CN105017766A - 具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 - Google Patents

具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 Download PDF

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Publication number: CN105017766A
Authority: CN; China
Prior art keywords: acid; weight; bis; ester; molding material
Prior art date: 2014-01-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN201510051198.0A

Other languages

English (en)

Chinese (zh)

Inventor

奥利弗·托马斯

尼古拉·兰贝茨

博托·霍夫曼

耶奥伊·贝斯奇亚施维利

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EMS Patent AG

Original Assignee

EMS Patent AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-01-31

Filing date

2015-01-30

Publication date

2015-11-04

2015-01-30 Application filed by EMS Patent AG filed Critical EMS Patent AG

2015-11-04 Publication of CN105017766A publication Critical patent/CN105017766A/zh

Status Pending legal-status Critical Current

Links

239000004952 Polyamide Substances 0.000 title claims abstract description 72
229920002647 polyamide Polymers 0.000 title claims abstract description 72
239000003063 flame retardant Substances 0.000 title claims abstract description 24
230000007774 longterm Effects 0.000 title abstract description 11
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 8
239000000206 moulding compound Substances 0.000 title abstract 4
230000032683 aging Effects 0.000 title description 11
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 64
229910052751 metal Inorganic materials 0.000 claims abstract description 19
239000002184 metal Substances 0.000 claims abstract description 19
239000000654 additive Substances 0.000 claims abstract description 9
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 9
150000004706 metal oxides Chemical class 0.000 claims abstract description 9
150000003839 salts Chemical class 0.000 claims abstract description 6
230000000737 periodic effect Effects 0.000 claims abstract description 4
229910052723 transition metal Inorganic materials 0.000 claims abstract description 4
150000003624 transition metals Chemical class 0.000 claims abstract description 4
150000001408 amides Chemical class 0.000 claims description 86
-1 3-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl)-propionic acid triethyleneglycol ester Chemical class 0.000 claims description 73
239000012778 molding material Substances 0.000 claims description 47
238000002425 crystallisation Methods 0.000 claims description 30
230000008025 crystallization Effects 0.000 claims description 30
239000000203 mixture Substances 0.000 claims description 30
239000000463 material Substances 0.000 claims description 28
125000003118 aryl group Chemical group 0.000 claims description 24
238000000465 moulding Methods 0.000 claims description 23
239000002253 acid Substances 0.000 claims description 22
239000000835 fiber Substances 0.000 claims description 22
239000003381 stabilizer Substances 0.000 claims description 21
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 claims description 18
239000003795 chemical substances by application Substances 0.000 claims description 16
150000001875 compounds Chemical class 0.000 claims description 16
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 11
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 claims description 9
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 claims description 8
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
229920000877 Melamine resin Polymers 0.000 claims description 8
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
150000002148 esters Chemical class 0.000 claims description 8
239000003365 glass fiber Substances 0.000 claims description 8
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 8
230000000996 additive effect Effects 0.000 claims description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 6
239000003513 alkali Substances 0.000 claims description 6
WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
239000007859 condensation product Substances 0.000 claims description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
229910052757 nitrogen Inorganic materials 0.000 claims description 6
229920000137 polyphosphoric acid Polymers 0.000 claims description 6
235000012239 silicon dioxide Nutrition 0.000 claims description 6
239000011734 sodium Substances 0.000 claims description 6
229910052708 sodium Inorganic materials 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
239000011701 zinc Substances 0.000 claims description 6
SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 claims description 5
239000000126 substance Substances 0.000 claims description 5
239000012747 synergistic agent Substances 0.000 claims description 5
239000012745 toughening agent Substances 0.000 claims description 5
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 claims description 4
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 4
235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 4
JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 4
235000011941 Tilia x europaea Nutrition 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
239000004110 Zinc silicate Substances 0.000 claims description 4
TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
230000015572 biosynthetic process Effects 0.000 claims description 4
229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
239000002826 coolant Substances 0.000 claims description 4
239000011521 glass Substances 0.000 claims description 4
150000002367 halogens Chemical class 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 4
FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 4
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
239000004571 lime Substances 0.000 claims description 4
239000001095 magnesium carbonate Substances 0.000 claims description 4
235000014380 magnesium carbonate Nutrition 0.000 claims description 4
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 4
229910000021 magnesium carbonate Inorganic materials 0.000 claims description 4
229960001708 magnesium carbonate Drugs 0.000 claims description 4
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 4
239000000347 magnesium hydroxide Substances 0.000 claims description 4
229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 4
150000007974 melamines Chemical class 0.000 claims description 4
229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
150000004692 metal hydroxides Chemical class 0.000 claims description 4
XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 4
235000019260 propionic acid Nutrition 0.000 claims description 4
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 4
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 4
229940071182 stannate Drugs 0.000 claims description 4
238000003786 synthesis reaction Methods 0.000 claims description 4
239000004408 titanium dioxide Substances 0.000 claims description 4
XSMMCTCMFDWXIX-UHFFFAOYSA-N zinc silicate Chemical compound [Zn+2].[O-][Si]([O-])=O XSMMCTCMFDWXIX-UHFFFAOYSA-N 0.000 claims description 4
235000019352 zinc silicate Nutrition 0.000 claims description 4
229910000147 aluminium phosphate Inorganic materials 0.000 claims description 3
239000012760 heat stabilizer Substances 0.000 claims description 3
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
230000003647 oxidation Effects 0.000 claims description 3
238000007254 oxidation reaction Methods 0.000 claims description 3
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 claims description 2
125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 claims description 2
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 claims description 2
239000005995 Aluminium silicate Substances 0.000 claims description 2
239000004114 Ammonium polyphosphate Substances 0.000 claims description 2
229920000049 Carbon (fiber) Polymers 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
235000005979 Citrus limon Nutrition 0.000 claims description 2
CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
229910021536 Zeolite Inorganic materials 0.000 claims description 2
FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 2
239000005083 Zinc sulfide Substances 0.000 claims description 2
JNVCSEDACVAATK-UHFFFAOYSA-L [Ca+2].[S-]SSS[S-] Chemical compound [Ca+2].[S-]SSS[S-] JNVCSEDACVAATK-UHFFFAOYSA-L 0.000 claims description 2
238000010521 absorption reaction Methods 0.000 claims description 2
125000001118 alkylidene group Chemical group 0.000 claims description 2
229910052782 aluminium Inorganic materials 0.000 claims description 2
235000012211 aluminium silicate Nutrition 0.000 claims description 2
LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
235000019826 ammonium polyphosphate Nutrition 0.000 claims description 2
229920001276 ammonium polyphosphate Polymers 0.000 claims description 2
150000004646 arylidenes Chemical group 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
239000012754 barrier agent Substances 0.000 claims description 2
229910052728 basic metal Inorganic materials 0.000 claims description 2
150000003818 basic metals Chemical class 0.000 claims description 2
OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
229910052791 calcium Inorganic materials 0.000 claims description 2
239000011575 calcium Substances 0.000 claims description 2
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
239000000292 calcium oxide Substances 0.000 claims description 2
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
239000004202 carbamide Substances 0.000 claims description 2
239000004917 carbon fiber Substances 0.000 claims description 2
239000002482 conductive additive Substances 0.000 claims description 2
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical class [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 2
125000004494 ethyl ester group Chemical group 0.000 claims description 2
239000010433 feldspar Substances 0.000 claims description 2
239000011888 foil Substances 0.000 claims description 2
JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 2
VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 claims description 2
150000002357 guanidines Chemical class 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
239000000314 lubricant Substances 0.000 claims description 2
239000011777 magnesium Substances 0.000 claims description 2
229910052749 magnesium Inorganic materials 0.000 claims description 2
