrylic resin 15～35 parts, epoxy saturated resin 10～25 parts, mixing rust resisting pigment 35～50 parts, defoamer 0.1～1.0 parts, mixed solvent 10～20 parts, levelling oil resistance agent 0.1～1.0 parts and anti-heavy agent 0.1～1.0 parts；Wherein said mixing rust resisting pigment is to be mixed by 190 iron oxide reds, zinc oxide, super-fine zinc dust, filling material barium sulfate and zinc yellow.The release rust special anticorrosive coating that the present invention provides, not only there is the advantages such as density is high, hardness is good, wearability is strong, anti-impact force is big, also it is avoided that contacting and absorption of new ferrum and outside moisture and oxygen, can fundamentally stop secondary to get rusty the generation of phenomenon, the most also there is easy construction, the advantage such as anticorrosion, favorable rust preventing effect.
Description
Technical field
The invention belongs to chemistry painting industry, paint field, be specifically related to one and be applied to power transformer industry
Release rust special anticorrosive coating.
Background technology
In the industry fields such as machinery, electric power, its metalwork generally uses paint to carry out surface protection,
Its paint mode is: initially with metallic anti-rust paint as prime, then selects not further according to demand
Brush with the finish paint of color.Conventional operational approach is: first metal surface is carried out pretreatment, adopts
With to the floating rust on metal surface or oxide layer through overpickling, phosphatization or sandblasting, then the rust cleaning being polished
Mode, carries out using antirust paint brushing to process the most again, repastes brush finish paint after parching.Its shortcoming is,
This Rustproof process intercepts the reaction of the moisture in air and oxygen just with coating, thus reaches anti-
The purpose that only secondary gets rusty.But in fact the floating rust of metal surface is to remove, and oxide layer just cannot
Remove, finally can many on matallic surface layer I haven't seen you for ages leaves nubbin.This is namely the most conventional to gold
After belonging to part employing antirust paint, easily cause the basic reason place of secondary rust.
At present, domestic either machinery industry, power equipment industry, or the industry such as railway, military project,
From the point of view of using general antirust paint effect, the most antirust effective period is short, and maintenance cost is high, 2-3
Also needing to carry out secondary after Nian antirust, particularly when the antirust brushing of secondary, produced acid washing phosphorization liquid also can
Surrounding is brought severe contamination.Therefore in the urgent need to promoting paint of coating industry by technological innovation
Development, adopts new technology, and new formula changes the traditional rust cleaning of metal current part and anticorrosion present situation.
Summary of the invention
It is an object of the invention in existing metalwork surface derusting, preservative treatment, for prior art
Not enough and provide before a kind of favorable rust preventing effect, easy construction, brushing construction without doing processing of rust removing, simultaneously
Also having acidproof, alkaline-resisting, a kind of of oil resistant characteristic exempts rust special anticorrosive coating and preparation method thereof.
The present invention can be reached by following technique and technical scheme:
A kind of release rust special anticorrosive coating, this coating is mixed by the component of following weight portion: propylene
Acid resin 15～35 parts, epoxy saturated resin 10～25 parts, mixing rust resisting pigment 35～50 parts, auxiliary agent
(defoamer) 0.1～1.0 part, mixed solvent 10～20 parts, levelling oil resistance agent 0.1～1.0 parts and anti-heavy
Agent 0.1～1.0 parts；Wherein said mixing rust resisting pigment is by 190 iron oxide reds, zinc oxide, ultra-fine zinc
Powder, filling material barium sulfate and zinc yellow mix.
Optimization formula is, the weight of each component of this coating is: acrylic resin 21～29 parts, ring
Oxygen saturation resin 14～19 parts, mixing rust resisting pigment 39～43 parts, defoamer 0.3～0.4 part, mixing
Solvent 15～16 parts, levelling oil resistance agent 0.5～0.6 part, anti-heavy agent 0.6～0.7 part.
In the present invention mixing each component of rust resisting pigment weight/mass percentage composition be: 190 iron oxide reds 30～
45%, zinc oxide 10～20%, super-fine zinc dust 20～30%, filling material 5～15%, zinc yellow 10～
20%(each component sum is 100%).Preferably, the weight/mass percentage composition of each component of rust resisting pigment is mixed
For: 190 iron oxide reds 35～41%, zinc oxide 11～15%, super-fine zinc dust 22～28%, filling material
8～12%, each component sum of zinc yellow 12～16%(is 100%).The preparation process of mixing rust resisting pigment
As follows, successively zinc oxide, 190 iron oxide reds, super-fine zinc dust, inserts and zinc yellow are carried out fully
Stir, finally cross 60 mesh fineness and sieve and get final product.
