CN105754753A - Antibacterial fabric detergent and preparation method thereof - Google Patents
Antibacterial fabric detergent and preparation method thereof Download PDFInfo
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- CN105754753A CN105754753A CN201610307397.8A CN201610307397A CN105754753A CN 105754753 A CN105754753 A CN 105754753A CN 201610307397 A CN201610307397 A CN 201610307397A CN 105754753 A CN105754753 A CN 105754753A
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- China
- Prior art keywords
- fabric detergent
- antibacterial
- carbon chain
- antibiotic fabric
- chain lengths
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 33
- 239000004744 fabric Substances 0.000 title claims abstract description 25
- 239000003599 detergent Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000002904 solvent Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 fatty acid ester Chemical class 0.000 claims description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 239000002736 nonionic surfactant Substances 0.000 claims description 18
- 230000008021 deposition Effects 0.000 claims description 17
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 17
- 230000003115 biocidal effect Effects 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 229930195729 fatty acid Natural products 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 claims description 7
- IQDGSYLLQPDQDV-UHFFFAOYSA-N dimethylazanium;chloride Chemical compound Cl.CNC IQDGSYLLQPDQDV-UHFFFAOYSA-N 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 229940032912 zephiran Drugs 0.000 claims description 7
- MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229930182478 glucoside Natural products 0.000 claims description 6
- 229960002717 gluceptate sodium Drugs 0.000 claims description 5
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 5
- YVJGIGDFHMIDFH-FTWQHDNSSA-N n-[(2s,3r,4r,5r,6r)-4,5-dihydroxy-6-(hydroxymethyl)-2-methoxyoxan-3-yl]-5-(dimethylamino)naphthalene-1-sulfonamide Chemical compound CO[C@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1NS(=O)(=O)C1=CC=CC2=C(N(C)C)C=CC=C12 YVJGIGDFHMIDFH-FTWQHDNSSA-N 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 5
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract 2
- 239000002738 chelating agent Substances 0.000 abstract 1
- 231100000344 non-irritating Toxicity 0.000 abstract 1
- 230000000452 restraining effect Effects 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 3
- 230000002159 abnormal effect Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 125000005313 fatty acid group Chemical group 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an antibacterial fabric detergent and a preparation method thereof. At present, few fabric detergents can achieve the effects of bacteriostasis and sterilization at the same time. The antibacterial fabric detergent is prepared from a nonionic surface active agent, an amphoteric ion surfactant, a solubilizer, a chelating agent, a dirt redeposition resisting agent, and softened water, and has double efficacies of decontamination and sterilization; besides, the antibacterial fabric detergent has the characteristics of removing peculiar smell of textile fabric, restraining peculiar smell from being generated, resisting dirt redeposition, being safe, non-toxic and non-irritating to human bodies, being pollution-free to environment, being low in production cost, and the like.
Description
Technical field
The present invention relates to a kind of fabric detergent, be specifically related to a kind of antibiotic fabric detergent and preparation method thereof.
Background technology
Along with the raising of people's living standard, everybody payes attention to more for self and family health care health.The acceleration of urbanization, wash environment and the life style of people there occurs change, and first, popularizing of automatic washing machine, the consciousness of saving water of people increases, and medicated clothing concentrates the consumer of washing to increase；Secondly, high-rise or multi-storey building resident population increases, and two-earners family increases, and causes the situation increase of washing at night, indoor seasoning medicated clothing；3rd, the change of environmental aspect, the aggravation of air pollution and haze weather and increase.Above-mentioned change causes that clothes washing condition changes so that medicated clothing becomes easily infected by and grow more antibacterial, produces abnormal flavour.For this, the antibacterial how effectively to remove and to kill on medicated clothing, it has also become the new demand that now people propose for fabric washing.
Antimicrobial cleaning product is many on the market at present, but performance difference is very big, also usually confusion of concepts in antibacterial publicity, especially some descriptions of product will sterilize and antibacterial, confusion of concepts that is antibacterial and degerming, antibacterial and that clean, allowing consumer take for antibacterial namely sterilize, degerming namely sterilize, clothing surface is cleaned and is namely sterilized.Part marks antibacterial product, and the testing result data being provided that are only antibacterial index or the examining report with other products of brand, and actual does not have sterilizing function.The product only having minority producer at present is clearly labeled with antibacterial functions and sterilization kind, and have the testing result of provincial Disease Control and Prevention Center, the existing sterilizing function of these products has again decontamination cleaning function, so following growth potential and development space are all very big, has extremely strong social benefit.
