CN104562708A - Preparation method for antistatic terylene tablecloth - Google Patents
Preparation method for antistatic terylene tablecloth Download PDFInfo
- Publication number
- CN104562708A CN104562708A CN201510009288.3A CN201510009288A CN104562708A CN 104562708 A CN104562708 A CN 104562708A CN 201510009288 A CN201510009288 A CN 201510009288A CN 104562708 A CN104562708 A CN 104562708A
- Authority
- CN
- China
- Prior art keywords
- tablecloth
- solution
- modified dacron
- aqueous solution
- terylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 80
- 229920004933 Terylene® Polymers 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000243 solution Substances 0.000 claims abstract description 44
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims abstract description 37
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000000178 monomer Substances 0.000 claims abstract description 18
- NYLGITXFVVEBLZ-UHFFFAOYSA-N 1-methylindazol-3-amine Chemical compound C1=CC=C2N(C)N=C(N)C2=C1 NYLGITXFVVEBLZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- WCDSVWRUXWCYFN-UHFFFAOYSA-N 4-aminobenzenethiol Chemical compound NC1=CC=C(S)C=C1 WCDSVWRUXWCYFN-UHFFFAOYSA-N 0.000 claims abstract description 17
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims abstract description 17
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 17
- 238000005406 washing Methods 0.000 claims abstract description 17
- 239000011259 mixed solution Substances 0.000 claims abstract description 9
- 229920004934 Dacron® Polymers 0.000 claims description 53
- 239000007864 aqueous solution Substances 0.000 claims description 40
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 229920000728 polyester Polymers 0.000 claims description 23
- 239000012153 distilled water Substances 0.000 claims description 16
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- 239000005457 ice water Substances 0.000 claims description 8
- 238000004900 laundering Methods 0.000 claims description 8
- 238000002791 soaking Methods 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 16
- 239000004753 textile Substances 0.000 abstract description 8
- 238000006116 polymerization reaction Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 235000017550 sodium carbonate Nutrition 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 108010022355 Fibroins Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- GDJYIXGPYCKDOV-UHFFFAOYSA-N n-phenylthiohydroxylamine Chemical compound SNC1=CC=CC=C1 GDJYIXGPYCKDOV-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a preparation method for an antistatic terylene tablecloth, and belongs to the technical field of textile materials. The preparation method comprises the following steps: carrying out continuous modification treatment on the terylene tablecloth sequentially through the mixed solution composed of Na2CO3 solution, N-(2-aminoethyl)-3-aminopropyl trimethoxy-silane and vinyl trimethoxy silane, and ammonium persulphate solution, then impregnating the terylene tablecloth in the mixed conjugated monomer solution composed of phenylamine and p-aminothiophenol, and carrying out polymerization reaction, washing and drying to prepare the antistatic terylene tablecloth under the synergistic effect of perchloric acid, 4-thiacalixarene sulfonated sodium and phenol red sodium salt. The antistatic terylene tablecloth prepared by the method disclosed by the invention has an electrical conductivity of 8.5*10<-3> to 3.6*10<-2> S.cm<-1>; the preparation method disclosed by the invention has the following characteristics that the preparation method is simple, and the product is excellent in antistatic performance, wide in applicability and the like.
Description
Technical field:
The invention belongs to textile material technical field, be specifically related to a kind of preparation method of the anti-electrostatic polyester tablecloth.
Background technology:
Electrostatic phenomenon is common in all kinds of textiles.Eliminate electrostatic phenomenon, obtain anti-static function is one of focus of textile material research field (Youyi Xia always, Yun Lu. " Fabrication and properties of conductive conjugatedpolymers/silk fibroin composite fibers ", " Compostie Science and Technology ", 2008,68,1471-1479).
The tablecloth is that a class is covered on platform, desktop in order to antifouling or increase textiles attractive in appearance.As the high-grade tablecloth of one, the terylene class tablecloth is widely used in furnishings, dinner party, dining etc.But, because the polyester fiber hydrophily forming the terylene class tablecloth is poor, cause its electrostatic phenomenon very serious, thus in processing and use procedure, often cause serious fluffing, pilling effect, blast, disaster hidden-trouble (Liu Yuqiang etc. also can be produced under particular surroundings, " nano zine oxide-iron oxide mixed sols is to the antistatic effect of dacron ", " textile journal ", 2013,34,17-23).Therefore, the anti-static function of the endowing terylene class tablecloth is a problem demanding prompt solution.
