CN104109439A - Heat preserving really stone paint and preparation method thereof - Google Patents
Heat preserving really stone paint and preparation method thereof Download PDFInfo
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- CN104109439A CN104109439A CN201410363216.4A CN201410363216A CN104109439A CN 104109439 A CN104109439 A CN 104109439A CN 201410363216 A CN201410363216 A CN 201410363216A CN 104109439 A CN104109439 A CN 104109439A
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- CN
- China
- Prior art keywords
- mineral varnish
- true mineral
- natvosol
- hollow glass
- parts
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- Granted
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- 239000003973 paint Substances 0.000 title claims abstract description 13
- 238000002360 preparation method Methods 0.000 title abstract description 19
- 239000004575 stone Substances 0.000 title abstract 4
- 239000011521 glass Substances 0.000 claims abstract description 25
- 239000004576 sand Substances 0.000 claims abstract description 19
- 239000008399 tap water Substances 0.000 claims abstract description 14
- 235000020679 tap water Nutrition 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 37
- 239000011707 mineral Substances 0.000 claims description 37
- 239000002966 varnish Substances 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 23
- 239000004816 latex Substances 0.000 claims description 23
- 229920000126 latex Polymers 0.000 claims description 23
- 238000009413 insulation Methods 0.000 claims description 20
- 239000011325 microbead Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 15
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 12
- 238000009736 wetting Methods 0.000 claims description 12
- 230000008961 swelling Effects 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 6
- 238000005304 joining Methods 0.000 claims description 3
- 239000004579 marble Substances 0.000 claims description 3
- 150000001282 organosilanes Chemical class 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 230000032683 aging Effects 0.000 abstract description 8
- 239000011324 bead Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008859 change Effects 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 229920001296 polysiloxane Polymers 0.000 abstract 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 22
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 21
- 239000011248 coating agent Substances 0.000 description 21
- -1 formed Substances 0.000 description 11
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 9
- 230000002528 anti-freeze Effects 0.000 description 7
- 238000005507 spraying Methods 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 230000002335 preservative effect Effects 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000005711 Benzoic acid Substances 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 208000034189 Sclerosis Diseases 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000000661 sodium alginate Substances 0.000 description 2
- 235000010413 sodium alginate Nutrition 0.000 description 2
- 229940005550 sodium alginate Drugs 0.000 description 2
- 235000010199 sorbic acid Nutrition 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical class OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 1
- YJGDZFAAUNCMCO-UHFFFAOYSA-N CCO[Si](OC)(OC)OC(C=C)=O Chemical compound CCO[Si](OC)(OC)OC(C=C)=O YJGDZFAAUNCMCO-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- SJRXVLUZMMDCNG-UHFFFAOYSA-N Gossypin Natural products OC1C(O)C(O)C(CO)OC1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical class 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVKRFMGSQUFFRH-UHFFFAOYSA-N [diethoxy(propoxy)silyl] prop-2-enoate Chemical compound CCCO[Si](OCC)(OCC)OC(C=C)=O HVKRFMGSQUFFRH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011805 ball Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- ARLJCLKHRZGWGL-UHFFFAOYSA-N ethenylsilicon Chemical group [Si]C=C ARLJCLKHRZGWGL-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- SJRXVLUZMMDCNG-KKPQBLLMSA-N gossypin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-KKPQBLLMSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- WFNUBGIJCOGTIA-UHFFFAOYSA-N methyl(prop-2-enoyloxy)silicon Chemical compound C[Si]OC(=O)C=C WFNUBGIJCOGTIA-UHFFFAOYSA-N 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000570 polyether Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a heat preserving really stone paint and a preparation method thereof. The heat preserving really stone paint is prepared from the following components in parts by weight: 150-200 parts of a silicone acrylic emulsion, 450-500 parts of natural colored sand, 150-200 parts of hollow glass beads, 5-8 parts of hydroxyethyl cellulose, 200-250 parts of tap water and 35-50 parts of an auxiliary. By combining the silicone acrylic emulsion, the natural colored sand and the hollow glass beads, the heat preserving really stone paint disclosed by the invention has stabilities such as excellent weather resistance, tarnish resistance, temperature change resistance and ageing resistance and heat preserving performance as well as color diversification. In addition, the preparation method disclosed by the invention does not need grinding. Only dispersion is needed to prepare a product paint, so that the paint is simple in production process.
