CN105038344A - Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator - Google Patents
Modified acrylic resin energy conservation and environment protection coating for back plate of refrigerator Download PDFInfo
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- CN105038344A CN105038344A CN201510552500.0A CN201510552500A CN105038344A CN 105038344 A CN105038344 A CN 105038344A CN 201510552500 A CN201510552500 A CN 201510552500A CN 105038344 A CN105038344 A CN 105038344A
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- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 58
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 58
- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000004134 energy conservation Methods 0.000 title abstract 2
- 239000004593 Epoxy Substances 0.000 claims description 25
- 239000003973 paint Substances 0.000 claims description 25
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- 239000003822 epoxy resin Substances 0.000 claims description 15
- 229920000647 polyepoxide Polymers 0.000 claims description 15
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 10
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 10
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 10
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 10
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 9
- JYTNGEWJAZCVAN-UHFFFAOYSA-N 2-hexadecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O JYTNGEWJAZCVAN-UHFFFAOYSA-N 0.000 claims description 7
- 239000005995 Aluminium silicate Substances 0.000 claims description 7
- 239000004952 Polyamide Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims description 7
- 229920003180 amino resin Polymers 0.000 claims description 7
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 7
- KWABLUYIOFEZOY-UHFFFAOYSA-N dioctyl butanedioate Chemical compound CCCCCCCCOC(=O)CCC(=O)OCCCCCCCC KWABLUYIOFEZOY-UHFFFAOYSA-N 0.000 claims description 7
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 7
- 229920002647 polyamide Polymers 0.000 claims description 7
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 9
- 238000010422 painting Methods 0.000 abstract description 7
- 238000012545 processing Methods 0.000 abstract description 7
- 230000032683 aging Effects 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000007761 roller coating Methods 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 description 10
- 239000012855 volatile organic compound Substances 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
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- 239000002932 luster Substances 0.000 description 2
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- 239000000843 powder Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- 206010067125 Liver injury Diseases 0.000 description 1
- 208000005374 Poisoning Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 206010041349 Somnolence Diseases 0.000 description 1
- -1 T-butyl Chemical group 0.000 description 1
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- 206010047700 Vomiting Diseases 0.000 description 1
- 231100000570 acute poisoning Toxicity 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 231100000739 chronic poisoning Toxicity 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
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- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002124 endocrine Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- IXSZQYVWNJNRAL-UHFFFAOYSA-N etoxazole Chemical compound CCOC1=CC(C(C)(C)C)=CC=C1C1N=C(C=2C(=CC=CC=2F)F)OC1 IXSZQYVWNJNRAL-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
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- 239000002184 metal Substances 0.000 description 1
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- 231100000572 poisoning Toxicity 0.000 description 1
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- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
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Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a modified acrylic resin energy conservation and environment protection coating for a back plate of a refrigerator. The coating adopts bisphenol A epoxy resin modified acrylic resin, and therefore the coating has the advantages that the excellent flame retardance and wear resistance property are achieved, the curing speed is high, the better mechanical property, aging resistance property and chemical corrosion resistance property are achieved, the adhesive force is high, the ductility is good, the high temperature resistance property is achieved, the service life is long, the processing technology is changed, roller coating processing is concentratedly completed on a plate blank of the black plate of the refrigerator, the processing procedure is simplified, and a painting workshop does not need to be separately arranged.
Description
Technical field
The present invention relates to the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard.
Background technology
Acrylic resin is the resin be made up of acrylate and methacrylic ester and other olefinic type monomers copolymerization, compared with other synthetic macromolecule resins, acrylic resin has many outstanding advantages, as fast light, the weathering resistance of excellence, open air weather resistance of being exposed to the sun is strong, ultraviolet resistance irradiates and not easily decomposes and turn yellow, original gloss and color and luster can be kept for a long time, good heat resistance, the chemical such as good acid-and base-resisting, salt, grease and washing composition are had to stain and corrosive nature, fabulous snappiness and minimum pigment reactivity.Therefore, have a wide range of applications automobile, household electrical appliances, art metal furniture, coiled material industry, instrument, building, textiles, woodwork, papermaking and plastics etc. are industrial.
