CN105802482A - Waterborne radiation curing coating decorative plate and preparation method thereof - Google Patents
Waterborne radiation curing coating decorative plate and preparation method thereof Download PDFInfo
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- CN105802482A CN105802482A CN201610173345.6A CN201610173345A CN105802482A CN 105802482 A CN105802482 A CN 105802482A CN 201610173345 A CN201610173345 A CN 201610173345A CN 105802482 A CN105802482 A CN 105802482A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention provides a waterborne radiation curing coating decorative plate and a preparation method thereof. The waterborne radiation curing coating decorative plate comprises an inorganic plate and finish with which the surface of the inorganic plate is coated. The finish comprises a waterborne radiation curing coating. The waterborne radiation curing coating comprises 1-40 wt% of acrylate monomers, 30-50 wt% of one or more of a water-soluble acrylate prepolymer, an organosilicone modified water-soluble acrylate polymer and oil-in-water acrylate prepolymer emulsion, 3-8 wt% of photoinitiator and 2-41 wt% of one or more of water or alcohol solvents. The waterborne radiation curing coating decorative plate has good patterns and color expressive force, the surface is smooth and compact, good antimicrobial performance, anti-fouling performance, anti-scratching performance, water-proof performance, mould-proof performance and heat-resistant performance are achieved, and the decorative plate can be widely applied to various decoration materials. The waterborne radiation curing coating decorative plate is simple in preparation process, suitable for batch production and good in environment friendliness and energy conservation.
Description
Technical field
The present invention relates to aqueous radiation curable coating decorative panel and preparation method thereof.
Background technology
At present, along with skyscraper increasingly increase with various interior decorations day by day luxurious, the environmental protection of building, energy-conservation and fire prevention etc. are required also more and more higher by country, therefore, various heat-preserving complex materials, fire proofing material occur in succession, mainly have fiber reinforced cement board, fiber reinforced calcium silicate board, fiber reinforcement magnesium oxide plate, lightweight chloro-magnesium cement plate, magnesite board, plasterboard etc. as exterior wall or inner wall decoration.
At present, general construction technology is after first being installed by decorative board for wall, application is carried out on its surface again, it is necessary to beat the multiple tracks techniques such as putty, priming and finish paint, particularly high-building construction difficulty with aqueous latex paint, cycle is long, cost is high, therefore, is badly in need of what a kind of painting installed, the decorative board for wall that environmental protection degree is high, shortens construction period, reduces difficulty of construction.Additionally in the production and processing of aqueous radiation curable coating and use procedure, very environmental protection and efficiency are very high, energy consumption is non-normally low, meet very much energy-saving and emission-reduction.
Summary of the invention
For the problems referred to above, it is an object of the invention to provide aqueous radiation curable coating decorative panel and preparation method thereof.
According to an aspect of the present invention, it is provided that aqueous radiation curable coating decorative panel, being contained in the finish paint on inorganic board surface including inorganic board and painting, wherein finish paint comprises aqueous radiation curable coating, and aqueous radiation curable coating comprises following components and constituent content:
Wherein, aqueous radiation curable coating also comprises following components and constituent content:
Pigment 0～35wt%；
Filler 0～30wt%；
Auxiliary agent 0～5wt%.
Wherein, aqueous radiation curable coating also comprises following components and constituent content:
Wherein, decorative panel also includes being coated with successively the infiltration on the surface being contained in inorganic board and strengthens primary coat, close and be coated with and/or white closing painting, ground floor attachment primer, white primary coat and/or white close painting and second layer attachment primer, and wherein primary coat is strengthened in infiltration, close painting and/or white is closed and is coated with, ground floor attachment primer, white primary coat and/or white close painting and second layer attachment primer between the surface and finish paint of inorganic board；
Infiltration strengthen primary coat, close be coated with and/or white close be coated with, white primary coat and/or white close be coated with, attachment primer comprise aqueous radiation curing material.
Wherein, decorative panel also includes the transfer film and the third layer attachment primer that are coated with the surface being contained in inorganic board successively, and wherein transfer film laminating is imprinted between second layer attachment primer and third layer attachment primer, and third layer attachment primer is coated with and is contained between transfer film and finish paint.
Wherein, decorative panel also includes the colored paint being coated with the surface being contained in inorganic board, and colored paint is coated with and is contained between second layer attachment primer and finish paint, and colored paint comprises aqueous radiation curable coating.
