CN105017766A - 具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 - Google Patents

具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 Download PDF

Info

Publication number: CN105017766A
Authority: CN; China
Prior art keywords: acid; weight; bis; ester; molding material
Prior art date: 2014-01-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN201510051198.0A

Other languages

English (en)

Chinese (zh)

Inventor

奥利弗·托马斯

尼古拉·兰贝茨

博托·霍夫曼

耶奥伊·贝斯奇亚施维利

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EMS Patent AG

Original Assignee

EMS Patent AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-01-31

Filing date

2015-01-30

Publication date

2015-11-04

2015-01-30 Application filed by EMS Patent AG filed Critical EMS Patent AG

2015-11-04 Publication of CN105017766A publication Critical patent/CN105017766A/zh

Status Pending legal-status Critical Current

Links

239000004952 Polyamide Substances 0.000 title claims abstract description 72
229920002647 polyamide Polymers 0.000 title claims abstract description 72
239000003063 flame retardant Substances 0.000 title claims abstract description 24
230000007774 longterm Effects 0.000 title abstract description 11
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 8
239000000206 moulding compound Substances 0.000 title abstract 4
230000032683 aging Effects 0.000 title description 11
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 64
229910052751 metal Inorganic materials 0.000 claims abstract description 19
239000002184 metal Substances 0.000 claims abstract description 19
239000000654 additive Substances 0.000 claims abstract description 9
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 9
150000004706 metal oxides Chemical class 0.000 claims abstract description 9
150000003839 salts Chemical class 0.000 claims abstract description 6
230000000737 periodic effect Effects 0.000 claims abstract description 4
229910052723 transition metal Inorganic materials 0.000 claims abstract description 4
150000003624 transition metals Chemical class 0.000 claims abstract description 4
150000001408 amides Chemical class 0.000 claims description 86
-1 3-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl)-propionic acid triethyleneglycol ester Chemical class 0.000 claims description 73
239000012778 molding material Substances 0.000 claims description 47
238000002425 crystallisation Methods 0.000 claims description 30
230000008025 crystallization Effects 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 30
239000000463 material Substances 0.000 claims description 28
125000003118 aryl group Chemical group 0.000 claims description 24
238000000465 moulding Methods 0.000 claims description 23
239000002253 acid Substances 0.000 claims description 22
239000000835 fiber Substances 0.000 claims description 22
239000003381 stabilizer Substances 0.000 claims description 21
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 18
239000003795 chemical substances by application Substances 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 16
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 11
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 9
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 8
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
229920000877 Melamine resin Polymers 0.000 claims description 8
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 8
239000003365 glass fiber Substances 0.000 claims description 8
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 8
230000000996 additive effect Effects 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
239000003513 alkali Substances 0.000 claims description 6
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
239000007859 condensation product Substances 0.000 claims description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
229920000137 polyphosphoric acid Polymers 0.000 claims description 6
235000012239 silicon dioxide Nutrition 0.000 claims description 6
239000011734 sodium Substances 0.000 claims description 6
229910052708 sodium Inorganic materials 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
239000011701 zinc Substances 0.000 claims description 6
SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
239000012747 synergistic agent Substances 0.000 claims description 5
239000012745 toughening agent Substances 0.000 claims description 5
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 4
235000011941 Tilia x europaea Nutrition 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
239000004110 Zinc silicate Substances 0.000 claims description 4
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
230000015572 biosynthetic process Effects 0.000 claims description 4
229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
239000002826 coolant Substances 0.000 claims description 4
239000011521 glass Substances 0.000 claims description 4
150000002367 halogens Chemical class 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 4
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 4
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
239000004571 lime Substances 0.000 claims description 4
239000001095 magnesium carbonate Substances 0.000 claims description 4
235000014380 magnesium carbonate Nutrition 0.000 claims description 4
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
229960001708 magnesium carbonate Drugs 0.000 claims description 4
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
239000000347 magnesium hydroxide Substances 0.000 claims description 4
229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
150000007974 melamines Chemical class 0.000 claims description 4
229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
150000004692 metal hydroxides Chemical class 0.000 claims description 4
XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 4
235000019260 propionic acid Nutrition 0.000 claims description 4