235000012254 magnesium hydroxide Nutrition 0.000 claims description 2
239000000395 magnesium oxide Substances 0.000 claims description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 claims description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 claims description 2
229910021645 metal ion Inorganic materials 0.000 claims description 2
229910001463 metal phosphate Inorganic materials 0.000 claims description 2
150000004702 methyl esters Chemical class 0.000 claims description 2
239000010445 mica Substances 0.000 claims description 2
229910052618 mica group Inorganic materials 0.000 claims description 2
150000004767 nitrides Chemical class 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
CSWFWSPPZMEYAY-UHFFFAOYSA-N octadecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(O)O CSWFWSPPZMEYAY-UHFFFAOYSA-N 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
VYAWNUGJSVJTSU-UHFFFAOYSA-N phenanthrene phosphane Chemical compound C1=CC=CC=2C3=CC=CC=C3C=CC12.P VYAWNUGJSVJTSU-UHFFFAOYSA-N 0.000 claims description 2
XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 2
239000011574 phosphorus Substances 0.000 claims description 2
229910052698 phosphorus Inorganic materials 0.000 claims description 2
239000000049 pigment Substances 0.000 claims description 2
239000001205 polyphosphate Substances 0.000 claims description 2
235000011176 polyphosphates Nutrition 0.000 claims description 2
150000003921 pyrrolotriazines Chemical class 0.000 claims description 2
239000010453 quartz Substances 0.000 claims description 2
150000003336 secondary aromatic amines Chemical class 0.000 claims description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
125000005402 stannate group Chemical group 0.000 claims description 2
229940051851 sulfurated lime Drugs 0.000 claims description 2
239000000454 talc Substances 0.000 claims description 2
235000012222 talc Nutrition 0.000 claims description 2
229910052623 talc Inorganic materials 0.000 claims description 2
NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 claims description 2
WNVQBUHCOYRLPA-UHFFFAOYSA-N triuret Chemical compound NC(=O)NC(=O)NC(N)=O WNVQBUHCOYRLPA-UHFFFAOYSA-N 0.000 claims description 2
BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
239000010456 wollastonite Substances 0.000 claims description 2
229910052882 wollastonite Inorganic materials 0.000 claims description 2
239000010457 zeolite Substances 0.000 claims description 2
AKJVMGQSGCSQBU-UHFFFAOYSA-N zinc azanidylidenezinc Chemical compound [Zn++].[N-]=[Zn].[N-]=[Zn] AKJVMGQSGCSQBU-UHFFFAOYSA-N 0.000 claims description 2
239000011667 zinc carbonate Substances 0.000 claims description 2
235000004416 zinc carbonate Nutrition 0.000 claims description 2
229910000010 zinc carbonate Inorganic materials 0.000 claims description 2
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 claims description 2
229910021511 zinc hydroxide Inorganic materials 0.000 claims description 2
229940007718 zinc hydroxide Drugs 0.000 claims description 2
239000011787 zinc oxide Substances 0.000 claims description 2
LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 2
229910000165 zinc phosphate Inorganic materials 0.000 claims description 2
PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical compound [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 claims description 2
DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims 2
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims 2
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UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
ULFVOGIINBRZRT-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-2-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O ULFVOGIINBRZRT-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
DPBLXKKOBLCELK-UHFFFAOYSA-N pentan-1-amine Chemical compound CCCCCN DPBLXKKOBLCELK-UHFFFAOYSA-N 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229920006115 poly(dodecamethylene terephthalamide) Polymers 0.000 description 1
229920006117 poly(hexamethylene terephthalamide)-co- polycaprolactam Polymers 0.000 description 1
229920006181 poly(hexamethylene terephthalamide)-co-poly(hexamethylene dodecanediamide) Polymers 0.000 description 1
229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
235000007715 potassium iodide Nutrition 0.000 description 1
229960004839 potassium iodide Drugs 0.000 description 1
230000008569 process Effects 0.000 description 1
230000011514 reflex Effects 0.000 description 1
230000003014 reinforcing effect Effects 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
229920006024 semi-aromatic copolyamide Polymers 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
238000004441 surface measurement Methods 0.000 description 1
238000009864 tensile test Methods 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000004416 thermosoftening plastic Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
229940005605 valeric acid Drugs 0.000 description 1
238000009423 ventilation Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/014—Stabilisers against oxidation, heat, light or ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)

