CN103146278A - Preparation method of low-temperature curing water-based acrylic amino baking coating - Google Patents
Preparation method of low-temperature curing water-based acrylic amino baking coating Download PDFInfo
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- CN103146278A CN103146278A CN2013100968465A CN201310096846A CN103146278A CN 103146278 A CN103146278 A CN 103146278A CN 2013100968465 A CN2013100968465 A CN 2013100968465A CN 201310096846 A CN201310096846 A CN 201310096846A CN 103146278 A CN103146278 A CN 103146278A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 238000013035 low temperature curing Methods 0.000 title claims abstract description 6
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000011248 coating agent Substances 0.000 title abstract description 16
- 238000000576 coating method Methods 0.000 title abstract description 16
- 229920003180 amino resin Polymers 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 20
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000013530 defoamer Substances 0.000 claims abstract description 12
- 239000002002 slurry Substances 0.000 claims abstract description 11
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 238000009736 wetting Methods 0.000 claims abstract description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000003973 paint Substances 0.000 claims description 14
- 239000004593 Epoxy Substances 0.000 claims description 11
- JYGXADMDTFJGBT-VWUMJDOOSA-N hydrocortisone Chemical compound O=C1CC[C@]2(C)[C@H]3[C@@H](O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 JYGXADMDTFJGBT-VWUMJDOOSA-N 0.000 claims description 10
- -1 sulfonic acid phosphamidon compound Chemical class 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000012856 packing Methods 0.000 claims description 8
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 8
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 8
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 229960000890 hydrocortisone Drugs 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical class OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 239000004816 latex Substances 0.000 claims description 4
- 229920000126 latex Polymers 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 239000013556 antirust agent Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000010790 dilution Methods 0.000 abstract description 2
- 239000012895 dilution Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 210000003205 muscle Anatomy 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- YTLYLLTVENPWFT-UPHRSURJSA-N (Z)-3-aminoacrylic acid Chemical compound N\C=C/C(O)=O YTLYLLTVENPWFT-UPHRSURJSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
一种低温固化水性丙烯酸氨基烘烤涂料的制备方法，属于水性氨基烘烤涂料的生产技术领域。将水、润湿分散剂、消泡剂、防沉剂、颜填料、防腐填料和水性环氧改性丙烯酸树脂混合后分散均匀，形成浆料，然后在搅拌状态下，将水性氨基树脂、防闪锈剂、催干剂和流平剂加入到研磨好的浆料中，再经高速分散机分散均匀。本发明方便生产，产品为单组份，稀释剂为水，成本低、环保，稀释后直接喷涂施工，施工方便，固化温度低，干燥速度快，提高了水性氨基烘烤涂料的施工效率，节约了资源，降低了成本。干燥后的涂膜平整、丰满、光亮，具有优良的保光性和保色性，机械性能、耐水、耐腐蚀性优异，涂膜耐油污、耐高温。The invention discloses a method for preparing a low-temperature curing water-based acrylic amino baking coating, which belongs to the production technical field of the water-based amino baking coating. Mix water, wetting and dispersing agent, defoamer, anti-settling agent, pigment and filler, anti-corrosion filler and water-based epoxy-modified acrylic resin and disperse evenly to form a slurry, and then mix water-based amino resin, anti-corrosion Add the flash rust agent, drier and leveling agent into the ground slurry, and then disperse evenly through the high-speed disperser. The invention is convenient for production, the product is a single component, the diluent is water, the cost is low, and it is environmentally friendly. It can be sprayed directly after dilution, and the construction is convenient. resources and reduce costs. After drying, the coating film is flat, plump and bright, with excellent gloss and color retention, excellent mechanical properties, water resistance and corrosion resistance, and the coating film is resistant to oil stains and high temperature.
Description
Technical field
The invention belongs to the production technical field of the amino baked paint of water-based.
Background technology
Aminoacrylic acid is that baked paint has excellent guarantor's light, unfading, especially suitablely makes the investment precoat of high-decoration, high-weatherability and favored by the people.But the amino baked paint of water soluble acrylic acid in the market, general storing time are long, storing temperature is higher, causes energy consumption high, and practical application efficient is lower, affects it and applies.For this reason, the research of carrying out water-based low-temperature bake acrylic coating has broad application prospects.