Wherein the particle diameter of zinc oxide is preferably 100 mesh, and described filling material is barium sulfate.The grain of super-fine zinc dust
Footpath scope 60-80 mesh." 190 iron oxide red " that the present invention uses, in rose-red powder, is usually used in system
Make, paint, coating industry, molecular formula: Fe2O3, molecular weight: 159.60.
The present invention can directly use existing various epoxy saturated resin to carry out, it is preferred that adopts in the present invention
Epoxy saturated resin be by bisphenol-A and epoxy six propane height of pyrocondensation under soda effect
Polymers, wherein setting-up point is 180～230 DEG C, and in pyrocondensation reaction, the mass parts of each raw material is joined
Ratio is: bisphenol-A 65～75 parts, epoxychloropropane 20～55 parts, soda 5～15 parts.This epoxy is satisfied
With the mean molecule quantity of resin is between 2000～7000.
Mixed solvent in the present invention is to be mixed by toluene, butanol, butyl ether and cyclohexanone.Concrete,
In mixed solvent, the mass content of each component is: toluene 65～70%, butanol 10～15%, butyl ether 8～
12%, each component sum of cyclohexanone 4～12%(is 100%).
Defoamer in the present invention is selected from organic silicon defoamer, and described levelling oil resistance agent is selected from SP-500 levelling
Oil resistance agent, described anti-heavy agent is selected from the anti-heavy agent of F118 coating.
Release rust special anticorrosive coating in the present invention is specifically prepared from by following steps:
(1) first mixing rust resisting pigment is joined in mixed solvent and soak, be simultaneously introduced defoamer；
(2) question response adds acrylic resin after 1-2 hour, epoxy saturated resin carries out high speed dispersion
Mixing；
(3) dispersion and full and uniform after carry out sand milling PROCESS FOR TREATMENT again, and fineness is controlled 60um with
In；
(4) last levelling oil resistance agent and anti-heavy agent are sufficiently stirred for, the viscosity of coating is adjusted to 86～
Between 92.
(5) by the made release got ready become rusty special anticorrosive coating, by national standard detection qualified after be packaged into
Storehouse.
The present invention is mixed with other raw material by epoxy saturated resin, mixing rust resisting pigment and mixed aid
Reaction is made, and it is excellent that the paint being prepared as has that density is high, hardness is good, wearability is strong, anti-impact force is big etc.
Point, moreover it is possible to avoid contacting and absorption of new ferrum and outside moisture and oxygen, fundamentally stopped two secondary
The generation of rust phenomenon.
Use release rust special anticorrosive coating prepared by this method, it and the district of traditional anti-corrosive antirusting paint
Not also residing in, this coating is relatively slow for drying time, and surface drying needs about 2 hours, parches needing 48 hours completely,
Reaching to react completely needs more than 120 hours, and adhesive force, covering power are extremely strong, and also have water-fast, resistance to
Oiliness, acid-fast alkali-proof, the mist of the most resistance to strong acid.
The release rust special anticorrosive coating of the present invention, its product Specifeca tion speeification is: viscosity is (by being coated with-4
Viscometer)≤50 seconds, fineness≤60um, drying time >=48 hour, hardness >=0.55, anti-impact force
>=50kg/cm, adhesive force is 1 grade, and salt tolerance 750 hours is non-foaming, non-corrosive.More than refer to room temperature bar
Under part (5-28 DEG C).
A kind of release rust special anticorrosive coating prepared by the present invention, the production technology of employing is high molecular crosslink
Learn reaction, i.e. by the cross-linking reaction of resin with firming agent, therefore more existing traditional handicraft system drying time
The drying time of standby rust-proof anti-corrosive paint to be grown, and this technical recipe is mainly by generating complex ion salt,
Ferrum oxide is changed into pigment salt required in paint, can directly penetrate into the bottommost of oxide layer,
Reach new ferrum to separate with floating ferrum and antirust, antiseptic effect.
The release rust special anticorrosive coating that the present invention provides, not only has that density is high, hardness is good, wearability
The advantage such as by force, anti-impact force is big, moreover it is possible to avoid contacting and absorption of new ferrum and outside moisture and oxygen, from
Fundamentally stop secondary to get rusty the generation of phenomenon.The most also there is easy construction, anticorrosion, rust-proof effect
The advantage such as good.
