CN105331231A - Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof - Google Patents
Energy-saving and environment-friendly real stone type composite coating and preparation method and construction method thereof Download PDFInfo
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- CN105331231A CN105331231A CN201510749300.4A CN201510749300A CN105331231A CN 105331231 A CN105331231 A CN 105331231A CN 201510749300 A CN201510749300 A CN 201510749300A CN 105331231 A CN105331231 A CN 105331231A
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- 238000000576 coating method Methods 0.000 title claims abstract description 189
- 239000011248 coating agent Substances 0.000 title claims abstract description 188
- 239000002131 composite material Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- 239000004575 stone Substances 0.000 title abstract description 14
- 238000010276 construction Methods 0.000 title abstract description 7
- 239000000463 material Substances 0.000 claims abstract description 185
- 239000000839 emulsion Substances 0.000 claims abstract description 93
- 239000003973 paint Substances 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 230000000694 effects Effects 0.000 claims abstract description 47
- 239000008204 material by function Substances 0.000 claims abstract description 46
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000008367 deionised water Substances 0.000 claims abstract description 27
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 27
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 16
- 239000004576 sand Substances 0.000 claims abstract description 13
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 105
- 239000006185 dispersion Substances 0.000 claims description 82
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 63
- 239000011707 mineral Substances 0.000 claims description 63
- 239000002966 varnish Substances 0.000 claims description 63
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- 230000008719 thickening Effects 0.000 claims description 59
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- 238000004581 coalescence Methods 0.000 claims description 55
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- 238000003756 stirring Methods 0.000 claims description 49
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- 239000000126 substance Substances 0.000 claims description 31
- 239000005321 cobalt glass Substances 0.000 claims description 25
- 239000002994 raw material Substances 0.000 claims description 24
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- 239000002002 slurry Substances 0.000 claims description 21
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- 239000000057 synthetic resin Substances 0.000 claims description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 18
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 18
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- 229920000126 latex Polymers 0.000 claims description 16
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- 238000000034 method Methods 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000011787 zinc oxide Substances 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- 229920000058 polyacrylate Polymers 0.000 claims description 8
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 claims description 2
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- 238000005118 spray pyrolysis Methods 0.000 claims description 2
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- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims 1
- 238000009413 insulation Methods 0.000 abstract description 26
- 238000005034 decoration Methods 0.000 abstract description 12
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- 238000005265 energy consumption Methods 0.000 description 4
- 239000004579 marble Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
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- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
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- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- CZIRZNRQHFVCDZ-UHFFFAOYSA-L titan yellow Chemical compound [Na+].[Na+].C1=C(C)C(S([O-])(=O)=O)=C2SC(C3=CC=C(C=C3)/N=N/NC3=CC=C(C=C3)C3=NC4=CC=C(C(=C4S3)S([O-])(=O)=O)C)=NC2=C1 CZIRZNRQHFVCDZ-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an energy-saving and environment-friendly real stone type composite coating which is prepared from a cover surface layer coating, a real stone paint middle layer coating and a prime coating. The prime coating is prepared from styrene-acrylic emulsion, water, titanium dioxide, special filler and auxiliary C. The real stone paint middle layer coating is prepared from synthesized resin emulsion, deionized water, functional material A, self-made functional color sand and auxiliary A. The cover surface layer coating is prepared from deionized water, synthesized resin emulsion, functional material B and auxiliary B. According to the composite coating layer, the nanometer functional materials are applied to the real stone paint middle layer coating and the cover surface layer coating, the reflection and thermal insulation effect of the nanometer functional materials and the decoration effect of natural stone of the real stone paint middle layer coating are organically and innovatively combined, the energy-saving and environment-friendly real stone type composite coating layer is ingeniously formed through a heat preservation layer formed according to the natural coating thickness of the real stone paint middle layer coating, energy can be saved by 40-50%, the indoor temperature can be decreased by 6-8 DEG C, and the remarkable thermal insulation and heat preservation effects are achieved. The invention further discloses a preparation method and construction method of the energy-saving and environment-friendly real stone type composite coating.
Description
Technical field
The invention belongs to decorating building decorative materials technical field, be specifically related to a kind of energy-saving ring fidelity stone-type composite dope, and relate to its preparation method and constructional method.
Background technology
As is known in the industry, to be directly sticked on the exterior wall of buildings or cladding such as marble, granite or other similar material can play decorative effect and certain heat insulation and preservation effect significantly.And the energy-saving effect outside the building wall making buildings have with dry hanging dry-hanging insulation board comes excellent for cladding marble, can by the Chinese patent CN101725311A(pearlite fiber composite fire-proof heat insulation board be not limited to this), CN2352333Y(composite heat insulation board), CN2825784Y(thermal insulation plate for external wall), CN20138361Y(exterior wall external insulation decorative flame-retardant thermal insulation board), CN102219455A(inorganic lightweight aggregate thermal insulation sheet material and preparation method thereof) and CN102417327A(external wall integral solidified organic heat insulation board and preparation method thereof) etc. confirmation, but cladding warming plate is inferior to marble to decorating building successful.
No matter be that dry-hanging insulation board or marble all exist and be not limited to the following logical fraud enumerated: one is from great, there is potential safety hazard; Two is complicated construction techniques, long in time limit; Three is that price is high, is unfavorable for embodying economy principle.In view of this, the exterior coating that comprehensively can make up these drawbacks is subject to the favor of people gradually, and be no lack of in published Chinese patent literature and be seen in, slightly with enumerate as CN11152100C(heat-insulation coating for house), this patent formula easy construction, cheap and antiageing effect are well its strong point, but owing to employing asbestos wool in formula, thus feature of environmental protection security is affected, and acid polyethylene (PVA) water tolerance in formula is poor, although use water glass modification, but still be not enough to the water-fast effect that the acquisition phase gets; CN1205279C(energy saving heat preserving paint) there is the low and construction excellent part easily of cost, but owing to being waste polystyrene foam plastic and pearlstone as heat insulation main raw material, again because the density of waste polystyrene foam plastic cannot ensure, particularly when particle diameter is less than 3 ㎜, effect of heat insulation is tending towards losing, cause its effect of heat insulation to be short of because the uncoated process of pearlstone easily absorbs water simultaneously, therefore heat insulation and preservation effect is low on the one hand, and ultimate compression strength is fragile on the other hand; CN1124320C(waterproof paint), this patent formula is famous has the elongated place of anti-aging and cracking resistance stood out from one's fellows, but does not have heat insulation and preservation effect; CN100344713C(bicomponent cement base polystyrene foamed particle heat insulation coating) and CN100344714C(bicomponent gypsum polystyrene foamed particle heat insulation paint) although respectively there is unique strong point, not having emulation (namely emulation property refers to imitative stone material) is its shortcoming.Again, Authorization Notice No. CN1124320C(waterproof paint) and CN1152100C(heat-insulation coating for house) same exist described in shortcoming.Especially, be not limited to skin coating disclosed in these documents of enumerating and all do not there is simulated effect, namely not there is the muddy imitative stone effect become as sky, thus the decoration decoration effect of buildings is affected, and the decoration of buildings decoration effect plays the multiple action promoting image and promote sight etc. to a great extent.
Further, for improving decorate properties, start in the market or widely use the aqueous colorful stone-like coating and true mineral varnish or texture coating with lithotome decoration texture, and there is more and more fiery gesture, also there is corresponding patent simultaneously, slightly recommend to have " a kind of Waterborne stone-like multicolor coating and preparation method thereof " as: application for a patent for invention publication No. CN102277045A with what enumerate, this patent application scheme has the appearance of coat levels are rich alleged by specification sheets the 0034th hurdle, the strong strong point with having lithotome decorative pattern of stereoscopic sensation, but, be the alcohol ester of 1: 1 and the aqueous solution of butyl glycol ether because film coalescence aid employs weight ratio, therefore security and the feature of environmental protection is lost, because butyl glycol ether is to human health damage and suction can be fatal, again, show to damage reproductive system in animal experiment, so must be double cautious to the coating produced containing this composition and this coating of use, Authorization Notice No. CN101338149B(water-soluble colorful coating and preparation method thereof), ZL201010533680.5 (a kind of composite dope that there is texture coating layer and use) although overcome above-mentioned shortcoming, not having heat preservation energy-saving effect is still its shortcoming.