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 4
229940071182 stannate Drugs 0.000 claims description 4
238000003786 synthesis reaction Methods 0.000 claims description 4
239000004408 titanium dioxide Substances 0.000 claims description 4
XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 claims description 4
235000019352 zinc silicate Nutrition 0.000 claims description 4
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
239000012760 heat stabilizer Substances 0.000 claims description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
230000003647 oxidation Effects 0.000 claims description 3
238000007254 oxidation reaction Methods 0.000 claims description 3
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 claims description 2
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 claims description 2
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 2
239000005995 Aluminium silicate Substances 0.000 claims description 2
239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
229920000049 Carbon (fiber) Polymers 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
235000005979 Citrus limon Nutrition 0.000 claims description 2
CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
229910021536 Zeolite Inorganic materials 0.000 claims description 2
FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
239000005083 Zinc sulfide Substances 0.000 claims description 2
JNVCSEDACVAATK-UHFFFAOYSA-L [Ca+2].[S-]SSS[S-] Chemical compound [Ca+2].[S-]SSS[S-] JNVCSEDACVAATK-UHFFFAOYSA-L 0.000 claims description 2
238000010521 absorption reaction Methods 0.000 claims description 2
125000001118 alkylidene group Chemical group 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
235000012211 aluminium silicate Nutrition 0.000 claims description 2
LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
235000019826 ammonium polyphosphate Nutrition 0.000 claims description 2
229920001276 ammonium polyphosphate Polymers 0.000 claims description 2
150000004646 arylidenes Chemical group 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
239000012754 barrier agent Substances 0.000 claims description 2
229910052728 basic metal Inorganic materials 0.000 claims description 2
150000003818 basic metals Chemical class 0.000 claims description 2
OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
239000011575 calcium Substances 0.000 claims description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
239000000292 calcium oxide Substances 0.000 claims description 2
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
239000004917 carbon fiber Substances 0.000 claims description 2
239000002482 conductive additive Substances 0.000 claims description 2
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
125000004494 ethyl ester group Chemical group 0.000 claims description 2
239000010433 feldspar Substances 0.000 claims description 2
239000011888 foil Substances 0.000 claims description 2
JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 2
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 2
150000002357 guanidines Chemical class 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
239000000314 lubricant Substances 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
235000012254 magnesium hydroxide Nutrition 0.000 claims description 2
239000000395 magnesium oxide Substances 0.000 claims description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 claims description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 claims description 2
229910021645 metal ion Inorganic materials 0.000 claims description 2
229910001463 metal phosphate Inorganic materials 0.000 claims description 2
150000004702 methyl esters Chemical class 0.000 claims description 2
239000010445 mica Substances 0.000 claims description 2
229910052618 mica group Inorganic materials 0.000 claims description 2
150000004767 nitrides Chemical class 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
CSWFWSPPZMEYAY-UHFFFAOYSA-N octadecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(O)O CSWFWSPPZMEYAY-UHFFFAOYSA-N 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
VYAWNUGJSVJTSU-UHFFFAOYSA-N phenanthrene phosphane Chemical compound C1=CC=CC=2C3=CC=CC=C3C=CC12.P VYAWNUGJSVJTSU-UHFFFAOYSA-N 0.000 claims description 2
XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 2
239000011574 phosphorus Substances 0.000 claims description 2
229910052698 phosphorus Inorganic materials 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
239000001205 polyphosphate Substances 0.000 claims description 2
235000011176 polyphosphates Nutrition 0.000 claims description 2
150000003921 pyrrolotriazines Chemical class 0.000 claims description 2
239000010453 quartz Substances 0.000 claims description 2
150000003336 secondary aromatic amines Chemical class 0.000 claims description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
125000005402 stannate group Chemical group 0.000 claims description 2
229940051851 sulfurated lime Drugs 0.000 claims description 2
239000000454 talc Substances 0.000 claims description 2
235000012222 talc Nutrition 0.000 claims description 2
229910052623 talc Inorganic materials 0.000 claims description 2
NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 claims description 2
WNVQBUHCOYRLPA-UHFFFAOYSA-N triuret Chemical compound NC(=O)NC(=O)NC(N)=O WNVQBUHCOYRLPA-UHFFFAOYSA-N 0.000 claims description 2
BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
239000010456 wollastonite Substances 0.000 claims description 2
229910052882 wollastonite Inorganic materials 0.000 claims description 2
239000010457 zeolite Substances 0.000 claims description 2
AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 claims description 2
239000011667 zinc carbonate Substances 0.000 claims description 2
235000004416 zinc carbonate Nutrition 0.000 claims description 2
229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 2