Description
Technical field
The present invention relates to building coating technical field, disclose especially true mineral varnish of a kind of insulation and preparation method thereof.
Background technology
Along with science technology and society expanding economy, the development of building coating industry is also with rapid changepl. never-ending changes and improvements.True mineral varnish because of its preparation technology simple, lucuriant in design true to nature, easy construction, through once spraying just can obtain the advantages such as decorative effect that stereoscopic sensation is very strong, the application percentage in construction work is more and more higher.Traditional true mineral varnish is mainly emphasized water tolerance, stain resistance, preservative property, ageing-resistant, but pays close attention to not aspect heat-insulating property.Variation along with social life level, people require more and more environmental protection for inhabitation, low-carbon green life is also familiar with by people gradually and accepts, open less or do not exploit warm household electrical appliances, saves energy for we such one per capita the country of resource scarcity seem particularly important, using the true mineral varnish of insulation is to realize this desirable reasonable approach.
Patent CN103275579A discloses true mineral varnish of a kind of insulation and preparation method thereof, main raw material is ACRYLIC EMULSION and pearlstone, common ACRYLIC EMULSION make the weathering resistance of final true mineral varnish and stability not good, and the water-intake rate of pearlstone is high and poor water resistance, cause the heat-insulating property in true mineral varnish later stage to reduce, easy to crack, workability is poor.
Be directed to this, in prior art, also exist employing organosilicon crylic acid latex and hollow glass microbead as the coating of raw material, for example patent CN101712835A discloses a kind of heat reflection paint with hollow glass microballoon, it is comprised of surface layer and priming paint, therefore execute that man-hour requirement is two-layer could realize its heat-reflecting heat-insulating and the diversified effect of color, and composite function nano material and hollow high molecular polymer cost in its raw material are high, are unfavorable for the competition of coating products.Patent CN101671523A discloses a kind of aqueous flame-retardant and thermal-insulated coating, by emulsion, fire retardant, titanium dioxide, hollow glass micropearl, water and auxiliary agent, formed, emulsion can be organosilicon crylic acid latex, although contain merger emulsion and hollow glass micropearl in this coating, but its color is dull, does not present color variation.In addition, the water-borne heat-insulating marble coating of patent CN102093798A is also cannot variation on color.The waterproof heat-insulating coating of patent CN102702904A is except organosilicon crylic acid latex and hollow glass micro-ball, and auxiliary packing also needs talcum powder, kaolin, wilkinite, mica powder, far infrared ceramic powder and xylogen etc., and the intensity of final coating may affect to some extent.Finally, the thermal insulating coating of patent CN102391754A adopts two coated hollow glass beads, glass microballon has been carried out to modification, has increased the cost of coating, and same in the variation of color defect to some extent.
Therefore a kind of weathering resistance of demand, resistance toly stain, ageing-resistant and temp. variation resistant equistability excellent, color is diversified and with low cost, the true mineral varnish of the easy insulation of construction, so true mineral varnish could have good competitive edge on Coating Market.
Summary of the invention
The object of the present invention is to provide the true mineral varnish of a kind of insulation, its weathering resistance, resistance toly stain, ageing-resistant and temp. variation resistant equistability excellence and color variation, simultaneously with low cost, construct simple and easy.
Another object of the present invention is to provide a kind of preparation method who is incubated true mineral varnish, and this preparation method grinds without process, only needs can be made into finished product paint through high speed dispersion, and production technique is simple, and production and operating efficiency are high, with low cost.
The invention provides the true mineral varnish of a kind of insulation, press mass fraction, by following component, formed: organosilicon crylic acid latex 150-200 part, natural colour sand 450-500 part, hollow glass microbead 150-200 part, Natvosol 5-8 part, tap water 200-250 part, auxiliary agent 35-50 part.