Carrying out modification in textile surface, is the common methods solving electrostatic phenomenon.Compared to all kinds of antistatic additive, conjugative monomer, in the polymerization of fiber surface, because it is convenient, nontoxic, has therefore developed into the new methods preparing antistatic textile.As Chinese patent CN103468541A discloses a kind of simple preparation process of antistatic surface dacron, the method carries out aniline polymerization in dacron surface, obtains anti-static fabric; Chinese patent CN102943388A discloses a kind of method that home position polymerization reaction prepares Antistatic polyester fabric, and the method adopts home position polymerization reaction to also obtain a class anti-static fabric.Though application said method can obtain the terylene class tablecloth of certain antistatic behaviour, but, also there is the problems such as resistance is bigger than normal, antistatic behaviour is not good enough.
Summary of the invention:
The present invention is directed in the existing anti-electrostatic polyester tablecloth and there is technical problem, provide a kind of preparation method of the anti-electrostatic polyester tablecloth.
The preparation method of a kind of anti-electrostatic polyester tablecloth provided by the invention, its concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C.
(2) described modified dacron tablecloth A is placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B, the mass ratio of described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) described modified dacron tablecloth B is placed in mass fraction be 10% ~ 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D; The molar concentration of described mixing conjugative monomer in described solution D is 0.05 ~ 0.2molL
-1, the mol ratio of described aniline and p-Mercaptoaniline is (10 ~ 15): 1, and the molar concentration of described perchloric acid in described mixed aqueous solution is 0.5molL
-1, the molar concentration of described 4-sulfo group Thiacalixarene sodium salt in described mixed aqueous solution is 1mmolL
-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmolL
-1.
(5) described modified dacron tablecloth C is placed in described solution D, leaves standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry the obtained anti-electrostatic polyester tablecloth; The mass ratio of described modified dacron tablecloth C and described solution D is 1:20.
The electrical conductivity of the anti-electrostatic polyester tablecloth prepared by the present invention is: 8.5 × 10
-3~ 3.6 × 10
-2scm
-1(test of standard four point probe), antistatic behaviour is good.The inventive method, given full play to the concertedness of the conductive compositions produced after aniline is polymerized with mercaptoaniline, impel the terylene tablecloth to have higher electrical conductivity, thus antistatic behaviour is good.In addition, because early stage has carried out effective process to the terylene tablecloth, therefore conducting polymer particle can grow at terylene tablecloth fiber surface securely, thus good stability.Preparation technology of the present invention is simple, products obtained therefrom antistatic property is excellent, applicability is wide.
Detailed description of the invention:
Embodiment 1: electrical conductivity is 8.5 × 10
-3scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
1.
(2) by modified dacron tablecloth A
1be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
1, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
1be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
1.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
1; Mixing conjugative monomer is in solution D
1in molar concentration be 0.05molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 10:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
1with solution D
1mass ratio be 1:20, by modified dacron tablecloth C
1be placed in solution D
1in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 8.5 × 10
-3scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 2: electrical conductivity is 1.0 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
2.
(2) by modified dacron tablecloth A
2be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
2, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
2be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
2.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
2; Mixing conjugative monomer is in solution D
2in molar concentration be 0.08molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
2with solution D
2mass ratio be 1:20, by modified dacron tablecloth C
2be placed in solution D
2in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 1.0 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 3: electrical conductivity is 1.4 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
3.
(2) by modified dacron tablecloth A
3be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
3, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
3be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
3.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
3; Mixing conjugative monomer is in solution D
3in molar concentration be 0.1molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 12:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
3with solution D
3mass ratio be 1:20, by modified dacron tablecloth C
3be placed in solution D
3in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 1.4 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 4: electrical conductivity is 2.0 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
4.
