CN103966692B - A kind of nylon ultrafine fiber long filament and skin sense pile fabric - Google Patents

A kind of nylon ultrafine fiber long filament and skin sense pile fabric Download PDF

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Publication number
CN103966692B
CN103966692B CN201410168265.2A CN201410168265A CN103966692B CN 103966692 B CN103966692 B CN 103966692B CN 201410168265 A CN201410168265 A CN 201410168265A CN 103966692 B CN103966692 B CN 103966692B
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China
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component
long filament
ultrafine fiber
nylon
pile fabric
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CN103966692A (en
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赵继东
徐华
陶志均
陶建军
金志芳
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Hangzhou Huvis Yong Sheng Dyeing And Finishing Co Ltd
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Hangzhou Huvis Yong Sheng Dyeing And Finishing Co Ltd
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Abstract

The present invention relates to a kind of nylon ultrafine fiber long filament, single fiber 1F is made up of 20~30 filament shape (about 0.2dpf) components A and component B surrounded and fill in component A periphery and space;Described component A weight/mass percentage composition is 85%~95%, component B weight/mass percentage composition is 5%~15%;Described component A degree of crystallinity is 70%~90%, and component B degree of crystallinity is 5%~40%;The beneficial effects are mainly as follows: use nylon ultrafine fiber long filament of the present invention to manufacture skin sensillary base cloth, K cryogenic treatment fibrillation, napping napping is used to process, acid stain 80~120 DEG C of low temperature dyeings, it is prone to colouring, dyeing waste will not be produced, environment will not cause dyeing pollute, reduce energy consumption, and product quality greatly improves.