Summary of the invention
The present invention seeks to propose a kind of easy to use, solidification value is low, the preparation method of the amino baked paint of low-temperature curing water soluble acrylic acid that time of drying is short.
The present invention includes following steps:
1) with being uniformly dispersed after water, wetting dispersing agent, defoamer, anti-settling agent, color stuffing, anticorrosive packing and waterborne epoxy modified acrylic resin mixing, form slurry;
2) slurry is ground to fineness≤25 μ m with sand mill;
3) under whipped state, water-compatible amino resin, anti-rust agent, siccative and the flow agent of dodging are joined in ground slurry, then be uniformly dispersed through the 1000r/min high speed dispersor.Described water-compatible amino resin is aqueous dispersion type and water-latex type water-borne acrylic resin.
The present invention is convenient to produce, and its superior effect is:
1, the present invention is single-component, and thinner is water, and cost is low, environmental protection, direct spraying construction after dilution, easy construction.
2, the amino baked paint solidification value of the prepared water soluble acrylic acid of the present invention is low, and rate of drying is fast, has improved the operating efficiency of the amino baked paint of water-based, has saved resource, has reduced cost.
3, the dried smooth coating of the present invention, plentiful, bright, have good gloss retention and tint retention, mechanical property, water-fast, excellent corrosion resistance, and the oil resistant dirt, high temperature resistant of filming can be used for the supercoat of locomotive engine.
4, the prepared product excellent storage stability of the present invention, and cost performance is high, can be widely used in the industrial circles such as automobile, household electrical appliances, five metals, also can be commonly used for the metallic surface anticorrosion with decorate, can do finish paint, base coat use, when application is unified in the bottom surface, have equally excellent decorative effect and protective effect.
In addition, aqueous dispersion type water-borne acrylic resin of the present invention can adopt waterborne epoxy modified acrylic resin 1628A; The water-latex type water-borne acrylic resin can adopt waterborne epoxy modified acrylic resin WR-553.
Described water-compatible amino resin is low methyl-etherified aminoresin 717, low methyl-etherified aminoresin 072, low methyl-etherified aminoresin MA-80 or low methyl-etherified aminoresin 5717W.
Described color stuffing comprises titanium dioxide, talcum powder and pigment, and described titanium dioxide is anatase thpe white powder or Rutile type Titanium Dioxide.
Described anticorrosive packing is zinc phosphate, composite zinc phosphate or aluminium triphosphate.
Described wetting dispersing agent is the compound WD-1010 of modification dihydroxy carboxylic acids salt; Described anti-settling agent is hydrophilic polyamide compound AS-280; Described defoamer is water-miscible paint defoamer AX-250; Described siccative is the sulfonic acid phosphamidon compound 2050W of sealing; Described flow agent is modification polyether diols compound F 17-hydroxy-corticosterone L-330.
Quality in order to ensure the product of producing, when mixing, water, wetting dispersing agent, defoamer, anti-settling agent, color stuffing, anticorrosive packing, waterborne epoxy modified acrylic resin, water-compatible amino resin, the anti-mass ratio that feeds intake that dodges rust agent, siccative and flow agent are 14～18 ︰ 0.4～1.2 ︰ 0.1～0.4 ︰ 1～3 ︰ 14～28 ︰ 8～15 ︰ 25～40 ︰ 7～15 ︰ 0.1～0.4 ︰ 0.5～2 ︰ 0.2～0.6.
