CN105802482B - Aqueous radiation curable coating decorative panel and preparation method thereof - Google Patents
Aqueous radiation curable coating decorative panel and preparation method thereof Download PDFInfo
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- CN105802482B CN105802482B CN201610173345.6A CN201610173345A CN105802482B CN 105802482 B CN105802482 B CN 105802482B CN 201610173345 A CN201610173345 A CN 201610173345A CN 105802482 B CN105802482 B CN 105802482B
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- layer
- primer
- radiation curable
- coat
- acrylate
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- 239000011425 bamboo Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000011365 complex material Substances 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- HNMCSUXJLGGQFO-UHFFFAOYSA-N hexaaluminum;hexasodium;tetrathietane;hexasilicate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].S1SSS1.S1SSS1.[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] HNMCSUXJLGGQFO-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- WKGDNXBDNLZSKC-UHFFFAOYSA-N oxido(phenyl)phosphanium Chemical compound O=[PH2]c1ccccc1 WKGDNXBDNLZSKC-UHFFFAOYSA-N 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0866—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements composed of several layers, e.g. sandwich panels or layered panels
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0871—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having an ornamental or specially shaped visible surface
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides aqueous radiation curable coating decorative panels and preparation method thereof, including inorganic board and it is painted on the finishing coat of inorganic plate surface, wherein finishing coat includes aqueous radiation curable coating, and aqueous radiation curable coating includes following components and constituent content: 1~40wt% of acrylate monomer；Water-soluble acrylic ester prepolymer, organic silicon modified aqueous acrylate polymer, oil-in-water acrylic ester prepolymer lotion one or more 30~50wt%；3~8wt% of photoinitiator；One or more 2~41wt% of water or alcoholic solvent.Aqueous radiation curable coating decorative panel of the invention has good pattern and color representation power, and smooth surface is fine and close, has both good antibacterial, anti-pollution, anti-scratch, waterproof, mould proof, heat resistance, can be widely applied to all kinds of decorative environments；Manufacturing process is simple, is suitable for batch production, and the feature of environmental protection, good energy saving property.
Description
Technical field
The present invention relates to aqueous radiation curable coating decorative panels and preparation method thereof.
Background technique
Currently, as increasing increasingly for skyscraper is increasingly luxurious with various interior decorations, ring of the country to building
The requirements such as guarantor, energy conservation and fire prevention are also higher and higher, and therefore, various heat-preserving complex materials, fire proofing material occur in succession, mainly have
Fiber reinforced cement board, fiber reinforced calcium silicate board, fiber reinforcement magnesium oxide plate, lightweight chloro-magnesium cement plate, magnesite board, plasterboard
Deng as exterior wall or inner wall decoration.
Currently, universal construction technology is after first installing decorative board for wall, then with aqueous latex paint its surface into
Row coating needs the multiple tracks technique such as puttying, priming and finishing coat, especially high-building construction difficult, and the period is long, cost
Therefore height is badly in need of a kind of apply and is installed, environmentally friendly degree high decorative board for wall, to shorten construction period, reduce difficulty of construction.Separately
Very environmentally friendly and efficiency is very high in the production and processing and use process of outer aqueous radiation curable coating, energy consumption is very low, very
Meet energy-saving and emission-reduction.
Summary of the invention
In view of the above-mentioned problems, the object of the present invention is to provide aqueous radiation curable coating decorative panels and preparation method thereof.
According to an aspect of the present invention, aqueous radiation curable coating decorative panel is provided, including inorganic board and is painted on
The finishing coat of inorganic plate surface, wherein finishing coat include aqueous radiation curable coating, aqueous radiation curable coating include following components and
Constituent content:
Wherein, aqueous radiation curable coating also includes following components and constituent content:
0~35wt% of pigment；
0~30wt% of filler；
0~5wt% of auxiliary agent.
Wherein, aqueous radiation curable coating also includes following components and constituent content:
Wherein, decorative panel further includes the infiltration reinforcement primary coat for being successively painted on the surface of inorganic board, and closing applies and/or white
Closing applies, and first layer adheres to primer, and white primary coat and/or white closing apply and the second layer adheres to primer, wherein infiltration is reinforced
Primary coat, closing applies and/or white is closed and applied, and first layer adheres to primer, white primary coat and/or white closing painting and the second layer is attached
Primer be located between the surface and finishing coat of inorganic board；
Infiltration reinforcement primary coat, closing apply and/or white closing painting, white primary coat and/or white closing apply, adhere to primer packet
Property of water-bearing radiation curing material.
Wherein, decorative panel further includes the transfer film and third layer attachment primer for being successively painted on the surface of inorganic board, wherein
Transfer film layer patch is imprinted on the second layer attachment primer and third layer attachment primer between, third layer attachment primer be painted on transfer film and
Between finishing coat.
Wherein, decorative panel further includes the colored paint for being painted on the surface of inorganic board, colored paint be painted on second layer attachment primer and
Between finishing coat, colored paint includes aqueous radiation curable coating.
Wherein, inorganic board includes cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite board, plasterboard.
Wherein, infiltration reinforces the coating of primary coat with a thickness of 0.001~500 micron；The coating that closing applies or white closing applies
With a thickness of 0.001~500 micron, it is 0.001~200 micro- that first layer, which adheres to primer and the coating thickness of second layer attachment primer,
Rice, the coating of finishing coat is with a thickness of 0.001~500 micron.
Wherein, water-soluble acrylic ester prepolymer includes soluble epoxide acrylate, aqueous polyurethane acrylate, water
Property unsaturated polyester (UP) acrylate, aqueous amino acrylates, water-borne acrylate copolymer, fluorine modified aqueous acrylate it is total
One of polymers is a variety of.
Wherein, acrylate monomer includes butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer, acrylic acid hydroxyl second
Ester, hydroxyethyl methacrylate, ethoxylated bisphenol A dimethylacrylate, tri (propylene glycol) diacrylate, dipropylene glycol
Diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, phthalic acid are bis- (diethylene glycol)
Diacrylate, three (2- ethoxy) isocyanuric acid triacrylates, 1,6 hexanediyl esters, trimethylolpropane tris
Acrylate, 2- phenoxyethyl acrylate, ethoxyquin trimethylolpropane trimethacrylate, the third oxidation trimethylolpropane
Triacrylate, pentaerythritol triacrylate, dipentaerythritol hexaacrylate, 2- hydroxyethyl methacrylate phosphoric acid
Ester, polyethylene glycol (600) dimethylacrylate, triethylene glycol dimethacrylate, polyethylene glycol (200) dimethyl allene
Acid esters, ethoxyquin pentaerythritol tetraacrylate, dioxy Lu Huan omega-diol diacrylate, the third oxidation neopentylglycol diacrylate
One of or it is a variety of.
Wherein, organic-silicon-modified water-soluble acrylic ester polymer includes organic silicon modified aqueous polyester acrylate, has
The silicon modified aqueous amino acrylates of machine, organic silicon modified aqueous acrylate copolymer, organic silicon modified aqueous propylene oxide
One of acid esters, fluosilicic modified aqueous acrylic acid ester copolymer, organic silicon modified aqueous polyurethane acrylate are a variety of.
Wherein, oil-in-water acrylic ester prepolymer lotion includes oil-in-water Epoxy-Acrylate Emulsion, oil-in-water
Polyurethane-acrylate emulsion, oil-in-water polyester acrylate lotion, oil-in-water amino acrylates, oil-in-water acrylic acid
One of ester copolymer is a variety of.
Wherein, photoinitiator includes benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzil diformazan
Base ketal, from acetophenone, 2,2- dimethoxy -2- phenyl acetophenone, 2,2- diethoxy -2- phenyl acetophenone, 1,1- dichloro
Acetophenone, 1- hydroxy acetophenone, 1- hydroxy-cyclohexyl phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone, (4- is different by 1-
Propyl phenyl) -2- hydroxy-2-methyl -1- acetone, 1- [4- (2- hydroxyl-oxethyl) phenyl] -2- hydroxy-2-methyl -1- acetone,
2- methyl-1-[4- (methyl mercapto) phenyl]-2- morpholinyl-1- acetone, 2- benzyl-2- dimethylamino-1- (4- morpholinyl benzene
Base) -1- butanone, 2- tert-butyl anthraquinone, 1- chloroanthraquinone, 2- amyl anthraquinone, 2,4- dimethyl thioxanthone, 2,4- diethyl thia
Anthrone, 2- isopropyl thioxanthone, 4- isopropyl thioxanthone, 2- chloro thioxanthone, 2,4- diisopropyl thioxanthone, two
Benzophenone, 4- chlorobenzophenone, to methyl benzophenone, 4- benzoyl -4 '-dimethyl diphenyl sulfide, 2,4,6- trimethyl
Benzoyl diphenyl phosphine oxide, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxides, two (2,6- dimethyl phenacyls
Base) -2,4,4- trimethylpentylphosphine oxide, 2,4,6- trimethylbenzoyl phenyl ethyoxyls phosphine oxide, benzoylbenzoic acid
One of methyl esters, methyl o-benzoylbenzoate are a variety of.
