CN105603748A - Hydrophobic and oileophobic finishing agent and preparation method thereof - Google Patents
Hydrophobic and oileophobic finishing agent and preparation method thereof Download PDFInfo
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- CN105603748A CN105603748A CN201610015461.5A CN201610015461A CN105603748A CN 105603748 A CN105603748 A CN 105603748A CN 201610015461 A CN201610015461 A CN 201610015461A CN 105603748 A CN105603748 A CN 105603748A
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- finishing agent
- thin
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- thin finishing
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- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 230000002209 hydrophobic effect Effects 0.000 title abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 18
- 239000011737 fluorine Substances 0.000 claims abstract description 18
- 239000000178 monomer Substances 0.000 claims abstract description 17
- 239000002253 acid Substances 0.000 claims abstract description 15
- 238000004132 cross linking Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 19
- 229920000126 latex Polymers 0.000 claims description 14
- 239000004816 latex Substances 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 2
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- XPTUVYVQDRTMRE-UHFFFAOYSA-N [N+](=[N-])=C.ONC(CCC(=O)N)=O Chemical compound [N+](=[N-])=C.ONC(CCC(=O)N)=O XPTUVYVQDRTMRE-UHFFFAOYSA-N 0.000 claims description 2
- 238000002454 metastable transfer emission spectrometry Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 239000004753 textile Substances 0.000 abstract description 12
- 238000005406 washing Methods 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 229920000742 Cotton Polymers 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000005020 polyethylene terephthalate Substances 0.000 abstract description 3
- 229920004934 Dacron® Polymers 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- 241001076939 Artines Species 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a hydrophobic and oileophobic finishing agent and a preparation method thereof. The method comprises the steps that 0.1-3 parts of fluorine-containing emulsion is added into 0-100 parts of water, after the mixture is stirred uniformly, 0-3 parts of a surfactant is added, after the mixture is stirred fully, 0-3 parts of cross-linking monomers are added, and after mixed liquid is stirred uniformly, acid is added to adjust a pH value to range from 4 to 6, so that the hydrophobic and oileophobic finishing agent is obtained. The hydrophobic and oileophobic finishing agent has excellent washing resistant performance, and can be applied to various textile materials such as cotton, dacron, nylon, real silk and polyester. In addition, the preparation method has the remarkable advantages of being low in investment, easy to operate, wide in prospect and the like.
Description
Technical field
The application belongs to textile technology field, particularly relates to a kind of two thin finishing agents and preparation method thereof.
Background technology
Follow the development that human society is huge, people more and more need to have the textile product of difference in functionality,Wherein more and more be subject to popular is to have hydrophobic and textile product oleophobic function simultaneously, and this is mainWanting to be summed up as it can automatically cleaning and can be anti-pollution. There is the textile product energy of hydrophobic oleophobic functionEnough large-scale application in garment material, cloth for kitchen use, decorating cloth, industry cloth, army with cloth andNumerous aspects such as cloth for labour protection, can greatly adapt to the development need of entire society, thereby at society's layerFace and economic aspect obtain significant benefit.
Water and oil are all greater than 90 ° at the contact angle of material surface, and this material is two thin materials, affects materialA chemical composition that key element is material surface of the two thin performances of material, present stage is mainly by fluorine-containing high scoreSub-material and silicone based material are for the preparation of two thin materials. Fluoro-containing macromolecule material is owing to having greatlyThe fluorine carbon bond of bond energy, less polarizability and shorter bond length, so have less cohesiveness,Low surface free energy and lower critical surface tension, can significantly reduce textile product surface tension,Make textile there is excellent hydrophobic oleophobic performance, simultaneously arrange after fabric have excellent feel andPermeability.