Embodiment
One, batching:
The formula of embodiment 1:
| Raw material | Quality (unit: g) |
| Water | 16.2 |
| Water-borne acrylic resin 1628A | 35.7 |
| Anatase thpe white powder | 8 |
| Phthalocyanine blue | 0.1 |
| Yellow in coating | 2 |
| Zinc phosphate | 10 |
| Talcum powder | 10 |
| The compound WD-1010 of modification dihydroxy carboxylic acids salt | 0.6 |
| Hydrophilic polyamide compound AS-280 | 1.5 |
| Water-miscible paint defoamer AX-250 | 0.3 |
| The agent of anti-sudden strain of a muscle rust | 0.2 |
| Low methyl-etherified aminoresin 717 or low methyl-etherified aminoresin 072 | 14.3 |
| The sulfonic acid phosphamidon compound 2050W of sealing | 1.5 |
| Modification polyether diols compound F 17-hydroxy-corticosterone L-330 | 0.3 |
The formula of embodiment 2:
| Raw material | Quality (unit: g) |
| Water | 16.2 |
| Water-borne acrylic resin WR-553 | 35.7 |
| Rutile type Titanium Dioxide | 8 |
| Phthalocyanine blue | 0.1 |
| Yellow in coating | 2 |
| Composite zinc phosphate or aluminium triphosphate | 10 |
| Talcum powder | 10 |
| The compound WD-1010 of modification dihydroxy carboxylic acids salt | 0.6 |
| Hydrophilic polyamide compound AS-280 | 1.5 |
| Water-miscible paint defoamer AX-250 | 0.3 |
| The agent of anti-sudden strain of a muscle rust | 0.2 |
| Low methyl-etherified aminoresin MA-80 or low methyl-etherified aminoresin 5717W | 14.3 |
| The sulfonic acid phosphamidon compound 2050W of sealing | 1.5 |
| Modification polyether diols compound F 17-hydroxy-corticosterone L-330 | 0.3 |
Two, preparation technology:
Above two Formulation Examples are operated respectively according to the following steps:
(1) water, wetting dispersing agent WD-1010, defoamer AX-250, anti-settling agent AS-280, color stuffing (Huang and talcum powder in anatase thpe white powder, phthalocyanine blue, coating), anticorrosive packing (zinc phosphate or composite zinc phosphate or aluminium triphosphate) and waterborne epoxy modified acrylic resin (waterborne epoxy modified acrylic resin 1628A or waterborne epoxy modified acrylic resin WR-553) are put into Scattered Kettle, disperse 15～20min with the 1200r/min high speed dispersor, form slurry.
(2) slurry is joined sand mill, be ground to fineness≤25 μ m.
(3) (methyl-etherified aminoresin 717, import low methyl-etherified aminoresin 072, domestic low methyl-etherified aminoresin MA-80 or domestic low methyl-etherified aminoresin 5717W are hanged down in import with water-compatible amino resin under whipped state.), anti-rust agent, siccative (the sulfonic acid phosphamidon compound 2050W of sealing) and the flow agent (modification polyether diols compound F 17-hydroxy-corticosterone L-330) of dodging join in ground slurry, be uniformly dispersed with the 1000r/min high speed dispersor.
(4) packing.
Three, the coating of above-described embodiment 1 and 2 detected respectively, the coating main performance index is:
1, the coating indices of embodiment 1:
| Index name | Technical requirement | The actual measurement index |
| The coating state | Evenly without lump | Qualified |
| Stability in storage/d (60 ℃) | 7d is unchanged | Qualified |
| Solid part, % | —— | ≧65 |
| Appearance of film | —— | Smooth smooth |
| Time of drying/min (110 ℃) | —— | 20min |
| Sticking power (cross-hatching)/level | —— | 1 |
| Shock-resistant, Kgcm | 35 | 50 |
| Hardness (pencil method)/level | 2H | ≧2H |
| Snappiness, mm | 2 | 1 |
| Glossiness (60 ℃) | 90 | ≧90 |
| Water tolerance/h (25 ℃) | 168 | 480 |
| Salt water resistance/h (3% NaCl, 25 ℃) | 168 | 500 |
| The H of acid resistance/h(5% 2SO 4，40℃） | 4 | ≧4 |
| The NaOH of alkali resistance/h(5%, 40 ℃) | 4 | ≧4 |
| Petrol-resistance/h(is dipped in GB 1922-80 solvent oil) | 48 | Non-foaming, wrinkle resistant, do not come off |
| Anti-neutral salt spray test | 600 h line unidirectional corrosion＜2 mm | Qualified |
