CN104294400A - Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof - Google Patents
Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof Download PDFInfo
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- CN104294400A CN104294400A CN201410540644.XA CN201410540644A CN104294400A CN 104294400 A CN104294400 A CN 104294400A CN 201410540644 A CN201410540644 A CN 201410540644A CN 104294400 A CN104294400 A CN 104294400A
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- 229920000742 Cotton Polymers 0.000 title claims abstract 11
- 230000000694 effects Effects 0.000 title claims abstract 5
- 230000000844 anti-bacterial effect Effects 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000000835 fiber Substances 0.000 claims abstract 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000002994 raw material Substances 0.000 claims abstract 4
- 108010022355 Fibroins Proteins 0.000 claims abstract 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract 3
- 240000000249 Morus alba Species 0.000 claims abstract 3
- 235000008708 Morus alba Nutrition 0.000 claims abstract 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 3
- 230000003115 biocidal effect Effects 0.000 claims abstract 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 3
- ZDIRKWICVFDSNX-UHFFFAOYSA-N diethyl phosphate 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium Chemical compound P(=O)(OCC)(OCC)O.C(C)N1CN(C=C1)C ZDIRKWICVFDSNX-UHFFFAOYSA-N 0.000 claims abstract 3
- 229930195729 fatty acid Natural products 0.000 claims abstract 3
- 239000000194 fatty acid Substances 0.000 claims abstract 3
- 150000004665 fatty acids Chemical class 0.000 claims abstract 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract 3
- 229910052708 sodium Inorganic materials 0.000 claims abstract 3
- 239000011734 sodium Substances 0.000 claims abstract 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract 3
- 238000003756 stirring Methods 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 3
- -1 polyoxyethylene Polymers 0.000 claims 3
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims 2
- 244000246386 Mentha pulegium Species 0.000 claims 2
- 235000016257 Mentha pulegium Nutrition 0.000 claims 2
- 235000004357 Mentha x piperita Nutrition 0.000 claims 2
- 244000242564 Osmanthus fragrans Species 0.000 claims 2
- 235000019083 Osmanthus fragrans Nutrition 0.000 claims 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 2
- 239000005844 Thymol Substances 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical group 0.000 claims 2
- 239000012752 auxiliary agent Substances 0.000 claims 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 238000001914 filtration Methods 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- 235000001050 hortel pimenta Nutrition 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 229920005573 silicon-containing polymer Polymers 0.000 claims 2
- 238000009987 spinning Methods 0.000 claims 2
- 239000000725 suspension Substances 0.000 claims 2
- 229960000790 thymol Drugs 0.000 claims 2
- 229940070527 tourmaline Drugs 0.000 claims 2
- 229910052613 tourmaline Inorganic materials 0.000 claims 2
- 239000011032 tourmaline Substances 0.000 claims 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 2
- 229920001661 Chitosan Polymers 0.000 claims 1
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 244000131522 Citrus pyriformis Species 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- 230000000740 bleeding effect Effects 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 239000012153 distilled water Substances 0.000 claims 1
- 239000000706 filtrate Substances 0.000 claims 1
- 238000000227 grinding Methods 0.000 claims 1
- 238000003837 high-temperature calcination Methods 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 238000002386 leaching Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 230000010355 oscillation Effects 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims 1
- 229930182490 saponin Natural products 0.000 claims 1
- 150000007949 saponins Chemical class 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 238000004804 winding Methods 0.000 claims 1
- 235000006679 Mentha X verticillata Nutrition 0.000 abstract 2
- 235000002899 Mentha suaveolens Nutrition 0.000 abstract 2
- 235000001636 Mentha x rotundifolia Nutrition 0.000 abstract 2
- 235000019082 Osmanthus Nutrition 0.000 abstract 2