But the heat that the linear structure of acrylic resin causes sticks cold short, anti-after-tackiness and thermotolerance is not good etc. that shortcoming has a definite limitation to its range of application.The equal phase structure of acrylic resin makes its cold tolerance and resistance toheat be difficult to take into account, and as increased resistance to low temperature, then can lose resistance to elevated temperatures, vice versa, and thus common acrylic acid or the like coating and decorating material just inevitably exists above-mentioned shortcoming.
By with other monomers, resin copolymerization and modification, the various aspects of performance of coating can be changed, make the coating of multiple different performance and Application Areas.Epoxy modified acrylic resin introduces propenyl unsaturated double-bond at the two ends of epoxy molecule chain, then with other monomer copolymerizations, like this, just make the various premium properties (fullness ratio of epoxy resin, gloss, hardness, sticking power etc.) be not fully exerted in acrylic resin, over-all properties respectively gets the chief, its dryness, fullness ratio, gloss, the over-all propertieies such as hardness are better than general acrylic resin, be applicable to the extra high occasion of cosmetic requirement, as frosting application, to meet the use of plastics, the course of processing is as surface treatment, plating, gold stamping, the needs of plated film etc.
At present, the following epoxy modified acrylic resin coating of domestic existence:
Chinese patent CN201210564995.5, disclosing a kind of take acrylic resin as the coating of raw material, is grouped into: epoxy resin 30 ~ 60 by the one-tenth of following weight part; Thermoplastic acrylic resin 20 ~ 30; Fire retardant 10 ~ 15; Zinc oxide 10 ~ 20; Pigment 10 ~ 15; Methyl alcohol 1 ~ 3; Deionized water 10 ~ 15.But, although this patent lists epoxy resin and thermoplastic acrylic resin, do not form the combination of epoxy modified acrylic resin, coating cannot be made to possess the premium properties of epoxy modified acrylic resin.
In addition, the application mode of existing acrylic resin paint adopts spray-coating mostly, such as Chinese patent CN201310607469.7, disclose a kind of thermosetting acrylic resin used for powder coating, this resin ester is equipped with the thermosetting powder coating(s) that unclassified stores is made, the film formed after spraying, has excellent weathering resistance, good flow leveling, excellent surface hardness and high-luster, weather resistance and decorate properties; Can be used for indoor or outdoors shape or material of construction.TGIC can be substituted to a certain extent, avoid the use of toxic substance.
But spraying is by spray gun or dish-style spraying gun, by means of pressure or centrifugal force, is dispersed into even and fine droplet, is applied over the coating process on coated article surface.Subject matter in spraying is the coating cloud of high dispersing and the solvent (i.e. volatile organic contaminant, VOCs) evaporated, and both contaminate environment, are unfavorable for HUMAN HEALTH, waste coating again, cause financial loss.Volatilization, the coating be diffused in air, then form volatile organic contaminant, be detrimental to health.At painting workshop, coating, as the main source of volatile organic contaminant, is easy to cause acute poisoning during volatile organic compounds excessive concentration in air in painting workshop, and the lighter there will be headache, dizziness, cough, Nausea and vomiting or is dead drunk liquor-saturated shape; Severe one there will be liver poisoning and even goes into a coma very soon, and what have also may be in peril of one's life.Treat for a long time, in the painting workshop of volatile organic compounds pollution, can chronic poisoning be caused, damage liver and neural system, cause general weakness, drowsiness, skin pruritus etc.What have also may cause endocrine disturbance, affects sexual function; Benzene and dimethylbenzene can also damage system, so that cause leukemia.
Summary of the invention
The object of the present invention is to provide the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard, described coating adopts bisphenol A epoxide resin acrylic resin modified, described coating is made to have excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by refrigerator backboard slab, simplify machining clearance, without the need to arranging painting workshop separately.