| Artificial weathering, h | 500 4 grades of variable colors | Qualified |
2, the coating indices of embodiment 2:
| Index name | Technical requirement | The actual measurement index |
| The coating state | Evenly without lump | Qualified |
| Stability in storage/d (60 ℃) | 7d is unchanged | Qualified |
| Solid part, % | —— | ≧55 |
| Appearance of film | —— | Smooth smooth |
| Time of drying/min (100 ℃) | —— | 20min |
| Sticking power (cross-hatching)/level | —— | 1 |
| Shock-resistant, Kgcm | 35 | 50 |
| Hardness (pencil method)/level | 2H | ≧2H |
| Snappiness, mm | 2 | 1 |
| Glossiness (60 ℃) | 90 | ≧90 |
| Water tolerance/h (25 ℃) | 168 | 400 |
| Salt water resistance/h (3% NaCl, 25 ℃) | 168 | 500 |
| The H of acid resistance/h(5% 2SO 4，40℃） | 4 | ≧4 |
| The NaOH of alkali resistance/h(5%, 40 ℃) | 4 | ≧4 |
| Petrol-resistance/h(is dipped in GB 1922-80 solvent oil) | 48 | Non-foaming, wrinkle resistant, do not come off |
| Anti-neutral salt spray test | 600 h line unidirectional corrosion＜2 mm | Qualified |
| Artificial weathering, h | 500 4 grades of variable colors | Qualified |
By above two tables as seen: aqueous dispersion type and water-latex type water-borne acrylic resin all can successfully be prepared into the amino baked paint of low-temperature curing water soluble acrylic acid of excellent performance.
Claims (7)
1. the preparation method of the amino baked paint of a low-temperature curing water soluble acrylic acid is characterized in that comprising the following steps:
1) with being uniformly dispersed after water, wetting dispersing agent, defoamer, anti-settling agent, color stuffing, anticorrosive packing and waterborne epoxy modified acrylic resin mixing, form slurry;
2) slurry is ground to fineness≤25 μ m with sand mill;
3) under whipped state, water-compatible amino resin, anti-rust agent, siccative and the flow agent of dodging are joined in ground slurry, then be uniformly dispersed through the 1000r/min high speed dispersor; Described water-compatible amino resin is aqueous dispersion type and water-latex type water-borne acrylic resin.
2. preparation method according to claim 1, is characterized in that described water-borne acrylic resin is waterborne epoxy modified acrylic resin 1628A or waterborne epoxy modified acrylic resin WR-553.
3. preparation method according to claim 1, it is characterized in that: described water-compatible amino resin is low methyl-etherified aminoresin 717, low methyl-etherified aminoresin 072, low methyl-etherified aminoresin MA-80 or low methyl-etherified aminoresin 5717W.
4. preparation method according to claim 1, it is characterized in that: described color stuffing comprises titanium dioxide, talcum powder and pigment, described titanium dioxide is anatase thpe white powder or Rutile type Titanium Dioxide.
5. preparation method according to claim 1, it is characterized in that: described anticorrosive packing is zinc phosphate, composite zinc phosphate or aluminium triphosphate.
6. preparation method according to claim 1, it is characterized in that: described wetting dispersing agent is the compound WD-1010 of modification dihydroxy carboxylic acids salt; Described anti-settling agent is hydrophilic polyamide compound AS-280; Described defoamer is water-miscible paint defoamer AX-250; Described siccative is the sulfonic acid phosphamidon compound 2050W of sealing; Described flow agent is modification polyether diols compound F 17-hydroxy-corticosterone L-330.
7. preparation method according to claim 1, it is characterized in that: during mixing, described water, wetting dispersing agent, defoamer, anti-settling agent, color stuffing, anticorrosive packing, waterborne epoxy modified acrylic resin, water-compatible amino resin, the anti-mass ratio that feeds intake that dodges rust agent, siccative and flow agent are 14～18 ︰ 0.4～1.2 ︰ 0.1～0.4 ︰ 1～3 ︰ 14～28 ︰ 8～15 ︰ 25～40 ︰ 7～15 ︰ 0.1～0.4 ︰ 0.5～2 ︰ 0.2～0.6.