Wherein, pigment includes titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue powder, ultramarine green powder, phthalocyanine blue
Powder, the green powder of the phthalein mountain valley with clumps of trees and bamboo, brown chrome yellow powder, organic pigment scarlet powder, organic bloom, green organic powder, aqueous Cu-Zn alloy powder, water aluminum-silver slurry powder,
One of pearl powder is a variety of.
Wherein, filler includes one of kaolin, flatting silica, aqueous delustring slurry, abrasion-resistant powder or a variety of.
Wherein, auxiliary agent includes thickener, levelling agent, substrate wetting agents, defoaming agent, wetting dispersing agent, adhesion promoter,
One of ultraviolet absorbing agent is a variety of.
Wherein, thickener includes: one or both of PUR40, fumed silica；Levelling agent include: BYK348,
One of BYK308N, CF736W or a variety of；, substrate wetting agents include: one of BYK190, CU190W, CJ60W, A80
Or it is a variety of；Defoaming agent includes: one of BYK028, CD761SW, TEGO450 or a variety of；Wetting dispersing agent include BYK190,
One of CU190W, CJ60W, WD264 or a variety of；Ultraviolet absorbing agent include one of 5050,5151,951,3310 or
It is a variety of.
Other side according to the present invention provides the preparation method of aqueous radiation curable coating decorative panel, including
Following steps:
Inorganic board external coating infiltration reinforce primary coat, infiltration reinforce primary coat external coating closing apply and/or it is white
Color closing applies, solidification, and formation closing applies and/or white seal coat, attached in closing painting and/or white seal coat external coating
Primer, solidification, formed first layer adhere to primer, first layer adhere to the primary coat of primer external coating white and/or white closing
It applies, solidification, forms white primary coat and/or white seal coat, in white primary coat and/or white seal coat surface coating one again
Layer attachment primer, solidification form the second layer and adhere to primer, adhere to primer external coating colored paint in the second layer, solidification forms colored paint
Layer, in colored paint layer surface coating finish, solidification forms top coat layer, and then forms aqueous radiation curable coating decorative panel；Or
In the external coating infiltration reinforcement primary coat of inorganic board, reinforce the external coating applied closing painting and/or white in infiltration
Closing applies, solidification, and formation closing applies and/or white seal coat, in closing painting and/or the external coating one of white seal coat
Layer attachment primer, solidification form first layer and adhere to primer, adhere to the primary coat of primer external coating white and/or white in first layer
Closing applies, solidification, forms white primary coat and/or white seal coat, the surface of white primary coat and/or white seal coat again
One layer of attachment primer of secondary coating, solidification form the second layer and adhere to primer, are bonded one layer of transfer on the surface of second layer attachment primer
Film, solidification remove the base load film of transfer film, form transfer film layer, are transferring film surface one layer of attachment primer of coating again, Gu
Change, form third layer and adhere to primer, in the external coating finishing coat of third layer attachment primer, solidification forms top coat layer, and then formed
Aqueous radiation curable coating decorative panel.
Wherein, preparation method is further comprising the steps of:
After reinforcement primary coat is permeated in coating, before painting and/or white closing painting are closed in coating, mend native, solidification；
Before reinforcement primary coat is permeated in coating, fixed thick sanding, dedusting are carried out；Adhere to primer in coating first layer and the second layer adheres to primer
Before, progress sanding, dedusting.
Wherein, it is cured as ultraviolet light or electronic beam curing, wherein the solidification power of ultraviolet light is 2~50KW, ultraviolet light
0.2~50 m/min of curing rate.
Wherein, water-soluble acrylic ester prepolymer, acrylate monomer, organic silicon modified aqueous acrylate polymer,
Oil-in-water acrylic ester prepolymer lotion and photoinitiator are main film forming matter；In the present invention, by using water as molten
Liquid cooperates specific film forming matter, and passes through water, alcoholic solution and organic silicon modified aqueous acrylate polymer and oil-in-water
Property the components such as acrylic ester prepolymer lotion rational proportion, the radiation curable coating of environmental protection is made, and applied inorganic
On plate, so that the water paint forms fine and close, aqueous spokes with rich colors, with defencive function in inorganic board
Penetrate solidify coating.