Present stage, main two thin materials were on the market conventionally to contain the perfluor alkane of 6 carbon, the even more carbon of 8 carbonBased compound is initial feed, but the hydrophobic oleophobic performance that these materials provide can not meet betterThe higher harsher hydrophobic oleophobic requirement of current textile product, and arrange after textile product washing fastnessCan be not good, can not keep lastingly two thin performances. Can prepare and there is splendid hydrophobic dredging by fluorine containing silaneThe two thin material of oiliness energy, but fluorine containing silane cost is higher, limits it in the two thin finishing field of textileApplication.
Although the two thin material property of current exploitation is very excellent, but also have some basic problems not separateCertainly:
(1) the hydrophobic oleophobic performance that the two thin materials of main flow have is relatively low;
(2) textile after the two thin material consolidations of main flow has not good scourability;
(3) the two thin material textile material kinds applicatory of main flow are limited;
(4) though the two thin material making taking silicon fluoride as initial feed has more excellent hydro-oleophobicity,But cost is higher, can not be widely used.
Summary of the invention
The object of the present invention is to provide a kind of two thin finishing agents and preparation method thereof, to overcome prior artIn deficiency.
For achieving the above object, the invention provides following technical scheme:
The embodiment of the present application discloses a kind of two thin finishing agent, comprises according to weight portion:
0.1～3 part of fluorine-containing latex;
0～3 part of surfactant, surfactant weight portion is greater than 0;
0～3 part of cross-linking monomer;
0～100 part of water, and acid,
The pH value of described two thin finishing agents is 4～6.
Preferably, in above-mentioned two thin finishing agent, described fluorine-containing latex be eight carbon perfluoroalkyl emulsions,Six carbon perfluoroalkyl emulsions or its combination.
Preferably, in above-mentioned two thin finishing agent, described surfactant is methyl trimethoxy oxygen base siliconAlkane, MTES, gamma-aminopropyl-triethoxy-silane, γ-glycidyl ether oxygen propyl threeMethoxy silane or its combination.
Preferably, in above-mentioned two thin finishing agent, described cross-linking monomer be 2-Hydroxy ethyl acrylate,2-hydroxypropyl acrylate, N-hydroxy-succinamide-diazomethane or its combination.
Preferably, in above-mentioned two thin finishing agent, described acid is hydrochloric acid, sulfuric acid, nitric acid, acetic acidOr its combination.
Accordingly, disclosed herein as well is a kind of preparation method of two thin finishing agents, comprise step: by 0.1～3Part fluorine-containing latex adds in 0～100 part of water, adds 0～3 part of surfactant after stirring, and fully stirsAfter mixing, add 0～3 part of cross-linking monomer, after above-mentioned mixing material is stirred by add acid regulate its pHValue, between 4～6, can make this pair of thin finishing agent.
Compared with prior art, the invention has the advantages that:
1, products obtained therefrom of the present invention has excellent hydrophobic oleophobic performance;
2, products obtained therefrom of the present invention has excellent washing resistance performance;
3, products obtained therefrom of the present invention can be used in all kinds of weavings such as cotton, terylene, polyamide fibre, real silk and polyester-cotton blendMaterial;
4, products obtained therefrom of the present invention, invests lowly, is convenient to large-scale production;
5, the present invention has feature simple to operate and that prospect is wide.
Detailed description of the invention
The present invention is based on the prepared two thin emulsion of existing carbon containing perfluoroalkyl, by introducing surfactantClass monomer and preparing has the finishing agent of excellent two thin property and washing fastness. By means of surfactantThe introducing of class monomer, one side can effectively improve the hydrophobic oleophobic performance of material, can carry on the other handThe washing resistance performance of high material, and it is all kinds of to can be used in cotton, terylene, polyamide fibre, real silk and polyester-cotton blend etc.Textile material, prepares that the required cost of above-mentioned material is lower and method is simple, thereby has overcome two dredging of present stageExisting problem in material application process, makes obtained material can apply to better widely weavingSeries products.
The present invention is described further by the following example: according to following embodiment, and can be better geographicalSeparate the present invention. But, those skilled in the art will readily understand the described concrete material of embodimentOnly for the present invention is described, and should can not limit claims than, process conditions and result thereof yetIn the present invention described in detail.