(2) by modified dacron tablecloth A
4be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
4, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
4be placed in mass fraction be 10% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
4.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
4; Mixing conjugative monomer is in solution D
4in molar concentration be 0.12molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
4with solution D
4mass ratio be 1:20, by modified dacron tablecloth C
4be placed in solution D
4in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 2.0 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 5: electrical conductivity is 2.8 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
5.
(2) by modified dacron tablecloth A
5be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
5, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
5be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
5.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
5; Mixing conjugative monomer is in solution D
5in molar concentration be 0.15molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
5with solution D
5mass ratio be 1:20, by modified dacron tablecloth C
5be placed in solution D
5in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 2.8 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Embodiment 6: electrical conductivity is 3.6 × 10
-2scm
-1anti-electrostatic polyester tablecloth preparation method, the method concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C
6.
(2) by modified dacron tablecloth A
6be placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B
6, the mass ratio of N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4.
(3) by modified dacron tablecloth B
6be placed in mass fraction be 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C
6.
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D
6; Mixing conjugative monomer is in solution D
6in molar concentration be 0.2molL
-1, the mol ratio of aniline and p-Mercaptoaniline is 15:1, and the molar concentration of perchloric acid in mixed aqueous solution is 0.5molL
-1, the molar concentration of 4-sulfo group Thiacalixarene sodium salt in mixed aqueous solution is 1mmolL
-1, the molar concentration of phenol red sodium salt in mixed aqueous solution is 0.05m molL
-1.
(5) according to terylene tablecloth C
6with solution D
6mass ratio be 1:20, by modified dacron tablecloth C
6be placed in solution D
6in, leave standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry obtained electrical conductivity is 3.6 × 10
-2scm
-1the anti-electrostatic polyester tablecloth.
Claims (1)
1. a preparation method for the anti-electrostatic polyester tablecloth, is characterized in that these preparation method's concrete steps are as follows:
(1) the terylene tablecloth be impregnated in the Na that mass fraction is 2%
2cO
330min in solution, after a large amount of distilled water washing, dries, obtains modified dacron tablecloth A at 40 DEG C;
(2) described modified dacron tablecloth A is placed in mass fraction be 0.5% N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and after the mixed solution that forms of vinyltrimethoxy silane soaks 30min, wash respectively through methyl alcohol, water, dry at 40 DEG C, obtain modified dacron tablecloth B, the mass ratio of described N-(2-aminoethyl)-3-aminopropyl trimethoxysilane and vinyltrimethoxy silane is 6:4;
(3) described modified dacron tablecloth B is placed in mass fraction be 10% ~ 20% ammonium persulfate aqueous solution soak 1h after, again through distilled water washing, obtain modified dacron tablecloth C;
(4) conjugative monomer that mixes aniline and p-Mercaptoaniline formed is dissolved in the mixed aqueous solution that perchloric acid, 4-sulfo group Thiacalixarene sodium salt and phenol red sodium salt form, and obtains solution D; The molar concentration of described mixing conjugative monomer in described solution D is 0.05 ~ 0.2molL
-1, the mol ratio of described aniline and p-Mercaptoaniline is (10 ~ 15): 1, and the molar concentration of described perchloric acid in described mixed aqueous solution is 0.5molL
-1, the molar concentration of described 4-sulfo group Thiacalixarene sodium salt in described mixed aqueous solution is 1mmolL