In recent years, along with industrialization, urbanization and modern acceleration advance, nearly 2,000,000,000 square metres of the floor area of building of China's annual town and country newly constructed house, wherein more than 80% is high energy consumption building, nearly 40,000,000,000 square metres of existing building, more than 95% all belongs to high energy consumption building, and energy utilization rate is only 33%, falls behind developed country 20 years.Building energy consumption accounts for 30% of China's total energy consumption, and building energy conservation improves the primary aspect of social energy use efficiency by becoming.For this reason, country shows great attention to building energy-saving and has put into effect a series of relevant regulations about building energy-saving.Because the energy-conservation materials for wall self that only leans on of buildings is difficult to reach the index of expectation as energy-conservation more than 65%, the skin coating therefore with good energy-saving effect receives the concern of people as a supplement and more and more and thinks highly of, wherein, integrate energy-conserving and environment-protective and contribute to promoting the coating of decorating building effect increasingly in one's favour.
Comprehensive above-mentioned prior art, has environmental protection and energy saving for exploitation and has the true stone-type composite dope that namely good simulated effect exactly like lithotome effect and have positive realistic meaning.
Summary of the invention
Primary and foremost purpose of the present invention be to provide a kind of be suitable for skin ornamental contribute to embodying muddy become as sky emmarble effect, be conducive to the true stone-type composite dope of environmental protection and energy saving that shows good heat insulating reflecting effect and use enhancement building energy-saving effect.Nano-functional material is applied in true mineral varnish middle coating intermediate, finishing coating materials by composite dope layer of the present invention; the reflective insulation effectiveness of nano-functional material, true mineral varnish middle coating intermediate lithotome decorative effect are combined; and the thermal insulation layer that the natural coat-thickness applying true mineral varnish middle coating intermediate is formed constitutes environmental protection and energy saving true stone-type composite dope layer; room temp 6 ~ 8 DEG C can be reduced; realize energy-conservation 40 ~ 50%, there is significant heat insulation and preservation effect; Meanwhile, due to the photoextinction of nano-functional material, natural dumb light film can be formed, be conducive to reducing difficulty of construction, improve surface simulating degree and surface decoration effect.This invention is applicable to villa, senior commercial and residential building, Administration Building, shop etc. and had not only required to have lithotome decorative effect, but also required to have the place decoration of energy-saving effect.
Another object of the present invention is to the preparation method that above-mentioned energy-saving ring fidelity stone-type composite dope is provided.
Another object of the present invention is to provide the constructional method of above-mentioned energy-saving ring fidelity stone-type composite dope.
For realizing primary and foremost purpose of the present invention, technical scheme provided by the invention is:
The true stone-type composite dope of a kind of environmental protection and energy saving, is made up of finishing coating materials, true mineral varnish middle coating intermediate and priming paint, wherein,
Described priming paint comprises following raw materials in part by weight: synthetic resin emulsion 28 ~ 34 parts, 26.3 ~ 28.1 parts, water, titanium dioxide 5 ~ 10 parts, special type filler 25 ~ 35 parts and auxiliary agent C4.7 ~ 4.9 part;
Described true mineral varnish middle coating intermediate is made up of following raw materials in part by weight: synthetic resin emulsion 10.0 ~ 25.0 parts, deionized water 0.5 ~ 11.0 part, functional materials A3.0 ~ 10.0 part, smalt 60.0 ~ 78 parts and auxiliary agent A 2.5 ~ 3.4 parts, described smalt is for crossing one or more combinations by the different ratios needed for actual model preparation in the self-control function white sand of 10 order to 200 order screen cloth at different levels, the color sand of assorted self-control function respectively, described function white sand, the color sand of function is by inorganic bond material, one or more cold pigment etc. mix according to certain ratio uniform, adopt spray pyrolysis technologies, carry out coated to the natural white sand of required particle diameter, by calculating the thermodynamics analysis methods of enthalpy produced in chemical reaction △ H and free energy △ G, determine design of material and technology controlling and process, preparation size is even, coated complete, thickness is consistent, there is excellent sunlight reflection function and the color sand of superior hiding powder function, and be applied in Project Product, described cold pigment comprises Dupont, the golden red type titanium dioxide of the companies such as Australia Mei Lilian, the anthraquinone ketone with excellent reflection function that the company such as Hai Bo chemical company and U.S. Xue Te chemical industry of Germany provides is red, phthalein is dark green, oxidation titan yellow, phthalein is blue or green blue, the various cold pigment such as carbon black.
Described finishing coating materials is formed by comprising following raw materials in part by weight: deionized water 18.8 ~ 48.05 parts, synthetic resin emulsion 40.0 ~ 60.0 parts, functional materials B3.0 ~ 15.0 part and auxiliary agent B 5.5 ~ 6.2 parts.
In specific embodiment of the present invention, described true mineral varnish middle coating intermediate synthetic resin emulsion is the mixing of a kind of in benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex, fluorine carbon emulsion, elastic emulsion or any two kinds.
In specific embodiment of the present invention, described finishing coating materials synthetic resin emulsion is pure-acrylic emulsion, organosilicon crylic acid latex or fluorine carbon emulsion;
In specific embodiment of the present invention, described priming paint synthetic resin emulsion is benzene emulsion, pure-acrylic emulsion or organosilicon crylic acid latex, and over-all properties and economy are considered, preferred benzene emulsion.
Described benzene emulsion, organosilicon crylic acid latex, fluorine carbon emulsion are respectively the ACRYLIC EMULSION containing styrene monomer, siloxane bond, carbon-fluorine bond grafting in molecule.
Described pure-acrylic emulsion is the ACRYLIC EMULSION of 100% Acrylic Acid Monomer synthesis.
Described elastic emulsion is the ACRYLIC EMULSION that after film forming, film has unit elongation.
Described benzene emulsion can give water-fast, alkaline-resisting, stain resistant and the water-whitening resistance of film excellence, as rich in the Ahmedabad RS992 of company, the TL668 of Shanghai sunrise company;
Described pure-acrylic emulsion, organosilicon crylic acid latex also have excellent weather resistance and lasting tint retention, 706T, 996AD of company as rich in Ahmedabad, AD15, AD51 etc. of Japanese Showa Corporation.
Described elastic emulsion as rich in the Ahmedabad 752D of company, 4369 of Shanghai sunrise company etc.
In specific embodiment of the present invention, the synthetic resin emulsion of described true mineral varnish middle coating intermediate is mixed by the elastic emulsion 752D of total emulsion weight basis 10 ~ 20% and the pure-acrylic emulsion 706T of total emulsion weight basis 80 ~ 90%.
In another specific embodiment of the present invention, described auxiliary agent A is made up of the raw material comprising following proportioning by weight: dispersion agent 0 ~ 0.8 part, wetting agent 0.1 ~ 0.3 part, defoamer 0 ~ 0.5 part, sanitas 0.1 ~ 0.3 part, antifreezing agent 0 ~ 1.0 part, film coalescence aid 0.1 ~ 1.0 part and thickening material 0.3 ~ 1.2 part.
Described auxiliary agent B is made up of the raw material comprising following proportioning by weight: dispersion agent 0.3 ~ 0.8 part, wetting agent 0.1 ~ 0.2 part, defoamer 0 ~ 0.5 part, sanitas 0.1 ~ 0.3 part, antifreezing agent 0.5 ~ 2.5 part, film coalescence aid 1.0 ~ 4.0 parts, thickening material 0.1 ~ 1.5 part.
Described auxiliary agent C is formed by comprising following raw material by weight: dispersion agent 0.3 ~ 0.5 part, wetting agent 0.1 ~ 0.2 part, defoamer 0.2 ~ 0.4 part, sanitas 0.1 ~ 0.2 part, antifreezing agent 1.0 ~ 1.5 parts, film coalescence aid 1.5 ~ 2.0 parts, thickening material 0.7 ~ 1.0 part.