For achieving the above object, the technical solution used in the present invention is:
The acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 80 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, methylene-bis hexamethylene alkanamine: 10 ~ 15 parts, diaminodiphenyl-methane: 3 ~ 8 parts, cetyl benzenesulfonic acid sodium: 5 ~ 10 parts, dioctyl succinate disulfonate acid: 1 ~ 5 part, kaolin: 15 ~ 20 parts, PSI: 2 ~ 6 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, vinylbenzene: 30 ~ 40 parts, water: 90 ~ 100 parts.
Further, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 75 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 7 parts, methylene-bis hexamethylene alkanamine: 10 ~ 13 parts, diaminodiphenyl-methane: 3 ~ 5 parts, cetyl benzenesulfonic acid sodium: 5 ~ 7 parts, dioctyl succinate disulfonate acid: 1 ~ 4 part, kaolin: 15 ~ 18 parts, PSI: 2 ~ 4 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 6 parts, diatomite: 4 ~ 6 parts, polyamide wax pulp: 5 ~ 7 parts, vinylbenzene: 30 ~ 35 parts, water: 90 ~ 94 parts.
Preferably, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 parts, Natvosol: 4 parts, aminoresin: 6 parts, methylene-bis hexamethylene alkanamine: 12 parts, diaminodiphenyl-methane: 4 parts, cetyl benzenesulfonic acid sodium: 5 parts, dioctyl succinate disulfonate acid: 3 parts, kaolin: 15 parts, PSI: 3 parts, silicone emulsion: 4 parts, aluminum phosphate: 5 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, vinylbenzene: 30 parts, water: 92 parts.
Separately, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 30 parts, vinylformic acid, methyl methacrylate 20 ~ 25 parts, Methacrylamide 10 ~ 15 parts, ethyl acrylate 10 ~ 15 parts, Dodecyl Mercaptan 1 ~ 5 part, pimelinketone 2 ~ 7 parts, bisphenol A epoxide resin 20 ~ 30 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 10 parts, 90 ~ 100 parts, water.
Separately have, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 25 parts, vinylformic acid, methyl methacrylate 20 ~ 23 parts, Methacrylamide 10 ~ 13 parts, ethyl acrylate 10 ~ 12 parts, Dodecyl Mercaptan 1 ~ 3 part, pimelinketone 2 ~ 5 parts, bisphenol A epoxide resin 20 ~ 25 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 8 parts, 90 ~ 95 parts, water.
Preferably, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 parts, vinylformic acid, methyl methacrylate 22 parts, Methacrylamide 12 parts, ethyl acrylate 10 parts, Dodecyl Mercaptan 3 parts, pimelinketone 4 parts, bisphenol A epoxide resin 25 parts, Viscoat 295 3 parts, t-butyl per(oxy)benzoate 6 parts, 90 parts, water.
And, the preparation of described epoxy modified acrylic resin, comprise the steps: reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
Again, described coating is coated to refrigerator backboard steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
Beneficial effect of the present invention is:
Described coating adopts bisphenol A epoxide resin acrylic resin modified, there is excellent fire-retardant and wear resisting property, and curing speed is fast, also there is good mechanical property, ageing-resistant performance and resistance to chemical corrosion, strong adhesion, ductility are good, high temperature resistant, long service life, change complete processing, roller coat process concentrated by refrigerator backboard slab, simplify machining clearance, without the need to arranging painting workshop separately.
In the refrigerator backboard slab stage namely by roller coat by paint spraying provided by the present invention in refrigerator backboard steel slab surface, form coating, directly can carry out following process, obtain shaping refrigerator backboard, even if baroque refrigerator rear panel structure, also paint spraying is completed in the slab stage, without the need to follow-up application, to instead of in existing technique " be first processed into desired shape; and then spraying obtains moulding product " technique, coating and refrigerator backboard slab strong adhesion, can not crack because of complete processing or come off.Owing to being the roller coating technology replacement spraying coating process of the shaping quick-drying of roller coat, during application, the availability of coating can reach more than 90%, decrease the volatilization in air and waste, the VOCs that effective reduction causes coating volatilization to be formed because of spraying, VOCs quantity discharged≤420ppm in roller coat workshop, coating environment protecting is good.The refrigerator backboard goods that roller coat application completes are processed, the curved performance of refrigerator backboard T can reach 0T (after the finished product slab after roller coat 180 ° bending, completely seamlessly to close up, coating does not burst and comes off) or 1T (after slab twice 180 ° of bendings, outermost painting charge level does not come off, do not burst), ensure refrigerator backboard quality.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment does not limit the scope of the invention.
Table 1 is refrigerator backboard a kind of described in the embodiment of the present invention acrylic resin modified energy-saving and environment-friendly paint composition quality mark list.Table 2 is epoxy modified acrylic resin composition quality mark list described in the embodiment of the present invention.Table 3 is refrigerator backboard acrylic resin modified energy-saving and environment-friendly paint performance perameter list a kind of described in the embodiment of the present invention.Table 4 is refrigerator backboard a kind of described in the embodiment of the present invention coating performance parameter list of acrylic resin modified energy-saving and environment-friendly paint roller coat after refrigerator backboard steel slab surface.
Described refrigerator backboard is as follows by acrylic resin modified energy-saving and environment-friendly paint compound method:
Each component is added in high speed dispersor, after stirring, high speed dispersion 30 ~ 60min, stirring, discharging, filtration, packaging, warehouse-in.
The preparation of described epoxy modified acrylic resin, comprise the steps: reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
Table 1 (unit: part)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Epoxy modified acrylic resin | 70 | 68 | 80 | 75 | 73 |
| Natvosol | 4 | 3 | 5 | 4 | 5 |
| Aminoresin | 6 | 5 | 10 | 7 | 6 |
| Methylene-bis hexamethylene alkanamine | 12 | 10 | 13 | 15 | 14 |
| Diaminodiphenyl-methane | 4 | 7 | 8 | 3 | 5 |
| Cetyl benzenesulfonic acid sodium | 5 | 8 | 9 | 10 | 6 |
| Dioctyl succinate disulfonate acid | 3 | 1 | 2 | 5 | 4 |
| Kaolin | 15 | 18 | 16 | 20 | 17 |
| PSI | 3 | 5 | 4 | 6 | 2 |
| Silicone emulsion | 4 | 2 | 5 | 2 | 3 |
| Aluminum phosphate | 5 | 6 | 8 | 5 | 7 |
| Diatomite | 4 | 8 | 7 | 5 | 6 |
| Polyamide wax pulp | 6 | 8 | 5 | 10 | 7 |
| Vinylbenzene | 30 | 35 | 40 | 32 | 38 |
| Water | 92 | 90 | 95 | 100 | 98 |
Table 2 (unit: part)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Vinylformic acid | 20 | 25 | 28 | 30 | 22 |
| Methyl methacrylate | 22 | 21 | 20 | 25 | 24 |
| Methacrylamide | 12 | 13 | 10 | 15 | 14 |
| Ethyl acrylate | 10 | 12 | 13 | 15 | 14 |
| Dodecyl Mercaptan | 3 | 2 | 5 | 4 | 1 |
| Pimelinketone | 4 | 6 | 5 | 7 | 2 |
| Bisphenol A epoxide resin | 25 | 22 | 20 | 28 | 30 |
| Viscoat 295 | 3 | 5 | 4 | 2 | 3 |
| T-butyl per(oxy)benzoate | 6 | 5 | 8 | 10 | 9 |
| Water | 90 | 98 | 95 | 100 | 92 |
Table 3
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Tensile strength (MPa) | 45 | 40 | 38 | 35 | 42 |
| Elongation at break (%) | 9.5 | 8.8 | 8.5 | 8.7 | 9.1 |
| Shore hardness | 70 | 60 | 63 | 65 | 66 |
The acrylic resin modified energy-saving and environment-friendly paint of refrigerator backboard a kind of described in the embodiment of the present invention is coated in refrigerator backboard steel slab surface by roll coating model, at 200 DEG C after solidification, be cooled to room temperature, place 48 hours, measure slab top coat performance as shown in table 4.Wherein, the method of the mensuration paint film impact resistance that impact resistance testing method specifies with reference to standard GB/T/T1732-93, falls within the weight of fixed mass (1kg) maximum height (cm) that test plate (panel) does not cause paint film to destroy and represents paint film impact resistance.
Table 4
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Impact resistance (cm) | 120 | 115 | 113 | 110 | 112 |
| Salt spray resistance duration (h) | 3150 | 3100 | 3120 | 3130 | 3140 |
| Artificial accelerated aging duration (h) | 3200 | 3180 | 3100 | 3170 | 3160 |
| Resistance toheat | 780 | 775 | 760 | 750 | 740 |
Adopt a kind of refrigerator backboard provided by the present invention packing of product can obtained after acrylic resin modified energy-saving and environment-friendly paint application refrigerator backboard slab, the curved performance of T can reach 0T or 1T.Utilization efficiency of coatings is high, and every 30 kilograms of coating can application 1 ton of slab.Do not ftracture under 230 DEG C of high temperature, nondiscoloration, resistance of aging is strong, is placed on the not yellowing in 10 ~ 15 years of outdoor consecutive sunlight, nondiscoloration.Acidproof corrosion resistance is strong, the product that roller coat is good is put into 85 DEG C of water and boils that 2H is raw is heated to 100 DEG C more gradually, product without variable color, fall paint, bubble.After using the Nad solution soaking 24H of 5% at normal temperatures, product surface non-corroding, variable color and coating come off.Pure cotton cloth is dipped in full 95% alcohol to be wrapped on 500g counterweight, wipes examination 50 circulation with the stroke of speed (20mm) left and right of per minute 40-60 time at product surface, and nothing fades de-oiling.Detect according to the X method of drawing in U.S. ASTM the shaping refrigerator backboard goods being coated with coating provided by the present invention, can reach the 0=ASTM grade of ISO grade, notching edge is completely smooth, and what edge had not a particle of peels off.
It should be noted that, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted.Although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to the technical scheme of invention or equivalent replacement, and not depart from the scope of technical solution of the present invention, it all should be encompassed in right of the present invention.
Claims (8)
1. the acrylic resin modified energy-saving and environment-friendly paint of refrigerator backboard, is characterized in that, in described coating, each composition quality mark is as follows:
Epoxy modified acrylic resin: 70 ~ 80 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 10 parts, methylene-bis hexamethylene alkanamine: 10 ~ 15 parts, diaminodiphenyl-methane: 3 ~ 8 parts, cetyl benzenesulfonic acid sodium: 5 ~ 10 parts, dioctyl succinate disulfonate acid: 1 ~ 5 part, kaolin: 15 ~ 20 parts, PSI: 2 ~ 6 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 8 parts, diatomite: 4 ~ 8 parts, polyamide wax pulp: 5 ~ 10 parts, vinylbenzene: 30 ~ 40 parts, water: 90 ~ 100 parts.
2. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 ~ 75 parts, Natvosol: 3 ~ 5 parts, aminoresin: 5 ~ 7 parts, methylene-bis hexamethylene alkanamine: 10 ~ 13 parts, diaminodiphenyl-methane: 3 ~ 5 parts, cetyl benzenesulfonic acid sodium: 5 ~ 7 parts, dioctyl succinate disulfonate acid: 1 ~ 4 part, kaolin: 15 ~ 18 parts, PSI: 2 ~ 4 parts, silicone emulsion: 2 ~ 5 parts, aluminum phosphate: 5 ~ 6 parts, diatomite: 4 ~ 6 parts, polyamide wax pulp: 5 ~ 7 parts, vinylbenzene: 30 ~ 35 parts, water: 90 ~ 94 parts.
3. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described coating, each composition quality mark is as follows: epoxy modified acrylic resin: 70 parts, Natvosol: 4 parts, aminoresin: 6 parts, methylene-bis hexamethylene alkanamine: 12 parts, diaminodiphenyl-methane: 4 parts, cetyl benzenesulfonic acid sodium: 5 parts, dioctyl succinate disulfonate acid: 3 parts, kaolin: 15 parts, PSI: 3 parts, silicone emulsion: 4 parts, aluminum phosphate: 5 parts, diatomite: 4 parts, polyamide wax pulp: 6 parts, vinylbenzene: 30 parts, water: 92 parts.
4. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 1, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 30 parts, vinylformic acid, methyl methacrylate 20 ~ 25 parts, Methacrylamide 10 ~ 15 parts, ethyl acrylate 10 ~ 15 parts, Dodecyl Mercaptan 1 ~ 5 part, pimelinketone 2 ~ 7 parts, bisphenol A epoxide resin 20 ~ 30 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 10 parts, 90 ~ 100 parts, water.
5. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 ~ 25 parts, vinylformic acid, methyl methacrylate 20 ~ 23 parts, Methacrylamide 10 ~ 13 parts, ethyl acrylate 10 ~ 12 parts, Dodecyl Mercaptan 1 ~ 3 part, pimelinketone 2 ~ 5 parts, bisphenol A epoxide resin 20 ~ 25 parts, Viscoat 295 2 ~ 5 parts, t-butyl per(oxy)benzoate 5 ~ 8 parts, 90 ~ 95 parts, water.
6. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, in described epoxy modified acrylic resin, each composition quality mark is as follows: 20 parts, vinylformic acid, methyl methacrylate 22 parts, Methacrylamide 12 parts, ethyl acrylate 10 parts, Dodecyl Mercaptan 3 parts, pimelinketone 4 parts, bisphenol A epoxide resin 25 parts, Viscoat 295 3 parts, t-butyl per(oxy)benzoate 6 parts, 90 parts, water.
7. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to claim 4, it is characterized in that, the preparation of described epoxy modified acrylic resin, comprises the steps:
Reflux exchanger is being housed, agitator, in the four-hole boiling flask of thermometer, add described bisphenol A epoxide resin, strong solvent and water, stir and be heated to 70 ~ 80 DEG C, drip vinylformic acid, dropwise in 1 ~ 2h, reaction 1.5 ~ 2h, then by methyl methacrylate, Methacrylamide, ethyl acrylate, Dodecyl Mercaptan and t-butyl per(oxy)benzoate mix in agitator, mixed solution is obtained after dissolving, described mixed solution is dropped in four-hole boiling flask, reaction 2 ~ 4h, be cooled to less than 50 DEG C, react complete, obtain described epoxy modified acrylic resin.
8. the acrylic resin modified energy-saving and environment-friendly paint of a kind of refrigerator backboard according to any one of claim 1 ~ 7, it is characterized in that, described coating is coated to refrigerator backboard steel slab surface by roll coating model, roller coat temperature 230 ~ 240 DEG C, and roller coat number of times is 1 ~ 2 time.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106118302A (en) * | 2016-07-19 | 2016-11-16 | 宜兴市巨人涂料有限公司 | A kind of preparation method for outdoor type water-based anticorrosive paint |
| CN107118311A (en) * | 2017-06-08 | 2017-09-01 | 华伦纳路新材料有限公司 | A kind of epoxy modified acrylic resin and preparation method thereof |
| CN107312368A (en) * | 2016-04-26 | 2017-11-03 | 芜湖艾蔓设备工程有限公司 | A kind of automobile engine oil pan energy-saving and environment-friendly paint |
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| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN103725146A (en) * | 2014-01-20 | 2014-04-16 | 天津市新丽华色材有限责任公司 | Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN103725146A (en) * | 2014-01-20 | 2014-04-16 | 天津市新丽华色材有限责任公司 | Protective coating of mirror back of water-based aluminum mirror capable of being dried at extremely high speed |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107312368A (en) * | 2016-04-26 | 2017-11-03 | 芜湖艾蔓设备工程有限公司 | A kind of automobile engine oil pan energy-saving and environment-friendly paint |
| CN106118302A (en) * | 2016-07-19 | 2016-11-16 | 宜兴市巨人涂料有限公司 | A kind of preparation method for outdoor type water-based anticorrosive paint |
| CN107118311A (en) * | 2017-06-08 | 2017-09-01 | 华伦纳路新材料有限公司 | A kind of epoxy modified acrylic resin and preparation method thereof |
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