CN201510051198.0A 2014-01-31 2015-01-30 具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料 Pending CN105017766A (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP14153391.9A EP2902444B1 (de)	2014-01-31	2014-01-31	Polyamid-Formmassen mit flammhemmenden Eigenschaften und sehr guter Langzeitwärmealterungsbeständigkeit
EP14153391.9		2014-01-31

Publications (1)

Publication Number	Publication Date
CN105017766A true CN105017766A (zh)	2015-11-04

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CN201510051198.0A Pending CN105017766A (zh)	2014-01-31	2015-01-30	具有阻燃特性和非常良好的耐长期热老化性的聚酰胺模塑材料

Country Status (7)

Country	Link
US (1)	US20150218374A1 (2)
EP (1)	EP2902444B1 (2)
JP (1)	JP2015145496A (2)
KR (1)	KR102460868B1 (2)
CN (1)	CN105017766A (2)
BR (1)	BR102015002100B1 (2)
TW (1)	TW201533156A (2)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
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CN107955368A (zh) *	2017-12-06	2018-04-24	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
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CN111670221A (zh) *	2017-12-20	2020-09-15	性能聚酰胺有限公司	高耐热性的聚酰胺模塑复合物
CN113544213A (zh) *	2019-03-06	2021-10-22	巴斯夫欧洲公司	用于高光泽应用的聚酰胺模塑组合物
CN113661214A (zh) *	2019-04-01	2021-11-16	奥升德功能材料运营有限公司	非卤化阻燃性聚酰胺组合物
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Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE102013217241A1 (de)	2013-08-29	2015-03-05	Ems-Patent Ag	Polyamid-Formmassen und hieraus hergestellte Formkörper
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1326481A (zh) *	1998-10-15	2001-12-12	L·布鲁克曼两合公司	用铜配合物和有机卤素化合物稳定的聚酰胺组合物
US20050113496A1 (en) *	2003-10-03	2005-05-26	Yuji Saga	Flame resistant polyamide resin composition containing phenolic resin and articles made therefrom
CN101802098A (zh) *	2007-05-17	2010-08-11	三菱工程塑料株式会社	阻燃性聚酰胺树脂组合物
CN102378784A (zh) *	2009-03-30	2012-03-14	纳幕尔杜邦公司	阻燃性半芳香聚酰胺树脂组合物以及由其制得的制品
CN102471530A (zh) *	2009-07-30	2012-05-23	纳幕尔杜邦公司	具有高胺末端的耐热聚酰胺组合物
CN102618023A (zh) *	2003-10-06	2012-08-01	Ems-化学公开股份有限公司	阻燃聚酰胺模塑材料及其用途
CN102827471A (zh) *	2011-06-17	2012-12-19	Ems专利股份公司	半芳香族模塑料及其应用

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1495393B2 (de)	1964-11-12	1979-10-18	Dynamit Nobel Ag, 5210 Troisdorf	Verfahren zur Herstellung von Polyamiden aus Methylestern der Tere- und/oder Isophthalsäure und alipatischen primären Diaminen
DE3321581A1 (de)	1983-06-15	1984-12-20	Basf Ag, 6700 Ludwigshafen	Verfahren zur kontinuierlichen herstellung von polyamiden
DE3321579A1 (de)	1983-06-15	1984-12-20	Basf Ag, 6700 Ludwigshafen	Verfahren zur kontinuierlichen herstellung von polyamiden
JPS60158220A (ja)	1984-01-27	1985-08-19	Mitsui Petrochem Ind Ltd	摺動材用成形材料
DE3707689A1 (de)	1987-03-11	1988-09-22	Basf Ag	Formaldehydarme bindemittel
DE3889787D1 (de)	1987-07-17	1994-07-07	Basf Ag	Teilaromatische Copolyamide mit verringertem Triamingehalt.
DE19513940A1 (de)	1994-07-14	1996-01-18	Inventa Ag	Verfahren zur Herstellung von Vorkondensaten teilkristalliner oder amorpher, thermoplastisch verarbeitbarer teilaromatischer Polyamide bzw. Copolyamide
JPH10130497A (ja) *	1996-11-01	1998-05-19	Mitsubishi Gas Chem Co Inc	ポリアミド樹脂組成物
JP4179703B2 (ja)	1998-07-30	2008-11-12	株式会社クラレ	ポリアミドの製造方法
JP2000204239A (ja) *	1999-01-08	2000-07-25	Kuraray Co Ltd	ポリアミド組成物
JP2001106907A (ja) *	1999-08-04	2001-04-17	Mitsubishi Engineering Plastics Corp	耐候性の改良されたポリアミド樹脂組成物及びそれを用いた成形品
EP1681313A1 (en)	2005-01-17	2006-07-19	DSM IP Assets B.V.	Heat stabilized moulding composition
JP2007077309A (ja) *	2005-09-15	2007-03-29	Toray Ind Inc	ポリアミド樹脂組成物
EP2718371B1 (en)	2011-06-09	2019-08-14	Solvay Specialty Polymers USA, LLC.	Polyamides compositions featuring improved thermal stability
US20130281589A1 (en) *	2012-04-23	2013-10-24	E I Du Pont De Nemours And Company	Thermoplastic polyamide composition
WO2013188323A1 (en) *	2012-06-13	2013-12-19	E. I. Du Pont De Nemours And Company	Thermoplastic melt-mixed composition with polyetherol heat stabilizer
WO2013188302A1 (en) *	2012-06-13	2013-12-19	E. I. Du Pont De Nemours And Company	Thermoplastic melt-mixed composition with amino acid heat stabilizer
EP2861668A1 (en) *	2012-06-13	2015-04-22	E. I. Du Pont de Nemours and Company	Thermoplastic melt-mixed composition with epoxy-carboxylic acid compound heat stabilizer