Described priming paint special type filler comprises 100 order ~ 200 order silica powders, and its hard provided, uneven surface, can give the ply adhesion of film excellence.
Described dispersion agent is polyacrylic acid sodium salt, ammonium polyacrylate salt, as SN5040, the SN5027 of Japanese Nuo Puke, the pleased of Dow Chemical, 2500D.
Described wetting agent selects WT, US Air gas chemistry painting industry wetting agent DCO1 or the US Air gas chemistry painting industry wetting agent 1340 of the CF-11 of German BASF, German BASF.
Described thickening material selects sub-250HBR, PLUS330 across dragon, the HS30000YP of Clariant, the RH-420 of rising sun electrification obtain one or more mixing in the TT-935 of Dow Chemical.
Described sanitas selects German Shu Mei company K40, German Shu Mei company A28S, the LX150 of Dow Chemical or the R640 of Dow Chemical.
The Byk024 of A10, SN8034 or Bi Ke company of Henkel KGaA selected by described defoamer.
Described antifreezing agent selects ethylene glycol or propylene glycol.
Described film coalescence aid selects the alcohol ester 12 of Yi Shiman.
In another specific embodiment of the present invention, described functional materials A is made up of the raw material comprising following parts by weight proportioning: zinc oxide: barium sulfate: talcum powder=1:9 ~ 15:25 ~ 35, especially with zinc oxide: barium sulfate: talcum powder=1:12:30 is good; Described functional materials B is made up of the raw material comprising following parts by weight proportioning: hollow ceramic microballon: Opacifying polymers=1 ~ 3:1, especially with hollow ceramic microballon: Opacifying polymers=2:1 is good.
Described Opacifying polymers comprises the Unihub-E of Dow Chemical, Snowtex25, Snowtex30 or Snowtex45 of Ying Zhou foreign firm of Korea S.
The technical scheme realizing another goal of the invention of the present invention is: the preparation method of the true stone-type composite dope of a kind of environmental protection and energy saving, comprises the preparation method of priming paint, true mineral varnish middle coating intermediate, finishing coating materials, wherein,
The preparation method of described priming paint comprises the following steps:
Deionized water 26.3 ~ 28.1 parts is added in coating material production still, start agitator, add the sanitas of formula ratio successively equably, dispersion agent, defoamer, antifreezing agent, film coalescence aid, Mierocrystalline cellulose, 1000 ~ 1350 revs/min of high speed dispersion 10 ~ 15min, slowly add titanium dioxide 5 ~ 10 parts and special type filler 25 ~ 35 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1000 ~ 1350 revs/min after terminating that feeds intake, high speed dispersion 35 ~ 45min, add the synthetic resin emulsion of 28 ~ 34 weight parts again, add thickening material, be in harmonious proportion, inspection, packaging,
The preparation method of described true mineral varnish middle coating intermediate comprises the following steps:
Step one) the producing of base-material: in coating material production still, add deionized water 0.5 ~ 11.0 part, start agitator, auxiliary agent A 2.5 ~ 3.4 parts, functional materials A3.0 ~ 10.0 part are added successively under the stirring velocity of 500 ~ 600 revs/min, reinforced complete, with the speed high speed dispersion 20 ~ 40 minutes of 1200 ~ 1500 revs/min, add the synthetic resin emulsion 10.0 ~ 25.0 parts taken by weight again, stirring 10 ~ 15 minutes is continued with the speed of 600 ~ 1000 revs/min, add thickening material, stir, namely obtain required base-material;
Step 2) the producing of true mineral varnish middle coating intermediate:
In the base-material of above-mentioned preparation, add self-control function smalt 60.0 ~ 78 parts, stir.
In the present invention and then a specific embodiment, step one) stirring velocity when feeding intake controls at 500 ~ 600 revs/min, and speed is too slow, and mixing effect is poor; Speed is too fast, can produce powder and fly upward, cause material waste and environmental pollution; High speed dispersion speed control, at 1200 ~ 1500 revs/min, is dispersed to less than 15 μm, jitter time 20 ~ 40 minutes.To control rate of dispersion 1350 ~ 1450 revs/min, jitter time 30 minutes is good.
In the present invention and then a specific embodiment, step 2) stirring velocity 600 ~ 1000 revs/min, feed intake complete continuation stirring 10 ~ 15 minutes.
The preparation method of described finishing coating materials comprises the following steps:
Step one) the producing of function slurry:
Deionized water 18.8 ~ 48.05 parts is added in coating material production still, start agitator, governing speed 500 ~ 600 revs/min, add auxiliary agent B 5.55 ~ 6.20 parts, functional materials B3.0 ~ 15.0 part are added after stirring, adopt frequency vibration polishing, obtained fineness controls the function slurry within 15 μm;
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add synthetic resin emulsion 40.0 ~ 60.0 parts, the speed of 500 ~ 600 revs/min stirs, and adds thickening material, stirs, and namely makes the finishing coating materials with environmental protection and energy saving effect.
The constructional method of a kind of environmental protection of the present invention true stone-type composite dope is as follows:
1. processing base level: basal plane is carried out levelling with consolidation process, drying, obtain firm flat surfaces;
2. described priming paint is stirred, optionally add water adjustment viscosity to the 75 ~ 80KU of 0 ~ 5%, be applied over basal plane, dry 4 ~ 6h;
3. leave standstill 10 ~ 15min after being stirred by described true stone shape middle coating intermediate, technique is constructed routinely, dry 24 ~ more than 48h;
4, with described finishing coating materials routinely technique carry out overlay treatment.
The beneficial effect that the present invention produces:
Nano-functional material is applied to true mineral varnish middle coating intermediate by composite dope layer of the present invention, in finishing coating materials, creatively by the reflective insulation effectiveness of nano-functional material, true mineral varnish middle coating intermediate lithotome decorative effect combines, and the thermal insulation layer that the natural coat-thickness applying true mineral varnish middle coating intermediate is dexterously formed constitutes environmental protection and energy saving true stone-type composite dope layer, coating content of volatile organic compound, free formaldehyde content is respectively at 10g/L, within 8mg/kg, extremely environmental protection, energy-conservation 40 ~ 50% can be realized, reduce room temp 6 ~ 8 DEG C, there is significant heat insulation and preservation effect, meanwhile, due to the photoextinction of nano-functional material, natural dumb light film can be formed, be conducive to reducing difficulty of construction, improve surface simulating degree and surface decoration effect.
Accompanying drawing explanation
The present invention is further illustrated below in conjunction with the drawings and specific embodiments.
Fig. 1 is coating process general flow chart of the present invention.
Number in the figure: 1 is finishing coating materials, 2 is true mineral varnish middle coating intermediate, and 3 is priming paint.
Embodiment
In order to make technique means of the present invention, creation characteristic, reach object and effect is easy to understand, below in conjunction with specific embodiment, set forth the present invention further.
Embodiment 1
Finishing coating materials (by weight)
Pure-acrylic emulsion 40 parts, 48.05 parts, water, functional materials B:6 part, auxiliary agent B: 5.95 parts.
Functional materials B is the mixture of hollow glass microbead and Opacifying polymers, and part by weight is 2.5:1.
Auxiliary agent B comprises dispersion agent, wetting agent, thickening material, sanitas, defoamer, antifreezing agent and film coalescence aid.
Dispersion agent is the pleased of ammonium polyacrylate salt, such as Dow Chemical, and consumption is the 0.5wt% of coating gross weight.
The WT of German BASF selected by wetting agent, and consumption is the 0.15wt% of finishing coating materials gross weight.
The RH-420 of rising sun electrification selected by thickening material, and consumption is the 1.5wt% of finishing coating materials gross weight.
German Shu Mei company K40 selected by sanitas, and consumption is the 0.3wt% of finishing coating materials gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 2.5wt% of finishing coating materials gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.0wt% of finishing coating materials gross weight.