Summary of the invention
It is an object of the invention to provide a kind of antibiotic fabric detergent and preparation method thereof, there is decontamination and sterilization double effects, have simultaneously removal fabric abnormal flavour and suppress abnormal flavour to produce, anti-dirt deposits again, nontoxic non-stimulated, the feature such as environmentally safe, production cost are low safe to the human body.
The technical solution adopted in the present invention is:
1, antibiotic fabric detergent, it is characterised in that:
Prepared by the component of following mass parts:
Nonionic surfactant 5-40 part
Zwitterionic surfactant 1-15 part
Antibacterial 0.05-10 part
Solubilizing agent 0.5-10 part
Chelating agen 0.1-10 part
Anti-dirt is deposition agent 0.1-5 part again
Softening water surplus
The mass parts summation of each component is 100 parts.
Nonionic surfactant is selected from fatty alcohol-polyoxyethylene ether, fatty acid ester ethoxylate, sugar derivatives；
Described fatty alcohol-polyoxyethylene ether, long alkyl chains is C8-C16, EO number is 5-15；
Described fatty acid ester ethoxylate, fatty acid is strand fatty acid or three chain fatty acids, and fatty acid chain is saturated or unsaturated, and carbon chain lengths is C8-C22, EO number is 5-20；
Described sugar derivatives is alkyl polyglucoside, alcohol ether glucoside or methyl glucamine: wherein, alkyl polyglucoside, and carbon chain lengths is C8-C16；Alcohol ether glucoside, carbon chain lengths is C8-C22, EO number is 2-15；Methyl glucamine, carbon chain lengths is C8-C22。
Zwitterionic surfactant is alkylamide propyl-betaine or alkyl dimethyl amine oxide；
Described alkylamide propyl-betaine, long alkyl chains is C8-C16；
Described alkyl dimethyl amine oxide, long alkyl chains is C8-C16。
Antibacterial is selected from zephiran, Dialkyl dimethyl ammonium chloride, hexamethylene；
Described zephiran, carbon chain lengths is C8-C16；
Described Dialkyl dimethyl ammonium chloride, carbon chain lengths is C8-C16。
Solubilizing agent is selected from C1-C6Alkylol.
Chelating agen is selected from sodium citrate, MDGA, α-gluceptate sodium.
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer.
The preparation method of antibiotic fabric detergent, it is characterised in that:
Adding softening water to reactor, heating, to 50 DEG C, under agitation, is sequentially added into nonionic surfactant, zwitterionic surfactant, solubilizing agent, anti-dirt deposition agent again, chelating agen, antibacterial, stir.
The invention have the advantages that
1, product of the present invention has the multi-efficiencies such as decontamination, sterilization, antistatic, softness.
2, the nonionic surfactant that the present invention adopts is plant origin, for Renewable resource, to human temperature and, environmentally safe.
3, inventive formulation is suitable for cold water washing, and washing foam is moderate, easily rinses.
4, in inventive formulation without triclosan, to antibacterial such as chlorine Resorcino, trichlorine card speckles.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention will be described in detail.
The antibiotic fabric detergent that the present invention relates to, is prepared by the component of following mass parts:
Nonionic surfactant 5-40 part
Zwitterionic surfactant 1-15 part
Antibacterial 0.05-10 part
Solubilizing agent 0.5-10 part
Chelating agen 0.1-10 part
Anti-dirt is deposition agent 0.1-5 part again
Softening water surplus
The mass parts summation of each component is 100 parts.
Wherein:
(1) nonionic surfactant is selected from fatty alcohol-polyoxyethylene ether, fatty acid ester ethoxylate, sugar derivatives；
Described fatty alcohol-polyoxyethylene ether, long alkyl chains is C8-C16, EO number is 5-15；
Described fatty acid ester ethoxylate, fatty acid is strand fatty acid or three chain fatty acids, and fatty acid chain is saturated or unsaturated, and carbon chain lengths is C8-C22, EO number is 5-20；
Described sugar derivatives is alkyl polyglucoside, alcohol ether glucoside or methyl glucamine: wherein, alkyl polyglucoside, and carbon chain lengths is C8-C16；Alcohol ether glucoside, carbon chain lengths is C8-C22, EO number is 2-15；Methyl glucamine, carbon chain lengths is C8-C22。
(2) zwitterionic surfactant is alkylamide propyl-betaine or alkyl dimethyl amine oxide；
Described alkylamide propyl-betaine, long alkyl chains is C8-C16；
Described alkyl dimethyl amine oxide, long alkyl chains is C8-C16。
(3) antibacterial is selected from zephiran, Dialkyl dimethyl ammonium chloride, hexamethylene；
Described zephiran, carbon chain lengths is C8-C16；
Described Dialkyl dimethyl ammonium chloride, carbon chain lengths is C8-C16。
(4) solubilizing agent is selected from C1-C6Alkylol.
(5) chelating agen is selected from sodium citrate, MDGA, α-gluceptate sodium.
(6) anti-dirt deposition agent again is polyethylene glycol polyester copolymer, as: Ashlandsorez100, ClariantSRN-100.
The preparation method of above-mentioned antibiotic fabric detergent is:
Adding softening water to reactor, heating, to 50 DEG C, under agitation, is sequentially added into nonionic surfactant, zwitterionic surfactant, solubilizing agent, anti-dirt deposition agent again, chelating agen, antibacterial, stir.
Embodiment 1:
Nonionic surfactant 10 parts
Zwitterionic surfactant 8 parts
Antibacterial 0.2 part
Solubilizing agent 2 parts
Chelating agen 0.5 part
Anti-dirt is deposition agent 0.5 part again
Softening water surplus
The parts by weight summation of each component is 100.
Nonionic surfactant is fatty alcohol-polyoxyethylene ether.
Zwitterionic surfactant is alkylamide propyl-betaine.
Antibacterial is zephiran.
Solubilizing agent is C1-C2Alkylol.
Chelating agen is sodium citrate.
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer.
Embodiment 2:
Nonionic surfactant 20 parts
Zwitterionic surfactant 15 parts
Antibacterial 0.5 part
Solubilizing agent 4 parts
Chelating agen 2 parts
Anti-dirt is deposition agent 2 parts again
Softening water surplus
The parts by weight summation of each component is 100.
Nonionic surfactant is fatty acid ester ethoxylate.
Zwitterionic surfactant is alkylamide propyl-betaine.
Antibacterial is Dialkyl dimethyl ammonium chloride.
Solubilizing agent is selected from C3-C4Alkylol.
Chelating agen is MDGA.
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer, as: Ashlandsorez100, ClariantSRN-100.
Embodiment 3:
Nonionic surfactant 5 parts
Zwitterionic surfactant 15 parts
Antibacterial 0.05 part
Solubilizing agent 10 parts
Chelating agen 0.1 part
Anti-dirt is deposition agent 5 parts again
Softening water surplus
The mass parts summation of each component is 100 parts.
Nonionic surfactant is sugar derivatives.
Zwitterionic surfactant is alkyl dimethyl amine oxide.
Antibacterial is hexamethylene.
Solubilizing agent is selected from C5-C6Alkylol.
Chelating agen is α-gluceptate sodium.
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer.
Embodiment 4:
Nonionic surfactant 40 parts
Zwitterionic surfactant 1 part
Antibacterial 10 parts
Solubilizing agent 0.5 part
Chelating agen 10 parts
Anti-dirt is deposition agent 0.1 part again
Softening water surplus
The mass parts summation of each component is 100 parts.
Nonionic surfactant is sugar derivatives.
Zwitterionic surfactant is alkyl dimethyl amine oxide.
Antibacterial is hexamethylene.
Solubilizing agent is selected from C5-C6Alkylol.
Chelating agen is α-gluceptate sodium.
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer.
It is below the performance test explanation of antibiotic fabric abluent involved in the present invention:
Experiment 1:
Test this contrivance and commercial products performance comparison in detergency.
Method of testing performs according to QB/T1224-2012, adopts three kinds of standard soiled cloths, JB-01 white carbon black soiled cotton, JB-02 albumen soiled cotton, JB-03 oils and fats soiled cotton, and evaluation result is as follows:
Experiment 2:
Test this contrivance bactericidal property.
Experimental technique performs according to GB/T15979-2002, and microorganism fungus kind is: escherichia coli (ATCC8099), staphylococcus aureus (ATCC6538), and test liquid is 1% sample stock solution, and action time is 20min.
Root test result is as follows:
Present disclosure is not limited to cited by embodiment, and the conversion of any equivalence that technical solution of the present invention is taked by those of ordinary skill in the art by reading description of the present invention, the claim being the present invention is contained.
Claims (8)
1. antibiotic fabric detergent, it is characterised in that:
Prepared by the component of following mass parts:
Nonionic surfactant 5-40 part
Zwitterionic surfactant 1-15 part
Antibacterial 0.05-10 part
Solubilizing agent 0.5-10 part
Chelating agen 0.1-10 part
Anti-dirt is deposition agent 0.1-5 part again
Softening water surplus
The mass parts summation of each component is 100 parts.
2. antibiotic fabric detergent according to claim 1, it is characterised in that:
Nonionic surfactant is selected from fatty alcohol-polyoxyethylene ether, fatty acid ester ethoxylate, sugar derivatives；
Described fatty alcohol-polyoxyethylene ether, long alkyl chains is C8-C16, EO number is 5-15；
Described fatty acid ester ethoxylate, fatty acid is strand fatty acid or three chain fatty acids, and fatty acid chain is saturated or unsaturated, and carbon chain lengths is C8-C22, EO number is 5-20；
Described sugar derivatives is alkyl polyglucoside, alcohol ether glucoside or methyl glucamine: wherein, alkyl polyglucoside, and carbon chain lengths is C8-C16；Alcohol ether glucoside, carbon chain lengths is C8-C22, EO number is 2-15；Methyl glucamine, carbon chain lengths is C8-C22。
3. antibiotic fabric detergent according to claim 2, it is characterised in that:
Zwitterionic surfactant is alkylamide propyl-betaine or alkyl dimethyl amine oxide；
Described alkylamide propyl-betaine, long alkyl chains is C8-C16；
Described alkyl dimethyl amine oxide, long alkyl chains is C8-C16。
4. antibiotic fabric detergent according to claim 3, it is characterised in that:
Antibacterial is selected from zephiran, Dialkyl dimethyl ammonium chloride, hexamethylene；
Described zephiran, carbon chain lengths is C8-C16；
Described Dialkyl dimethyl ammonium chloride, carbon chain lengths is C8-C16。
5. antibiotic fabric detergent according to claim 4, it is characterised in that:
Solubilizing agent is selected from C1-C6Alkylol.
6. antibiotic fabric detergent according to claim 5, it is characterised in that:
Chelating agen is selected from sodium citrate, MDGA, α-gluceptate sodium.
7. antibiotic fabric detergent according to claim 6, it is characterised in that:
Anti-dirt deposition agent again is polyethylene glycol polyester copolymer.
8. the preparation method of antibiotic fabric detergent, it is characterised in that:
Adding softening water to reactor, heating, to 50 DEG C, under agitation, is sequentially added into nonionic surfactant, zwitterionic surfactant, solubilizing agent, anti-dirt deposition agent again, chelating agen, antibacterial, stir.
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| CN108559657A (en) * | 2018-06-22 | 2018-09-21 | 湖北煜韩环境科技有限公司 | A kind of Fabric detergent and preparation method thereof |
| CN110903918A (en) * | 2019-11-25 | 2020-03-24 | 广州立白企业集团有限公司 | Antibacterial fabric detergent composition |
| CN111117811A (en) * | 2019-12-27 | 2020-05-08 | 上海家化联合股份有限公司 | Cleaning composition for removing odor of fabrics dried in the shade |
| CN111690469A (en) * | 2020-07-08 | 2020-09-22 | 青岛拜士特新材料有限公司 | Degerming washing powder containing zinc pyrithione antibacterial agent and preparation method thereof |
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| CN111733027A (en) * | 2020-07-08 | 2020-10-02 | 青岛拜士特新材料有限公司 | Instant washing antibacterial master batch and preparation method thereof |
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| CN116728933A (en) * | 2023-06-20 | 2023-09-12 | 宜禾股份有限公司 | Special clothes with heat insulation capability and preparation process thereof |
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| CN111733027B (en) * | 2020-07-08 | 2022-03-11 | 青岛拜士特新材料有限公司 | Instant washing antibacterial master batch and preparation method thereof |
| CN111733021B (en) * | 2020-07-08 | 2022-03-29 | 青岛拜士特新材料有限公司 | Sterilizing washing powder containing PCMX and preparation method thereof |
| CN116728933A (en) * | 2023-06-20 | 2023-09-12 | 宜禾股份有限公司 | Special clothes with heat insulation capability and preparation process thereof |
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Application publication date: 20160713 |