2014
- 2014-01-31 EP EP14153391.9A patent/EP2902444B1/de active Active
2015
- 2015-01-28 US US14/607,676 patent/US20150218374A1/en not_active Abandoned
- 2015-01-28 TW TW104102896A patent/TW201533156A/zh unknown
- 2015-01-29 JP JP2015014995A patent/JP2015145496A/ja active Pending
- 2015-01-29 BR BR102015002100-3A patent/BR102015002100B1/pt active IP Right Grant
- 2015-01-30 KR KR1020150015543A patent/KR102460868B1/ko active Active
- 2015-01-30 CN CN201510051198.0A patent/CN105017766A/zh active Pending

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN1326481A (zh) *	1998-10-15	2001-12-12	L·布鲁克曼两合公司	用铜配合物和有机卤素化合物稳定的聚酰胺组合物
US20050113496A1 (en) *	2003-10-03	2005-05-26	Yuji Saga	Flame resistant polyamide resin composition containing phenolic resin and articles made therefrom
CN102618023A (zh) *	2003-10-06	2012-08-01	Ems-化学公开股份有限公司	阻燃聚酰胺模塑材料及其用途
CN101802098A (zh) *	2007-05-17	2010-08-11	三菱工程塑料株式会社	阻燃性聚酰胺树脂组合物
CN102378784A (zh) *	2009-03-30	2012-03-14	纳幕尔杜邦公司	阻燃性半芳香聚酰胺树脂组合物以及由其制得的制品
CN102471530A (zh) *	2009-07-30	2012-05-23	纳幕尔杜邦公司	具有高胺末端的耐热聚酰胺组合物
CN102827471A (zh) *	2011-06-17	2012-12-19	Ems专利股份公司	半芳香族模塑料及其应用

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN107236281A (zh) *	2017-06-19	2017-10-10	成都新柯力化工科技有限公司	一种发泡聚氨酯专用复合阻燃剂及制备方法
CN111433026A (zh) *	2017-12-05	2020-07-17	利安德巴塞尔先进聚合物公司	高性能聚酰胺化合物及其用途
CN107955368A (zh) *	2017-12-06	2018-04-24	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
CN107955368B (zh) *	2017-12-06	2020-07-07	厦门源亚泰塑胶科技有限公司	一种改进耐热性的导热尼龙及其制备方法
CN111670221B (zh) *	2017-12-20	2023-08-11	巴斯夫欧洲公司	高耐热性的聚酰胺模塑复合物
CN111670221A (zh) *	2017-12-20	2020-09-15	性能聚酰胺有限公司	高耐热性的聚酰胺模塑复合物
US12312467B2 (en)	2019-03-06	2025-05-27	Basf Se	Polyamide molding composition for high-gloss applications
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BR102015002100A2 (pt)	2015-12-08
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Publication	Publication Date	Title
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