CN103981690A - Stinking-proof finishing method of wool fabric - Google Patents
Stinking-proof finishing method of wool fabric Download PDFInfo
- Publication number
- CN103981690A CN103981690A CN201410166822.7A CN201410166822A CN103981690A CN 103981690 A CN103981690 A CN 103981690A CN 201410166822 A CN201410166822 A CN 201410166822A CN 103981690 A CN103981690 A CN 103981690A
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- CN
- China
- Prior art keywords
- wool fabric
- fabric
- padding
- owf
- wool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 52
- 210000002268 wool Anatomy 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000005406 washing Methods 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000004332 deodorization Methods 0.000 claims description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 229920000858 Cyclodextrin Polymers 0.000 abstract 2
- 239000001116 FEMA 4028 Substances 0.000 abstract 2
- 235000011175 beta-cyclodextrine Nutrition 0.000 abstract 2
- 229960004853 betadex Drugs 0.000 abstract 2
- 238000009210 therapy by ultrasound Methods 0.000 abstract 2
- 238000007598 dipping method Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- 206010040904 Skin odour abnormal Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- -1 cyclic oligosaccharide Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides a stinking-proof finishing method of wool fabric, which comprises the following steps: A)preparing fabric, washing the wool fabric by warn water and drying; B)preparing fishing liquid, adding 2-5% owf beta-cyclodextrin, 6-9% owf cross-linking agent and 1-4% owf catalyst in a roll groove to prepare a solution; C) dipping and padding twice, employing ultrasonic treatment with 30-40 KHz during a padding process, wherein the padding temperature is 50-65 DEG C, the padding time is 10-15 minutes for each time; D)drying; E)heating the dried wool fabric for 1-3 minutes at the temperature of 140-180 DEG C; F)washing by cold water; and G)drying. The stinking-proof finishing method has the advantages of simple operation, environmental protection and no pollution, the ultrasonic treatment can greatly increase the grafting rate of beta-cyclodextrin on surface of wool fiber. The treated wool fabric has perdurable stinking-proof effect; the change of breaking strength of the finished fabric is little, and the washing shrinkage accords with the machine-washable standards.
Description
Technical field
The present invention relates to a kind of finishing technique of fabric, especially relate to a kind of deodorization method for sorting of wool fabric.
Background technology
In recent years, wool and BLENDED FABRIC thereof are just towards frivolous, leisure series and health care future development, and market increases the demand of pure and fresh deodorization fabric, and stimulation and the bio-toxicity of current chemical deodorization finishing agent to skin is the controversial topics of people always.Beta-schardinger dextrin-(β-CD) is cyclic oligosaccharide, has unique hydrophobic cavity structure, can inclusion foul smell molecule, absorb offensive odour (sweat, body odour, cigarette smell etc.), and therefore there is ecological odor-resistant result.
Conventional β-CD has microcapsule method, binder method, sol-gal process, epoxychloropropane method and polybasic carboxylic acid grafting copolymerization process to fabric deodorization afterfinish method, and wherein polybasic carboxylic acid grafting copolymerization process is simple to operate, water-wash resistance good and affect little on the feel of fabric.
Summary of the invention
The object of this invention is to provide a kind of deodorization method for sorting of wool fabric.
Complex procedures that existing wool deodorization method for sorting exists that what the present invention will solve is, finishing agent is toxic to skin and environment, and the defect such as after arranging the odor-resistant result of fabric is not lasting.
Technical scheme of the present invention is: a kind of deodorization method for sorting of wool fabric, and described method at least comprises the steps: the preparation of a. fabric: wool fabric, with after 40 DEG C of warm water cleanings, is dried to constant weight; B. dressing liquid preparation: add 2～5% owf beta-schardinger dextrin-s, 6～9% owf crosslinking agents and 1～4% owf catalyst in groove, be mixed with clear solution; C. pad: wool fabric is put in dressing liquid and padded, described padding finishing operation employing two is soaked two and is rolled, described padding adopts the ultrasonic wave of 30～40KHz to process wool fabric in process, described in to pad temperature be 50～65 DEG C, the time of at every turn padding is 10～15 minutes; D. dry: the wool fabric after padding is dried 3～5 minutes at 70～80 DEG C; E. bake: the wool fabric after drying is baked to 1～3 minute at 140～180 DEG C; F. cold wash: will bake and bank up with earth wool fabric cold water washing after treatment; G. dry: fabric is dried 3～5 minutes at 70～80 DEG C.