- 241000333181 Osmanthus Species 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- HCGMDEACZUKNDY-UHFFFAOYSA-N 1-butyl-3-methyl-1,2-dihydroimidazol-1-ium;acetate Chemical compound CC(O)=O.CCCCN1CN(C)C=C1 HCGMDEACZUKNDY-UHFFFAOYSA-N 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses cotton fibers with antibacterial anti-mite effects. The cotton fibers are characterized by being prepared from the following raw materials in parts by weight: 17-23 parts of cotton fibers, 8-9 parts of soft silk fibers, 7-12 parts of silk fibroin, 5-7 parts of high-shrinkage polyester fiber, 6-10 parts of mulberry fibers, 4-7 parts of densefruit pittany root-bark extract, 1.1-3.1 parts of nanometer zirconia powder, 1-3 parts of diatomite, 6-8 parts of polyvinyl alcohol, 2.1-4.3 parts of fatty acid amide sodium sulfonate, 18-22 parts of alkylphenol ethoxylates, 2-3 parts of mint, 3-4 parts of sweet-scented osmanthus, 100-110 parts of 1-ethyl-3-methylimidazole diethyl phosphate, 105-110 parts of 1-butyl-3-methylimidazole acetate, 3-6 parts of aids and a proper amount of water. The densefruit pittany root-bark extract is added into the raw materials by utilizing ultrasonic technology means, the mint, sweet-scented osmanthus and other active ingredients are added, the prepared cotton fibers have the advantages of antibiosis, mite resistance, lightness, softness, flame retardant property and heat retention property, and the cotton fabrics prepared by the cotton fibers prepared by the invention have the effects of dispelling the wind and detoxifying.
Description
Technical field
The present invention relates to textile material technical field, be specifically related to a kind of to there is cotton fiber of antibiosis anti-acarien effect and preparation method thereof.
Background technology
Cotton fiber is fiber coating on the seed of Malvaceae cotton, and also known as cotton, being called for short cotton, is the main raw material of China's textile industry.The moisture absorption of cotton fiber goods and good permeability, wear-resisting washable, soft and warming, wear warmth retention property winter good, dress in summer is ventilative nice and cool, is widely used in garment material, drapery.
But cotton fiber makes it apply to be restricted because it exists many defects in the prior art.Such as cotton fiber goods are subject to microbial action, are easily corroded by bacterium, mould, and antibacterial and mouldproof effect is not remarkable; The anti-uv-ray of cotton fiber own is poor, makes it make summer clothes and skin chromogenesis precipitation can be caused even to cause cutaneum carcinoma; Cotton fiber flame retardant effect is poor, and the disaster hidden-trouble caused thus is in rising trend.For overcoming the deficiencies in the prior art, be necessary natural cotton fiber in addition modification, thus be obtainedly applicable to the cotton fiber with functions such as cost low, function diversification, fire-retardant, intensity high, sterilization uvioresistant, radiation proofs of modern for the different demands of cotton fiber goods.
Summary of the invention
Object of the present invention is just to provide a kind ofly has cotton fiber of antibiosis anti-acarien effect and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of cotton fiber with antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 17-23, soft silk fiber 8-9, fibroin fiber 7-12, high-shrinkage polyster 5-7, mulberry fibre 6-10, Cortex Dictamni extract 4-7, nano oxidized zirconium powder 1.1-3.1, diatomite 1-3, polyvinyl alcohol 6-8, fatty acid amide sodium sulfonate 2.1-4.3, alkylphenol polyoxyethylene 18-22, peppermint 2-3, sweet osmanthus 3-4, 1-ethyl-3-methylimidazole diethyl phosphate 100-110, 1-butyl-3-N-Methylimidazoleacetic salt 105-110, auxiliary agent 3-6, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1-3, lemon 2-5, butyl 10-13, diepoxy triethylene glycol glycidol ether 8-10, thymol 4-6, chitosan 1.2-2.2, nanoscale Tourmaline 3-5, Tea Saponin 0.5-0.8, dimethyl silicone polymer two quaternary amine 4.5-6.5, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
Described a kind of preparation method with the cotton fiber of antibiosis anti-acarien effect, is characterized in that comprising the following steps:
(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;
(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;
(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
The present invention has following beneficial effect: the present invention prepares simple to operation, and cost is low; Ultrasonic technology means are utilized by Cortex Dictamni extract to add in raw material, also added peppermint, sweet osmanthus and other active ingredient, obtained cotton fiber has the advantages such as antibiosis anti-acarien, light and handy softness, fire-retardant warmth retention property be good, also has the detoxicating functions that dispels the wind with the cotton goods that the present invention obtains.