Detailed description of the invention
Raw material used in each embodiment:
1, mixing rust resisting pigment
The concrete consumption of component is: 190 iron oxide reds: 37kg, zinc oxide: 20kg, super-fine zinc dust:
25kg, barium sulfate: 8kg, zinc yellow: 10kg.
Preparation method: (1), first zinc oxide is added in 190 ferric oxide red colorants and be stirred uniformly.
(2), add super-fine zinc dust after 5 minutes to be stirred.(3) inserts barium sulfate, it is then respectively adding
Stir with zinc yellow.(4), after 10 minutes, shake with 60 mesh um fineness sieves
Dynamic filtration, i.e. available required mixing rust resisting pigment.
2, epoxy saturated resin
The concrete consumption of component is: bisphenol-A: 68kg, epoxychloropropane: 40kg, alkali liquor: 15kg.
Preparation method: (1), be first dissolved in the NaOH aqueous solution of 10% by bisphenol-A, the most slowly rises
Temperature is to 180～220 DEG C of temperature.(2), add epoxychloropropane be allowed to react, temperature controls at 210 DEG C.
(3), 30 minutes are stood after completion of the reaction.(4) boiling water cyclic washing 3～4 is used after, removing upper strata aqueous alkali
Secondary, the residual alkali in resin and byproduct salt can be removed.(5), full by obtaining required epoxy after dehydration
And resin.
3, mixed solvent
The concrete consumption of component is: toluene: 70kg, butanol: 15kg, butyl ether: 10kg, cyclohexanone:
5kg。
Preparation method: first butanol is slowly added in toluene solution by (1), to be mixed uniformly after add again
Enter butyl ether；(2) question response adds cyclohexanone after 1-2 hour, and is sufficiently stirred for；(3) treat instead
After answering 0.5-1 hour, i.e. available required mixed solvent.
4, auxiliary agent
Defoamer uses organic silicon defoamer, and levelling oil resistance agent uses SP-500 levelling oil resistance agent, anti-heavy agent
Use the anti-heavy agent of F118 coating.
Embodiment 1:
Raw material composition and ratio (being unit by 100kg):
Operating procedure:
(1), first by mixing rust resisting pigment join in mixed solvent and soak, be simultaneously introduced defoamer.
(2), question response adds appropriate acrylic resin after 1-2 hour, epoxy saturated resin enters
Row high speed dispersion mixes；
(3) until dispersion within 10-20 minute, make its obtain full and uniform after, then carry out sand milling PROCESS FOR TREATMENT, and
Fineness is controlled within 60um (i.e.≤60um)；
(4) by the mixed slurry that sand milling is good, in proportion with remaining mixed with resin, and it is separately added into stream
Flat oil resistance agent and anti-heavy agent stir.
(5), again the rust special anticorrosive coating of exempting being configured to is transferred in the range of viscosities of 86-92；
(6), by chemical examination detection qualified after carry out metering packing warehouse-in.
Embodiment 2:
Raw material composition and ratio (being unit by 100kg):
Operating procedure:
(1), first by mixing rust resisting pigment join in mixed solvent and soak, be simultaneously introduced defoamer；
(2) question response adds acrylic resin after 1-2 hour, epoxy saturated resin carries out dividing at a high speed
Dissipate mixing；
(3) until dispersion within 8-15 minute, just can get full and uniform after carry out sand milling PROCESS FOR TREATMENT again, and will
Fineness controls within 60um；
(4), by the good mixed slurry of sand milling, in proportion with remaining mixed with resin, and it is separately added into stream
Flat oil resistance agent and anti-heavy agent stir.
(5), again the rust special anticorrosive coating of exempting being configured to is transferred in the range of viscosities of 86-92；
(6), by chemical examination detection qualified after carry out metering packing warehouse-in.
Embodiment 3:
Raw material composition and ratio (being unit by 100kg):
Operating procedure:
(1), first by mixing rust resisting pigment join in mixed solvent and soak, be simultaneously introduced defoamer；
(2) question response adds acrylic resin after 1-2 hour, epoxy saturated resin carries out dividing at a high speed
Dissipate mixing；
(3) until dispersion within 10-18 minute, just can get full and uniform after carry out sand milling PROCESS FOR TREATMENT again, and will
Fineness controls within 60um；
(4), by the good mixed slurry of sand milling, in proportion with remaining mixed with resin, and it is separately added into stream
Flat oil resistance agent and anti-heavy agent stir.
(5), again the rust special anticorrosive coating of exempting being configured to is transferred in the range of viscosities of 86-92；
(6), by chemical examination detection qualified after carry out metering packing warehouse-in.