229910021511 zinc hydroxide Inorganic materials 0.000 claims description 2
229940007718 zinc hydroxide Drugs 0.000 claims description 2
239000011787 zinc oxide Substances 0.000 claims description 2
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 2
229910000165 zinc phosphate Inorganic materials 0.000 claims description 2
PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 claims description 2
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims 2
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
FGHOOJSIEHYJFQ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) dihydrogen phosphite Chemical compound CC(C)(C)C1=CC=C(OP(O)O)C(C(C)(C)C)=C1 FGHOOJSIEHYJFQ-UHFFFAOYSA-N 0.000 claims 1
NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
244000248349 Citrus limon Species 0.000 claims 1
239000006229 carbon black Substances 0.000 claims 1
239000002041 carbon nanotube Substances 0.000 claims 1
229910021393 carbon nanotube Inorganic materials 0.000 claims 1
239000000975 dye Substances 0.000 claims 1
239000003112 inhibitor Substances 0.000 claims 1
ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 claims 1
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims 1
230000003068 static effect Effects 0.000 claims 1
229920006012 semi-aromatic polyamide Polymers 0.000 abstract description 7
239000004608 Heat Stabiliser Substances 0.000 abstract 1
150000004985 diamines Chemical class 0.000 description 27
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 25
125000004432 carbon atom Chemical group C* 0.000 description 25
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 20
229920006111 poly(hexamethylene terephthalamide) Polymers 0.000 description 19
230000007797 corrosion Effects 0.000 description 11
238000005260 corrosion Methods 0.000 description 11
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 11
PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical group C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 10
238000012360 testing method Methods 0.000 description 10
125000002723 alicyclic group Chemical group 0.000 description 9
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 8
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
238000000034 method Methods 0.000 description 8
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
125000001931 aliphatic group Chemical group 0.000 description 7
229910052802 copper Inorganic materials 0.000 description 7
239000010949 copper Substances 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
239000000243 solution Substances 0.000 description 6
229920002302 Nylon 6,6 Polymers 0.000 description 5
230000003750 conditioning effect Effects 0.000 description 5
229920006119 nylon 10T Polymers 0.000 description 5
QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 4
229920002292 Nylon 6 Polymers 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 4
VMPHSYLJUKZBJJ-UHFFFAOYSA-N lauric acid triglyceride Natural products CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 4
239000000178 monomer Substances 0.000 description 4
KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 4
BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 4
SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 4
RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 4
YCOZIPAWZNQLMR-UHFFFAOYSA-N pentadecane Chemical compound CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 4
229920006131 poly(hexamethylene isophthalamide-co-terephthalamide) Polymers 0.000 description 4
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 4
239000000758 substrate Substances 0.000 description 4
BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 4
DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical group NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 4
RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 4
IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 description 3
238000011156 evaluation Methods 0.000 description 3
125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 3
SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 description 3
RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 3
238000002844 melting Methods 0.000 description 3
229940100630 metacresol Drugs 0.000 description 3
238000006068 polycondensation reaction Methods 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
150000003504 terephthalic acids Chemical class 0.000 description 3
XBZSBBLNHFMTEB-PHDIDXHHSA-N (1r,3r)-cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)[C@@H]1CCC[C@@H](C(O)=O)C1 XBZSBBLNHFMTEB-PHDIDXHHSA-N 0.000 description 2
XBZSBBLNHFMTEB-OLQVQODUSA-N (1s,3r)-cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)[C@H]1CCC[C@@H](C(O)=O)C1 XBZSBBLNHFMTEB-OLQVQODUSA-N 0.000 description 2
PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
MSWZFWKMSRAUBD-UHFFFAOYSA-N 2-Amino-2-Deoxy-Hexose Chemical compound NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 2
HCUZVMHXDRSBKX-UHFFFAOYSA-N 2-decylpropanedioic acid Chemical compound CCCCCCCCCCC(C(O)=O)C(O)=O HCUZVMHXDRSBKX-UHFFFAOYSA-N 0.000 description 2
AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 2
RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
229920006153 PA4T Polymers 0.000 description 2
BHHGXPLMPWCGHP-UHFFFAOYSA-N Phenethylamine Chemical compound NCCC1=CC=CC=C1 BHHGXPLMPWCGHP-UHFFFAOYSA-N 0.000 description 2
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 2
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
239000000539 dimer Substances 0.000 description 2
TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 2
PWSKHLMYTZNYKO-UHFFFAOYSA-N heptane-1,7-diamine Chemical compound NCCCCCCCN PWSKHLMYTZNYKO-UHFFFAOYSA-N 0.000 description 2
QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
229940033355 lauric acid Drugs 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