Description

A kind of nylon ultrafine fiber long filament and skin sense pile fabric
(1) technical field
The present invention relates to a kind of nylon ultrafine fiber long filament, and utilize this nylon ultrafine fiber long filament system The method making skin sense pile fabric.
(2) background technology
The life of the present people of the long silk face fabric of superfine fibre is applied more and more extensive, be mainly used in man High-grade women's leisure jacket, wind, leisure Western-style clothes, trousering, leisure cotton dress, leisure feather dress fabric.One As main use island superfine fiber long filament or polyester polyamide superfine fibre long filament to manufacture, fabric passes through The operations such as preshrunk, Alkali reduction fibrillation, pre-setting, plucking sanding, dyeing produce this kind of skin sense matte Material.
General superfine fibre long filament skin sense pile fabric major part needs to carry out synthetic fiber spinning and Final finishing dye Color is processed.Such as Chinese Patent No. 83109961, No. 76102732, No. 79108906, No. 8110032, No. 200410000690.7, be by chemical fibre fibrillation and machinery fibrillation after, The super long and slender dimension of fabric is dyeed.Owing to chamois flannel face fabric uses terylene sea-island fibre, washs The fiber manufactures such as brocade superfine fibre, after fibrillation, the fiber number of fiber reaches about 0.2dtex.Fiber Specific surface area reach tens times of conventional fibre, the therefore suction on the surface of fiber during disperse dyeing Attached ability is greatly reinforced.Some dyestuffs are combined dyeing with fiber, and 1/4~1/3 is dye adsorption at fiber Surface, fabric cleans when, often enter sewage, increase COD discharge, cause environment dirty Dye.
(3) summary of the invention
It is an object of the present invention to provide a kind of nylon ultrafine fiber long filament, acid dyeing method can be used, Rather than the high-temperature dyeing of employing disperse dyes 130 DEG C, first reducing dyeing temperature is 80~120 DEG C, Saving heat energy, reduces and consumes, and improve dyefastness, reduces and pollutes, and reduces discharge, protects environment.
The technical solution used in the present invention is:
A kind of nylon ultrafine fiber long filament, single fiber 1F by 20~30 filament shape components A and The component B composition surrounded in component A periphery and space and fill;Described component A percent mass contains Amount is 85%~95%, component B weight/mass percentage composition is 5%~15%;Described component A degree of crystallinity is 70%~90%, component B degree of crystallinity is 5%~40%;Described component A is selected from following macromolecular material One of: nylon 6, nylon66 fiber, nylon 11, nylon 12, preferably nylon 6 or nylon66 fiber;Institute Stating component B is monomer one and the polymer of monomer two, and described monomer one is one of following: adipic acid, Azelaic Acid, p-phthalic acid, M-phthalic acid, hexamethylene-1,4 dihydroxy acid, 1,6 hexamethylene diamines, three Methyl isophthalic acid, 6 hexamethylene diamines, 4,4 '-diaminourea-dicyclohexyl propane, isophorone diamine, caprolactam, 4,4 '-diphenylmethane diisocyanate fat, preferably M-phthalic acid or adipic acid;Described monomer two For one of following: formic acid, to alkyl benzoic acid, isophthalic first diacid, ethylene glycol, methanol, second diester, It is preferably dioctyl phthalate or ethylene glycol.
Two kinds of polymeric properties of A, B used in the present invention differ greatly, and add man-hour carrying out fibrillation Being easy to make fiber detaching, therefore, component A uses the polymer of high-crystallinity, the most labile B component uses the polymer of low-crystallinity.Described nylon ultrafine fiber long filament cross section sees Fig. 1, in Between small circular be component A, around component A cladding white B component be component A parcel bonding Material.After this fiber is made base fabric (grey cloth), by shrink process, fiber is through air-flow and water-bath Stream rubbing is clashed into, decrement fibrillation, adds to dissolve and removes B part, and the structure of fiber forms component A Fluffy tow, individual filament fineness dpf is about 0.2dtex, and the present invention around this principle sets Meter invention nylon ultrafine fiber, base fabric and making skin sense pile fabric.
Concrete, described nylon ultrafine fiber long filament by component A and component B at spinning temperature 160 DEG C~290 DEG C, make with composite spinning method under the conditions of draw off rate 2800~3600m/min.
The invention still further relates to a kind of side utilizing described nylon ultrafine fiber long filament to make skin sense pile fabric Method, described method includes:
(1) grey cloth makes: does warp thread with chinlon filament, does tram with described nylon ultrafine fiber long filament, Thread count: (68~78) * (60~68) root/cm, is organized as 1/2 left oblique;
(2) skin sense pile fabric makes: by step (1) grey cloth first 85 DEG C of preshrunk 30min, then 95 DEG C After hot water treatment 40min, fibrillation 40min at 80 DEG C, fibrillation agents useful for same is benzene first Alcohol 2%~6% (to cloth weight ratio, lower same), butyl glycidyl ether 1%, NaOH 2%~4%, grey cloth and water weight ratio are 1:10~15;Then through pre-setting, napping, 80~120 DEG C of acid dyeings, capillary effects arrange, and obtain described skin sense pile fabric finished product. After fibrillation processes, component B is dissolved in water, and the component A nylon of high-crystallinity is ultra-fine Fiber filament is the most prominent embodies (seeing Fig. 2).