Embodiment 1
0.1 part of fluorine-containing latex is added in 50 parts of water, after stirring, add 3 parts of surfactants, fillPoint stir after add 0 part of cross-linking monomer, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 1, can make this pair of thin finishing agent.
Use the made finishing agent of embodiment 1 fully to spray taffeta surface, be placed in60 DEG C of closed environments are dried, and after taffeta is completely dry, closed environment temperature are adjusted to 100 DEG CAnd keep 15min, then taffeta is placed in to 150 DEG C of closed environments and cures 3min, withAfter taffeta be placed in to 170 DEG C of closed environments cure 1min, finally taffeta is taken outMust there is the taffeta of hydrophobic oleophobic performance.
To in the present embodiment 1, carry out contact angle pair by the taffeta of two thin arrangements and without arranging taffetaRatio, the results detailed in Table 1.
Table 1
Taffeta after using washing machine to two thin arrangements is washed, and adds1993AATCC washing powder and water, washing 5min counts once, and then take out and dry, thenSurvey its pair of thin performance.
By the present embodiment by washing arrangement after taffeta with do not wash arrangement after taffeta contactAngle contrast, the results detailed in Table 2.
Table 2
As can be seen from Table 1, arrange after taffeta have than do not arrange the better hydrophobic performance of taffeta andOleophobic performance; Can draw by table 2, after arranging, taffeta has excellent washing resistance performance, is washingWash the two thin performance that still keeps excellence after 20 times.
Embodiment 2
0.1 part of fluorine-containing latex is added in 50 parts of water, after stirring, add 3 parts of surfactants, fillPoint stir after add 3 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 4, can make this pair of thin finishing agent.
Embodiment 3
0.1 part of fluorine-containing latex is added in 50 parts of water, after stirring, add 3 parts of surfactants, fillPoint stir after add 3 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 5, can make this pair of thin finishing agent.
Embodiment 4
0.1 part of fluorine-containing latex is added in 50 parts of water, after stirring, add 0 part of surfactant, fillPoint stir after add 1.5 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 6, can make this pair of thin finishing agent.
Embodiment 5
0.1 part of fluorine-containing latex is added in 50 parts of water, after stirring, add 3 parts of surfactants, fillPoint stir after add 3 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 3, can make this pair of thin finishing agent.
Embodiment 6
3 parts of fluorine-containing latexs are added in 0 part of water, after stirring, add 3 parts of surfactants, fullyAfter stirring, add 0 part of cross-linking monomer, after above-mentioned mixing material is stirred by add acid regulate its pHValue, between 6, can make this pair of thin finishing agent.
Embodiment 7
1.5 parts of fluorine-containing latexs are added in 100 parts of water, after stirring, add 2 parts of surfactants, fillPoint stir after add 1.5 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 1, can make this pair of thin finishing agent.
Embodiment 8
2 parts of fluorine-containing latexs are added in 80 parts of water, after stirring, add 1.5 parts of surfactants, fillPoint stir after add 2 parts of cross-linking monomers, after above-mentioned mixing material is stirred by add acid regulate itsPH value, between 6, can make this pair of thin finishing agent.
Finally, also it should be noted that, term " comprises ", " comprising " or its any other variant meaningContaining comprising of nonexcludability, thus make to comprise a series of key elements process, method, article orEquipment not only comprises those key elements, but also comprises other key elements of clearly not listing, or also wrapsDraw together the key element intrinsic by this process, method, article or equipment.
Claims (6)
1. two thin finishing agents, is characterized in that, comprise according to weight portion:
0.1～3 part of fluorine-containing latex;
0～3 part of surfactant;
0～3 part of cross-linking monomer;
0～100 part of water, and acid,
The pH value of described two thin finishing agents is 4～6.