Preparation method:
Step one) the producing of function slurry:
Deionized water 48.05 parts is added in coating material production still, start agitator, governing speed 500 revs/min, adds dispersion agent pleased successively equably: 0.5w part, wetting agent WT:0.15 part, sanitas K40:0.3 part, antifreezing agent propylene glycol: 2.5 parts, film coalescence aid alcohol ester 12: 1.0 parts, functional materials B6.0 part is added after stirring, adopt frequency vibration polishing, fineness is controlled within 15 μm, obtained required order number function slurry.
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add pure-acrylic emulsion 40.0 parts, governing speed 600 revs/min, add thickening material RH-420:1.5 part, stir, namely make the finishing coating materials with environmental protection and energy saving effect.
True mineral varnish middle coating intermediate (by weight)
Benzene emulsion 21.25 parts, 2.6 parts, water, self-control function smalt (10#-200#) 64.5 parts, functional materials A8.25 part, auxiliary agent A 3.4 parts.
Auxiliary agent A comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polyacrylic acid sodium salt, as Japanese Nuo Puke 5040, consumption is the 0.7wt% of true mineral varnish middle coating intermediate gross weight;
The WT of German BASF selected by wetting agent, and consumption is the 0.2wt% of true mineral varnish middle coating intermediate gross weight.
The HS30000YP of Clariant selected by thickening material, and consumption is the 0.6wt% of true mineral varnish middle coating intermediate gross weight.
German Shu Mei company A28S selected by sanitas, and consumption is the 0.25wt% of true mineral varnish middle coating intermediate gross weight.
The B556 of Japanese rising sun electrification Co., Ltd. selected by defoamer, and consumption is the 0.4wt% of true mineral varnish middle coating intermediate gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 0.5wt% of true mineral varnish middle coating intermediate gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 0.75wt% of true mineral varnish middle coating intermediate gross weight.
Self-control function smalt is the sand grains of 10#-200#.
Functional materials A is mixed by the raw material of following parts by weight proportioning to form: zinc oxide: barium sulfate: talcum powder=1:9:35.
Preparation method:
Step one) the producing of base-material:
In coating material production still, add deionized water 2.6 parts, start agitator, governing speed to 500 rev/min, add dispersion agent 5040:0.7 part successively, wetting agent WT:0.2 part, thickening material HS30000YP:0.6w part,
Sanitas A28S:0.25 part, defoamer B556:0.4 part, antifreezing agent ethylene glycol: 0.5 part, film coalescence aid alcohol ester 12: 0.75 part, functional materials A8.25 part, feeds intake after terminating, improves rate of dispersion to 1200 rev/min, disperse 40 minutes, to fineness 15 μm, then add the benzene emulsion 21.25 parts taken by weight, continue to stir, namely obtain required base-material.
Step 2) the producing of true mineral varnish middle coating intermediate:
Regulate stirring velocity to 600 rev/min, in the base-material of above-mentioned preparation, slowly add self-control function smalt (10#-200#) 64.5 parts, improve rotating speed to 800 rev/min, stir, the attentional manipulation time is within 15 minutes.
Priming paint (by weight):
Benzene emulsion 420V34 part, 26.3 parts, water, titanium dioxide 10 parts, 100 order ~ 200 order silica powders 25 parts, auxiliary agent C4.7 part.
Auxiliary agent C comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polyacrylic acid sodium salt, and as 5040 of Japanese Nuo Puke, consumption is the 0.3wt% of priming paint gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.1wt% of priming paint gross weight.
The combination of the HS30000YP of Clariant and the TT-935 of Dow Chemical selected by thickening material, and consumption is respectively 0.3wt% and 0.4wt% of priming paint gross weight.
German Shu Mei company A28S selected by sanitas, and consumption is the 0.20wt% of priming paint gross weight.
The B556 of Japanese rising sun electrification Co., Ltd. selected by defoamer, and consumption is the 0.4wt% of priming paint gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 1.0wt% of priming paint gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 2.0wt% of priming paint gross weight.
The preparation method of this priming paint comprises the following steps:
Deionized water 26.3 parts is added in coating material production still, start agitator, add dispersion agent 5040:0.3 part successively equably, wetting agent CF-11:0.1 part, thickening material HS30000YP0.3 part, sanitas A28S:0.20 part, defoamer B556:0.4 part, antifreezing agent ethylene glycol: 1.0 parts, film coalescence aid alcohol ester 12: 2.0 parts, 1000 revs/min of high speed dispersion 15min, slowly add titanium dioxide 10 parts and 100 order ~ 200 order silica powder 25 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1200 revs/min after terminating that feeds intake, high speed dispersion 45min, add the benzene emulsion of 34 weight parts, add TT-935:0.4 part again, be in harmonious proportion, inspection, packaging.
Embodiment 2
Finishing coating materials (by weight)
Organosilicon crylic acid latex 45 parts, 46.55 parts, water, functional materials B:3 part, auxiliary agent B: 5.55 parts.Wherein:
Functional materials B is the mixture of hollow glass microbead and Opacifying polymers, and part by weight is 1.5:1.
Auxiliary agent B comprises dispersion agent, wetting agent, thickening material, sanitas, defoamer, antifreezing agent and film coalescence aid.
Dispersion agent is ammonium polyacrylate salt, and as the 2500D of Dow Chemical, consumption is the 0.3wt% of finishing coating materials gross weight.
US Air gas chemistry painting industry wetting agent DCO1 selected by wetting agent, and consumption is the 0.10wt% of finishing coating materials gross weight.
The TT-935 of Dow Chemical selected by thickening material, and consumption is the 1.15wt% of finishing coating materials gross weight.
German Shu Mei company A28S selected by sanitas, and consumption is the 0.25wt% of finishing coating materials gross weight.
The Byk024 of Bi Ke company, consumption is the 0.15wt% of finishing coating materials gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 2.0wt% of finishing coating materials gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.6wt% of finishing coating materials gross weight.
Preparation method:
Step one) the producing of function slurry:
In coating material production still, add deionized water 46.55 parts, start agitator, governing speed 550 revs/min, add dispersion agent 2500D:0.3 part successively equably, wetting agent DCO1:0.10 part, sanitas A28S:0.25, defoamer Byk024:0.15 part, antifreezing agent ethylene glycol: 2.0 parts, film coalescence aid alcohol ester 12: 1.6 parts, adds functional materials B3.0 part after stirring, adopt frequency vibration polishing, fineness is controlled within 15 μm, obtained required order number function slurry.
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add organosilicon crylic acid latex emulsion 45.0 parts, governing speed 600 revs/min, add thickening material TT-935:1.15 part, stir, namely make the finishing coating materials with environmental protection and energy saving effect.
True stone shape middle coating intermediate (by weight)
Pure-acrylic emulsion 25 parts, 1.9 parts, water, self-control function smalt (10#-200#) 60.0 parts, functional materials A10.0 part, auxiliary agent A 3.1 parts.
Auxiliary agent A comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polypropylene acid sodium-salt, and as the pleased of Dow Chemical, consumption is the 0.8wt% of true mineral varnish middle coating intermediate gross weight.
US Air gas chemistry painting industry wetting agent DCO1 selected by wetting agent, and consumption is the 0.2wt% of true mineral varnish middle coating intermediate gross weight.
The TT-935 of Dow Chemical selected by thickening material, and consumption is the 0.3wt% of true mineral varnish middle coating intermediate gross weight.
German Shu Mei company K40 selected by sanitas, and consumption is the 0.30wt% of true mineral varnish middle coating intermediate gross weight.
The SN8034 of Henkel KGaA selected by defoamer, and consumption is the 0.5wt% of coating gross weight.
Film coalescence aid selects propandiol butyl ether, alcohol ester 12 or both combinations, and consumption is respectively 0.6wt% and 0.4wt% of true mineral varnish middle coating intermediate gross weight.
Self-control function smalt: the smalt of 10#-200#.
Functional materials A is made up of the raw material comprising following parts by weight proportioning: zinc oxide: barium sulfate: talcum powder=1:12:23.
