CN104194574A - Coating with high flame retardancy and strong adhesive force - Google Patents
Coating with high flame retardancy and strong adhesive force Download PDFInfo
- Publication number
- CN104194574A CN104194574A CN201410510017.1A CN201410510017A CN104194574A CN 104194574 A CN104194574 A CN 104194574A CN 201410510017 A CN201410510017 A CN 201410510017A CN 104194574 A CN104194574 A CN 104194574A
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- CN
- China
- Prior art keywords
- parts
- high flame
- coating
- flame retardant
- adhesive force
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title abstract description 5
- 239000011248 coating agent Substances 0.000 title abstract description 4
- 239000000853 adhesive Substances 0.000 title abstract 2
- 230000001070 adhesive effect Effects 0.000 title abstract 2
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims description 18
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 17
- 239000003973 paint Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 7
- 229920003987 resole Polymers 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 4
- LNEUSAPFBRDCPM-UHFFFAOYSA-N carbamimidoylazanium;sulfamate Chemical compound NC(N)=N.NS(O)(=O)=O LNEUSAPFBRDCPM-UHFFFAOYSA-N 0.000 abstract description 3
- 235000019832 sodium triphosphate Nutrition 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 2
- 229960000892 attapulgite Drugs 0.000 abstract description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 2
- 239000007822 coupling agent Substances 0.000 abstract description 2
- 239000010445 mica Substances 0.000 abstract description 2
- 229910052618 mica group Inorganic materials 0.000 abstract description 2
- 229910052625 palygorskite Inorganic materials 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- BQPNUOYXSVUVMY-UHFFFAOYSA-N [4-[2-(4-diphenoxyphosphoryloxyphenyl)propan-2-yl]phenyl] diphenyl phosphate Chemical compound C=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 BQPNUOYXSVUVMY-UHFFFAOYSA-N 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- 235000007586 terpenes Nutrition 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- WGKLIJDVPACLGG-UHFFFAOYSA-N trizinc diborate hydrate Chemical class O.[Zn++].[Zn++].[Zn++].[O-]B([O-])[O-].[O-]B([O-])[O-] WGKLIJDVPACLGG-UHFFFAOYSA-N 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- -1 dihydroxyphenyl Chemical group 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a coating with high flame retardancy and strong adhesive force. The coating comprises the following raw materials in parts by weight: 83-86 parts of epoxy resin, 35-38 parts of terpene resin, 10-13 parts of phenolic resin, 2.2-2.5 parts of sodium carboxymethylcellulose, 3.5-3.8 parts of sodium tripolyphosphate, 2.6-2.9 parts of fatty acid polyethyleneglycol, 1.2-1.5 parts of a zircoaluminate coupling agent TL-4, 27-30 parts of light calcium carbonate, 13-16 parts of nano attapulgite, 14-17 parts of fumed silica, 10-13 parts of mica powder, 3-4 parts of bisphenol-A bis(diphenyl phosphate), 16-19 parts of guanidine sulfamate, 25-28 parts of 2ZnO.3B2O3.1.5H2O, 5.2-5.6 parts of a flexibilizer, 1.2-1.5 parts of a curing agent, 1.5-1.8 parts of a defoamer, 1.6-1.9 parts of an advection agent, 1-1.3 parts of a mildew inhibitor, 2.2-2.5 parts of a pigment and 65-70 parts of a solvent.
Description
Technical field
The present invention relates to technical field of coatings, relate in particular to a kind of high flame retardant high adhesion paint.
Background technology
In recent years, due to a large amount of uses of finishing material, this fire is in rising trend.Prepare novel do not fire, difficult combustion finishing material, be subject to the great attention of national departments concerned.Therefore anti-flaming dope becomes the focus of research, but existing anti-flaming dope still exists some shortcomings, catalysis carbon-forming by film is done in order to realize the prior art fire-retardant to base material, and the dehydration catalyst decomposition temperature of employing is higher and low temperature active is poor, and the flame retardant properties of coating is not good enough.Because when fire occurs, filmogen, often prior to dehydration catalyst decomposes, produces more flammable volatile organic compounds, affects formation and the structure of charcoal layer, and then the provide protection of impact to base material.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes a kind of high flame retardant high adhesion paint, have excellent heat-proof combustion-resistant performance and sticking power, and corrosion-resistant and anti-thixotroping ability is outstanding.
A kind of high flame retardant high adhesion paint that the present invention proposes, its raw material comprises by weight:
Preferably, the weight ratio of epoxy resin, terpine resin and resol is 84-85:36-37:11-12.Preferably, in ring and ball method, the softening temperature of terpine resin is 85-100 DEG C.
Preferably, its raw material comprises by weight:
The present invention is using terpine resin, resol and Blending Modification of Epoxy Resin as major ingredient, makes the present invention have excellent sticking power, water-fast, oil resistant, weather-proof and heat-proof combustion-resistant performance, also improved heat-resisting, light fastness; Light calcium carbonate, nano-attapulgite, aerosil, mica powder and 1.5 hydrate zinc borates add in major ingredient and solvent, by assisting of tripoly phosphate sodium STPP, cithrol, can be dispersed in uniformly between major ingredient molecule, make each component compatibility of raw material good by aluminum-zirconium coupling agent TL-4 again, significantly improve high temperature resistant, corrosion resistant performance of the present invention and anti-thixotroping ability; And dihydroxyphenyl propane-bis-(diphenyl phosphoesters), Guanidine Sulfamate 99,1.5 hydrate zinc borates coordinate and form flame-retardant systems, wherein Guanidine Sulfamate 99 is as nitrogenated flame retardant, dihydroxyphenyl propane-bis-(diphenyl phosphoester) is as phosphorus flame retardant, the two cooperation has significantly improved oxygen index of the present invention, improve flame retardant properties of the present invention, and 1.5 hydrate zinc borates can decompose generation water in the process of burning, the smog that can suppress in combustion processes forms.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
A kind of high flame retardant high adhesion paint that the present invention proposes, its raw material comprises by weight:
Wherein the softening temperature of terpine resin (taking ring and ball method) is 95 DEG C.
Embodiment 2
A kind of high flame retardant high adhesion paint that the present invention proposes, its raw material comprises by weight:
Wherein the softening temperature of terpine resin (taking ring and ball method) is 90 DEG C.
Embodiment 3
A kind of high flame retardant high adhesion paint that the present invention proposes, its raw material comprises by weight:
Wherein the softening temperature of terpine resin (taking ring and ball method) is 85 DEG C.
Embodiment 4
A kind of high flame retardant high adhesion paint that the present invention proposes, its raw material comprises by weight:
Wherein the softening temperature of terpine resin (taking ring and ball method) is 100 DEG C.
The above; it is only preferably embodiment of the present invention; but protection scope of the present invention is not limited to this; any be familiar with those skilled in the art the present invention disclose technical scope in; be equal to replacement or changed according to technical scheme of the present invention and inventive concept thereof, within all should being encompassed in protection scope of the present invention.
Claims (4)
1. a high flame retardant high adhesion paint, is characterized in that, its raw material comprises by weight:
2. high flame retardant high adhesion paint according to claim 1, is characterized in that, the weight ratio of epoxy resin, terpine resin and resol is 84-85:36-37:11-12.
3. according to high flame retardant high adhesion paint described in claim 1 or 2, it is characterized in that, in ring and ball method, the softening temperature of terpine resin is 85-100 DEG C.