Aqueous radiation curable coating decorative panel of the invention, has good pattern and color representation power, and smooth surface causes
It is close, good antibacterial, anti-pollution, anti-scratch, waterproof, mould proof, heat resistance are had both, can be widely applied to all kinds of decorative environments；Manufacture
Simple process is suitable for batch production, and the feature of environmental protection, good energy saving property.
Specific embodiment
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention,
Technical solution of the present invention is clearly and completely described, it is clear that described embodiment is that a part of the invention is implemented
Example, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creativeness
Every other embodiment obtained, shall fall within the protection scope of the present invention under the premise of labour.It should be noted that not conflicting
In the case where, the features in the embodiments and the embodiments of the present application can mutual any combination.
Radiation curing negative ion paint provided by the invention will be explained in detail by way of specific embodiment below.
The decorative panel 1 of the aqueous radiation curable coating walnut pattern of embodiment 1
Decorative panel 1 includes cement fibrolite plate and the infiltration reinforcement primary coat for being successively painted on Cement fibre plate surface, closing
Coating, first layer adhere to primer, white primary coat, and the second layer adheres to primer, transfer film, and third layer adheres to primer, finishing coat.
Wherein primary coat, seal coat, first layer attachment primer, white primary coat are reinforced in infiltration, and the second layer adheres to primer, third
Layer attachment primer, finishing coat, successively include aqueous radiation curable coating X1, X2, X3, X4, X3, X3, X6.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino
Acrylate 10wt%, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethyl alcohol 21wt%, pure water
20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate
10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2- hydroxy-2-methyl -1- acetone 5wt%,
EFKA40103wt%, ethyl alcohol 1wt%, pure water 1wt%, PUR4010wt%, talcum powder 5wt%, A805wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%, HMEA10wt%, PEG (200) DMA10wt%, soluble polyurethane third
Olefin(e) acid ester 10wt%, water-soluble modified acrylate 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 5wt%, 2.4.6 (trimethyl
Benzoyl group) diphenyl phosphine oxide 5wt%, bis- (2.4.6- trimethylbenzoyl)-phenyl phosphine oxide 1wt%, EFKA4010
1wt%, adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X4 includes following components and content:
Soluble epoxide acrylate 15wt%, oil-in-water urethane acrylate 5wt%, water-soluble polyester acrylic acid
Ester 10wt%, PET5EO4A5wt%, PEG (600) DMA15wt%, white pearlescent powder 10wt%, titanium dioxide 2wt%, 1- hydroxyl-
Cyclohexyl-phenyl ketone 2wt%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, bis- (2.4.6- trimethylbenzene first
Acyl group)-phenyl phosphine oxide 1wt%, adhesion promoter 1wt%, TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether
5wt%, pure water 25wt%.
Aqueous radiation curable coating X6 includes following components and content:
Fluosilicic modified soluble acrylate 15wt%, fluorine richness water-soluble acrylic ester copolymer 25wt%, PEG
(600) 15wt%, 1- hydroxy-cyclohexyl-phenyl first are starched in DMA15wt%, PHEA10wt%, flatting silica 3.5wt%, aqueous delustring
Ketone 3.2wt%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK1900.3wt%,
TEGO4500.2wt%, BYK3480.3wt%, ethyl alcohol 10wt%.
Wherein, it is 150 microns that the depth of priming coat is reinforced in the infiltration of decorative panel 1, seal coat with a thickness of 50 microns, the
One layer of attachment primer with a thickness of 0.001 micron, white bottom coating layer with a thickness of 50 microns, the second layer adhere to primer with a thickness of
200 microns, third layer adhere to primer with a thickness of 200 microns, 10 microns of the thickness of top coat layer.
The preparation method of decorative panel 1, comprising the following steps:
Fixed thick sanding, dedusting are carried out to inorganic board, reinforce primary coat X1 in one layer of infiltration of surface roller coating of inorganic board, into line
The pipeline that 10 ms/min of speed conveys 1 minute, then applies X2 in the one layer of closing of its external coating, into 10 ms/min of linear velocity
The uv cure machine of the bis- mercury lamps of clock, 9.6KW, solidification, sanding, dedusting, then adhere to primer X3 in its external coating first layer, into
Enter the mono- mercury lamp uv cure machine of 10 ms/min of linear velocity, 9.6KW, semi-solid preparation, then in its external coating white primary coat X4, into
Enter 10 ms/min of linear velocity, 11.2KW gallium lamp, gallium lamp, mercury lamp, mercury lamp uv cure machine, solidification, sanding, dedusting, then
Its external coating second layer adheres to primer X3, solid into 10 ms/min of linear velocity, the uv cure machine of the bis- mercury lamps of 9.6KW, half
Change, then its surface using with gum X3 transfer interpreter fitting walnut pattern transfer film X5, into 10 ms/min of linear velocity,
16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp uv cure machine, solidification removes base load film, then attached in its external coating third
Primer layer X3, into the uv cure machine of 10 ms/min of linear velocity, 11.2KW gallium lamp, gallium lamp, semi-solid preparation, then in its table
Face coating finish X6, the ultraviolet light into 10 ms/min of linear velocity, 16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp, mercury lamp solidify
Machine, solidification, test, pasting protective film, are as follows: the decorative panel of aqueous radiation curable coating walnut pattern.