Carrying out chemical examination detection by the national standard implemented at present, the index of the anticorrosive paint of each example gained is as follows:
Claims (8)
1. exempt rust special anticorrosive coating for one kind, it is characterised in that this coating is mixed by the component of following weight portion: acrylic resin 15～35 parts, epoxy saturated resin 10～25 parts, mixing rust resisting pigment 35～50 parts, organic silicon defoamer 0.1～1.0 parts, mixed solvent 10～20 parts, SP-500 levelling oil resistance agent 0.1～1.0 parts and the anti-heavy agent 0.1 of F118 coating～1.0 parts；Wherein said mixing rust resisting pigment is to be mixed by 190 iron oxide reds, zinc oxide, super-fine zinc dust, inserts barium sulfate and zinc yellow；Particle size range 60～80 mesh of described super-fine zinc dust, described epoxy saturated resin is by bisphenol-A and epoxychloropropane high polymer of pyrocondensation under soda effect, wherein setting-up point is 180～220 DEG C, and in pyrocondensation reaction, the proportion by weight of each raw material is: bisphenol-A 65～75 parts, epoxychloropropane 20～55 parts, soda 5～15 parts.
Release rust special anticorrosive coating the most according to claim 1, it is characterised in that the weight of each component of this coating is: acrylic resin 21～29 parts, epoxy saturated resin 14～19 parts, mixing rust resisting pigment 39～43 parts, organic silicon defoamer 0.3～0.4 part, mixed solvent 15～16 parts, levelling oil resistance agent 0.5～0.6 part, anti-heavy agent 0.6～0.7 part.
Release rust special anticorrosive coating the most according to claim 1, the weight/mass percentage composition that it is characterized in that the described each component of mixing rust resisting pigment is: 190 iron oxide reds 30～45%, zinc oxide 10～20%, super-fine zinc dust 20～30%, inserts 5～15%, zinc yellow 10～20%.
Release rust special anticorrosive coating the most according to claim 3, the weight/mass percentage composition that it is characterized in that the described each component of mixing rust resisting pigment is: 190 iron oxide reds 35～41%, zinc oxide 11～15%, super-fine zinc dust 22～28%, inserts 8～12%, zinc yellow 12～16%.
5. according to the release rust special anticorrosive coating described in claim 3 or 4, it is characterised in that the particle diameter of described zinc oxide is 1000 mesh.
Release rust special anticorrosive coating the most according to claim 1, it is characterised in that described mixed solvent is mixed by toluene, butanol, butyl ether and cyclohexanone.
The most according to claim 6 exempt rust special anticorrosive coating, it is characterised in that in described mixed solvent, the mass content of each component is: toluene 65～70%, butanol 10～15%, butyl ether 8～12%, cyclohexanone 4～12%.
Release rust special anticorrosive coating the most according to claim 1, it is characterised in that this coating is prepared from by following steps:
(1) first mixing rust resisting pigment is joined in mixed solvent and soak, be simultaneously introduced defoamer；
(2) question response adds acrylic resin after 1-2 hour, epoxy saturated resin carries out high speed dispersion mixing；
(3) carry out sand milling PROCESS FOR TREATMENT again after disperseing and be full and uniform, and fineness is controlled within 60 μm；
(4) it is eventually adding levelling oil resistance agent and anti-heavy agent is sufficiently stirred for, the viscosity of coating is adjusted between 86～92.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410038629.5A CN103805010B (en) | 2013-07-30 | 2014-01-26 | A kind of release rust special anticorrosive coating |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310323937.8 | 2013-07-30 | ||
| CN2013103239378 | 2013-07-30 | ||
| CN201310323937 | 2013-07-30 | ||
| CN201410038629.5A CN103805010B (en) | 2013-07-30 | 2014-01-26 | A kind of release rust special anticorrosive coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103805010A CN103805010A (en) | 2014-05-21 |
| CN103805010B true CN103805010B (en) | 2016-08-31 |
Family
ID=50702418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410038629.5A Active CN103805010B (en) | 2013-07-30 | 2014-01-26 | A kind of release rust special anticorrosive coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103805010B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861824A (en) * | 2015-05-29 | 2015-08-26 | 黄强 | Blistering-proof and wear-resistant coating for automobile |
| CN107573775A (en) * | 2017-07-17 | 2018-01-12 | 江苏艺博防水防腐工程有限公司 | One kind is exempted to dry metallic conduit sprayed on material and its construction method |