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| CN201310096846.5A CN103146278B (en) | 2013-03-25 | 2013-03-25 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
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| CN103805013A (en) * | 2014-02-24 | 2014-05-21 | 深圳市宝骏环保涂料有限公司 | Single-component acrylic water-based low temperature resistant wood floor paint and production method thereof |
| CN104804633A (en) * | 2015-05-08 | 2015-07-29 | 江苏科技大学 | A kind of low-temperature fast-drying type acrylic polyurethane coating and preparation method thereof |
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| CN112029352A (en) * | 2020-08-14 | 2020-12-04 | 珠海展辰新材料股份有限公司 | Water-based metal paint and preparation method thereof |
| CN112724797A (en) * | 2020-10-10 | 2021-04-30 | 南京锐迈涂料科技有限公司 | Low-temperature baking amino baking paint for automobile hub coating and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099781A (en) * | 1993-08-25 | 1995-03-08 | 洪万亮 | Multi-polymerizing blend resin varnish |
| CN101255017A (en) * | 2007-12-01 | 2008-09-03 | 芜湖力特尔涂料制造有限公司 | Glass hot curing lacquer enamel and preparation method thereof |
| CN101397471A (en) * | 2007-09-27 | 2009-04-01 | 比亚迪股份有限公司 | Primer coating composition for polypropylene substrate and preparation method thereof |
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
| CN101429319A (en) * | 2008-12-12 | 2009-05-13 | 重庆斯耐博涂料有限公司 | Watersoluble acrylic acid modified saturated polyester, production method and watersoluble baking aluminum paint |
| CN101775109A (en) * | 2010-02-03 | 2010-07-14 | 江苏柏鹤涂料有限公司 | Epoxy modified silicon-contained waterborne acrylic resin and coating thereof |
-
2013
- 2013-03-25 CN CN201310096846.5A patent/CN103146278B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099781A (en) * | 1993-08-25 | 1995-03-08 | 洪万亮 | Multi-polymerizing blend resin varnish |
| CN101397471A (en) * | 2007-09-27 | 2009-04-01 | 比亚迪股份有限公司 | Primer coating composition for polypropylene substrate and preparation method thereof |
| CN101255017A (en) * | 2007-12-01 | 2008-09-03 | 芜湖力特尔涂料制造有限公司 | Glass hot curing lacquer enamel and preparation method thereof |
| CN101407655A (en) * | 2008-11-14 | 2009-04-15 | 上海维凯化学品有限公司 | Environment-friendly type aqueous aluminum foil protecting agent and preparation thereof |
| CN101429319A (en) * | 2008-12-12 | 2009-05-13 | 重庆斯耐博涂料有限公司 | Watersoluble acrylic acid modified saturated polyester, production method and watersoluble baking aluminum paint |
| CN101775109A (en) * | 2010-02-03 | 2010-07-14 | 江苏柏鹤涂料有限公司 | Epoxy modified silicon-contained waterborne acrylic resin and coating thereof |
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| CN109504201A (en) * | 2018-10-29 | 2019-03-22 | 河北晨阳工贸集团有限公司 | A kind of acrylic-amino baking vanish and preparation method thereof |
| CN109666380A (en) * | 2018-12-26 | 2019-04-23 | 南京长江涂料有限公司 | A kind of aluminium aqueous amino sand streak baking vanish and preparation method thereof |
| CN110408286A (en) * | 2019-07-24 | 2019-11-05 | 河南青山环保科技有限公司 | A kind of amorphous alloy and its aqueous industrial anticorrosive paint |
| CN111892847A (en) * | 2020-07-24 | 2020-11-06 | 安徽江锐新材料有限公司 | Water-based acrylic amino varnish for improving drying rate and preparation method thereof |
| CN112029352A (en) * | 2020-08-14 | 2020-12-04 | 珠海展辰新材料股份有限公司 | Water-based metal paint and preparation method thereof |
| CN111995920A (en) * | 2020-08-24 | 2020-11-27 | 江苏华夏制漆科技有限公司 | Preparation method of low-temperature cured modified water-based acrylic amino hydrophilic coating |
| CN112724797A (en) * | 2020-10-10 | 2021-04-30 | 南京锐迈涂料科技有限公司 | Low-temperature baking amino baking paint for automobile hub coating and preparation method thereof |
| CN115873505A (en) * | 2022-12-27 | 2023-03-31 | 江苏扬瑞新材料有限公司 | Water-based environment-friendly coating and preparation method thereof |
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