HYZLXDXICHITBR-UHFFFAOYSA-N n'-methyloctane-1,8-diamine Chemical compound CNCCCCCCCCN HYZLXDXICHITBR-UHFFFAOYSA-N 0.000 description 2
229940038384 octadecane Drugs 0.000 description 2
150000003008 phosphonic acid esters Chemical class 0.000 description 2
229920006139 poly(hexamethylene adipamide-co-hexamethylene terephthalamide) Polymers 0.000 description 2
HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
229910052709 silver Inorganic materials 0.000 description 2
239000004332 silver Substances 0.000 description 2
TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 2
NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
230000000007 visual effect Effects 0.000 description 2
OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 1
BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 1
AOGDNNLIBAUIIX-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-1-ylbenzene-1,4-diamine Chemical compound C1=CC=C2C(NC=3C=CC(NC=4C5=CC=CC=C5C=CC=4)=CC=3)=CC=CC2=C1 AOGDNNLIBAUIIX-UHFFFAOYSA-N 0.000 description 1
ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 1
GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
AFTPEBDOGXRMNQ-UHFFFAOYSA-N 2,2,4-Trimethylhexane Chemical compound CCC(C)CC(C)(C)C AFTPEBDOGXRMNQ-UHFFFAOYSA-N 0.000 description 1
FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
SVEMKBCPZYWEPH-UHFFFAOYSA-N 2,4,4-trimethylhexane Chemical compound CCC(C)(C)CC(C)C SVEMKBCPZYWEPH-UHFFFAOYSA-N 0.000 description 1
QUBNFZFTFXTLKH-UHFFFAOYSA-N 2-aminododecanoic acid Chemical compound CCCCCCCCCCC(N)C(O)=O QUBNFZFTFXTLKH-UHFFFAOYSA-N 0.000 description 1
JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 1
ZLFHNCHMEGLFKL-UHFFFAOYSA-N 3,3-bis(3-tert-butyl-4-hydroxyphenyl)butanoic acid Chemical compound C1=C(O)C(C(C)(C)C)=CC(C(C)(CC(O)=O)C=2C=C(C(O)=CC=2)C(C)(C)C)=C1 ZLFHNCHMEGLFKL-UHFFFAOYSA-N 0.000 description 1
YEXOWHQZWLCHHD-UHFFFAOYSA-N 3,5-ditert-butyl-4-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC(C(O)=O)=CC(C(C)(C)C)=C1O YEXOWHQZWLCHHD-UHFFFAOYSA-N 0.000 description 1
UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 1
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
MNDTVJMRXYKBPV-UHFFFAOYSA-N 4-amino-2,6-ditert-butylphenol Chemical class CC(C)(C)C1=CC(N)=CC(C(C)(C)C)=C1O MNDTVJMRXYKBPV-UHFFFAOYSA-N 0.000 description 1
SWVKFORRAJEMKK-UHFFFAOYSA-N 4-methylcyclohexane-1,1-diamine Chemical compound CC1CCC(N)(N)CC1 SWVKFORRAJEMKK-UHFFFAOYSA-N 0.000 description 1
SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
UQXNEWQGGVUVQA-UHFFFAOYSA-N 8-aminooctanoic acid Chemical compound NCCCCCCCC(O)=O UQXNEWQGGVUVQA-UHFFFAOYSA-N 0.000 description 1
RTJUWEUCUSQYAV-UHFFFAOYSA-N C(C)(C)(C)C=1C=C(C=C(C1O)CN)CCC(=O)O Chemical compound C(C)(C)(C)C=1C=C(C=C(C1O)CN)CCC(=O)O RTJUWEUCUSQYAV-UHFFFAOYSA-N 0.000 description 1
244000131522 Citrus pyriformis Species 0.000 description 1
229940126062 Compound A Drugs 0.000 description 1
244000241257 Cucumis melo Species 0.000 description 1
235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 description 1
229920000393 Nylon 6/6T Polymers 0.000 description 1
REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
235000020661 alpha-linolenic acid Nutrition 0.000 description 1
159000000013 aluminium salts Chemical class 0.000 description 1
229910000329 aluminium sulfate Inorganic materials 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
239000004566 building material Substances 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
230000008859 change Effects 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
239000004567 concrete Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
YMHQVDAATAEZLO-UHFFFAOYSA-N cyclohexane-1,1-diamine Chemical compound NC1(N)CCCCC1 YMHQVDAATAEZLO-UHFFFAOYSA-N 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 1
JXIKLABFTFGIQB-UHFFFAOYSA-N dioxaphosphocine Chemical compound C=1C=COOP=CC=1 JXIKLABFTFGIQB-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000005357 flat glass Substances 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
229960003692 gamma aminobutyric acid Drugs 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
230000006872 improvement Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
229960004488 linolenic acid Drugs 0.000 description 1
KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
ITZPOSYADVYECJ-UHFFFAOYSA-N n'-cyclohexylpropane-1,3-diamine Chemical compound NCCCNC1CCCCC1 ITZPOSYADVYECJ-UHFFFAOYSA-N 0.000 description 1
UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
ULFVOGIINBRZRT-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-2-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O ULFVOGIINBRZRT-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229920006115 poly(dodecamethylene terephthalamide) Polymers 0.000 description 1
229920006117 poly(hexamethylene terephthalamide)-co- polycaprolactam Polymers 0.000 description 1
229920006181 poly(hexamethylene terephthalamide)-co-poly(hexamethylene dodecanediamide) Polymers 0.000 description 1
229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
235000007715 potassium iodide Nutrition 0.000 description 1
229960004839 potassium iodide Drugs 0.000 description 1
230000008569 process Effects 0.000 description 1
230000011514 reflex Effects 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
229920006024 semi-aromatic copolyamide Polymers 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
238000004441 surface measurement Methods 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/014—Stabilisers against oxidation, heat, light or ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CN201510051198.0A 2014-01-31 2015-01-30 具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 Pending CN105017766A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP14153391.9		2014-01-31
EP14153391.9A EP2902444B1 (de)	2014-01-31	2014-01-31	Polyamid-Formmassen mit flammhemmenden Eigenschaften und sehr guter Langzeitwärmealterungsbeständigkeit