The light blue decorative panel 2 of the aqueous radiation curable coating of embodiment 2
Decorative panel 2 includes cement fibrolite plate and the infiltration reinforcement primary coat for being successively painted on Cement fibre plate surface, closing
It applies, white closing applies, and first layer adheres to primer, and white closing applies, and the second layer adheres to primer, colored paint layer, top coat layer.
Wherein primary coat is reinforced in infiltration, closing applies, white closing applies, first layer attachment primer, the second layer adhere to primer, color
Paint, finishing coat, successively separately include: aqueous radiation curable coating X1, X2, X3, X4, X4, X7, X6.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino
Acrylate 10wt%, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethyl alcohol 21wt%, pure water
20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate
10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2- hydroxy-2-methyl -1- acetone 5wt%,
EFKA40103wt%, ethyl alcohol 1wt%, pure water 1wt%, PUR4010wt%, talcum powder 5wt%, A80 5wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%, HMEA10wt%, PEG (200) DMA10wt%, soluble polyurethane third
Olefin(e) acid ester 10wt%, water-soluble modified acrylate 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 5wt%, 2.4.6 (trimethyl
Benzoyl group) diphenyl phosphine oxide 5wt%, bis- (2.4.6- trimethylbenzoyl)-phenyl phosphine oxide 1wt%,
EFKA40101wt%, adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X4 includes following components and content:
Soluble epoxide acrylate 15wt%, oil-in-water urethane acrylate 5wt%, water-soluble polyester acrylic acid
Ester 10wt%, PET5EO4A5wt%, PEG (600) DMA15wt%, white pearlescent powder 10wt%, titanium dioxide 2wt%, 1- hydroxyl-
Cyclohexyl-phenyl ketone 2wt%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, bis- (2.4.6- trimethylbenzene first
Acyl group)-phenyl phosphine oxide 1wt%, adhesion promoter 1wt%, TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether
5wt%, pure water 25wt%.
Aqueous radiation curable coating X6 includes following components and content:
Fluosilicic modified soluble acrylate 15wt%, fluorine richness water-soluble acrylic ester copolymer 25wt%, PEG
(600) 15wt%, 1- hydroxy-cyclohexyl-phenyl first are starched in DMA15wt%, PHEA10wt%, flatting silica 3.5wt%, aqueous delustring
Ketone 3.2wt%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK1900.3wt%,
TEGO4500.2wt%, BYK3480.3wt%, ethyl alcohol 10wt%.
Aqueous radiation curable coating X7 includes following components and content:
Aqueous polyurethane acrylate copolymer 1 0wt%, organic-silicon-modified water-soluble acrylic ester copolymer 20wt%,
DPGDA10wt%, PHEA5wt%, titanium dioxide 30wt%, ultramarine blue powder 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 4wt%,
2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 4wt%, dispersing agent WD2642wt%, ethyl alcohol 5wt%, pure water 5wt%.
Wherein, decorative panel 1 infiltration reinforce priming coat depth be 500 microns, seal coat it is micro- with a thickness of 0.001
Rice, white seal coat with a thickness of 500 microns, first layer adhere to primer with a thickness of 200 microns, white closing coating layer is thick
Degree is 500 microns, the second layer adhere to primer with a thickness of 0.001 micron, colored paint layer with a thickness of 30 microns, the thickness of top coat layer
0.001 micron.