Wherein, inorganic board includes cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite board, plasterboard.
Wherein, the application thickness of primary coat is strengthened in infiltration is 0.001～500 micron；The application thickness closing painting or white closing painting is 0.001～500 micron, and ground floor attachment primer and the second layer adhere to the application thickness of primer and be 0.001～200 micron, and the application thickness of finish paint is 0.001～500 micron.
Wherein, water-soluble acrylic ester prepolymer includes one or more in soluble epoxide acrylate, aqueous polyurethane acrylate, aqueous unsaturated polyester (UP) acrylate, aqueous amino acrylates, water-borne acrylate copolymer, fluorine modified aqueous acrylate copolymer.
nullWherein，Acrylate monomer includes butyl acrylate、Cyclohexyl acrylate、Isooctyl acrylate monomer、2-(Acryloyloxy)ethanol、Hydroxyethyl methylacrylate、Ethoxylated bisphenol A dimethylacrylate、Tri (propylene glycol) diacrylate、Propylene glycol diacrylate、Neopentylglycol diacrylate、Third oxidation neopentylglycol diacrylate、Double; two (diethylene glycol) diacrylate of phthalic acid、Three (2-ethoxy) isocyanuric acid triacrylate、1，6 hexanediyl esters、Trimethylolpropane trimethacrylate、2-phenoxyethyl acrylate、Ethoxyquin trimethylolpropane trimethacrylate、Third oxidation trimethylolpropane trimethacrylate、Pentaerythritol triacrylate、Dipentaerythritol acrylate、2-HEMA phosphate ester、Polyethylene Glycol (600) dimethylacrylate、TEGDMA、Polyethylene Glycol (200) dimethylacrylate、Ethoxyquin tetramethylol methane tetraacrylate、Dioxy Lu Huan omega-diol diacrylate、Third aoxidizes one or more in neopentylglycol diacrylate.
Wherein, organic-silicon-modified water-soluble acrylic ester polymer includes one or more in organic silicon modified aqueous polyester acrylate, organic silicon modified aqueous amino acrylates, organic silicon modified aqueous acrylate copolymer, organic silicon modified aqueous epoxy acrylate, fluosilicic modified aqueous acrylic acid ester copolymer, organic silicon modified aqueous polyurethane acrylate.
Wherein, oil-in-water acrylic ester prepolymer emulsion includes one or more in oil-in-water Epoxy-Acrylate Emulsion, oil-in-water polyurethane-acrylate emulsion, oil-in-water polyester acrylate emulsion, oil-in-water amino acrylates, oil-in-water acrylate copolymer.
nullWherein，Light trigger includes benzoin methyl ether、Benzoin ethyl ether、Benzoin isopropyl ether、Benzil dimethyl ketal、From 1-Phenylethanone.、2,2-dimethoxy-2-phenyl acetophenone、2,2-diethoxy-2-phenyl acetophenone、1,1-dichloroacetophenone、1-hydroxy acetophenone、1-hydroxy-cyclohexyl phenyl ketone、2-hydroxy-2-methyl-1-phenyl-1-acetone、1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone、1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone、2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone、2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone、2-tert-butyl group anthraquinone、1-chloroanthraquinone、2-amyl anthraquinone、2,4-dimethyl thioxanthone、2,4-diethyl thioxanthone、2-isopropyl thioxanthone、4-isopropyl thioxanthone、2-chloro thioxanthone、2,4-diisopropyl thioxanthone、Benzophenone、4-chlorobenzophenone、To methyl benzophenone、4-benzoyl-4 '-dimethyl diphenyl sulfide、2,4,6-trimethyl benzoyl diphenyl base phosphine oxide、Double; two (2,4,6-trimethylbenzoyl)-phenyl phosphine oxide、Two (2,6-dimethylbenzoyl)-2,4,4-trimethylpentylphosphine oxide、2,4,6-trimethylbenzoyl phenyl ethyoxyl phosphine oxide、Methyl benzoylbenzoate、One or more in methyl o-benzoylbenzoate.
Wherein, pigment includes one or more in titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue powder, ultramarine green powder, phthalocyanine blue powder, the green powder of the phthalein mountain valley with clumps of trees and bamboo, palm fibre chrome yellow powder, organic red, organic bloom, green organic powder, aqueous copper bronze, water aluminum-silver slurry powder, pearl essence.
Wherein, filler includes one or more in Kaolin, flatting silica, aqueous delustring slurry, abrasion-resistant powder.
