CN1052995C - Fragrant water-base ink capable of being faded naturally and production thereof - Google Patents
Fragrant water-base ink capable of being faded naturally and production thereof Download PDFInfo
- Publication number
- CN1052995C CN1052995C CN96105629A CN96105629A CN1052995C CN 1052995 C CN1052995 C CN 1052995C CN 96105629 A CN96105629 A CN 96105629A CN 96105629 A CN96105629 A CN 96105629A CN 1052995 C CN1052995 C CN 1052995C
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- CN
- China
- Prior art keywords
- sodium
- ink
- add
- water
- buffer solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000000975 dye Substances 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 239000007853 buffer solution Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 239000003463 adsorbent Substances 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000003352 sequestering agent Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical group [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims 1
- 239000004141 Sodium laurylsulphate Substances 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229940005740 hexametaphosphate Drugs 0.000 claims 1
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 1
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
- 239000013522 chelant Substances 0.000 abstract 1
- 239000003230 hygroscopic agent Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 20
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 2
- 235000010234 sodium benzoate Nutrition 0.000 description 2
- 239000004299 sodium benzoate Substances 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- CCBJETYDMFCKJZ-UHFFFAOYSA-L [OH-].[OH-].[Na+].[Cl+] Chemical compound [OH-].[OH-].[Na+].[Cl+] CCBJETYDMFCKJZ-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- OBRMNDMBJQTZHV-UHFFFAOYSA-N cresol red Chemical compound C1=C(O)C(C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C=C(C)C(O)=CC=2)=C1 OBRMNDMBJQTZHV-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides an ink capable of naturally decoloring and a production method thereof. The ink is made from organic dye, solvent, chelate complexes, preservative, an antifreezing hygroscopic agent, compound perfume, etc. The ink is suitable for drawing, learning and garment cutting. The ink can completely decolor without traces within certain time under certain conditions.
Description
The present invention relates to a kind of ink, particularly under natural environmental condition through the water base color inks of the fragrant of colour killing automatically after a while.
Present being seen ink has various ways, as normally used carbon ink, blue-black ink, red ink, also have the special-purpose ink of some special purposes, in a single day these inks are write on paper and the article, just can forever leave a trace, be difficult to remove, and people do not wish that sometimes ink marks is retained on paper and the article forever in study and work, as some student's reading, like at ordinary times on book, annotating and commenting on, but wish again sometimes to annotate and comment on elimination; And for example when tailoring, need be with the chalk line segment that on cloth, draws, and do not need after sewing it up to leave a trace, this just need people go to seek or study a kind of can be under field conditions (factors) the ink of colour killing automatically on request.
The purpose of this invention is to provide a kind of can be under natural environmental condition the fragrant color inks of colour killing automatically, this ink is applicable to that the student learns, engineering technical personnel's cartographic sketching, cutter's setting-out.
The present invention realizes in following mode: select some that Exposure to Sunlight, illumination, washing, distillation, temperature, humidity are changed organic compound dyestuff more sensitive, that performance is more stable again under certain condition, by adding other Chemical Composition, under air-isolation and certain potential of hydrogen condition, carry out chemical reaction, obtain product, concrete chemical constitution and content following (content unit is a grams per liter):
Organic dye 0.01-50
Organic solvent 50-400 milliliter
Sequestrant 0.1-5
Fluent agent 0.05-0.5
Sanitas 0.05-5
Freeze proof moisture adsorbent 10-300
Alkaline buffer solution is an amount of
Essence is an amount of
The deionized water surplus
Above-mentioned said organic dye is selected the organic monoacid dye composition of multi-phenol conjugated structure; Organic solvent is selected ethanol, acetone, butanols, toluene etc. for use; Integrated agent is selected EDTA sodium salt, Sodium hexametaphosphate 99 etc. for use; Negatively charged ion and nonionogenic tenside are selected in fluent agent for use, as K12, draw back powder, peregal etc.; Sanitas is selected phenol, sorbate, Sodium Benzoate etc. for use; Freeze proof moisture adsorbent is selected ethylene glycol, glycerol etc. for use; Several alkali that alkaline buffer solution is following and the mixture of salt: as sodium hydroxide, ammonium hydroxide, borax, tertiary sodium phosphate, water glass, yellow soda ash, sodium bicarbonate, sodium-chlor, Repone K etc.; Essence is selected commercially available compound essence for use.
The production method of above-mentioned fragrant water-base nature colour killing ink is earlier with sequestrant, fluent agent, sanitas, freeze proof moisture adsorbent deionized water dissolving, add alkaline buffer solution, the pH value of regulator solution is between the 7.5-12.5, add organic dye again with organic solvent dissolution, at vacuum reactor and inflated with nitrogen, fill the reactor of inert gas with 25-60 ℃ of following stirring reaction 0.5-1 hour, add an amount of essence at last, stir on one side at normal temperatures, adding deionized water on one side is diluted to volume required, filter, vacuum tank installs in the container, and packing promptly becomes product.