4. according to high flame retardant high adhesion paint described in claim 1-3 any one, it is characterized in that, its raw material comprises by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410510017.1A CN104194574B (en) | 2014-09-28 | 2014-09-28 | A kind of high fire-retardance high adhesion paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410510017.1A CN104194574B (en) | 2014-09-28 | 2014-09-28 | A kind of high fire-retardance high adhesion paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104194574A true CN104194574A (en) | 2014-12-10 |
| CN104194574B CN104194574B (en) | 2016-08-24 |
Family
ID=52079952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410510017.1A Expired - Fee Related CN104194574B (en) | 2014-09-28 | 2014-09-28 | A kind of high fire-retardance high adhesion paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104194574B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559673A (en) * | 2015-01-20 | 2015-04-29 | 芜湖县双宝建材有限公司 | High-adhesion wear-resistant antifouling paint |
| CN105778698A (en) * | 2016-03-30 | 2016-07-20 | 安徽青花坊瓷业股份有限公司 | Mold coating for semi-dry pressing of simple ceramic ware |
| US10590152B2 (en) | 2017-12-14 | 2020-03-17 | International Business Machines Corporation | Pinene-based flame retardant compounds |
| CN112322143A (en) * | 2020-11-20 | 2021-02-05 | 福建省三俊环保科技有限公司 | Flame-retardant high-adhesion coating and preparation process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002529571A (en) * | 1998-11-10 | 2002-09-10 | アイル・フアイアストツプ・リミテツド | Composition for fire protection coating |
| CN101659823A (en) * | 2009-09-27 | 2010-03-03 | 中国科学技术大学 | Expanded type fireproof coating and preparation method thereof |
| CN102702962A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Expansion type fire-retardant coating |
| CN102898930A (en) * | 2012-09-21 | 2013-01-30 | 信和新材料股份有限公司 | Hydrocarbon flame resistant intumescent coating and preparation method thereof |
| CN103602208A (en) * | 2013-10-10 | 2014-02-26 | 安徽真信涂料有限公司 | A kind of high temperature resistant flame retardant antirust paint and preparation method thereof |
-
2014
- 2014-09-28 CN CN201410510017.1A patent/CN104194574B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002529571A (en) * | 1998-11-10 | 2002-09-10 | アイル・フアイアストツプ・リミテツド | Composition for fire protection coating |
| CN101659823A (en) * | 2009-09-27 | 2010-03-03 | 中国科学技术大学 | Expanded type fireproof coating and preparation method thereof |
| CN102702962A (en) * | 2012-06-14 | 2012-10-03 | 天长市银狐漆业有限公司 | Expansion type fire-retardant coating |
| CN102898930A (en) * | 2012-09-21 | 2013-01-30 | 信和新材料股份有限公司 | Hydrocarbon flame resistant intumescent coating and preparation method thereof |
| CN103602208A (en) * | 2013-10-10 | 2014-02-26 | 安徽真信涂料有限公司 | A kind of high temperature resistant flame retardant antirust paint and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559673A (en) * | 2015-01-20 | 2015-04-29 | 芜湖县双宝建材有限公司 | High-adhesion wear-resistant antifouling paint |
| CN105778698A (en) * | 2016-03-30 | 2016-07-20 | 安徽青花坊瓷业股份有限公司 | Mold coating for semi-dry pressing of simple ceramic ware |
| US10590152B2 (en) | 2017-12-14 | 2020-03-17 | International Business Machines Corporation | Pinene-based flame retardant compounds |
| CN112322143A (en) * | 2020-11-20 | 2021-02-05 | 福建省三俊环保科技有限公司 | Flame-retardant high-adhesion coating and preparation process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104194574B (en) | 2016-08-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Jiang Jinzhong Inventor after: He Wei Inventor before: Hu Changti |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171201 Address after: 437000 Xianning province Hubei City Haman Xingfa Road Economic Development Zone No. 9 (Huaning Anticorrosion Technology Industrial Park) Patentee after: HUBEI HUANING ANTICORROSION TECHNIC SHARE CO.,LTD. Address before: Wuhu County Industrial Park, 241100 Anhui Huaqiao city in Wuhu Province Patentee before: WUHU SHUANGBAO BUILDING MATERIAL Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160824 |