Wherein, auxiliary agent includes thickening agent, levelling agent, substrate wetting agents, defoamer, one or more in wetting dispersing agent, adhesion promoter, UV absorbent.
Wherein, thickening agent includes: one or both in PUR40, aerosil；Levelling agent includes: one or more in BYK348, BYK308N, CF736W；, substrate wetting agents includes: one or more in BYK190, CU190W, CJ60W, A80；Defoamer includes: one or more in BYK028, CD761SW, TEGO450；Wetting dispersing agent includes one or more in BYK190, CU190W, CJ60W, WD264；UV absorbent includes one or more in 5050,5151,951,3310.
According to the present invention another aspect, it is provided that the preparation method of aqueous radiation curable coating decorative panel, comprise the following steps:
External coating in inorganic board permeates strengthens primary coat, external coating in infiltration reinforcement primary coat closes painting and/or white closes painting, solidify, formed to close and be coated with and/or white seal coat, it is coated with and/or white seal coat external coating attachment primer closing, solidify, form ground floor attachment primer, primer external coating white primary coat and/or white closing painting is adhered at ground floor, solidify, form white primary coat and/or white seal coat, at white primary coat and/or white seal coat surface application one layer again attachment primer, solidify, form second layer attachment primer, primer external coating colored paint is adhered at the second layer, solidify, form colored paint layer, at colored paint layer external coating finish paint, solidify, form top coat layer, and then form aqueous radiation curable coating decorative panel；Or
nullExternal coating in inorganic board permeates strengthens primary coat，External coating in infiltration reinforcement painting is closed and is coated with and/or white closing painting，Solidify，Formed to close and be coated with and/or white seal coat，Closing the external coating one layer attachment primer of painting and/or white seal coat，Solidify，Form ground floor attachment primer，Primer external coating white primary coat and/or white closing painting is adhered at ground floor，Solidify，Form white primary coat and/or white seal coat，Surface application one layer again attachment primer at white primary coat and/or white seal coat，Solidify，Form second layer attachment primer，One layer of transfer film of surface laminating of primer is adhered at the second layer，Solidify，Remove the base load film of transfer film，Form transfer rete，At transfer film surface application one layer again attachment primer，Solidify，Form third layer attachment primer，The external coating finish paint of primer is adhered in third layer，Solidify，Form top coat layer，And then form aqueous radiation curable coating decorative panel.
Wherein, preparation method is further comprising the steps of:
After primary coat is strengthened in application infiltration, close before being coated with in application closing painting and/or white, carry out benefit native, solidify；Before primary coat is strengthened in application infiltration, carry out fixed thick sanding, dedusting；Adhere to primer and second layer attachment primer at application ground floor before, all carry out sanding, dedusting.
Wherein, being cured as ultraviolet light or electronic beam curing, wherein the solidification power of ultraviolet light is 2～50KW, the curing rate of ultraviolet light 0.2～50 m/min.
Wherein, water-soluble acrylic ester prepolymer, acrylate monomer, organic silicon modified aqueous acrylate polymer, oil-in-water acrylic ester prepolymer emulsion and light trigger are main film forming matter；In the present invention; by using water as solution; coordinate specific film forming matter; and by the rational proportion of water, alcoholic solution and the component such as organic silicon modified aqueous acrylate polymer and oil-in-water acrylic ester prepolymer emulsion; make the radiation curable coating of environmental protection; and it being applied on inorganic plate so that this water paint forms aqueous radiation-curable couting fine and close, that have rich colors, that have defencive function in inorganic board.
The aqueous radiation curable coating decorative panel of the present invention, has good pattern and color representation power, the smooth densification in surface, has good antibacterial, anti-soil, anti-scratch, waterproof, mildew-resistant, heat resistance concurrently, can be widely applied to all kinds of decorative environment；Manufacturing process is simple, it is adaptable to batch production, and the feature of environmental protection, good energy saving property.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the embodiment of the present invention, technical scheme is clearly and completely described, it is clear that, described embodiment is a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.It should be noted that when not conflicting, the embodiment in the application and the feature in embodiment can combination in any mutually.
Mode following by specific embodiment explains in detail radiation curing negative ion paint provided by the invention.