| CN108165138A (en) * | 2017-12-29 | 2018-06-15 | 天津索菲特建筑材料有限公司 | Insulation rust-proof anti-corrosive paint |
| CN111548692A (en) * | 2020-05-22 | 2020-08-18 | 成都新柯力化工科技有限公司 | Rust-removing anticorrosive paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519565A (en) * | 2009-03-04 | 2009-09-02 | 宜兴市巨人涂料有限公司 | Special anti-corrosion rust-proof paint with rust removal and preparation method thereof |
| CN102391743A (en) * | 2011-09-01 | 2012-03-28 | 中国海洋石油总公司 | Aqueous primer used for bicycles |
| CN102634259A (en) * | 2011-06-21 | 2012-08-15 | 漳州鑫展旺化工有限公司 | Low-temperature curing anticorrosive paint and preparation method thereof |
| CN103031036A (en) * | 2012-12-17 | 2013-04-10 | 吕龙云 | Thick coating type epoxy corrosion-resistant coating certified by Water Regulation Advisory Scheme (WRAS) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004338236A (en) * | 2003-05-15 | 2004-12-02 | Nippon Parkerizing Co Ltd | Surface-treated weather-resistant steel, surface-treating agent for weather-resistant steel, and method for producing surface-treated weather-resistant steel |
-
2014
- 2014-01-26 CN CN201410038629.5A patent/CN103805010B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101519565A (en) * | 2009-03-04 | 2009-09-02 | 宜兴市巨人涂料有限公司 | Special anti-corrosion rust-proof paint with rust removal and preparation method thereof |
| CN102634259A (en) * | 2011-06-21 | 2012-08-15 | 漳州鑫展旺化工有限公司 | Low-temperature curing anticorrosive paint and preparation method thereof |
| CN102391743A (en) * | 2011-09-01 | 2012-03-28 | 中国海洋石油总公司 | Aqueous primer used for bicycles |
| CN103031036A (en) * | 2012-12-17 | 2013-04-10 | 吕龙云 | Thick coating type epoxy corrosion-resistant coating certified by Water Regulation Advisory Scheme (WRAS) |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103805010A (en) | 2014-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104109450B (en) | A kind of Graphene anti-corrosive powder paint and preparation method thereof | |
| CN106221458B (en) | Special anticorrosive water paint for steel structure and preparation method thereof | |
| CN103805010B (en) | A kind of release rust special anticorrosive coating | |
| CN107057533A (en) | A kind of aqueous one-component paint for priming paint and top lacquer and preparation method thereof | |
| CN105331268A (en) | Low-carbon waterborne coating and preparation method thereof | |
| CN104046149A (en) | Water-based on-rust paint and preparation method thereof | |
| CN105524505A (en) | Double-ingredient chrome-free water-based metal anticorrosive paint and preparation method thereof | |
| CN102618143B (en) | Heavy-duty anticorrosion coating | |
| CN105111860A (en) | Water-based double-component corrosion-resistant industrial paint and production method thereof | |
| CN107474700A (en) | A kind of environment-friendly type aqueous creeper tread dip-coating paint and preparation method thereof | |
| CN104817929B (en) | A kind of track traffic water-base epoxy dual-component coating and preparation method thereof | |
| CN103232796A (en) | Quick-drying anticorrosive dipping prime paint with low viscosity as well as preparation and application method thereof | |
| CN105801071A (en) | Formula of primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and making technology | |
| CN104804613A (en) | Corrosion resistant thermal spraying hole sealing agent and application method thereof | |
| CN106280864A (en) | A kind of epoxy turns rust type anticorrosion water-soluble coating | |
| CN107189639A (en) | A kind of stable type corrosion-resistant epoxy paint capable of coating with rust | |
| CN104250512A (en) | Water-based alcohol acid primer-topcoat antirust paint and preparation method thereof | |
| CN103980853A (en) | Environment-friendly building adhesive and preparation method thereof | |
| CN103820008B (en) | One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof | |
| CN106675399A (en) | Moisture curable crylic acid modified polysiloxane coating and preparation method thereof | |
| CN103665942A (en) | Attapulgite nano complex iron oxide brown for easily-dispersible water-based paint | |
| CN104789086A (en) | High-temperature-resistant thermal spraying hole sealing agent and application method thereof | |
| CN102993842A (en) | Styrene-acrylic emulsion aqueous rust coating and preparation method thereof | |
| CN107779040A (en) | A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof | |
| CN107722773A (en) | A kind of one-component Compound waterborne coating capable of coating with rust |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |