CN1041380A - Benzene-free nitro-varnish - Google Patents
Benzene-free nitro-varnish Download PDFInfo
- Publication number
- CN1041380A CN1041380A CN 89107813 CN89107813A CN1041380A CN 1041380 A CN1041380 A CN 1041380A CN 89107813 CN89107813 CN 89107813 CN 89107813 A CN89107813 A CN 89107813A CN 1041380 A CN1041380 A CN 1041380A
- Authority
- CN
- China
- Prior art keywords
- benzene
- varnish
- kilograms
- free nitro
- cellulose nitrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002966 varnish Substances 0.000 title abstract description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 12
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims abstract description 11
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- DKGXIVRSAKPDHF-UHFFFAOYSA-N 6-chloro-3-methyl-1-phenylpyrimidine-2,4-dione Chemical compound O=C1N(C)C(=O)C=C(Cl)N1C1=CC=CC=C1 DKGXIVRSAKPDHF-UHFFFAOYSA-N 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 229940043232 butyl acetate Drugs 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229940079938 nitrocellulose Drugs 0.000 abstract description 3
- 229920003002 synthetic resin Polymers 0.000 abstract description 3
- 239000000057 synthetic resin Substances 0.000 abstract description 3
- 150000002148 esters Chemical class 0.000 abstract 1
- 231100000572 poisoning Toxicity 0.000 abstract 1
- 230000000607 poisoning effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 241000282412 Homo Species 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The product innovation of organic chemical industry's technology---benzene-free nitro-varnish, maximum characteristics be unlike pyroxylin(e)finish contain benzene, its main component is a cellulose nitrate, common ester, pure and mild synthetic resins, thereby the murder by poisoning of no benzene in production and the use.
Description
The invention belongs to field of chemical technology.
As paint anticorrosion, that decorate, in manufacturing process, often use a large amount of benzene.Pyroxylin(e)finish is also like this.Benzene in the paint in use volatilizees naturally in the space, causes the serious environmental topsoil.Benzene on human suction benzene or the direct contagion of health has serious threat to HUMAN HEALTH.The scientific experimentation and the fact prove that benzene is the material that makes us carcinogenic.How to replace the effect of benzene in producing paint with other materials, reach and eliminate the harm of benzene to human health, be the target of chemist struggle always, also is purpose of the present invention.
Characteristics of the present invention are with the benzene in N-BUTYL ACETATE, vinyl acetic monomer, butanols, ethanol, the ricinoleyl alcohol acid resin replacement original production pyroxylin(e)finish technology, produce benzene-free nitro-varnish.
The various substances content of benzene-free nitro-varnish of the present invention are as follows: (percent by weight)
Butylacetate 15-18 ethyl acetate 8-11
Butanols 7-10 ethanol 3-6
Cellulose nitrate 20-25 ricinoleyl alcohol acid resin 21-26
Solvent oil 8-12 dibutyl phthalate 3-5
Illustrate below in conjunction with embodiment how the present invention realizes.
Embodiment 1: at first take by weighing 17 kilograms of butylacetates, 9 kilograms of ethyl acetate, 8 kilograms of butanols, 5 kilograms of ethanol, in a reactor, fully stir and make mixed solvent, this is drawn solvent delivery goes in the cellulose nitrate dissolving tank, then 23 kilograms cellulose nitrate is slowly put in the cellulose nitrate dissolving tank, stir while adding, until becoming transparent cellulose nitrate Colloidal fluid.Take by weighing 24 ricinoleyl alcohol acid resins and 9 kilograms of solvent oils again, it is transparent to make it be dissolved in the resin dissolves groove
The gluey liquid of synthetic resins.At last cellulose nitrate Colloidal fluid and the gluey liquid of synthetic resins are sent in another container, fully stirred, and add 5 kilograms of dibutyl phthalates, after waiting to stir, remove by filter mechanical impurity with supercentrifuge and promptly obtain benzene-free nitro-varnish.
Embodiment 2: implementation method, step are identical with embodiment 1, are that various amount of substances are changed into respectively: 18 kilograms of butylacetates, 10 kilograms of ethyl acetate, 7 kilograms in butanols, 4 kilograms of ethanol; 25 kilograms of cellulose nitrates; 23 kilograms of ricinoleyl alcohol acid resins, 10 kilograms of solvent oils; 3 kilograms of dibutyl phthalates.According to the working method of embodiment 1, step can make benzene-free nitro-varnish equally.
As long as various amounts in percentage composition scope provided by the invention, according to embodiment 1 working method and step, all can be produced the benzene-free nitro-varnish that conforms to quality requirements.
The benzene-free nitro-varnish that the present invention produces does not contain benzene, does not therefore have environmental pollution that benzene causes and the health of harm humans.
Claims (1)
- A kind of nitro paint that does not contain benzene is characterized in that the weight percent of various material compositions is:Butylacetate 15-18 ethyl acetate 8-11Butanols 7-10 ethanol 3-6Cellulose nitrate 20-25 ricinoleyl alcohol acid resin 21-26Solution oil 8-12 dibutyl phthalate 3-5
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107813 CN1041380A (en) | 1989-09-26 | 1989-09-26 | Benzene-free nitro-varnish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 89107813 CN1041380A (en) | 1989-09-26 | 1989-09-26 | Benzene-free nitro-varnish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1041380A true CN1041380A (en) | 1990-04-18 |
Family
ID=4857344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89107813 Pending CN1041380A (en) | 1989-09-26 | 1989-09-26 | Benzene-free nitro-varnish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1041380A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618126A (en) * | 2012-04-16 | 2012-08-01 | 广州立邦涂料有限公司 | Nitrocellulose transparent primer and application thereof |
| CN104327575A (en) * | 2014-11-25 | 2015-02-04 | 三友（天津）高分子技术有限公司 | Single-component high-adhesion quick-drying repair putty |
-
1989
- 1989-09-26 CN CN 89107813 patent/CN1041380A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102618126A (en) * | 2012-04-16 | 2012-08-01 | 广州立邦涂料有限公司 | Nitrocellulose transparent primer and application thereof |
| CN102618126B (en) * | 2012-04-16 | 2014-03-19 | 广州立邦涂料有限公司 | Nitrocellulose transparent primer and application thereof |
| CN104327575A (en) * | 2014-11-25 | 2015-02-04 | 三友（天津）高分子技术有限公司 | Single-component high-adhesion quick-drying repair putty |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |