CN105802413A - Algae-preventing fishing net coating - Google Patents
Algae-preventing fishing net coating Download PDFInfo
- Publication number
- CN105802413A CN105802413A CN201610234023.8A CN201610234023A CN105802413A CN 105802413 A CN105802413 A CN 105802413A CN 201610234023 A CN201610234023 A CN 201610234023A CN 105802413 A CN105802413 A CN 105802413A
- Authority
- CN
- China
- Prior art keywords
- algae
- fishing net
- parts
- coating
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 claims abstract description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 15
- 230000000996 additive effect Effects 0.000 claims abstract description 15
- 229940120503 dihydroxyacetone Drugs 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002545 silicone oil Polymers 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 241000195493 Cryptophyta Species 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 12
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 claims description 9
- 238000004132 cross linking Methods 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- GVCGWXSZNUOTDW-UHFFFAOYSA-N sulfo cyanate Chemical compound OS(=O)(=O)OC#N GVCGWXSZNUOTDW-UHFFFAOYSA-N 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 241000251468 Actinopterygii Species 0.000 abstract 1
- 241000195474 Sargassum Species 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an algae-preventing fishing net coating.The algae-preventing fishing net coating is prepared from, by weight, 100-110 parts of waterborne acrylate, 6-8 parts of dihydroxyacetone, 4-5 parts of adopyl diacidhydrazine, 3-4 parts of an algae-preventing additive, 5-7 parts of a fluorescent pigment, 6-10 parts of kaolin, 3-5 parts of emulsified silicone oil and 12-18 parts of deionized water.The algae-preventing fishing net coating uses the dihydroxyacetone and the adopyl diacidhydrazine to prepare crosslinked type waterborne acrylate, the weatherability of the coating is improved, the algae-preventing capability of the coating is also improved by adding the algae-preventing additive, meanwhile a fish trapping effect can be played by adding the fluorescent pigment, and the fishing efficiency is improved.
Description
Technical field
The present invention relates to paint field, be specially a kind of Algae-resistant fishing net coating.
Background technology
At present, fishing-net composition kind is more single, and the coating the most anti-algae composition major part of some antifouling anti-algaes is chemical agent, easily causes environmental pollution in actual use, therefore it provides a kind of environment friendly and pollution-free Algae-resistant fishing net coating is imperative.
Summary of the invention
For reaching object above, the present invention provides techniques below scheme:
A kind of Algae-resistant fishing net coating, is made up of following raw material: it is characterized in that being made up of the raw material of following weight portion: water-and acrylate 100-110, dihydroxy acetone 6-8, adipic acid dihydrazide 4-5, anti-algae additive 3-4, fluorescent pigment 5-7, Kaolin 6-10, emulsified silicone oil 3-5, deionized water 12-18.
Described anti-algae additive is made up of the raw material of following weight portion: Cuprous sulfocyanate 10-12, manganese oxide 3-5, acrylic resin 20-25, pure-acrylic emulsion 10-15, titanium dioxide 4-5, Pulvis Talci 3-5.
A kind of Algae-resistant fishing net coating, is made up of following steps:
(1) water-and acrylate and dihydroxy acetone are put in reactor, at a temperature of 65-70 DEG C, carry out prepolymerization reaction 50-55min；Then add adipic acid dihydrazide at a temperature of 70-75 DEG C, carry out chain extending reaction 100-110min, prepare crosslinking type aqueous acrylate；
(2) prepared crosslinking type aqueous acrylate is gradually added anti-algae additive, fluorescent pigment, Kaolin, emulsified silicone oil, deionized water, then mixing and stirring at 40-50 DEG C.
Beneficial effect:
The present invention uses dihydroxy acetone, adipic acid dihydrazide to prepare crosslinking type aqueous acrylate, improves the weatherability of coating；Being also added into anti-algae additive and improve the anti-algae ability of coating, the fluorescent pigment being simultaneously introduced can play the effect of trapping Fish, improves fishing efficiency.
Detailed description of the invention
Embodiment 1
A kind of Algae-resistant fishing net coating, is made up of following raw material: it is characterized in that being made up of the raw material of following weight portion: water-and acrylate 106, dihydroxy acetone 7, adipic acid dihydrazide 4.5, anti-algae additive 3.5, fluorescent pigment 6, Kaolin 8, emulsified silicone oil 4, deionized water 16.
Described anti-algae additive is made up of the raw material of following weight portion: Cuprous sulfocyanate 12, manganese oxide 4, acrylic resin 22, pure-acrylic emulsion 13, titanium dioxide 5, Pulvis Talci 3.
A kind of Algae-resistant fishing net coating, is made up of following steps:
(1) water-and acrylate and dihydroxy acetone are put in reactor, at a temperature of 66 DEG C, carry out prepolymerization reaction 50min；Then add adipic acid dihydrazide at a temperature of 72 DEG C, carry out chain extending reaction 110min, prepare crosslinking type aqueous acrylate；
(2) prepared crosslinking type aqueous acrylate is gradually added anti-algae additive, fluorescent pigment, Kaolin, emulsified silicone oil, deionized water, then mixing and stirring at 48 DEG C.
Embodiment 2
A kind of Algae-resistant fishing net coating, is made up of following raw material: it is characterized in that being made up of the raw material of following weight portion: water-and acrylate 102, dihydroxy acetone 8, adipic acid dihydrazide 4, anti-algae additive 3, fluorescent pigment 5, Kaolin 7, emulsified silicone oil 3.5, deionized water 15.
Described anti-algae additive is made up of the raw material of following weight portion: Cuprous sulfocyanate 10, manganese oxide 3.5, acrylic resin 22, pure-acrylic emulsion 12.5, titanium dioxide 45, Pulvis Talci 3.5.
A kind of Algae-resistant fishing net coating, is made up of following steps:
(1) water-and acrylate and dihydroxy acetone are put in reactor, at a temperature of 66 DEG C, carry out prepolymerization reaction 55min；Then add adipic acid dihydrazide at a temperature of 75 DEG C, carry out chain extending reaction 106min, prepare crosslinking type aqueous acrylate；
(2) prepared crosslinking type aqueous acrylate is gradually added anti-algae additive, fluorescent pigment, Kaolin, emulsified silicone oil, deionized water, then mixing and stirring at 48 DEG C.
Embodiment 3
By embodiment 1,2 with commercially available Algae-resistant fishing net coatings in fishing lines, then weave into fishing net, be put in same waters 30 days, take out after 60 days, contrast its algae preventive effect, result such as following table:
| Sequence number | Sargassum adhesive rate (30 days) | Sargassum adhesive rate (60 days) |
| Embodiment 1 | 4.6% | 5.1% |
| Embodiment 2 | 4.3% | 4.8% |
| Commercially available matched group | 8.2% | 14.5% |
The algae preventive effect being understood the present invention by data above contrast is good, and anti-algae timeliness is long.
Claims (3)
1. an Algae-resistant fishing net coating, it is characterised in that be made up of following raw material: it is characterized in that being made up of the raw material of following weight portion: water-and acrylate 100-110, dihydroxy acetone 6-8, adipic acid dihydrazide 4-5, anti-algae additive 3-4, fluorescent pigment 5-7, Kaolin 6-10, emulsified silicone oil 3-5, deionized water 12-18.
2. a kind of Algae-resistant fishing net coating as claimed in claim 1, it is characterised in that described anti-algae additive is made up of the raw material of following weight portion: Cuprous sulfocyanate 10-12, manganese oxide 3-5, acrylic resin 20-25, pure-acrylic emulsion 10-15, titanium dioxide 4-5, Pulvis Talci 3-5.
3. an Algae-resistant fishing net coating, it is characterised in that be made up of following steps:
(1) water-and acrylate and dihydroxy acetone are put in reactor, at a temperature of 65-70 DEG C, carry out prepolymerization reaction 50-55min；Then add adipic acid dihydrazide at a temperature of 70-75 DEG C, carry out chain extending reaction 100-110min, prepare crosslinking type aqueous acrylate；
(2) prepared crosslinking type aqueous acrylate is gradually added anti-algae additive, fluorescent pigment, Kaolin, emulsified silicone oil, deionized water, then mixing and stirring at 40-50 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610234023.8A CN105802413A (en) | 2016-04-16 | 2016-04-16 | Algae-preventing fishing net coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610234023.8A CN105802413A (en) | 2016-04-16 | 2016-04-16 | Algae-preventing fishing net coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105802413A true CN105802413A (en) | 2016-07-27 |
Family
ID=56460247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610234023.8A Pending CN105802413A (en) | 2016-04-16 | 2016-04-16 | Algae-preventing fishing net coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105802413A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101351514A (en) * | 2005-12-28 | 2009-01-21 | 中国涂料株式会社 | High-solid antifouling coating composition, antifouling coating film, substrate with coating film, antifouling substrate, method for forming coating film on substrate surface, method for preventing fouling of substrate, and high-solid multi-liquid antifouling coating composition set |
| CN103757732A (en) * | 2013-12-11 | 2014-04-30 | 巢湖亚塑网具制造有限公司 | Algae-resistant fishing net |
| CN104559535A (en) * | 2013-10-22 | 2015-04-29 | 青岛德固建筑材料有限公司 | Algae prevention coating |
| CN104911742A (en) * | 2015-05-14 | 2015-09-16 | 巢湖市大江渔具有限公司 | Anti-algae fishing net |
| CN105420874A (en) * | 2016-01-06 | 2016-03-23 | 江苏工程职业技术学院 | A method for manufacturing ultra-light and high-strength antibacterial and algae-removing fishing net yarn |
| CN105482576A (en) * | 2015-12-31 | 2016-04-13 | 辛范范 | Environment-friendly latex paint and preparation method thereof |
-
2016
- 2016-04-16 CN CN201610234023.8A patent/CN105802413A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101351514A (en) * | 2005-12-28 | 2009-01-21 | 中国涂料株式会社 | High-solid antifouling coating composition, antifouling coating film, substrate with coating film, antifouling substrate, method for forming coating film on substrate surface, method for preventing fouling of substrate, and high-solid multi-liquid antifouling coating composition set |
| CN104559535A (en) * | 2013-10-22 | 2015-04-29 | 青岛德固建筑材料有限公司 | Algae prevention coating |
| CN103757732A (en) * | 2013-12-11 | 2014-04-30 | 巢湖亚塑网具制造有限公司 | Algae-resistant fishing net |
| CN104911742A (en) * | 2015-05-14 | 2015-09-16 | 巢湖市大江渔具有限公司 | Anti-algae fishing net |
| CN105482576A (en) * | 2015-12-31 | 2016-04-13 | 辛范范 | Environment-friendly latex paint and preparation method thereof |
| CN105420874A (en) * | 2016-01-06 | 2016-03-23 | 江苏工程职业技术学院 | A method for manufacturing ultra-light and high-strength antibacterial and algae-removing fishing net yarn |
Non-Patent Citations (2)
| Title |
|---|
| 曲岩松等: "《石油石化市场年度分析报告 2014》", 31 December 2015, 中国石化咨询公司 * |
| 阎旭等: "室温自交联水性聚丙烯酸酯乳液的合成、结构与性能", 《现代涂层技术》 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20160727 |