Preparation method:
Step one) the producing of base-material:
Deionized water 1.9 parts is added in coating material production still, start agitator, governing speed to 600 rev/min, add dispersion agent pleased equably successively: 0.8 part, wetting agent DCO1:0.2 part, sanitas K40:0.30 part, defoamer SN8034:0.5 part, film coalescence aid propandiol butyl ether, alcohol ester 12 is respectively 0.6 part and 0.4 part, functional materials A10.0 part, feed intake after terminating, improve fast rate of dispersion to 1500 rev/min, disperse 30 minutes, to fineness 15 μm, speed is down to 550 revs/min, add the pure-acrylic emulsion 25 parts taken by weight again, thickening material TT-935:0.3 part, continue to stir, namely required base-material is obtained.
Step 2) the producing of true mineral varnish middle coating intermediate:
Regulate stirring velocity to 500 rev/min, in the base-material of above-mentioned preparation, slowly add self-control function smalt (10#-200#) 60.0 parts, improve rotating speed to 1000 rev/min, stir, the attentional manipulation time is within 15 minutes.
Priming paint (by weight):
Benzene emulsion 420V28 part, 27.1 parts, water, titanium dioxide 5 parts, 100 order ~ 200 order silica powders 35 parts, auxiliary agent C4.9 part.
Auxiliary agent C comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Described dispersion agent is polyacrylic acid sodium salt, as Japanese Nuo Puke 5040, consumption is the 0.5wt% of priming paint gross weight.
The WT of German BASF selected by wetting agent, and consumption is the 0.2wt% of priming paint gross weight.
The sub-combination across the 250HBR of dragon and the RH-420 of Japanese rising sun electrification selected by thickening material, and consumption is respectively 0.2wt%, 0.8wt% of priming paint gross weight.
The R640 of Dow Chemical selected by sanitas, and consumption is the 0.1wt% of priming paint gross weight.
The NXZ of Henkel KGaA company selected by defoamer, and consumption is the 0.1wt% of priming paint gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 1.5wt% of priming paint gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.5wt% of priming paint gross weight.
The preparation method of described priming paint comprises the following steps:
Deionized water 27.1 parts is added in coating material production still, start agitator, add dispersion agent 5040:0.5 part successively equably, wetting agent WT:0.2 part, thickening material 250HBR:0.2 part, sanitas R640:0.1 part, defoamer NXZ:0.1 part, antifreezing agent propylene glycol: 1.5 parts, film coalescence aid alcohol ester 12: 1.5 parts, 1350 revs/min of high speed dispersion 10min, slowly add titanium dioxide 5 parts and 100 order ~ 200 order silica powder 35 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1200 revs/min after terminating that feeds intake, high speed dispersion 45min, add the emulsion of 28 parts again, thickening material RH-420:0.8 part, be in harmonious proportion, inspection, packaging.
Embodiment 3
Finishing coating materials (by weight)
Pure-acrylic emulsion 55 parts, 30 parts, water, functional materials B:9 part, auxiliary agent B: 6.0 parts.
Functional materials B is the mixture of hollow glass microbead and Opacifying polymers, and part by weight is 1:1.
Auxiliary agent B comprises dispersion agent, wetting agent, thickening material, sanitas, defoamer, antifreezing agent and film coalescence aid.
Dispersion agent is ammonium polyacrylate salt, and as the 2500D of Dow Chemical, consumption is the 0.7wt% of finishing coating materials gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.15wt% of finishing coating materials gross weight.
The RH-420 of rising sun electrification selected by thickening material, and consumption is the 0.45wt% of finishing coating materials gross weight.
German Shu Mei company K40 selected by sanitas, and consumption is the 0.15wt% of finishing coating materials gross weight.
The A10 of Henkel KGaA selected by defoamer, and consumption is the 0.35wt% of finishing coating materials gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 1.0wt% of finishing coating materials gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 3.2wt% of finishing coating materials gross weight.
Preparation method:
Step one) the producing of function slurry:
In coating material production still, add deionized water 30 parts, start agitator, governing speed 600 revs/min, add dispersion agent 2500D:0.7 part successively equably, wetting agent CF-11:0.15 part, sanitas K40:0.15 part, defoamer A10:0.35 part, antifreezing agent ethylene glycol: 1.0 parts, film coalescence aid alcohol ester 12: 3.2 parts, adds functional materials B9.0 part after stirring, adopt frequency vibration polishing, fineness is controlled within 15 μm, obtained required order number function slurry.
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add pure-acrylic emulsion 55.0 parts, governing speed 500 revs/min, then add thickening material RH-420:0.45 part, stir, namely make the finishing coating materials with environmental protection and energy saving effect.
True mineral varnish middle coating intermediate (by weight)
Organosilicon crylic acid latex 13.75 parts, 0.5 part, water, self-control function smalt (10#-200#) 78.0 parts, functional materials A4.75 part, auxiliary agent A 3.0 parts.
Auxiliary agent A comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is ammonium polyacrylate salt, and as the 2500D of Dow Chemical, consumption is the 0.4wt% of true mineral varnish middle coating intermediate gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.1wt% of true mineral varnish middle coating intermediate gross weight.
The sub-mixing across the 250HBR of dragon and the RH-420 of rising sun electrification selected by thickening material, and consumption is respectively 0.7wt% and 0.3wt% of true mineral varnish middle coating intermediate gross weight.
The mixing of the LX150 of Dow Chemical and the R640 of Dow Chemical selected by sanitas, and consumption is respectively 0.10wt% and 0.05wt% of true mineral varnish middle coating intermediate gross weight.
The B556 of Japanese rising sun electrification Co., Ltd. selected by defoamer, and consumption is the 0.25wt% of true mineral varnish middle coating intermediate gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 0.8wt% of true mineral varnish middle coating intermediate gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 0.3wt% of true mineral varnish middle coating intermediate gross weight.
Self-control function smalt is the smalt of 10#-200#.
Functional materials A is mixed by the raw material of following parts by weight proportioning to form: zinc oxide: barium sulfate: talcum powder=1:15:25.
Preparation method:
Step one) the producing of base-material:
Deionized water 0.5 part is added in coating material production still, start agitator, governing speed to 500 rev/min, add dispersion agent 2500D:0.4 part successively equably, wetting agent CF-11:0.1 part, thickening material 250HBR:0.7 part, sanitas LX150 and R640 difference: 0.10 part and 0.05 part, defoamer B556:0.25 part, antifreezing agent propylene glycol: 0.8 part, film coalescence aid alcohol ester 12: 0.3 part, functional materials A4.75 part, feed intake after terminating, improve fast rate of dispersion to 1200 rev/min, disperse 25 minutes, to fineness 15 μm, speed is down to 800 revs/min, add the synthetic resin emulsion 13.75 parts taken by weight again, RH-420:0.3 part, continue to stir, namely required base-material is obtained.
Step 2) the producing of true mineral varnish middle coating intermediate:
Regulate stirring velocity to 500 rev/min, in the base-material of above-mentioned preparation, slowly add self-control function smalt (10#-200#) 60.0 parts, raising rotating speed to 800 rev/min, stir, the attentional manipulation time within 12 minutes.
Priming paint (by weight):
Benzene emulsion 420V31 part, 26.7 parts, water, titanium dioxide 7.5 parts, 100 order ~ 200 order silica powders 30 parts, auxiliary agent C4.8 part.
Auxiliary agent C comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polyacrylic acid sodium salt, as Japanese Nuo Puke 5040, consumption is the 0.4wt% of priming paint gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.15wt% of priming paint gross weight.
The sub-combination across the 250HBR of dragon and the TT-935 of Dow Chemical selected by thickening material, and consumption is respectively 0.25wt%, 0.6wt% of priming paint gross weight.
The K40 of German Shu Mei company selected by sanitas, and consumption is the 0.15wt% of priming paint gross weight.
The A10 of Henkel KGaA company selected by defoamer, and consumption is the 0.25wt% of priming paint gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 1.25wt% of priming paint gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.75wt% of priming paint gross weight.
The preparation method of described priming paint comprises the following steps:
In coating material production still, add deionized water 26.7 parts, start agitator, add dispersion agent 5040:0.4 part successively equably, wetting agent CF-11:0.15 part, thickening material 250HBR:0.25 part, sanitas K40:0.15 part, defoamer A10:0.25 part, antifreezing agent ethylene glycol: 1.25 parts
Film coalescence aid alcohol ester 12: 1.75 parts, 1300 revs/min of high speed dispersion 12min, slowly add titanium dioxide 7.5 parts and 100 order ~ 200 order silica powder 30 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1350 revs/min after terminating that feeds intake, high speed dispersion 35min, then emulsion, TT-935:0.6 part of adding 31 parts, be in harmonious proportion, check, pack.