Preferably, described crosslinking agent is 1,2,3,4-BTCA or citric acid.
Preferably, described catalyst is inferior sodium phosphate.
The beneficial effect that the present invention produces is: compared with prior art, deodorization method for sorting operation provided by the invention is simple, environment friendly and pollution-free, and ultrasonic wave processing can improve the percent grafting of beta-schardinger dextrin-at wool surface greatly.Through method provided by the invention wool fabric after treatment, check the test of association's detector tube method through Japanese Textile, it is after 99%, 10 washing to be 95% to the slip of ammonia to the slip of ammonia, shows that fabric has durable odor-resistant result; And after arranging, the ultimate strength of fabric changes not quite, and washing shrinkage meets machine washable standard.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
A deodorization method for sorting for wool fabric, described method at least comprises the steps: the preparation of a. fabric: wool fabric, with after 40 DEG C of warm water cleanings, is dried to constant weight; B. dressing liquid preparation: add 4% owf beta-schardinger dextrin-, 6% owf crosslinking agent 1,2,3 in groove, 4-BTCA and 2% owf catalyst inferior sodium phosphate, be mixed with clear solution; C. pad: wool fabric is put in dressing liquid and padded, described padding finishing operation employing two is soaked two and is rolled, described padding adopts the ultrasonic wave of 30～40KHz to process wool fabric in process, described in to pad temperature be 55 DEG C, the time of at every turn padding is 10 minutes; D. dry: the wool fabric after padding is dried 3 minutes at 80 DEG C; E. bake: the wool fabric after drying is baked to 2 minutes at 160 DEG C; F. cold wash: will bake and bank up with earth wool fabric cold water washing after treatment; G. dry: fabric is dried 3 minutes at 80 DEG C.
In the process of padding, adopt ultrasonic wave processing, can wool fibre is expanded, and be conducive to the scale layer of wool surface to be opened, make crosslinking agent be more prone to wool fibre on amino react, improved the percent grafting of beta-schardinger dextrin-on wool fabric surface.
Utilize representative bad smell of perspiration material-ammonia to study suction-operated and the influence factor of the wool fabric arranging through beta-schardinger dextrin-to bad smell of perspiration material.Check the test of association detector tube method through Japanese Textile, it is after 99%, 10 washing to be 95% to the slip of ammonia to the slip of ammonia, shows that fabric has durable odor-resistant result.After arranging, the ultimate strength of fabric changes not quite, and washing shrinkage meets machine washable standard.
Claims (3)
1. a deodorization method for sorting for wool fabric, is characterized in that described method at least comprises the steps: the preparation of a. fabric: wool fabric, with after 40 DEG C of warm water cleanings, is dried to constant weight; B. dressing liquid preparation: add 2～5% owf beta-schardinger dextrin-s, 6～9% owf crosslinking agents and 1～4% owf catalyst in groove, be mixed with clear solution; C. pad: wool fabric is put in dressing liquid and padded, described padding finishing operation employing two is soaked two and is rolled, described padding adopts the ultrasonic wave of 30～40KHz to process wool fabric in process, described in to pad temperature be 50～65 DEG C, the time of at every turn padding is 10～15 minutes; D. dry: the wool fabric after padding is dried 3～5 minutes at 70～80 DEG C; E. bake: the wool fabric after drying is baked to 1～3 minute at 140～180 DEG C; F. cold wash: will bake and bank up with earth wool fabric cold water washing after treatment; G. dry: fabric is dried 3～5 minutes at 70～80 DEG C.
2. the deodorization method for sorting of a kind of wool fabric as claimed in claim 1, is characterized in that described crosslinking agent is 1,2,3,4-BTCA or citric acid.