Detailed description of the invention
Described a kind of cotton fiber with antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 18, soft silk fiber 9, fibroin fiber 7, high-shrinkage polyster 6, mulberry fibre 8, Cortex Dictamni extract 5, nano oxidized zirconium powder 2.1, diatomite 1, polyvinyl alcohol 6, fatty acid amide sodium sulfonate 3.4, alkylphenol polyoxyethylene 22, peppermint 2, sweet osmanthus 4,1-ethyl-3-methylimidazole diethyl phosphate 100,1-butyl-3-N-Methylimidazoleacetic salt 105, auxiliary agent 4, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1, lemon 3, butyl 12, diepoxy triethylene glycol glycidol ether 9, thymol 5, chitosan 1.8, nanoscale Tourmaline 4, Tea Saponin 0.6, dimethyl silicone polymer two quaternary amine 4.9, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
Preparation method comprises the following steps:
(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;
(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;
(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
The technical parameter index of the cotton fiber using the present invention to produce is as follows:
(1) pliability is fluffy smooth flexible, and intensity is high, flame retardant effect is excellent;
(2) bacteriostasis rate of finished product to Escherichia coli, staphylococcus aureus, Candida albicans is all greater than 99.5%.
Claims (2)
1. one kind has the cotton fiber of antibiosis anti-acarien effect, it is characterized in that, be made up of the raw material of following weight portion: cotton fiber 17-23, soft silk fiber 8-9, fibroin fiber 7-12, high-shrinkage polyster 5-7, mulberry fibre 6-10, Cortex Dictamni extract 4-7, nano oxidized zirconium powder 1.1-3.1, diatomite 1-3, polyvinyl alcohol 6-8, fatty acid amide sodium sulfonate 2.1-4.3, alkylphenol polyoxyethylene 18-22, peppermint 2-3, sweet osmanthus 3-4, 1-ethyl-3-methylimidazole diethyl phosphate 100-110, 1-butyl-3-N-Methylimidazoleacetic salt 105-110, auxiliary agent 3-6, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: bleeding agent OE-35 1-3, lemon 2-5, butyl 10-13, diepoxy triethylene glycol glycidol ether 8-10, thymol 4-6, chitosan 1.2-2.2, nanoscale Tourmaline 3-5, Tea Saponin 0.5-0.8, dimethyl silicone polymer two quaternary amine 4.5-6.5, its preparation method is by the swelling 2-3 hour of nanoscale Tourmaline room temperature in distilled water, form suspension, then butyl, diepoxy triethylene glycol glycidol ether, thymol, dimethyl silicone polymer two quaternary amine mix and blend is also warming up to 140-160 DEG C of stirring 1-2 hour, join in above-mentioned suspension and stir 30-40 minute, add other residual componentss again strong agitation 2-3 hour and get final product.