Described organosilicon crylic acid latex is that the organosilane monomer and the acrylic monomer that contain unsaturated link(age) are coated the emulsion of the nucleocapsid structure being polymerized by nucleocapsid.Wherein organosilane monomer can be vinyl silicon monomer such as vinyltrimethoxy silane, vinyltriethoxysilane etc., or (methyl) acryloxy silicon monomer such as (methyl) acryloxy Trimethoxy silane, (methyl) acryloxy triethoxyl silane etc.Acrylic monomer wherein can be (methyl) vinylformic acid, (methyl) acrylate methyl esters, (methyl) ethyl propenoate, (methyl) butyl acrylate, (methyl) Octyl acrylate, (methyl) stearyl acrylate ester etc.
Above-mentioned organosilicon crylic acid latex combines organosilyl high thermal resistance, weathering resistance, chemical-resistant, and hydrophobicity, surface can the low contaminative that is difficult for, the high tint retention of acrylic resin, snappiness, tack are a kind of high weather-proof, high water-fast, resistant to pollution environment-friendly type building emulsions.
Described natural colour sand is to be processed through multiple working procedures such as selected, broken, pulverizing, classification, packings by ores such as marble or grouan, has firm wear-resisting, waterproof, anticorrosion, nontoxic, cohesive force is strong, the feature such as lucuriant in design.And its addition is very large, can make the color that is incubated true mineral varnish product present fabulous variation.
Described hollow glass microbead is that a kind of ball of hollow is Powdered, excellent performance, broad-spectrum Ultralight new inorganic non-metallic materials, and it will become the main flow of 21st century advanced composite material, and its particle diameter is between 2-125um; It has lightweight, volume is large, thermal conductivity is low, ultimate compression strength is high, oil absorbency is low, dispersiveness and good fluidity, chemical stability high, is the high quality filler of thermal insulation coatings, has improved widely the heat-insulating property of true mineral varnish.
Described Natvosol is to use highly pure gossypin as raw material, after alkaline purification, uses through professional etherificate and obtains, and be a kind of tensio-active agent of non-ionic type, there is good anti-splashing property, contribute to improve operating efficiency and saving color.
Described auxiliary agent is comprised of wetting dispersing agent, sanitas, membrane-forming agent, freeze proof stablizer.Sanitas refers to natural or synthetic chemical composition, can postpone coating and cause owing to affected by external factor the corruption that microorganism growth or chemical transformation cause; Can be phenylformic acid and salt thereof, phenylcarbinol, oxybenzene ester class, Sorbic Acid, chlorxylone etc.Wetting dispersing agent has surperficial parents' molecular structure, in interface direction, qualitative absorption occurs, and reduces the surface tension of liquid, and it act as fine-particle pigments and fillers dispersed in base-material; It can be mineral-type, organic and high score subclass, such as trisodium phosphate, tertiary sodium phosphate, silicate, alkyl aryl sulfonate, fatty acid amide derivant sulfuric ester, alkylphenol polyoxyethylene, polycarboxylate, poly-(methyl) acrylic acid derivative, polyether derivative etc.; Preferably polycarboxylate, is more preferably poly carboxylic acid sodium.Freeze proof stablizer can play the effect of frost protection and stable storing, can be propylene glycol, ethylene glycol etc., preferably propylene glycol.Membrane-forming agent claims again coalescing aid, can promote macromolecular compound plastic flow and recoverable deformation, improve coalescent performance, can make the material of coating film forming sclerosis within the scope of more extensive construction temperature, can be polyvinyl alcohol, sodium alginate, carbomer, xanthan gum etc., preferably polyethylene alcohol.
It is main body that the true mineral varnish of insulation of the present invention has adopted organosilicon crylic acid latex, hollow glass microbead and natural colour sand, through form paint film after dry, the ability with good weather resistance, anti-stain characteristic, chemical resistance and insulation, auxiliary agent add the over-all properties that can further improve coating.And the two be combined with of hollow glass microbead and natural colour sand, can effectively control the surface temperature of coating system, coating temperature-change resistance is excellent, make the ageing resistance of coating better simultaneously, and then play the effect of insulation, environmental protection and energy saving, improve the hot comfort of environment, can extend the life-span of coating simultaneously.
The present invention also provides the preparation method of the true mineral varnish of above-mentioned insulation, comprise the following steps: in mixing vessel, add tap water, under stirring, add Natvosol, until add auxiliary agent and stir after the abundant swelling of Natvosol, then limit stirring adds below organosilicon crylic acid latex, natural colour sand, hollow glass microbead and stirs.