Advantage of the present invention is:
1, fragrant water-base nature colour killing ink can use on multiple occasions such as study, drawing, cutting; be used to practice calligraphy as the student; can save paper greatly; protect forest resources; be used to cut out a garment, more convenient than traditional chalk, need not wash after several days and just can eliminate the picture trace automatically; be used for the short drawing of skeletonizing and preservation period and on books, annotate and comment on, also very convenient.
2, can make multicolour such as redness, yellow, blueness, purple as required, write smoothly, can pour into multiple tool such as pen, fibre-tip pen and use.The lines that be used for cutting, draw are thinner, more straight than chalk, accuracy is high, if think faster remove person's handwritings, dip slightly in water can be eliminated color immediately, and is very convenient.
Below be the embodiment of ink of the present invention and production method thereof:
Embodiment one, gets EDTA disodium salt 2 grams, draws back powder 0.3 gram, Sorbic Acid 1 gram, and glycerol 100 grams behind the 200ml deionized water dissolving, add 200mlNaHCO
3-Na
2CO
3-Na
2B
4O
7Buffered soln, making PH is between the 8.0-11.0, adds 20 gram o-cresol red weak acid dyes with 100ml 90% dissolve with ethanol again, is put into vacuum reactor, stirring reaction is 1 hour under 40 ℃ temperature, add an amount of essence at last, add deionized water and be diluted to 1 liter, filter while stir at normal temperatures, vacuum tank installs in glass or the Plastic Bottle, sealing obtains red natural colour killing ink, and this ink is write the back can natural colour killing in one week.
Embodiment two, get Sodium hexametaphosphate 99 3 grams, the K120.3 gram, and Sodium Benzoate 2 grams, glycerol 150 grams are with adding 100-300ml NH behind the 300ml deionized water dissolving
4OH-NH
4The buffered soln of CL or water glass-sodium hydroxide-sodium-chlor, the pH value of solution is remained between the 7.5-12, add again with the acid dyestuff of 150ml acetone solution 25 gram brominated phenol salt, in vacuum reactor,, add an amount of essence again, stir with 30-35 ℃ of stirring reaction 1 hour, add deionized water and be diluted to 1 liter, filter, install to bottle and sealed and obtain blue natural colour killing ink, this ink can natural colour killing in 10 days.
Claims (2)
1. fragrant water-base nature colour killing ink includes organic dye, organic solvent and water, it is characterized in that it composition and every liter of ink in the content of each composition be:
Organic dye 0.5-50 gram organic solvent 50-400ml
Sequestrant 0.1-5 restrains fluent agent 0.1-5 gram
Sanitas 0.5-5 restrains freeze proof moisture adsorbent 10-300 gram
Alkaline buffer solution 100-300ml essence is an amount of
The deionized water surplus
Described organic dye is the organic monoacid compound of multi-phenol conjugated structure, organic solvent is ethanol or acetone, butanols, toluene, sequestrant is EDTA sodium salt or hexametaphosphate, fluent agent is a sodium lauryl sulphate, 1,2-dibutyl naphthalene-6-sodium sulfonate, fatty alcohol-polyoxyethylene ether, freeze proof moisture adsorbent is ethylene glycol or glycerol, alkaline buffer solution is the mixture of alkali and salt, the alkaline buffer solution of assembly in sodium hydroxide, ammonium hydroxide, borax, tertiary sodium phosphate, water glass, yellow soda ash, sodium bicarbonate, sodium-chlor, Repone K.
2. the production method of a fragrant water-base as claimed in claim 1 nature colour killing ink, it is characterized in that earlier with deionized water sequestrant, fluent agent, sanitas, freeze proof moisture adsorbent dissolving, add alkaline buffer solution, the pH value of regulator solution is between 7-12.5, add organic dye again with organic solvent dissolution, at vacuum reactor or inflated with nitrogen, the reactor of inert gas was with 25-60 ℃ of stirring reaction 0.5-1 hour, add an amount of essence, stir on one side at normal temperatures, add on one side deionized water be diluted to volume required, filtration, vacuum tank installs in the container, and sealing obtains product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96105629A CN1052995C (en) | 1996-05-03 | 1996-05-03 | Fragrant water-base ink capable of being faded naturally and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96105629A CN1052995C (en) | 1996-05-03 | 1996-05-03 | Fragrant water-base ink capable of being faded naturally and production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1142519A CN1142519A (en) | 1997-02-12 |
| CN1052995C true CN1052995C (en) | 2000-05-31 |
Family
ID=5118929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96105629A Expired - Fee Related CN1052995C (en) | 1996-05-03 | 1996-05-03 | Fragrant water-base ink capable of being faded naturally and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1052995C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753873A (en) * | 2017-01-13 | 2017-05-31 | 蓝思科技（长沙）有限公司 | A kind of glass cleaner and its application method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61271361A (en) * | 1985-05-27 | 1986-12-01 | Daiwa Kagaku Kogyo Kk | ink composition |
-
1996
- 1996-05-03 CN CN96105629A patent/CN1052995C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61271361A (en) * | 1985-05-27 | 1986-12-01 | Daiwa Kagaku Kogyo Kk | ink composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1142519A (en) | 1997-02-12 |
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