Concrete, it is as follows that described capillary effect arranges parameter: uses carbon brush that fabric is carried out capillary effect arrangement, carbon 15 meters/min of brush speed, the 1st roller rotates forward, the 2nd roller inverts, the 3rd roller rotates forward, corresponding carbon brush mesh Number is respectively 200 mesh, 240 mesh, 300 mesh.
The present invention utilizes the nylon component A of high-crystallinity and the B component being easily dissolved with low-crystallinity to adopt Use composite spinning technology spinning;Chinlon filament is utilized to do warp thread, manufactured nylon ultrafine fiber long filament Do tram, manufacture skin sense grey cloth, through acid dyeing, nylon ultrafine fiber long filament scrim surfaces Dyestuff enters fibrous inside and reacts with fiber molecule, bright-colored firmly will not produce the phenomenon that fades, Dyefastness is greatly improved, from original 2.5 grades bring up to 3.0 grades and more than.Leading indicator: rub Wipe color fastness: dry grind 3.0 grades and more than, wet grinding 3.0 grades and more than;Washing: water logging 3.0 Level and more than, staining 3.0 grades and more than;WASHING COLOR FASTNESS: water logging 3.0 grades and more than, staining 3.0 Level and more than, improve and improve clothing level and the quality of life of people, and filled up domestic blank.
The beneficial effects are mainly as follows: use nylon ultrafine fiber long filament of the present invention to manufacture skin Sensillary base cloth, uses K cryogenic treatment fibrillation, napping napping to process, acid stain low temperature dyeing, it is easy on Color, will not produce dyeing waste, environment will not cause dyeing pollute, reduce energy consumption, and finished product Nylon skin sense pile fabric quality greatly improves.
(4) accompanying drawing explanation
Fig. 1 is nylon ultrafine fiber long filament single fiber 1F schematic cross-section of the present invention;
Fig. 2 is the single fiber schematic cross-section after nylon ultrafine fiber long filament of the present invention carries out Colour Difference;
A is nylon high-crystallinity copolymer, and B is low crystallinity polymers.
(5) detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention It is not limited to that:
Embodiment 1:
(1) making of nylon ultrafine fiber long filament:
Component A is nylon 6, and weight/mass percentage composition is 90%, and degree of crystallinity is 85%;
Component B is the monomer-polymer of M-phthalic acid and methanol, and weight/mass percentage composition is 10%, Degree of crystallinity is 30%.
Use composite spinning method, spinning temperature 200 DEG C~250 DEG C, draw off rate 3000~3200m/min Under the conditions of make.The nylon ultrafine fiber long filament 100D/24F*24 schematic cross-section prepared sees Fig. 1, This fiber package contains middle nylon polymer A and surrounds the polymer B of polymer A with ocean form. As shown, B the fiber surrounded has a component A (single fiber fineness 0.2dtex left side for 21 circles Right), illustrate that in this fiber, island number is 21, in actual production, this island number can be 20~30 Individual, shape can be circular, it is also possible to is other shapes.
(2) making of nylon skin sense pile fabric grey cloth:
Warp thread, nylon ultrafine fiber long filament with aforementioned preparation is done with chinlon filament (68D/24F) (100D/24F*24) do tram, thread count: (68~78) * (60~68) root/cm, be organized as 1/2 Left oblique.
(3) making of nylon skin sense pile fabric:
Nylon ultrafine fiber grey cloth 95 DEG C of hot water treatment 40min of 85 DEG C of preshrunk 30min Fibrillation: benzyl alcohol 5%, butyl glycidyl ether 1%, NaOH3%, 80 DEG C of fibrillation of temperature 170 DEG C of pre-setting 30s of 40min (overfeeding 5%), speed 30 meters/min napping roller turns to: 1 positive 1 anti-2 just (totally 4 roller), husky skin mesh number be followed successively by 180 mesh (just), 200 mesh (instead), 240 Mesh (just), 240 mesh (just), 12 meters/min of speed, the amount of feeding 2 lattice about 100 DEG C acid Property dyeing washing sizing capillary effect arrange: 15 meters/min of carbon brush speed, the 1st Roller rotate forward, the 2nd roller reversion, the 3rd roller rotate forward, carbon brush correspondence mesh number be respectively 200 mesh (rotating forward), 240 mesh (reversion), 300 mesh (rotating forward) skin sense pile fabric finished product.
The skin sense pile fabric finished product leading indicator prepared is as follows:
Colorfastness to rubbing index: dry grind more than 3.0 grades, wet grinding more than 3.0 grades;Washing: Water logging more than 3.0 grades, staining more than 3.0 grades;WASHING COLOR FASTNESS: water logging more than 3.0 grades, staining More than 3.0 grades.
Embodiment 2:
Component A and component B raw material are as follows:
Component A is nylon66 fiber, and weight/mass percentage composition is 95%, and degree of crystallinity is 90%;
Component B is the monomer-polymer of M-phthalic acid and ethylene glycol, and weight/mass percentage composition is 5%, Degree of crystallinity is 15%.
Preparation method is with embodiment 1.The skin sense pile fabric finished product leading indicator prepared is as follows:
Colorfastness to rubbing: dry grind 3.5 grades, wet grinding 3 grades;Washing: water logging 3.5 grades, is stained with Color 3 grades;WASHING COLOR FASTNESS: water logging 3.5 grades, staining 3.5 grades.