Publications (1)

Publication Number	Publication Date
CN105017766A true CN105017766A (zh)	2015-11-04

Family

ID=50030105

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN201510051198.0A Pending CN105017766A (zh)	2014-01-31	2015-01-30	具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料

Country Status (7)

Country	Link
US (1)	US20150218374A1 (2)
EP (1)	EP2902444B1 (2)
JP (1)	JP2015145496A (2)
KR (1)	KR102460868B1 (2)
CN (1)	CN105017766A (2)
BR (1)	BR102015002100B1 (2)
TW (1)	TW201533156A (2)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN107236281A (zh) *	2017-06-19	2017-10-10	成都新柯力化工科技有限公司	一种发泡聚氨酯专用复合阻燃剂及制备方法
CN107955368A (zh) *	2017-12-06	2018-04-24	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
CN111286218A (zh) *	2020-03-26	2020-06-16	青海大学	一种有机-无机杂化复合粒子的制备方法
CN111433026A (zh) *	2017-12-05	2020-07-17	利安德巴塞尔先进聚合物公司	高性能聚酰胺化合物及其用途
CN111670221A (zh) *	2017-12-20	2020-09-15	性能聚酰胺有限公司	高耐热性的聚酰胺模塑复合物
CN113544213A (zh) *	2019-03-06	2021-10-22	巴斯夫欧洲公司	用于高光泽应用的聚酰胺模塑组合物
CN113661214A (zh) *	2019-04-01	2021-11-16	奥升德功能材料运营有限公司	非卤化阻燃性聚酰胺组合物
CN114716812A (zh) *	2022-02-17	2022-07-08	上海金发科技发展有限公司	一种mca阻燃聚酰胺复合材料及其制备方法和应用
CN119592065A (zh) *	2024-12-26	2025-03-11	湖北合聚高分子材料有限公司	一种玄武岩增强无卤阻燃pa66mxd6复合材料及其制备方法

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102013217241A1 (de)	2013-08-29	2015-03-05	Ems-Patent Ag	Polyamid-Formmassen und hieraus hergestellte Formkörper
EP3184577B1 (de)	2015-12-23	2025-08-20	Ems-Chemie Ag	Verfahren und behälter für die lagerung und den transport von polyamidgranulaten und entsprechend gelagertes oder transportiertes polyamidgranulat sowie hieraus hergestellte formkörper
EP3222649B1 (de) *	2016-03-23	2018-04-18	Ems-Patent Ag	Hochtemperaturbeständige polyamidformmassen und deren verwendungen insbesondere im automobilbereich
EP3309199B1 (de)	2016-10-12	2020-04-01	Ems-Patent Ag	Glasfüller-verstärkte polyamid-formmassen auf basis amorpher copolyamide
EP3312224B1 (en)	2016-10-21	2018-12-26	Ems-Patent Ag	Polyamide moulding composition and multi-layered structure made herefrom
EP3369760B1 (de)	2017-03-03	2023-05-10	Ems-Chemie Ag	Mikrowellenbeständige formkörper
EP3369761B1 (de)	2017-03-03	2022-06-01	Ems-Chemie Ag	Copolyamide enthaltend dimere fettsäure als monomer
EP3392290B8 (de)	2017-04-18	2020-11-11	Ems-Chemie Ag	Polyamidformmasse und daraus hergestellter formkörper
EP3444112B1 (de)	2017-08-18	2020-12-23	Ems-Chemie Ag	Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus
EP3444114B1 (de)	2017-08-18	2023-10-25	Ems-Chemie Ag	Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus
EP3444113B1 (de)	2017-08-18	2021-01-20	Ems-Chemie Ag	Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus
EP3450481B1 (de)	2017-08-31	2020-10-21	Ems-Chemie Ag	Polyamid-formmasse mit hohem glanz und hoher kerbschlagzähigkeit
EP3502191B1 (de)	2017-12-22	2021-02-17	Ems-Chemie Ag	Polyamid-formmasse
EP3502164B1 (de)	2017-12-22	2022-10-05	Ems-Chemie Ag	Polyamid-formmasse
EP3636406B1 (de)	2018-10-09	2021-04-28	Ems-Chemie Ag	Schlagzähmodifizierte polyamid-formmassen
TWI779258B (zh)	2019-01-07	2022-10-01	美商阿散德性能材料營運公司	非鹵化阻燃聚醯胺組合物
EP3772520B1 (de)	2019-08-09	2023-07-12	Ems-Chemie Ag	Polyamid-formmasse und deren verwendung sowie aus der formmasse hergestellte formkörper
EP3772521B1 (de)	2019-08-09	2023-06-07	Ems-Chemie Ag	Teilkristalline copolyamide, diese enthaltende formmassen und deren verwendung sowie daraus hergestellte formkörper
WO2021043929A1 (en)	2019-09-06	2021-03-11	Dsm Ip Assets B.V.	Flame retardant polyamide-based 3d printing extrusion materials
EP3842470A1 (de)	2019-12-23	2021-06-30	Ems-Chemie Ag	Polyamid-formmassen für hypochlorit-beständige anwendungen
EP3842496A1 (de)	2019-12-23	2021-06-30	Ems-Chemie Ag	Polyamid-formmassen für hypochlorit-beständige anwendungen
WO2021181362A1 (en)	2020-03-13	2021-09-16	Inv Nylon Chemicals Americas, Llc	Thermoplastic resins for network applications
WO2022043345A1 (en)	2020-08-26	2022-03-03	Basf Se	Polyamide filaments for use in 3d printing
EP4015562A1 (de)	2020-12-17	2022-06-22	Ems-Chemie Ag	Polyamid-formmassen, hieraus hergestellte formkörper und verwendung der polyamid-formmassen
EP4015575A1 (de)	2020-12-17	2022-06-22	Ems-Chemie Ag	Gefüllte polyamid-formmassen, hieraus hergestellte formkörper und verwendung der gefüllten polyamid-formmassen
TWI784445B (zh) *	2021-01-27	2022-11-21	英商英威達紡織（英國）有限公司	包含用於網路應用之熱塑性樹脂的殼體物件、天線系統及通信方法
KR102858902B1 (ko) *	2022-02-25	2025-09-11	롯데케미칼 주식회사	열가소성 수지 조성물 및 이로부터 제조되는 성형품

Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1326481A (zh) *	1998-10-15	2001-12-12	L·布鲁克曼两合公司	用铜配合物和有机卤素化合物稳定的聚酰胺组合物
US20050113496A1 (en) *	2003-10-03	2005-05-26	Yuji Saga	Flame resistant polyamide resin composition containing phenolic resin and articles made therefrom
CN101802098A (zh) *	2007-05-17	2010-08-11	三菱工程塑料株式会社	阻燃性聚酰胺树脂组合物
CN102378784A (zh) *	2009-03-30	2012-03-14	纳幕尔杜邦公司	阻燃性半芳香聚酰胺树脂组合物以及由其制得的制品
CN102471530A (zh) *	2009-07-30	2012-05-23	纳幕尔杜邦公司	具有高胺末端的耐热聚酰胺组合物
CN102618023A (zh) *	2003-10-06	2012-08-01	Ems-化学公开股份有限公司	阻燃聚酰胺模塑材料及其用途
CN102827471A (zh) *	2011-06-17	2012-12-19	Ems专利股份公司	半芳香族模塑料及其应用