3. the deodorization method for sorting of a kind of wool fabric as claimed in claim 1, is characterized in that described catalyst is inferior sodium phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166822.7A CN103981690A (en) | 2014-04-23 | 2014-04-23 | Stinking-proof finishing method of wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410166822.7A CN103981690A (en) | 2014-04-23 | 2014-04-23 | Stinking-proof finishing method of wool fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103981690A true CN103981690A (en) | 2014-08-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410166822.7A Pending CN103981690A (en) | 2014-04-23 | 2014-04-23 | Stinking-proof finishing method of wool fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103981690A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105220508A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | A kind of environmental protection real silk deodorization antibacterial finishing agent |
| CN105239411A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Anti-pilling odor-resistant woolen sweater |
| CN105239410A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Anti-pilling deodorization finishing agent for cashmere sweater |
| CN105239373A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Strong deodorization finishing process of wool blended fabric |
| CN105239412A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Deodorization finishing technology for washable wool blended fabric |
| CN105256591A (en) * | 2015-11-13 | 2016-01-20 | 浙江森悦纺织科技有限公司 | Production technology for environment-friendly sun-proof cotton fabric |
| CN105951436A (en) * | 2016-05-18 | 2016-09-21 | 江南大学 | Antibacterial finishing method for grafting beta-cyclodextrin onto wool fabric under catalysis of laccase |
| CN112878044A (en) * | 2021-02-07 | 2021-06-01 | 绍兴绿地针织有限公司 | Preparation process of deodorant socks |
| CN119465614A (en) * | 2025-01-09 | 2025-02-18 | 鲁泰纺织股份有限公司 | Production method and device for improving the durability of non-ironing fabrics |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270548A (en) * | 2008-04-29 | 2008-09-24 | 东华大学 | A kind of deodorant sol-gel finishing agent and its preparation method and application |
| CN102936838A (en) * | 2012-11-07 | 2013-02-20 | 西安工程大学 | Method for preparing fabric with deodorizing function |
| CN103422339A (en) * | 2013-08-23 | 2013-12-04 | 华南理工大学 | Method for preparing antibacterial functional cellulosic fibers |
-
2014
- 2014-04-23 CN CN201410166822.7A patent/CN103981690A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270548A (en) * | 2008-04-29 | 2008-09-24 | 东华大学 | A kind of deodorant sol-gel finishing agent and its preparation method and application |
| CN102936838A (en) * | 2012-11-07 | 2013-02-20 | 西安工程大学 | Method for preparing fabric with deodorizing function |
| CN103422339A (en) * | 2013-08-23 | 2013-12-04 | 华南理工大学 | Method for preparing antibacterial functional cellulosic fibers |
Non-Patent Citations (1)
| Title |
|---|
| 杨玉芳等: ""β-环糊精用于羊毛混纺织物防臭整理"", 《毛纺科技》 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105239411A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Anti-pilling odor-resistant woolen sweater |
| CN105239410A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Anti-pilling deodorization finishing agent for cashmere sweater |
| CN105239373A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Strong deodorization finishing process of wool blended fabric |
| CN105239412A (en) * | 2015-11-12 | 2016-01-13 | 长兴永杰纺织有限公司 | Deodorization finishing technology for washable wool blended fabric |
| CN105220508A (en) * | 2015-11-13 | 2016-01-06 | 长兴县三星纺织有限公司 | A kind of environmental protection real silk deodorization antibacterial finishing agent |
| CN105256591A (en) * | 2015-11-13 | 2016-01-20 | 浙江森悦纺织科技有限公司 | Production technology for environment-friendly sun-proof cotton fabric |
| CN105951436A (en) * | 2016-05-18 | 2016-09-21 | 江南大学 | Antibacterial finishing method for grafting beta-cyclodextrin onto wool fabric under catalysis of laccase |
| CN105951436B (en) * | 2016-05-18 | 2018-01-09 | 江南大学 | A kind of antibiotic finishing method of Laccase Catalyzed wool fabric grafting beta cyclodextrin |
| CN112878044A (en) * | 2021-02-07 | 2021-06-01 | 绍兴绿地针织有限公司 | Preparation process of deodorant socks |
| CN119465614A (en) * | 2025-01-09 | 2025-02-18 | 鲁泰纺织股份有限公司 | Production method and device for improving the durability of non-ironing fabrics |
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Application publication date: 20140813 |