Claims (1)

1. utilize the method that nylon ultrafine fiber long filament makes skin sense pile fabric, described nylon ultrafine fiber Long filament single fiber 1F is by 20~30 filament shape components A with at component A periphery and space Nei Bao The component B composition enclosed and fill;Described component A weight/mass percentage composition is 85%~95%, component B weight/mass percentage composition is 5%~15%;Described component A degree of crystallinity is 70%~90%, component B Degree of crystallinity is 5%~40%;Described component A is nylon 6 or nylon66 fiber;Described component B is single Body one and the polymer of monomer two, described monomer one is M-phthalic acid, and described monomer two is methanol Or ethylene glycol;Described nylon ultrafine fiber long filament by component A and component B spinning temperature 160 DEG C ~290 DEG C, make with composite spinning method under the conditions of draw off rate 2800~3600m/min;Described The method making skin sense pile fabric includes:
(1) grey cloth makes: does warp thread with chinlon filament, does tram with described nylon ultrafine fiber long filament, Thread count: (68~78) * (60~68) root/cm, is organized as 1/2 left oblique;
(2) skin sense pile fabric makes: by step (1) grey cloth first 85 DEG C of preshrunk 30min, then 95 DEG C After hot water treatment 40min, fibrillation 40min at 80 DEG C, fibrillation agents useful for same presses reagent Weight accounts for grey cloth percentage by weight and is calculated as: benzyl alcohol 2%~6%, butyl glycidyl ether 1%, NaOH 2%~4%, grey cloth and water weight ratio are 1:10~15;Then through pre-setting, mill Floss, 80~120 DEG C of acid dyeings, capillary effects arrange, and obtain described skin sense pile fabric Product;Using carbon brush that fabric carries out capillary effect arrangement, 15 meters/min of carbon brush speed, carbon brush turns To: the 1st roller rotates forward, the 2nd roller inverts, the 3rd roller rotates forward, corresponding carbon fiber brush mesh number It is respectively 200,240,300 mesh.
CN201410168265.2A 2014-04-24 2014-04-24 A kind of nylon ultrafine fiber long filament and skin sense pile fabric Active CN103966692B (en)

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CN111719222A (en) * 2020-07-08 2020-09-29 江苏贝尔特福新材料有限公司 A kind of woven suede fabric and production process
CN119753876A (en) * 2024-12-25 2025-04-04 杭州永盛高纤股份有限公司 Fiber filament with good moisture absorption and perspiration wicking performance and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1641096A (en) * 2004-01-16 2005-07-20 三芳化学工业股份有限公司 Superfine fiber artificial leather and fabric manufacturing method
CN101712815A (en) * 2009-11-23 2010-05-26 浙江大井化工有限公司 Environment-friendly acid black dye composition
CN102995150A (en) * 2012-11-29 2013-03-27 张家港保税区长江塑化有限公司 Modified cross section chinlon 6 composite fiber
CN103525123A (en) * 2013-10-14 2014-01-22 东华大学 Nylon sea-island microfiber leather fabric composite dye and application thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007023442A (en) * 2005-07-20 2007-02-01 Opelontex Co Ltd Polyester fiber dyed yarn and method for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1641096A (en) * 2004-01-16 2005-07-20 三芳化学工业股份有限公司 Superfine fiber artificial leather and fabric manufacturing method
CN101712815A (en) * 2009-11-23 2010-05-26 浙江大井化工有限公司 Environment-friendly acid black dye composition
CN102995150A (en) * 2012-11-29 2013-03-27 张家港保税区长江塑化有限公司 Modified cross section chinlon 6 composite fiber
CN103525123A (en) * 2013-10-14 2014-01-22 东华大学 Nylon sea-island microfiber leather fabric composite dye and application thereof

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Denomination of invention: A nylon ultra-fine fiber filament and leather felt velvet fabric

Granted publication date: 20160817

Pledgee: Zhejiang Xiaoshan rural commercial bank Limited by Share Ltd. Jingjiang branch

Pledgor: HANGZHOU HUIWEISHI YONGSHENG DYEING & FINISHING CO.,LTD.

Registration number: Y2024980000680