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1495393B2 (de)	1964-11-12	1979-10-18	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur Herstellung von Polyamiden aus Methylestern der Tere- und/oder Isophthalsäure und alipatischen primären Diaminen
DE3321579A1 (de)	1983-06-15	1984-12-20	Basf Ag, 6700 Ludwigshafen	Verfahren zur kontinuierlichen herstellung von polyamiden
DE3321581A1 (de)	1983-06-15	1984-12-20	Basf Ag, 6700 Ludwigshafen	Verfahren zur kontinuierlichen herstellung von polyamiden
JPS60158220A (ja)	1984-01-27	1985-08-19	Mitsui Petrochem Ind Ltd	摺動材用成形材料
DE3707689A1 (de)	1987-03-11	1988-09-22	Basf Ag	Formaldehydarme bindemittel
DE3889787D1 (de)	1987-07-17	1994-07-07	Basf Ag	Teilaromatische Copolyamide mit verringertem Triamingehalt.
DE19513940A1 (de)	1994-07-14	1996-01-18	Inventa Ag	Verfahren zur Herstellung von Vorkondensaten teilkristalliner oder amorpher, thermoplastisch verarbeitbarer teilaromatischer Polyamide bzw. Copolyamide
JPH10130497A (ja) *	1996-11-01	1998-05-19	Mitsubishi Gas Chem Co Inc	ポリアミド樹脂組成物
JP4179703B2 (ja)	1998-07-30	2008-11-12	株式会社クラレ	ポリアミドの製造方法
JP2000204239A (ja) *	1999-01-08	2000-07-25	Kuraray Co Ltd	ポリアミド組成物
JP2001106907A (ja) *	1999-08-04	2001-04-17	Mitsubishi Engineering Plastics Corp	耐候性の改良されたポリアミド樹脂組成物及びそれを用いた成形品
EP1681313A1 (en)	2005-01-17	2006-07-19	DSM IP Assets B.V.	Heat stabilized moulding composition
JP2007077309A (ja) *	2005-09-15	2007-03-29	Toray Ind Inc	ポリアミド樹脂組成物
CN110079078A (zh)	2011-06-09	2019-08-02	索尔维特殊聚合物美国有限责任公司	以改善的热稳定性为特征的聚酰胺组合物
US20130281589A1 (en) *	2012-04-23	2013-10-24	E I Du Pont De Nemours And Company	Thermoplastic polyamide composition
EP2861667A1 (en) *	2012-06-13	2015-04-22	E.I. Du Pont De Nemours And Company	Thermoplastic melt-mixed composition with polyetherol heat stabilizer
WO2013188488A1 (en) *	2012-06-13	2013-12-19	E. I. Du Pont De Nemours And Company	Thermoplastic melt-mixed composition with epoxy-carboxylic acid compound heat stabilizer
CN104350096B (zh) *	2012-06-13	2017-02-22	纳幕尔杜邦公司	具有氨基酸热稳定剂的熔融混合的热塑性组合物

2014
- 2014-01-31 EP EP14153391.9A patent/EP2902444B1/de active Active
2015
- 2015-01-28 TW TW104102896A patent/TW201533156A/zh unknown
- 2015-01-28 US US14/607,676 patent/US20150218374A1/en not_active Abandoned
- 2015-01-29 BR BR102015002100-3A patent/BR102015002100B1/pt active IP Right Grant
- 2015-01-29 JP JP2015014995A patent/JP2015145496A/ja active Pending
- 2015-01-30 CN CN201510051198.0A patent/CN105017766A/zh active Pending
- 2015-01-30 KR KR1020150015543A patent/KR102460868B1/ko active Active

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1326481A (zh) *	1998-10-15	2001-12-12	L·布鲁克曼两合公司	用铜配合物和有机卤素化合物稳定的聚酰胺组合物
US20050113496A1 (en) *	2003-10-03	2005-05-26	Yuji Saga	Flame resistant polyamide resin composition containing phenolic resin and articles made therefrom
CN102618023A (zh) *	2003-10-06	2012-08-01	Ems-化学公开股份有限公司	阻燃聚酰胺模塑材料及其用途
CN101802098A (zh) *	2007-05-17	2010-08-11	三菱工程塑料株式会社	阻燃性聚酰胺树脂组合物
CN102378784A (zh) *	2009-03-30	2012-03-14	纳幕尔杜邦公司	阻燃性半芳香聚酰胺树脂组合物以及由其制得的制品
CN102471530A (zh) *	2009-07-30	2012-05-23	纳幕尔杜邦公司	具有高胺末端的耐热聚酰胺组合物
CN102827471A (zh) *	2011-06-17	2012-12-19	Ems专利股份公司	半芳香族模塑料及其应用