-1, the molar concentration of described phenol red sodium salt in described mixed aqueous solution is 0.05mmolL
-1;
(5) described modified dacron tablecloth C is placed in described solution D, leaves standstill under the ice water bath environment of 0 DEG C ~ 5 DEG C after soaking 24h, wash through massive laundering, at 40 DEG C, dry the obtained anti-electrostatic polyester tablecloth; The mass ratio of described modified dacron tablecloth C and described solution D is 1:20.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510009288.3A CN104562708B (en) | 2015-01-08 | 2015-01-08 | A kind of preparation method of the anti-electrostatic polyester tablecloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510009288.3A CN104562708B (en) | 2015-01-08 | 2015-01-08 | A kind of preparation method of the anti-electrostatic polyester tablecloth |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104562708A true CN104562708A (en) | 2015-04-29 |
| CN104562708B CN104562708B (en) | 2016-05-11 |
Family
ID=53079728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510009288.3A Active CN104562708B (en) | 2015-01-08 | 2015-01-08 | A kind of preparation method of the anti-electrostatic polyester tablecloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104562708B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463833A (en) * | 2015-12-02 | 2016-04-06 | 马鞍山金姿纺织装饰用品有限公司 | Preparation method of antistatic polyester fabric |
| CN106480752A (en) * | 2016-12-01 | 2017-03-08 | 西南大学 | Colouring method of the sulfuretin to dacron |
| CN106676720A (en) * | 2016-11-25 | 2017-05-17 | 威海恒基伟业信息科技发展有限公司 | Antistatic cloth production method |
| CN108677525A (en) * | 2018-05-06 | 2018-10-19 | 邳州易萨新型材料有限公司 | A kind of preparation method of novel antistatic polyester fabric |
| CN115948816A (en) * | 2023-02-14 | 2023-04-11 | 无锡聚新科技股份有限公司 | Method for manufacturing white polyester composite conductive fiber |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03249272A (en) * | 1990-02-27 | 1991-11-07 | Achilles Corp | Electrically conductive textile product and its production |
| CN1099443A (en) * | 1993-08-25 | 1995-03-01 | 沈陆海 | Method for making polyaniline conductive dacron fibre |
| US5691062A (en) * | 1995-02-16 | 1997-11-25 | Clemson University | Molecularly bonded inherently conductive polymers on substrates and shaped articles thereof |
| CN1846026A (en) * | 2003-07-03 | 2006-10-11 | 联邦科学及工业研究组织 | Conductive Textiles |
| JP2006328610A (en) * | 2005-05-30 | 2006-12-07 | Gunze Ltd | Conductive fiber and method for producing the same |
| CN101168923A (en) * | 2007-10-17 | 2008-04-30 | 江苏正本净化节水科技实业有限公司 | Method for preparing conductive textile fibre |
| CN102220597A (en) * | 2011-05-20 | 2011-10-19 | 湖南大学 | Preparation method of conducting polymer-graphene composition |
| CN102337668A (en) * | 2011-06-30 | 2012-02-01 | 苏州新纶超净技术有限公司 | Washable polyaniline/terylene composite conductive fabric and manufacture method thereof |
-
2015
- 2015-01-08 CN CN201510009288.3A patent/CN104562708B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03249272A (en) * | 1990-02-27 | 1991-11-07 | Achilles Corp | Electrically conductive textile product and its production |
| CN1099443A (en) * | 1993-08-25 | 1995-03-01 | 沈陆海 | Method for making polyaniline conductive dacron fibre |
| US5691062A (en) * | 1995-02-16 | 1997-11-25 | Clemson University | Molecularly bonded inherently conductive polymers on substrates and shaped articles thereof |
| CN1846026A (en) * | 2003-07-03 | 2006-10-11 | 联邦科学及工业研究组织 | Conductive Textiles |
| JP2006328610A (en) * | 2005-05-30 | 2006-12-07 | Gunze Ltd | Conductive fiber and method for producing the same |
| CN101168923A (en) * | 2007-10-17 | 2008-04-30 | 江苏正本净化节水科技实业有限公司 | Method for preparing conductive textile fibre |
| CN102220597A (en) * | 2011-05-20 | 2011-10-19 | 湖南大学 | Preparation method of conducting polymer-graphene composition |
| CN102337668A (en) * | 2011-06-30 | 2012-02-01 | 苏州新纶超净技术有限公司 | Washable polyaniline/terylene composite conductive fabric and manufacture method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105463833A (en) * | 2015-12-02 | 2016-04-06 | 马鞍山金姿纺织装饰用品有限公司 | Preparation method of antistatic polyester fabric |
| CN105463833B (en) * | 2015-12-02 | 2017-10-31 | 马鞍山金姿纺织装饰用品有限公司 | A kind of preparation method of antistatic polyester kind fabric |