Embodiment 4
Finishing coating materials (by weight)
Fluorine carbon emulsion 50 parts, 35.5 parts, water, functional materials B:9 part, auxiliary agent B: 5.5 parts.
Functional materials B is the mixture of hollow glass microbead and Opacifying polymers, and part by weight is 2.0:1.
Auxiliary agent B comprises dispersion agent, wetting agent, thickening material, sanitas, defoamer, antifreezing agent and film coalescence aid.
Dispersion agent is the SN5027 of ammonium polyacrylate salt, Japanese Nuo Puke, and consumption is the 0.6wt% of finishing coating materials gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.15wt% of finishing coating materials gross weight.
Thickening material selects the TT-935 consumption of Dow Chemical to be the 0.40wt% of finishing coating materials gross weight.
The LX150 of Dow Chemical and the R640 of Dow Chemical selected by sanitas, and consumption is respectively the 0.10wt% of finishing coating materials gross weight.
The SN8034 of Henkel KGaA selected by defoamer, and consumption is the 0.15wt% of finishing coating materials gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 1.5wt% of finishing coating materials gross weight.
Film coalescence aid selects the combination of propandiol butyl ether, both alcohol esters 12, and consumption is respectively 1.5wt% and 1.0wt% of finishing coating materials gross weight.
Preparation method:
Step one) the producing of function slurry:
Deionized water 32 parts is added in coating material production still, start agitator, governing speed 580 revs/min, add dispersion agent SN5027:0.6 part successively equably, wetting agent CF-11:0.15 part, sanitas LX150 and R640, consumption is respectively 0.10 part, defoamer SN8034:0.15 part, antifreezing agent propylene glycol: 1.5 parts, film coalescence aid propandiol butyl ether, alcohol ester 12 consumption are respectively 1.5 parts and 1.0 parts, functional materials B12.0 part is added after stirring, adopt frequency vibration polishing, fineness is controlled within 15 μm, obtained required order number function slurry.
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add finish coat emulsion 50.0 parts, thickening material TT-935:0.40 part, governing speed 580 revs/min, stirs, and namely makes the finishing coating materials with environmental protection and energy saving effect.
True mineral varnish middle coating intermediate (by weight)
Organosilicon crylic acid latex 17.5 parts, 3.85 parts, water, self-control function smalt (10#-200#) 69.0 parts, functional materials A6.5 part, auxiliary agent A 3.15 parts,
Auxiliary agent A comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is 5027 of ammonium polyacrylate salt Japan Nuo Puke, and consumption is the 0.6wt% of true mineral varnish middle coating intermediate gross weight.
Wetting agent selects the CF-11 consumption of German BASF to be the 0.15wt% of true mineral varnish middle coating intermediate gross weight.
The sub-mixing across the 250HBR of dragon and the TT-935 of Dow Chemical selected by thickening material, and consumption is respectively 0.6wt% and 0.2wt% of true mineral varnish middle coating intermediate gross weight.
The mixing of the LX150 of Dow Chemical and the R640 of Dow Chemical selected by sanitas, and consumption is respectively the 0.10wt% of true mineral varnish middle coating intermediate gross weight.
The NXZ of Henkel KGaA selected by defoamer, and consumption is the 0.30wt% of true mineral varnish middle coating intermediate gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 0.6wt% of true mineral varnish middle coating intermediate gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 0.5wt% of true mineral varnish middle coating intermediate gross weight.
Self-control function smalt is the smalt of 10#-200#.
Described functional materials A is mixed by the raw material of following parts by weight proportioning to form: zinc oxide: barium sulfate: talcum powder=1:12:30.
Preparation method:
Step one) the producing of base-material:
Deionized water 3.85 parts is added in coating material production still, start agitator, governing speed to 520 rev/min, add dispersion agent 5027:0.6 part successively equably, wetting agent CF-11:0.15 part, thickening material 250HBR:0.6 part, sanitas LX150 and R640 consumption are respectively 0.10 part, defoamer NXZ:0.30 part, antifreezing agent propylene glycol: 0.6 part, film coalescence aid alcohol ester 12: 0.5 part, functional materials A6.5 part, feed intake after terminating, improve fast rate of dispersion to 1350 rev/min, disperse 20 minutes, to fineness 15 μm, speed is down to 800 revs/min, add the organosilicon crylic acid latex emulsion 17.5 parts taken by weight again, TT-935:0.2 part, continue to stir, namely required base-material is obtained.
Step 2) the producing of true mineral varnish middle coating intermediate:
Regulate stirring velocity to 580 rev/min, in the base-material of above-mentioned preparation, slowly add self-control function smalt (10#-200#) 69.0 parts, raising rotating speed to 950 rev/min, stir, the attentional manipulation time within 11 minutes.
Priming paint (by weight):
Benzene emulsion TB-1532.5 part, 27.675 parts, water, titanium dioxide 7.5 parts, 100 order ~ 200 order silica powders 27.5 parts, auxiliary agent C4.825 part.
Auxiliary agent C comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polyacrylic acid sodium salt, and as the pleased of Dow Chemical, consumption is the 0.35wt% of priming paint gross weight.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.125wt% of priming paint gross weight.
The sub-combination across the 250HBR of dragon and the RH-420 of Japanese rising sun electrification selected by thickening material, and consumption is respectively 0.275wt%, 0.5wt% of priming paint gross weight.
The combination of LXE and R640 of Dow Chemical selected by sanitas, and consumption is respectively 0.1wt%, 0.075wt% of priming paint gross weight.
The B556 of Japanese rising sun electrification selected by defoamer, and consumption is the 0.3wt% of priming paint gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 1.2wt% of priming paint gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.9wt% of priming paint gross weight.
The preparation method of described priming paint comprises the following steps:
Deionized water 27.675 parts is added in coating material production still, start agitator, add dispersion agent pleased equably successively: 0.35, wetting agent CF-11:0.125 part, thickening material 250HBR:0.275 part, sanitas LXE and R640 consumption are respectively 0.1 part, 0.075 part, defoamer B556:0.3 part, antifreezing agent propylene glycol 1.2 parts, film coalescence aid alcohol ester 12: 1.9 parts, 1000 revs/min of high speed dispersion 15min, slowly add titanium dioxide 7.5 parts and 100 order ~ 200 order silica powder 27.5 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1200 revs/min after terminating that feeds intake, high speed dispersion 40min, add the emulsion of 32.5 parts again, RH-420:0.5 part, be in harmonious proportion, inspection, packaging.
Embodiment 5
Finishing coating materials (by weight)
Organosilicon crylic acid latex 60 parts, 18.8 parts, water, functional materials B:15 part, auxiliary agent B: 6.2 parts.
Functional materials B is the mixture of hollow glass microbead and Opacifying polymers, and part by weight is 3:1.
Auxiliary agent B comprises dispersion agent, wetting agent, thickening material, sanitas, defoamer, antifreezing agent and film coalescence aid.
Dispersion agent is the SN5040 of polyacrylic acid sodium salt as Japanese Nuo Puke, and consumption is the 0.8wt% of finishing coating materials gross weight.
US Air gas chemistry painting industry wetting agent 1340 selected by wetting agent, and consumption is the 0.20wt% of finishing coating materials gross weight.
The HS30000YP of Clariant selected by thickening material, and consumption is the 0.10wt% of finishing coating materials gross weight.
The R640 of Dow Chemical selected by sanitas, and consumption is the 0.10wt% of finishing coating materials gross weight.
The A10 of Henkel KGaA selected by defoamer, and consumption is the 0.50wt% of finishing coating materials gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 0.5wt% of finishing coating materials gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 4.0wt% of finishing coating materials gross weight.