The decorative panel 1 of embodiment 1 aqueous radiation curable coating walnut pattern
Decorative panel 1 includes cement fibrolite plate and is coated with the infiltration reinforcement primary coat being contained in cement fibrolite plate surface, seal coat, ground floor attachment primer, white primary coat, second layer attachment primer, transfer film, third layer attachment primer, finish paint successively.
Wherein primary coat, seal coat, ground floor attachment primer, white primary coat, second layer attachment primer, third layer attachment primer, finish paint are strengthened in infiltration, comprise aqueous radiation curable coating X1, X2, X3, X4, X3, X3, X6 successively.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino acrylates 10wt%, double; two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethanol 21wt%, pure water 20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate 10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2-hydroxy-2-methyl-1-acetone 5wt%, EFKA40103wt%, ethanol 1wt%, pure water 1wt%, PUR4010wt%, Pulvis Talci 5wt%, A805wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%; HMEA10wt%; PEG (200) DMA10wt%, soluble polyurethane acrylate 10wt%, water-soluble modified acrylate 5wt%; 1-hydroxy-cyclohexyl-phenyl ketone 5wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 5wt%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%, EFKA40101wt%; adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X4 includes following components and content:
Soluble epoxide acrylate 15wt%; oil-in-water urethane acrylate 5wt%; water-soluble polyester acrylate 10wt%; PET5EO4A5wt%; PEG (600) DMA15wt%; white pearlescent powder 10wt%; titanium dioxide 2wt%; 1-hydroxy-cyclohexyl-phenyl ketone 2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%, adhesion promoter 1wt%; TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether 5wt%, pure water 25wt%.
Aqueous radiation curable coating X6 includes following components and content:
Fluosilicic modified soluble acrylate 15wt%; fluorine richness water-soluble acrylic ester copolymer 25wt%; PEG (600) DMA15wt%; PHEA10wt%, flatting silica 3.5wt%, aqueous delustring slurry 15wt%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK1900.3wt%, TEGO4500.2wt%, BYK3480.3wt%, ethanol 10wt%.
Wherein, it is 150 microns that the degree of depth of priming coat is strengthened in the infiltration of decorative panel 1, the thickness of seal coat is 50 microns, the thickness of ground floor attachment primer is 0.001 micron, white primary coat coating layer thickness is 50 microns, the thickness of second layer attachment primer is 200 microns, and the thickness of third layer attachment primer is 200 microns, the thickness of top coat layer 10 microns.
The preparation method of decorative panel 1, comprises the following steps:
nullInorganic board is carried out fixed thick sanding、Dedusting，Surface roller coating one layer in inorganic board permeates strengthens primary coat X1，The pipeline entering linear velocity 10 ms/min is carried 1 minute，Close its external coating one layer again and be coated with X2，Enter linear velocity 10 ms/min、The uv cure machine of the double; two mercury lamp of 9.6KW，Solidify，Sanding、Dedusting，Primer X3 is adhered to again at its external coating ground floor，Enter linear velocity 10 ms/min、The mono-mercury lamp uv cure machine of 9.6KW，Semi-solid preparation，Again at its external coating white primary coat X4，Enter linear velocity 10 ms/min、11.2KW gallium lamp、Gallium lamp、Mercury lamp、The uv cure machine of mercury lamp，Solidify，Sanding、Dedusting，Primer X3 is adhered to again at its external coating second layer，Enter linear velocity 10 ms/min、The uv cure machine of the double; two mercury lamp of 9.6KW，Semi-solid preparation，Its surface utilizes the transfer film X5 of the transfer interpreter laminating walnut pattern with gum X3 again，Enter linear velocity 10 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、The uv cure machine of mercury lamp，Solidify，Remove base load film，Primer layer X3 is adhered to again at its external coating the 3rd，Enter linear velocity 10 ms/min、11.2KW gallium lamp、The uv cure machine of gallium lamp，Semi-solid preparation，Again at its external coating finish paint X6，Enter linear velocity 10 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、Mercury lamp、The uv cure machine of mercury lamp，Solidify，Testing、Pasting protective film，Namely become: the decorative panel of aqueous radiation curable coating walnut pattern.
The light blue decorative panel 2 of embodiment 2 aqueous radiation curable coating
Decorative panel 2 includes cement fibrolite plate and is coated with the infiltration reinforcement primary coat being contained in cement fibrolite plate surface successively, closes and is coated with, and white closes painting, and ground floor attachment primer, white is closed and is coated with, and the second layer adheres to primer, colored paint layer, top coat layer.
Wherein infiltration reinforcement primary coat, closing are coated with, white closes painting, ground floor adheres to primer, the second layer attachment primer, colored paint, finish paint, comprise respectively successively: aqueous radiation curable coating X1, X2, X3, X4, X4, X7, X6.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino acrylates 10wt%, double; two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethanol 21wt%, pure water 20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate 10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2-hydroxy-2-methyl-1-acetone 5wt%, EFKA40103wt%, ethanol 1wt%, pure water 1wt%, PUR4010wt%, Pulvis Talci 5wt%, A805wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%; HMEA10wt%; PEG (200) DMA10wt%, soluble polyurethane acrylate 10wt%, water-soluble modified acrylate 5wt%; 1-hydroxy-cyclohexyl-phenyl ketone 5wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 5wt%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%, EFKA40101wt%; adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X4 includes following components and content:
Soluble epoxide acrylate 15wt%; oil-in-water urethane acrylate 5wt%; water-soluble polyester acrylate 10wt%; PET5EO4A5wt%; PEG (600) DMA15wt%; white pearlescent powder 10wt%; titanium dioxide 2wt%; 1-hydroxy-cyclohexyl-phenyl ketone 2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%, adhesion promoter 1wt%; TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether 5wt%, pure water 25wt%.
Aqueous radiation curable coating X6 includes following components and content:
Fluosilicic modified soluble acrylate 15wt%; fluorine richness water-soluble acrylic ester copolymer 25wt%; PEG (600) DMA15wt%; PHEA10wt%, flatting silica 3.5wt%, aqueous delustring slurry 15wt%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK1900.3wt%, TEGO4500.2wt%, BYK3480.3wt%, ethanol 10wt%.
Aqueous radiation curable coating X7 includes following components and content:
Aqueous polyurethane acrylate copolymer 1 0wt%; organic-silicon-modified water-soluble acrylic ester copolymer 20wt%; DPGDA10wt%; PHEA5wt%; titanium dioxide 30wt%, ultramarine blue powder 5wt%, 1-hydroxy-cyclohexyl-phenyl ketone 4wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 4wt%, dispersant WD2642wt%, ethanol 5wt%, pure water 5wt%.
Wherein, it is 500 microns that the degree of depth of priming coat is strengthened in the infiltration of decorative panel 1, the thickness of seal coat is 0.001 micron, the thickness of white seal coat is 500 microns, the thickness of ground floor attachment primer is 200 microns, and it is 500 microns that white closes coating layer thickness, and the thickness of second layer attachment primer is 0.001 micron, the thickness of colored paint layer is 30 microns, the thickness of top coat layer 0.001 micron.
The preparation method of decorative panel 1, comprises the following steps:
nullInorganic board is carried out fixed thick sanding、Dedusting，Surface roller coating one layer in inorganic board permeates strengthens primary coat X1，The pipeline entering linear velocity 15 ms/min is carried 1 minute，Enter back into benefit soil machine and mend soil X2，Enter linear velocity 15 ms/min、The uv cure machine of the mono-mercury lamp of 7.2KW，Semi-solid preparation，Close its external coating one layer again and be coated with X3，Enter linear velocity 15 ms/min、The uv cure machine of the double; two gallium lamp of 9.6KW，Solidify，Sanding、Dedusting，Primer X4 is adhered to again at its external coating ground floor，Enter linear velocity 10 ms/min、The mono-mercury lamp uv cure machine of 9.6KW，Semi-solid preparation，X3 is closed again in its external coating white，Enter linear velocity 15 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、The uv cure machine of mercury lamp，Solidify，Sanding、Dedusting，Primer X4 is adhered to again at its external coating second layer，Enter linear velocity 15 ms/min、11.2KW the uv cure machine of double; two mercury lamps，Semi-solid preparation，Its external coating X5 again，Enter linear velocity 15 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、Uv cure machine，Semi-solid preparation，Again at its external coating finish paint X6，Enter linear velocity 15 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、Mercury lamp、The uv cure machine of mercury lamp，Solidify，Testing、Pasting protective film，Namely become: the lurid decorative panel of aqueous radiation curable coating.
The light yellow decorative panel 3 of embodiment 3 aqueous radiation curable coating
Decorative panel 3 includes cement fibrolite plate and is coated with the infiltration reinforcement primary coat being contained in cement fibrolite plate surface successively, closes and is coated with, and ground floor attachment primer, white primary coat, the second layer adheres to primer, colored paint, finish paint.
Wherein primary coat, closing painting, white primary coat, ground floor attachment primer, the second layer attachment primer, colored paint, finish paint are strengthened in infiltration, comprise respectively successively: aqueous radiation curable coating X1, X2, X8, X3, X3, X5, X9.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino acrylates 10wt%, double; two (2; 4,6-trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethanol 21wt%, pure water 20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate 10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2-hydroxy-2-methyl-1-acetone 5wt%, EFKA40103wt%, ethanol 1wt%, pure water 1wt%, PUR4010wt%, Pulvis Talci 5wt%, A805wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%; HMEA10wt%; PEG (200) DMA10wt%, soluble polyurethane acrylate 10wt%, water-soluble modified acrylate 5wt%; 1-hydroxy-cyclohexyl-phenyl ketone 5wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 5wt%, double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%, EFKA40101wt%; adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X5 includes following components and content:
Aqueous polyurethane acrylate copolymer 20wt%; organic-silicon-modified water-soluble acrylic ester copolymer 20wt%; DPGDA10wt%; PHEA5wt%; titanium dioxide 20wt%, iron oxide yellow 5wt%, 1-hydroxy-cyclohexyl-phenyl ketone 4wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 4wt%, dispersant WD2642wt%, ethanol 5wt%, pure water 5wt%.
Aqueous radiation curable coating X8 includes following components and content:
Soluble epoxide acrylate 15wt%; oil-in-water urethane acrylate 5wt%; water-soluble polyester acrylate 10wt%; PET5EO4A5wt%; PEG (600) DMA15wt%; titanium dioxide 12wt%; 1-hydroxy-cyclohexyl-phenyl ketone 2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%; double; two (2.4.6-trimethylbenzoyl)-phenyl phosphine oxide 1wt%; adhesion promoter 1wt%, TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether 5wt%, pure water 25wt%.
Aqueous radiation curable coating X9 includes following components and content:
Fluosilicic modified soluble acrylate 23.5wt%; fluorine richness water-soluble acrylic ester copolymer 25wt%; PEG (600) DMA15wt%; PHEA10wt%; 1-hydroxy-cyclohexyl-phenyl ketone 3.2wt%; 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK1900.3wt%, TEGO4500.2wt%, BYK3480.3wt%, ethanol 20wt%.
Wherein, it is 200 microns that the degree of depth of priming coat is strengthened in the infiltration of decorative panel 1, the thickness of seal coat is 10 microns, the thickness of white seal coat is 80 microns, the thickness of ground floor attachment primer is 12 microns, and it is 90 microns that white closes coating layer thickness, and the thickness of second layer attachment primer is 10 microns, the thickness of light yellow coating is 30 microns, the thickness of top coat layer 50 microns；
The preparation method of decorative panel 1, comprises the following steps:
nullInorganic board is carried out fixed thick sanding、Dedusting，Surface roller coating one layer in inorganic board permeates strengthens primary coat X1，The pipeline entering linear velocity 15 ms/min is carried 1 minute，Enter back into benefit soil machine and mend soil X2，Enter linear velocity 15 ms/min、The uv cure machine of the mono-mercury lamp of 7.2KW，Semi-solid preparation，Close its external coating one layer again and be coated with X3，Enter linear velocity 15 ms/min、The uv cure machine of the double; two gallium lamp of 9.6KW，Solidify，Sanding、Dedusting，Primer X4 is adhered to again at its external coating ground floor，Enter linear velocity 10 ms/min、The mono-mercury lamp uv cure machine of 9.6KW，Semi-solid preparation，X3 is closed again in its external coating white，Enter linear velocity 15 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、The uv cure machine of mercury lamp，Solidify，Sanding、Dedusting，Primer X4 is adhered to again at its external coating second layer，Enter linear velocity 15 ms/min、11.2KW the uv cure machine of double; two mercury lamps，Semi-solid preparation，Its external coating X5 (10 microns) again，Enter linear velocity 15 ms/min、11.2KW gallium lamp、The uv cure machine of gallium lamp，Semi-solid preparation，Again at its external coating X5 (10 microns)，Enter linear velocity 15 ms/min、11.2KW gallium lamp、The uv cure machine of gallium lamp，Semi-solid preparation，Again at its external coating X5 (10 microns)，Enter linear velocity 15 ms/min、11.2KW gallium lamp、The uv cure machine of gallium lamp，Semi-solid preparation，(three total coating thicknesses: 30 microns) are again at its external coating finish paint X6，Enter linear velocity 15 ms/min、16.8KW gallium lamp、Gallium lamp、Ferrum lamp、Mercury lamp、The uv cure machine of mercury lamp，Solidify，Testing、Pasting protective film，Namely become: the lurid decorative panel of aqueous radiation curable coating.
It addition, the component of the radiation curing negative ion paint of the decorative panel use of the present invention and weight/mass percentage composition can also represent by the form of form, specifically include:
In sum, the aqueous radiation curable coating decorative panel of the present invention, there is good pattern and color representation power, the smooth densification in surface, manufacturing process is simple, it is adaptable to batch production, and good environmental protection.
It should be noted that, in this article, term " includes ", " comprising " or its any other variant are intended to comprising of nonexcludability, so that include the article of a series of key element or equipment not only includes those key elements, but also include other key elements being not expressly set out, or also include the key element intrinsic for this article or equipment.When there is no more restriction, statement " including ... " key element limited, it is not excluded that there is also other identical element in the article including key element or equipment.
The present invention only in order to technical scheme to be described and unrestricted, has been described in detail by above example reference only to preferred embodiment.It will be understood by those within the art that, it is possible to technical scheme is modified or equivalent replacement, without deviating from the spirit and scope of technical solution of the present invention, all should be encompassed in the middle of scope of the presently claimed invention.
Claims (10)
1. aqueous radiation curable coating decorative panel, it is characterised in that including inorganic board and painting is contained in the finish paint on described inorganic board surface, wherein said finish paint comprises aqueous radiation curable coating, and described aqueous radiation curable coating comprises following components and constituent content:
2. aqueous radiation curable coating decorative panel as claimed in claim 1, it is characterised in that described aqueous radiation curable coating also comprises following components and constituent content:
Pigment 0～35wt%；
Filler 0～30wt%；
Auxiliary agent 0～5wt%.
3. aqueous radiation curable coating decorative panel as claimed in claim 1, it is characterised in that described aqueous radiation curable coating also comprises following components and constituent content:
4. aqueous radiation curable coating decorative panel as claimed in claim 1, it is characterised in that
Described decorative panel also includes being coated with successively the infiltration on the surface being contained in described inorganic board and strengthens primary coat, close and be coated with and/or white closing painting, ground floor attachment primer, white primary coat and/or white are closed and are coated with and second layer attachment primer, primary coat is strengthened in wherein said infiltration, described closing is coated with and/or white closing painting, described ground floor attachment primer, and the primary coat of described white and/or white closing painting and described second layer attachment primer are respectively positioned between the surface of described inorganic board and described finish paint；
Described infiltration strengthen primary coat, described closing be coated with and/or white close be coated with, described white primary coat and/or white close be coated with, described attachment primer comprise described aqueous radiation curing material.
5. aqueous radiation curable coating decorative panel as claimed in claim 4, it is characterised in that
Described decorative panel also includes being coated with attachment primer described in the transfer film on surface being contained in described inorganic board and third layer successively, wherein said transfer film patch is imprinted between described second layer attachment primer and described third layer attachment primer, adheres to primer painting and be contained between described transfer film and described finish paint described in third layer.
6. aqueous radiation curable coating decorative panel as claimed in claim 4, it is characterised in that
Described decorative panel also includes the colored paint being coated with the surface being contained in described inorganic board, and described colored paint is coated with and is contained between described second layer attachment primer and described finish paint, and described colored paint comprises described aqueous radiation curable coating.
7. aqueous radiation curable coating decorative panel as claimed in claim 1, it is characterised in that
Described inorganic board includes cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite board, plasterboard.
8. aqueous radiation curable coating decorative panel as claimed in claim 4, it is characterised in that
The application thickness that primary coat is strengthened in described infiltration is 0.001～500 micron；The described application thickness closing painting or white closing painting is 0.001～500 micron, and described ground floor attachment primer and the described second layer adhere to the application thickness of primer and be 0.001～200 micron, and the application thickness of described finish paint is 0.001～500 micron.