| CN106676720A (en) * | 2016-11-25 | 2017-05-17 | 威海恒基伟业信息科技发展有限公司 | Antistatic cloth production method |
| CN106480752A (en) * | 2016-12-01 | 2017-03-08 | 西南大学 | Colouring method of the sulfuretin to dacron |
| CN108677525A (en) * | 2018-05-06 | 2018-10-19 | 邳州易萨新型材料有限公司 | A kind of preparation method of novel antistatic polyester fabric |
| CN115948816A (en) * | 2023-02-14 | 2023-04-11 | 无锡聚新科技股份有限公司 | Method for manufacturing white polyester composite conductive fiber |
| CN115948816B (en) * | 2023-02-14 | 2023-09-05 | 无锡聚新科技股份有限公司 | Manufacturing method of white polyester composite conductive fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104562708B (en) | 2016-05-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101638847B (en) | Formaldehyde-free durable non-ironing finishing agent for treating cellulose fiber fabric | |
| CN104499294B (en) | A kind of have antistatic, the antibacterial and method for sorting of Hydrophilic Polyester Fiber fabric | |
| CN104562708A (en) | Preparation method for antistatic terylene tablecloth | |
| CN104179013B (en) | Composition of waterproofing and oil-proof agent and water and oil repellent agent compositions of additives | |
| JP6522627B2 (en) | Brominated epoxy polymers as flame retardant compositions for textile finishing | |
| CN109295698A (en) | A kind of preparation method of anti-ultraviolet cotton fabric with electrical conductivity | |
| CN102978901A (en) | Preparation technology of water, oil and pollution resistant texture fabric | |
| CN106555248B (en) | The preparation method of moisture absorption acrylic fibers | |
| CN101805995A (en) | Fabric finishing agent and fabric finishing method | |
| CN103614915A (en) | Super-hydrophobic natural fiber fabric and preparation method thereof | |
| CN106283664A (en) | Hydrophobic performance can the preparation method of water-fastness fabric of selfreparing | |
| CN105088800A (en) | Low-temperature water-based water-proofing agent and production process thereof | |
| Jiang et al. | Water repellent treatment of cotton fabrics by electron beam irradiation | |
| CN101948557B (en) | Method for preparing grafted modified starch | |
| CN116084178A (en) | Bio-based magic tape back gluing and preparation method and application thereof | |
| CN103255621B (en) | Kapok fiber pretreatment auxiliary agent and kapok fiber pretreatment method | |
| CN109306066A (en) | High cleaning is water-fastness, the high transparency of resistance to alcohol antistatic packaging material and preparation method thereof | |
| CN103570860A (en) | Method for preparing fluorine-containing waterproof and oil-proof agent through emulsifier-free emulsion polymerization | |
| CN107761383A (en) | A kind of method for sorting for improving dacron hydrophilic performance | |
| CN105200789A (en) | Antistatic agent and preparation method and application thereof | |
| CN105755826A (en) | Preparation method for electrostatic elimination in high-performance fiber spinning process | |
| CN105544193A (en) | Hydrophilic modification method for polyester fibers with bromoethane and PVA | |
| Yu et al. | A study of surface morphology and structure of cotton fibres with soluble immobilized-cellulase treatment | |
| CN106400487A (en) | Wool fabric non-ironing hydrophilic finishing agent | |
| CN105803666A (en) | Super-water-absorbent food packaging material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method for antistatic terylene tablecloth Effective date of registration: 20181029 Granted publication date: 20160511 Pledgee: Merchants Bank Ma'anshan branch of Limited by Share Ltd Bowang Pledgor: MAANSHAN JINZI TEXTILE OMAMENT CO., LTD. Registration number: 2018340000595 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20191209 Granted publication date: 20160511 Pledgee: Merchants Bank Ma'anshan branch of Limited by Share Ltd Bowang Pledgor: MAANSHAN JINZI TEXTILE OMAMENT CO., LTD. Registration number: 2018340000595 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method for antistatic terylene tablecloth Effective date of registration: 20200113 Granted publication date: 20160511 Pledgee: Hengshan Ma'anshan finance Company limited by guarantee Pledgor: MAANSHAN JINZI TEXTILE OMAMENT CO., LTD. Registration number: Y2020980000087 |