Preferably, described mixing vessel, for joining paint can, stirs and adopts stirrer, and it is 25-30 minute that Natvosol adds the time of rear swelling; Adding churning time after organosilicon crylic acid latex, natural colour sand, hollow glass microbead is 25-30 minute; Mixing speed is 1000-1200 rpm.
Preferred, when adding tap water, add sanitas, after the abundant swelling of Natvosol, add wetting dispersing agent, freeze proof stablizer, membrane-forming agent.
The constructional method of the described true mineral varnish of insulation, comprises the following steps:
1, spraying seal coat: select lower kettle spray gun, pressure is 4-6kg/m
2, spraying twice, every all over interval 1 hour, the about 30um of thickness, under normal temperature dry 8 hours.
2, the true mineral varnish of spray coating heat preservation: select true mineral varnish spray gun, air-pressure controlling is at 5-7kg/m
2, the about 2-3mm of coat-thickness, certainly dry can sclerosis completely for 7 days.
Beneficial effect of the present invention has:
1, adopt the combination of organosilicon crylic acid latex, natural colour sand and hollow glass microbead, make final coating there is weathering resistance, resistance to staining property and temp. variation resistant, ageing-resistant equistability, and good heat insulating, color variation.
2, the preparation method of the true mineral varnish of insulation of the present invention is simple and easy, with low cost, and form of construction work is also simple and easy.
Embodiment
By specific embodiments of the invention given below and comparing embodiment, can further be well understood to the present invention, but they not limitation of the invention.The part not describing in detail in specific embodiment and comparing embodiment is to adopt prior art, known technology means and industry standard to obtain.
If do not specialize, the conventional means that the technique means adopting in embodiment is well known to those skilled in the art, the reagent adopting and product are also and can business obtain.The source of agents useful for same, trade(brand)name, to be necessary to list its moiety person, are all indicated when occurring first.
Reflectivity: U.S. Filmetrics, the F10-RT-UVX reflectance test instrument of Inc. company carries out precision measurement.
Resistance to coating temperature sex change: the many will CZ-A-150D in Taiwan can journey try constant temperature and humid test machine set temperature humidity and set test duration temperature-change resistance test condition and test.
Cohesive strength: the DeFelsko board drawing force tester of imported from America carries out precision measurement.
Artificial weathering ageing resistance: the Q-SUN-XE-3 type photo-stability testing case that U.S. Q=LAB company produces arranges light wave at 340nm, irradiance 0.51W/m
2, 63 ℃ of illumination temperatures, humidity is carried out continuity artificial weathering ageing resistance 80% and is tested 500h.
Each measuring technology index following (table 1):
Table 1
embodiment 1
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 450 weight parts, hollow glass microbead 150 weight parts.
Its preparation method, comprises the following steps:
Within joining paint can, drop into tap water, sanitas, with stirrer with 1000 rpms of stirrings of rotating speed, add while stirring Natvosol, until the abundant swelling of Natvosol, time is 25 minutes, then adds successively wetting dispersing agent, antifreeze stablizer, membrane-forming agent and stir with same rotating speed, then add organosilicon crylic acid latex while stirring, natural colour sand, hollow glass microbead stir, time is 25 minutes, can pack.The constructional method of the true mineral varnish of described insulation, comprises the following steps:
1, spraying seal coat: select lower kettle spray gun, pressure is 4kg/m
2, spraying twice, every all over interval 1 hour, the about 30um of thickness, under normal temperature dry 8 hours.
2, the true mineral varnish of spray coating heat preservation: select true mineral varnish spray gun, air-pressure controlling is at 4-7kg/m
2, the about 2mm of coat-thickness, certainly dry can sclerosis completely for 7 days.
embodiment 2
Be incubated each component that true mineral varnish adopts following weight part: tap water 220 weight parts, sanitas Sorbic Acid 1.5 weight parts, Natvosol 7 weight parts, wetting dispersing agent polyoxyethylene 6 weight parts, antifreeze stablizer ethylene glycol 18 weight parts, membrane-forming agent polyvinyl alcohol 10 weight parts, organosilicon crylic acid latex 180 weight parts, natural colour sand 480 weight parts, hollow glass microbead 180 weight parts.