2. a kind of preparation method with the cotton fiber of antibiosis anti-acarien effect according to claim 1, is characterized in that comprising the following steps:
(1) get peppermint, sweet osmanthus puts into hot water and soak filtration in 6-8 hour, cotton fiber, soft silk fiber, fibroin fiber, high-shrinkage polyster, mulberry fibre immersion 7-10 hour is added in filtrate, filtering drying, sprays into Cortex Dictamni extract, nano oxidized zirconium powder sonic oscillation grinding 1-2 hour;
(2) by diatomite high-temperature calcination 30-40 minute, add polyvinyl alcohol, fatty acid amide sodium sulfonate adds water and grind spraying dry after 30-50 minute together, add alkylphenol polyoxyethylene and stir and evenly mix;
(3) step (1) product is dipped in step (2) and adopts two leaching two roll process, then steam treatment 5-10 minute, also dewatered drying adds 1-ethyl-3-methylimidazole diethyl phosphate, 1-butyl-3-N-Methylimidazoleacetic salt stirs 20-40 minute in cleaning, be heated to 90-100 DEG C, add other residual components again and stir 40-60 minute, obtained spinning solution is through spinning, winding, boundling, stretching and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410540644.XA CN104294400A (en) | 2014-10-14 | 2014-10-14 | Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410540644.XA CN104294400A (en) | 2014-10-14 | 2014-10-14 | Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104294400A true CN104294400A (en) | 2015-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410540644.XA Pending CN104294400A (en) | 2014-10-14 | 2014-10-14 | Cotton fibers with antibacterial anti-mite effects and manufacturing method thereof |
Country Status (1)
| Country | Link |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104562260A (en) * | 2015-02-01 | 2015-04-29 | 晋江市科创源专利服务有限公司 | Antibacterial Chinese herbal medicine fabric fiber and preparation method thereof |
| CN104862803A (en) * | 2015-06-09 | 2015-08-26 | 苏州市轩德纺织科技有限公司 | Antibiosis acarus killing textile material and preparation method |
| CN116289224A (en) * | 2023-03-22 | 2023-06-23 | 安徽高梵电子商务有限公司 | Insect-proof and mite-proof down quilt fabric and preparation method thereof |
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| WO2008153239A1 (en) * | 2007-06-11 | 2008-12-18 | Nanopoly Co., Ltd | Manufacture method of wet-tissue with antimicrobial and anti-fungus function |
| CN101352943A (en) * | 2008-08-26 | 2009-01-28 | 江苏紫荆花纺织科技股份有限公司 | Sandwich cocoon fibre filling core material |
| CN102409530A (en) * | 2011-07-21 | 2012-04-11 | 苏州邦安新材料科技有限公司 | Antibacterial and anti-mite plant fiber textile and preparation method thereof |
| CN103668547A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Mixed-fiber antibacterial towel |
| CN103898623A (en) * | 2014-03-22 | 2014-07-02 | 南通蛇类治疗研究所 | Natural antibacterial anti-acarien health-care bedding |
-
2014
- 2014-10-14 CN CN201410540644.XA patent/CN104294400A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008153239A1 (en) * | 2007-06-11 | 2008-12-18 | Nanopoly Co., Ltd | Manufacture method of wet-tissue with antimicrobial and anti-fungus function |
| CN101352943A (en) * | 2008-08-26 | 2009-01-28 | 江苏紫荆花纺织科技股份有限公司 | Sandwich cocoon fibre filling core material |
| CN102409530A (en) * | 2011-07-21 | 2012-04-11 | 苏州邦安新材料科技有限公司 | Antibacterial and anti-mite plant fiber textile and preparation method thereof |
| CN103668547A (en) * | 2012-09-22 | 2014-03-26 | 青岛道合生物科技有限公司 | Mixed-fiber antibacterial towel |
| CN103898623A (en) * | 2014-03-22 | 2014-07-02 | 南通蛇类治疗研究所 | Natural antibacterial anti-acarien health-care bedding |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104562260A (en) * | 2015-02-01 | 2015-04-29 | 晋江市科创源专利服务有限公司 | Antibacterial Chinese herbal medicine fabric fiber and preparation method thereof |
| CN104862803A (en) * | 2015-06-09 | 2015-08-26 | 苏州市轩德纺织科技有限公司 | Antibiosis acarus killing textile material and preparation method |
| CN116289224A (en) * | 2023-03-22 | 2023-06-23 | 安徽高梵电子商务有限公司 | Insect-proof and mite-proof down quilt fabric and preparation method thereof |
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Application publication date: 20150121 |