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN107236281A (zh) *	2017-06-19	2017-10-10	成都新柯力化工科技有限公司	一种发泡聚氨酯专用复合阻燃剂及制备方法
CN111433026A (zh) *	2017-12-05	2020-07-17	利安德巴塞尔先进聚合物公司	高性能聚酰胺化合物及其用途
CN107955368A (zh) *	2017-12-06	2018-04-24	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
CN107955368B (zh) *	2017-12-06	2020-07-07	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
CN111670221B (zh) *	2017-12-20	2023-08-11	巴斯夫欧洲公司	高耐热性的聚酰胺模塑复合物
CN111670221A (zh) *	2017-12-20	2020-09-15	性能聚酰胺有限公司	高耐热性的聚酰胺模塑复合物
US12312467B2 (en)	2019-03-06	2025-05-27	Basf Se	Polyamide molding composition for high-gloss applications
CN113544213A (zh) *	2019-03-06	2021-10-22	巴斯夫欧洲公司	用于高光泽应用的聚酰胺模塑组合物
CN113661214A (zh) *	2019-04-01	2021-11-16	奥升德功能材料运营有限公司	非卤化阻燃性聚酰胺组合物
CN111286218B (zh) *	2020-03-26	2021-02-05	青海大学	一种有机-无机杂化复合粒子的制备方法
CN111286218A (zh) *	2020-03-26	2020-06-16	青海大学	一种有机-无机杂化复合粒子的制备方法
CN114716812A (zh) *	2022-02-17	2022-07-08	上海金发科技发展有限公司	一种mca阻燃聚酰胺复合材料及其制备方法和应用
CN114716812B (zh) *	2022-02-17	2023-11-07	上海金发科技发展有限公司	一种mca阻燃聚酰胺复合材料及其制备方法和应用
CN119592065A (zh) *	2024-12-26	2025-03-11	湖北合聚高分子材料有限公司	一种玄武岩增强无卤阻燃pa66mxd6复合材料及其制备方法

Also Published As

Publication number	Publication date
KR102460868B1 (ko)	2022-11-08
BR102015002100B1 (pt)	2020-06-30
EP2902444B1 (de)	2018-01-17
KR20150091266A (ko)	2015-08-10
TW201533156A (zh)	2015-09-01
JP2015145496A (ja)	2015-08-13
EP2902444A1 (de)	2015-08-05
BR102015002100A2 (pt)	2015-12-08
US20150218374A1 (en)	2015-08-06

Legal Events

Date	Code	Title	Description
2015-11-04	C06	Publication
2015-11-04	PB01	Publication
2017-01-04	C10	Entry into substantive examination
2017-01-04	SE01	Entry into force of request for substantive examination
2019-05-07	WD01	Invention patent application deemed withdrawn after publication	Application publication date: 20151104
2019-05-07	WD01	Invention patent application deemed withdrawn after publication

Publication	Publication Date	Title
KR102460868B1 (ko)	2022-11-08	난연성 및 우수한 장기 내열노화성을 가진 폴리아미드 성형 화합물
KR101464782B1 (ko)	2014-11-26	개선된 열 노화 및 가수분해 안정성을 갖는 폴리아미드 성형 조성물
KR102194448B1 (ko)	2020-12-24	폴리아미드 성형 화합물 및 이로부터 제조된 성형품
CN102827471B (zh)	2014-05-07	半芳香族模塑料及其应用
US8487024B2 (en)	2013-07-16	Polyamide, polyamide composition, and method for producing polyamide
TWI534200B (zh)	2016-05-21	阻焰半芳族聚醯胺模製組成物
CN105283509B (zh)	2018-06-08	聚酰胺树脂组合物和包含该组合物的成形品
CN100564454C (zh)	2009-12-02	阻燃聚酰胺模塑材料
US10017628B2 (en)	2018-07-10	Flame retarded thermoplastic moulding composition
CN101891953A (zh)	2010-11-24	一种无卤阻燃增强聚酰胺组合物及其模制品
US12110392B2 (en)	2024-10-08	Filled polyamide moulding compounds, moulded articles produced therefrom, and use of the filled polyamide moulding compounds
KR20110033257A (ko)	2011-03-30	주석산아연을 포함하는 난연성 반방향족 폴리아미드 수지 조성물 및 그로부터의 용품
CN102719093B (zh)	2015-01-07	一种无卤阻燃聚酰胺组合物及其制备方法与应用
EP2944674A1 (en)	2015-11-18	Polyamide composition and molded article
US20070054992A1 (en)	2007-03-08	Flame-Retardant Resin Composition
JP2020056003A (ja)	2020-04-09	ポリアミド組成物及びその製造方法、並びに、成形品
TW201920468A (zh)	2019-06-01	具有高抗熱變形性之阻燃性聚醯胺組成物及其用途
BR112019018985A2 (pt)	2020-04-14	material de moldagem termoplástico, processo para a produção de materiais de moldagem termoplásticos, uso de materiais de moldagem termoplásticos, artigo, fibra ou filme moldado, processo para a produção de artigos, fibras ou filmes moldados e uso de uma mistura
JPH05209123A (ja)	1993-08-20	未強化ポリアミド成形材料
JP2020524740A (ja)	2020-08-20	リン及びＡｌ−ホスホネートを有するポリアミド
US8541489B2 (en)	2013-09-24	Flame resistant semiaromatic polyamide resin composition including zinc stannate, and articles therefrom
JP2023157584A (ja)	2023-10-26	ポリアミド組成物及び成形品
KR20220113982A (ko)	2022-08-17	흑색으로 염색된 폴리아미드 조성물, 이의 제조 및 용도