9. the preparation method of the aqueous radiation curable coating decorative panel as described in claim 5 or 6, it is characterised in that comprise the following steps:
nullPrimary coat is strengthened in infiltration described in the external coating of inorganic board，Painting is closed in closing painting and/or white described in the external coating of infiltration reinforcement primary coat，Solidify，Formed to close and be coated with and/or white seal coat，It is coated with and/or attachment primer described in white seal coat external coating closing，Solidify，Form described ground floor attachment primer，White primary coat described in primer external coating and/or white closing painting is adhered at described ground floor，Solidify，Form white primary coat and/or white seal coat，At white primary coat and/or the white seal coat surface described attachment primer of application one layer again，Solidify，Form described second layer attachment primer，Colored paint described in primer external coating is adhered at the described second layer，Solidify，Form colored paint layer，At finish paint described in colored paint layer external coating，Solidify，Form top coat layer，And then form described aqueous radiation curable coating decorative panel；Or
nullPrimary coat is strengthened in infiltration described in the external coating of inorganic board，Described in the external coating that infiltration reinforcement is coated with, close painting and/or white closing is coated with，Solidify，Formed to close and be coated with and/or white seal coat，Closing painting and/or the described attachment primer of external coating one layer of white seal coat，Solidify，Form described ground floor attachment primer，White primary coat described in primer external coating and/or white closing painting is adhered at described ground floor，Solidify，Form white primary coat and/or white seal coat，The surface described attachment primer of application one layer again in white primary coat and/or white seal coat，Solidify，Form described second layer attachment primer，One layer of transfer film of surface laminating of primer is adhered at the described second layer，Solidify，Remove the base load film of described transfer film，Form transfer rete，At the transfer film surface described attachment primer of application one layer again，Solidify，Form third layer attachment primer，At finish paint described in the external coating of described third layer attachment primer，Solidify，Form top coat layer，And then form described aqueous radiation curable coating decorative panel.
10. the preparation method that profit requires the aqueous radiation curable coating decorative panel described in 9, it is characterised in that described preparation method is further comprising the steps of:
After described in application, primary coat is strengthened in infiltration, closing described in application is coated with and/or white is closed before being coated with, and carries out benefit soil, solidifies；Before primary coat is strengthened in infiltration described in application, carry out fixed thick sanding, dedusting；Before ground floor attachment primer described in application and described second layer attachment primer, all carry out sanding, dedusting.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3336067A1 (en) * | 2016-12-19 | 2018-06-20 | Eternit GmbH | Coated fiber cement products and methods for the production thereof |
| EP3875552A1 (en) * | 2020-03-04 | 2021-09-08 | Lambson Limited | Photoinitiator emulsions |
| US12351659B2 (en) | 2020-03-04 | 2025-07-08 | Arkema France | Curable composition comprising a photoinitiator |
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| CN103774816A (en) * | 2014-01-08 | 2014-05-07 | 珠海市佳伟力环保科技有限公司 | Radiation cured colored decorative sheet |
| CN104927632A (en) * | 2015-07-01 | 2015-09-23 | 卓达新材料科技集团有限公司 | Xanthochromia-resistant UV paint for external wall sheet material and preparation method of xanthochromia-resistant UV paint |
| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
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| JPS5217516A (en) * | 1975-06-28 | 1977-02-09 | Dainippon Toryo Co Ltd | Preparation of decorative laminate |
| CN103774816A (en) * | 2014-01-08 | 2014-05-07 | 珠海市佳伟力环保科技有限公司 | Radiation cured colored decorative sheet |
| CN104989045A (en) * | 2014-12-29 | 2015-10-21 | 中关村人居环境工程与材料研究院 | Ultraviolet curing transfer-printing high-gloss decoration plate and manufacturing method thereof |
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| EP3336067A1 (en) * | 2016-12-19 | 2018-06-20 | Eternit GmbH | Coated fiber cement products and methods for the production thereof |
| WO2018114847A1 (en) * | 2016-12-19 | 2018-06-28 | Eternit Gmbh | Coated fiber cement products and methods for the production thereof |
| RU2762053C2 (en) * | 2016-12-19 | 2021-12-15 | Этернит ГмбХ | Coated fiber cement products and their manufacture methods |
| EP3875552A1 (en) * | 2020-03-04 | 2021-09-08 | Lambson Limited | Photoinitiator emulsions |
| WO2021176021A1 (en) * | 2020-03-04 | 2021-09-10 | Lambson Limited | Photoinitiator emulsions |
| US12351659B2 (en) | 2020-03-04 | 2025-07-08 | Arkema France | Curable composition comprising a photoinitiator |
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| CN105802482B (en) | 2018-12-25 |
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