Preparation method and constructional method are substantially the same manner as Example 1, difference while being preparation method stirrer rotating speed be 1100 rpms, Natvosol swelling time is 28 minutes, adding churning time after organosilicon crylic acid latex is 30 minutes.
embodiment 3
Be incubated each component that true mineral varnish adopts following weight part: tap water 250 weight parts, sanitas methyl hydroxybenzoate 2 weight parts, Natvosol 8 weight parts, wetting dispersing agent polyoxyethylene nonylphenol ether 7 weight parts, antifreeze stablizer propylene glycol 25 weight parts, membrane-forming agent sodium alginate 12 weight parts, organosilicon crylic acid latex 200 weight parts, natural colour sand 500 weight parts, hollow glass microbead 200 weight parts.
Preparation method and constructional method are substantially the same manner as Example 1, difference while being preparation method stirrer rotating speed be 1200 rpms, Natvosol swelling time is 30 minutes, adding churning time after organosilicon crylic acid latex is 30 minutes.
comparative example 1
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, hollow glass microbead 600 weight parts.Preparation method is identical with constructional method and embodiment 1.
ratio is compared with 2
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 600 weight parts.Preparation method is identical with constructional method and embodiment 1.
comparative example 3
Be incubated each component that true mineral varnish adopts following weight part: tap water 200 weight parts, preservative benzoic acid 1 weight part, Natvosol 5 weight parts, wetting dispersing agent poly carboxylic acid sodium 5 weight parts, antifreeze stablizer propylene glycol 15 weight parts, membrane-forming agent polyvinyl alcohol 8 weight parts, organosilicon crylic acid latex 150 weight parts, natural colour sand 450 weight parts, pearlstone 150 weight parts.Preparation method is identical with constructional method and embodiment 1.
True mineral varnish to each embodiment and comparative example is tested, and the results of property obtaining is as follows:
Embodiment the performance test results following (table 2):
Table 2
Comparative example the performance test results following (table 3):
Table 3
Above disclosed is only the preferred embodiments of the present invention, certainly can not limit with this interest field of the present invention, and the equivalent variations of therefore doing according to the present patent application the scope of the claims, still belongs to the scope that the present invention is contained.
Claims (10)
1. the true mineral varnish of insulation, by mass fraction, is comprised of following component: organosilicon crylic acid latex 150-200 part, natural colour sand 450-500 part, hollow glass microbead 150-200 part, Natvosol 5-8 part, tap water 200-250 part, auxiliary agent 35-50 part.
2. the true mineral varnish of insulation according to claim 1, is characterized in that: described organosilicon crylic acid latex is the emulsion with nucleocapsid structure that organosilane monomer and acrylic monomer are polymerized.
3. the true mineral varnish of insulation according to claim 1, is characterized in that: described hollow glass microbead is that ball is Powdered, particle diameter is 2-125 μ m.
4. the true mineral varnish of insulation according to claim 1 and 2, is characterized in that: described natural colour sand is to be processed through the operation of selected, broken, pulverizing, classification, packing by marble or grouan.
5. the true mineral varnish of insulation according to claim 1 and 2, is characterized in that: described auxiliary agent is comprised of wetting dispersing agent, sanitas, membrane-forming agent, freeze proof stablizer.
6. prepare the method that is incubated true mineral varnish described in claim 1-4 any one for one kind, it is characterized in that: comprise the steps: to add tap water in mixing vessel, under stirring, add Natvosol, until add auxiliary agent and stir after the abundant swelling of Natvosol, then limit stirring adds below organosilicon crylic acid latex, natural colour sand, hollow glass microbead and stirs.
7. method according to claim 5, is characterized in that: described mixing vessel is for joining paint can; Stir and adopt stirrer to carry out.
8. method according to claim 5, is characterized in that: the time of Natvosol swelling is 25-30 minute; Adding churning time after organosilicon crylic acid latex, natural colour sand, hollow glass microbead is 25-30 minute.
9. method according to claim 5, is characterized in that: mixing speed is 1000-1200 rpm.
10. method according to claim 5, is characterized in that: when adding tap water, add sanitas, add wetting dispersing agent, freeze proof stablizer, membrane-forming agent after the abundant swelling of Natvosol.
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