2. two thin finishing agent according to claim 1, is characterized in that: described fluorine-containing latex isEight carbon perfluoroalkyl emulsions, six carbon perfluoroalkyl emulsions or its combination.
3. two thin finishing agent according to claim 1, is characterized in that: described surfactantFor MTMS, MTES, gamma-aminopropyl-triethoxy-silane, γ-contractingWater glycerin ether oxygen propyl trimethoxy silicane or its combination.
4. two thin finishing agent according to claim 1, is characterized in that: described cross-linking monomer is2-Hydroxy ethyl acrylate, 2-hydroxypropyl acrylate, N-hydroxy-succinamide-diazomethane or its groupClose.
5. two thin finishing agent according to claim 1, is characterized in that: described acid be hydrochloric acid,Sulfuric acid, nitric acid, acetic acid or its combination.
6. the preparation method of the arbitrary described two thin finishing agents of claim 1 to 5, is characterized in that, bagDraw together step: 0.1～3 part of fluorine-containing latex is added in 0～100 part of water, after stirring, add 0～3 part of surfaceActivating agent, adds 0～3 part of cross-linking monomer after fully stirring, and after above-mentioned mixing material is stirred, passes throughAdd acid to regulate its pH value between 4～6, can make this pair of thin finishing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610015461.5A CN105603748A (en) | 2016-01-11 | 2016-01-11 | Hydrophobic and oileophobic finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610015461.5A CN105603748A (en) | 2016-01-11 | 2016-01-11 | Hydrophobic and oileophobic finishing agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105603748A true CN105603748A (en) | 2016-05-25 |
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| CN201610015461.5A Pending CN105603748A (en) | 2016-01-11 | 2016-01-11 | Hydrophobic and oileophobic finishing agent and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685156A (en) * | 2018-07-05 | 2020-01-14 | 京准化工技术(上海)有限公司 | Waterproof easy-to-clean processing agent for spinning |
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|---|---|---|---|---|
| WO2003100157A1 (en) * | 2002-05-24 | 2003-12-04 | 3M Innovative Properties Company | Fluorochemical composition for treatment of a fibrous substrate |
| CN101851854A (en) * | 2009-03-31 | 2010-10-06 | 北京华美精创纳米相材料科技有限责任公司 | Nano finishing method for preparing super hydrophilic wool fabric with washing fastness |
| CN103319900A (en) * | 2013-06-07 | 2013-09-25 | 浙江汇杰有机硅有限公司 | High-transparency room-temperature-cured silicone composition and preparation method thereof |
| CN105220450A (en) * | 2014-05-29 | 2016-01-06 | 天津工业大学 | A kind of rabbit hair textile waterproof oil-refusing finishing agent and composite finishing technique |
-
2016
- 2016-01-11 CN CN201610015461.5A patent/CN105603748A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003100157A1 (en) * | 2002-05-24 | 2003-12-04 | 3M Innovative Properties Company | Fluorochemical composition for treatment of a fibrous substrate |
| CN101851854A (en) * | 2009-03-31 | 2010-10-06 | 北京华美精创纳米相材料科技有限责任公司 | Nano finishing method for preparing super hydrophilic wool fabric with washing fastness |
| CN103319900A (en) * | 2013-06-07 | 2013-09-25 | 浙江汇杰有机硅有限公司 | High-transparency room-temperature-cured silicone composition and preparation method thereof |
| CN105220450A (en) * | 2014-05-29 | 2016-01-06 | 天津工业大学 | A kind of rabbit hair textile waterproof oil-refusing finishing agent and composite finishing technique |
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| Title |
|---|
| 代少俊等: "《涂料与黏合剂》", 31 August 2014, 江苏大学出版社 * |
| 朱平: "《功能纤维及功能纺织品》", 31 August 2006, 中国纺织出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685156A (en) * | 2018-07-05 | 2020-01-14 | 京准化工技术(上海)有限公司 | Waterproof easy-to-clean processing agent for spinning |
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Application publication date: 20160525 |