Preparation method:
Step one) the producing of function slurry:
Deionized water 18.8 parts is added in coating material production still, start agitator, governing speed 540 revs/min, add dispersion agent SN5040:0.8 part successively equably, wetting agent 1340:0.20 part, thickening material HS30000YP:0.10 part, sanitas R640:0.10 part, defoamer A10:0.50 part, antifreezing agent ethylene glycol: 0.5 part, film coalescence aid alcohol ester 12: 4.0 parts, functional materials B15.0 part is added after stirring, adopt frequency vibration polishing, fineness is controlled within 15 μm, obtained required order number function slurry.
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add organosilicon crylic acid latex 60.0 parts, governing speed 580 revs/min, stirs, and namely makes the finishing coating materials with environmental protection and energy saving effect.
True mineral varnish middle coating intermediate (by weight)
Pure-acrylic emulsion 8.0 parts, elastic emulsion 2 parts, 11.0 parts, water, self-control function smalt (10#-200#) 73.5 parts, functional materials A3.0 part, auxiliary agent A 2.5 parts.
Auxiliary agent A comprises wetting agent, sanitas, antifreezing agent, film coalescence aid and thickening material.
The CF-11 of German BASF selected by wetting agent, and consumption is the 0.10wt% of true mineral varnish middle coating intermediate gross weight.
The sub-mixing across the 250HBR of dragon and the RH-420 two kinds of rising sun electrification selected by thickening material, and consumption is respectively 0.8wt% and 0.4%wt% of true mineral varnish middle coating intermediate gross weight.
The R640 of Dow Chemical selected by sanitas, and consumption is the 0.10wt% of true mineral varnish middle coating intermediate gross weight.
Propylene glycol selected by antifreezing agent, and consumption is the 1.0wt% of true mineral varnish middle coating intermediate gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 0.1wt% of true mineral varnish middle coating intermediate gross weight.
Self-control function smalt is the smalt of 10#-200#.
Functional materials A is mixed by the raw material of following parts by weight proportioning to form: zinc oxide: barium sulfate: talcum powder=1:15:30.
Preparation method:
Step one) the producing of base-material:
Deionized water 11.0 parts is added in coating material production still, start agitator, governing speed to 500 rev/min, add wetting agent CF-11:0.10 part successively equably, thickening material 250HBR:0.8 part, sanitas R640:0.10 part, antifreezing agent propylene glycol: 1.0 parts, film coalescence aid alcohol ester 12: 0.1 part
Functional materials A3.0 part, feed intake after terminating, improve fast rate of dispersion to 1200 rev/min, disperse 25 minutes, to fineness 15 μm, speed is down to 650 revs/min, add the pure-acrylic emulsion 8.0 parts, the elastic emulsion 2 parts that take by weight again, RH-420:0.4 part, continues to stir, namely obtains required base-material.
Step 2) the producing of true mineral varnish middle coating intermediate:
Regulate stirring velocity to 750 rev/min, in the base-material of above-mentioned preparation, slowly add self-control function smalt (10#-200#) 73.5 parts, raising rotating speed to 1000 rev/min, stir, the attentional manipulation time within 35 minutes.
Priming paint (by weight):
Benzene emulsion TB-1529.5 part, 28.125 parts, water, titanium dioxide 5 parts, 100 order ~ 200 order silica powders 32.5 parts, auxiliary agent C4.875 part.
Auxiliary agent C comprises dispersion agent, wetting agent, defoamer, sanitas, antifreezing agent, film coalescence aid and thickening material.
Dispersion agent is polyacrylic acid sodium salt, and as the pleased of Dow Chemical, consumption is the 0.45wt% of priming paint gross weight.
The WT of German BASF selected by wetting agent, and consumption is the 0.175wt% of priming paint gross weight.
Thickening material select Clariant HS30000YP and the combination of RH-420 of Japanese rising sun electrification, consumption is respectively 0.225wt%, 0.7wt% of priming paint gross weight.
The A28S of German Shu Mei selected by sanitas, and consumption is the 0.125wt% of priming paint gross weight.
The SN8034 of Henkel KGaA company selected by defoamer, and consumption is the 0.2wt% of priming paint gross weight.
Ethylene glycol selected by antifreezing agent, and consumption is the 1.4wt% of priming paint gross weight.
Film coalescence aid selects alcohol ester 12, and consumption is the 1.6wt% of priming paint gross weight.
The preparation method of described priming paint comprises the following steps:
Deionized water 28.1 parts is added in coating material production still, start agitator, add dispersion agent pleased equably successively: 0.45 part, wetting agent WT:0.175 part, thickening material HS30000YP:0.225 part, sanitas A28S:0.125 part, defoamer SN8034:0.2 part, antifreezing agent ethylene glycol: 1.4 parts, film coalescence aid alcohol ester 12: 1.6 parts, 1200 revs/min of high speed dispersion 12min, slowly add titanium dioxide 5 parts and 100 order ~ 200 order silica powder 32.5 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1000 ~ 1350 revs/min after terminating that feeds intake, high speed dispersion 35 ~ 45min, add the benzene emulsion TB-15 of 29.5 parts again, RH-420:0.7 part, be in harmonious proportion, inspection, packaging.
The present invention is applicable to villa, senior commercial and residential building, Administration Building, shop etc. and had not only required to have lithotome decorative effect, but also required to have the place decoration of energy-saving effect.
Performance of the present invention is see table 1.
Table 1
As seen from Table 1, properties of the present invention all meets national standard requirement, and environmental-protecting performance is superior, can be used for the occasion that various environmental requirement is higher, and wherein, embodiment 4 is preference.
The present invention, compared with conventional stone-imitation type composite dope, conventional thermal barrier reflective coating and common exterior coating, has obvious energy-conserving action and decorative effect true to nature, integrate decoration and energy-conservation, its salient features contrast in table 2.
The salient features of table 2 the present invention and conventional stone-imitation type composite dope, conventional thermal barrier reflective coating, common exterior coating contrasts
Table 2 the performance test results shows: the present invention had both had the lithotome decorative effect true to nature of conventional true stone-type coating and lasting decorate properties, had again the energy-conserving action more superior than conventional thermal barrier reflective coating, had very strong creativeness; The present invention can be used for villa, senior commercial and residential building, Administration Building, shop etc. and had not only required to have lithotome decorative effect, but also required to have the place decoration of energy-saving effect.
More than show and describe ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (22)
1. the true stone-type composite dope of environmental protection and energy saving, is made up of finishing coating materials, true mineral varnish middle coating intermediate and priming paint, it is characterized in that:
Described priming paint is made up of following raw materials in part by weight: synthetic resin emulsion 28 ~ 34 parts, 26.3 ~ 28.1 parts, water, titanium dioxide 5 ~ 10 parts, special type filler 25 ~ 35 parts and auxiliary agent C4.7 ~ 4.9 part;
Described true mineral varnish middle coating intermediate is made up of following raw materials in part by weight: synthetic resin emulsion 10.0 ~ 25.0 parts, deionized water 0.5 ~ 11.0 part, functional materials A3.0 ~ 10.0 part, function smalt 60.0 ~ 78 parts and auxiliary agent A 2.5 ~ 3.4 parts;
Described function smalt is cross one or more the combination in the function white sand of 10 order to 200 order screen cloth at different levels, the color sand of assorted function respectively; The color sand of described function white sand, function is mixed according to certain ratio uniform inorganic bond material, one or more cold pigment, adopt spray pyrolysis technologies, carry out coated to the natural white sand of required particle diameter, obtained by the thermodynamics analysis methods calculating enthalpy produced in chemical reaction △ H and free energy △ G;
Described finishing coating materials is made up of following raw materials in part by weight: deionized water 18.8 ~ 48.05 parts, synthetic resin emulsion 40.0 ~ 60.0 parts, functional materials B3.0 ~ 15.0 part and auxiliary agent B 5.5 ~ 6.2 parts.
2. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 1, it is characterized in that, described true mineral varnish middle coating intermediate synthetic resin emulsion is the mixing of a kind of in benzene emulsion, pure-acrylic emulsion, organosilicon crylic acid latex, fluorine carbon emulsion, elastic emulsion or any two kinds.
3. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 1, it is characterized in that, described finishing coating materials synthetic resin emulsion is pure-acrylic emulsion, organosilicon crylic acid latex or fluorine carbon emulsion.
4. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 1, it is characterized in that, described priming paint synthetic resin emulsion is benzene emulsion, pure-acrylic emulsion or organosilicon crylic acid latex.
5. the true stone-type composite dope of the environmental protection and energy saving as described in Claims 2 or 3 or 4, is characterized in that, described benzene emulsion, organosilicon crylic acid latex are respectively the ACRYLIC EMULSION containing styrene monomer, siloxane bond grafting in molecule.
6. the true stone-type composite dope of the environmental protection and energy saving as described in Claims 2 or 3 or 4, is characterized in that, described pure-acrylic emulsion is the ACRYLIC EMULSION of 100% Acrylic Acid Monomer synthesis.
7. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 2, is characterized in that, described fluorine carbon emulsion is the ACRYLIC EMULSION containing carbon-fluorine bond grafting in molecule.
8. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 2, it is characterized in that, described elastic emulsion is the ACRYLIC EMULSION that after film forming, film has unit elongation.
9. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 2, it is characterized in that, the synthetic resin emulsion of described true mineral varnish middle coating intermediate is mixed by the elastic emulsion 752D of total emulsion weight basis 10 ~ 20% and the pure-acrylic emulsion 706T of total emulsion weight basis 80 ~ 90%.
10. the true stone-type composite dope of environmental protection and energy saving as claimed in claim 1, it is characterized in that, described auxiliary agent A is made up of the raw material of following proportioning by weight: dispersion agent 0 ~ 0.8 part, wetting agent 0.1 ~ 0.3 part, defoamer 0 ~ 0.5 part, sanitas 0.1 ~ 0.3 part, antifreezing agent 0 ~ 1.0 part, film coalescence aid 0.1 ~ 1.0 part and thickening material 0.3 ~ 1.2 part.
The true stone-type composite dope of 11. environmental protection and energy saving as claimed in claim 1, it is characterized in that, described auxiliary agent B is made up of the raw material of following proportioning by weight: dispersion agent 0.3 ~ 0.8 part, wetting agent 0.1 ~ 0.2 part, defoamer 0 ~ 0.5 part, sanitas 0.1 ~ 0.3 part, antifreezing agent 0.5 ~ 2.5 part, film coalescence aid 1.0 ~ 4.0 parts, thickening material 0.1 ~ 1.5 part.
The true stone-type composite dope of 12. environmental protection and energy saving as claimed in claim 1, it is characterized in that, described auxiliary agent C is made up of following raw material by weight: dispersion agent 0.3 ~ 0.5 part, wetting agent 0.1 ~ 0.2 part, defoamer 0.2 ~ 0.4 part, sanitas 0.1 ~ 0.2 part, antifreezing agent 1.0 ~ 1.5 parts, film coalescence aid 1.5 ~ 2.0 parts, thickening material 0.7 ~ 1.0 part.
The true stone-type composite dope of 13. environmental protection and energy saving as claimed in claim 1, it is characterized in that, described special type filler comprises 100 order ~ 200 order silica powders.
14. true stone-type composite dopes of environmental protection and energy saving as described in claim 10 or 11 or 12, it is characterized in that, described dispersion agent is sodium polyacrylate dipersant or ammonium polyacrylate dipersant.
15. true stone-type composite dopes of environmental protection and energy saving as described in claim 10 or 11 or 12, it is characterized in that, described antifreezing agent selects ethylene glycol or propylene glycol.
The true stone-type composite dope of 16. environmental protection and energy saving as claimed in claim 1, is characterized in that, is be made up of the raw material comprising following parts by weight proportioning: zinc oxide: barium sulfate: talcum powder=1:9 ~ 15:25 ~ 35 at described functional materials A.
The true stone-type composite dope of 17. environmental protection and energy saving as claimed in claim 1, is characterized in that, is be made up of the raw material comprising following parts by weight proportioning: zinc oxide: barium sulfate: talcum powder=1:12:30 at described functional materials A.
The true stone-type composite dope of 18. environmental protection and energy saving as claimed in claim 1, is characterized in that, described functional materials B is made up of the raw material of following parts by weight proportioning: hollow ceramic microballon: Opacifying polymers=1 ~ 3:1.
The true stone-type composite dope of 19. environmental protection and energy saving as claimed in claim 1, is characterized in that, described functional materials B is made up of the raw material of following parts by weight proportioning: hollow ceramic microballon: Opacifying polymers=2:1.
The true stone-type composite dope of 20. environmental protection and energy saving as claimed in claim 1, is characterized in that, described Opacifying polymers is the Unihub-E of Dow Chemical, Snowtex25, Snowtex30 or Snowtex45 of Ying Zhou foreign firm of Korea S.
The preparation method of the true stone-type composite dope of environmental protection and energy saving described in 21. 1 kinds of any one of claim 1 to 20 claims, comprises the preparation method of priming paint, true mineral varnish middle coating intermediate, finishing coating materials, it is characterized in that,
The preparation method of described priming paint comprises the following steps:
Deionized water 26.3 ~ 28.1 parts is added in coating material production still, start agitator, add the sanitas of formula ratio successively equably, dispersion agent, defoamer, antifreezing agent, film coalescence aid, Mierocrystalline cellulose, 1000 ~ 1350 revs/min of high speed dispersion 10 ~ 15min, slowly add titanium dioxide 5 ~ 10 parts and special type filler 25 ~ 35 parts again, and the stirring velocity 500 ~ 600 revs/min controlled when feeding intake, and control the high speed dispersion speed 1000 ~ 1350 revs/min after terminating that feeds intake, high speed dispersion 35 ~ 45min, add the synthetic resin emulsion of 28 ~ 34 weight parts again, add thickening material, be in harmonious proportion, inspection, packaging,
The preparation method of described true mineral varnish middle coating intermediate comprises the following steps:
Step one) the producing of base-material:
Deionized water 0.5 ~ 11.0 part is added in coating material production still, start agitator, auxiliary agent A 2.5 ~ 3.4 parts, functional materials A3.0 ~ 10.0 part are added successively under the stirring velocity of 500 ~ 600 revs/min, reinforced complete, with the speed high speed dispersion 20 ~ 40 minutes of 1200 ~ 1500 revs/min, add the synthetic resin emulsion 10.0 ~ 25.0 parts taken by weight again, stirring 10 ~ 15 minutes is continued with the speed of 600 ~ 1000 revs/min, add thickening material, stir, namely obtain required base-material;
Step 2) the producing of true mineral varnish middle coating intermediate:
In the base-material of above-mentioned preparation, add self-control function smalt 60.0 ~ 78 parts, stir;
The preparation method of described finishing coating materials comprises the following steps:
Step one) the producing of function slurry:
Deionized water 18.8 ~ 48.05 parts is added in coating material production still, start agitator, governing speed 500 ~ 600 revs/min, add auxiliary agent B 5.55 ~ 6.20 parts, functional materials B3.0 ~ 15.0 part are added after stirring, adopt frequency vibration polishing, obtained fineness controls the function slurry within 15 μm;
Step 2) the producing of finishing coating materials:
In above-mentioned obtained function slurry, add synthetic resin emulsion 40.0 ~ 60.0 parts, the speed of 500 ~ 600 revs/min stirs, and adds thickening material, stirs, and namely makes the finishing coating materials with environmental protection and energy saving effect.
The constructional method of the true stone-type composite dope of environmental protection described in 22. 1 kinds of any one of claim 1 to 20 claims, is characterized in that, comprise the steps:
1). processing base level: basal plane is carried out levelling with consolidation process, drying, obtain firm flat surfaces;
2). described priming paint is stirred, optionally adds water adjustment viscosity to the 75 ~ 80KU of 0 ~ 5%, be applied over basal plane, dry 4 ~ 6h;
3). leave standstill 10 ~ 15min after being stirred by described true mineral varnish middle coating intermediate, technique is constructed routinely, dry 24 ~ more than 48h;
4). with described finishing coating materials routinely technique carry out overlay treatment.
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