The preparation method of decorative panel 1, comprising the following steps:
Fixed thick sanding, dedusting are carried out to inorganic board, reinforce primary coat X1 in one layer of infiltration of surface roller coating of inorganic board, into line
The pipeline that 15 ms/min of speed conveys 1 minute, enters back into the native machine of benefit and mends soil X2, mono- into 15 ms/min of linear velocity, 7.2KW
The uv cure machine of mercury lamp, semi-solid preparation, then apply X3 in the one layer of closing of its external coating, into 15 ms/min of linear velocity,
The uv cure machine of the bis- gallium lamps of 9.6KW, solidification, sanding, dedusting, then adhere to primer X4 in its external coating first layer, enter
The mono- mercury lamp uv cure machine of 10 ms/min of linear velocity, 9.6KW, semi-solid preparation, then X3 is closed in its external coating white, enter
15 ms/min of linear velocity, 16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp uv cure machine, solidification, sanding, dedusting, then at it
The external coating second layer adheres to primer X4, solid into 15 ms/min of linear velocity, the uv cure machine of the bis- mercury lamps of 11.2KW, half
Change, then its external coating X5, into 15 ms/min of linear velocity, 16.8KW gallium lamp, gallium lamp, iron lamp, uv cure machine, partly
Solidification, then in its external coating finishing coat X6, into 15 ms/min of linear velocity, 16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp, mercury lamp
Uv cure machine, solidification, test, pasting protective film, are as follows: the aqueous lurid decoration of radiation curable coating
Plate.
The light yellow decorative panel 3 of the aqueous radiation curable coating of embodiment 3
Decorative panel 3 includes cement fibrolite plate and the infiltration reinforcement primary coat for being successively painted on Cement fibre plate surface, closing
It applies, first layer adheres to primer, white primary coat, and the second layer adheres to primer, colored paint, finishing coat.
Wherein primary coat is reinforced in infiltration, closing applies, white primary coat, first layer attachment primer, second layer attachment primer, colored paint,
Finishing coat successively separately includes: aqueous radiation curable coating X1, X2, X8, X3, X3, X5, X9.
Aqueous radiation curable coating X1 includes following components and content:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino
Acrylate 10wt%, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethyl alcohol 21wt%, pure water
20wt%.
Aqueous radiation curable coating X2 includes following components and content:
Water-soluble polyester acrylate 40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate
10wt%, TMPTA7wt%, EO-TMODA3wt%, HEMA2wt%, 2- hydroxy-2-methyl -1- acetone 5wt%,
EFKA40103wt%, ethyl alcohol 1wt%, pure water 1wt%, PUR4010wt%, talcum powder 5wt%, A805wt%.
Aqueous radiation curable coating X3 includes following components and content:
Soluble epoxide acrylate 20wt%, HMEA10wt%, PEG (200) DMA10wt%, soluble polyurethane third
Olefin(e) acid ester 10wt%, water-soluble modified acrylate 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 5wt%, 2.4.6 (trimethyl
Benzoyl group) diphenyl phosphine oxide 5wt%, bis- (2.4.6- trimethylbenzoyl)-phenyl phosphine oxide 1wt%,
EFKA40101wt%, adhesion promoter 3wt%, pure water 30wt%.
Aqueous radiation curable coating X5 includes following components and content:
Aqueous polyurethane acrylate copolymer 20wt%, organic-silicon-modified water-soluble acrylic ester copolymer 20wt%,
DPGDA10wt%, PHEA5wt%, titanium dioxide 20wt%, iron oxide yellow 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 4wt%,
2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 4wt%, dispersing agent WD2642wt%, ethyl alcohol 5wt%, pure water 5wt%.
Aqueous radiation curable coating X8 includes following components and content:
Soluble epoxide acrylate 15wt%, oil-in-water urethane acrylate 5wt%, water-soluble polyester acrylic acid
Ester 10wt%, PET5EO4A5wt%, PEG (600) DMA15wt%, titanium dioxide 12wt%, 1- hydroxy-cyclohexyl-phenyl ketone
2wt%, 2.4.6 (trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, bis- (2.4.6- trimethylbenzoyl)-phenyl oxidations
Phosphine 1wt%, adhesion promoter 1wt%, TEGO4501wt%, BYK0281wt%, propylene glycol monomethyl ether 5wt%, pure water
25wt%.
Aqueous radiation curable coating X9 includes following components and content:
Fluosilicic modified soluble acrylate 23.5wt%, fluorine richness water-soluble acrylic ester copolymer 25wt%, PEG
(600) DMA15wt%, PHEA10wt%, 1- hydroxy-cyclohexyl-phenyl ketone 3.2wt%, 2.4.6 (trimethylbenzene acyl group) two
Phenyl phosphine oxide 2.5wt%, BYK1900.3wt%, TEGO4500.2wt%, BYK3480.3wt%, ethyl alcohol 20wt%.
Wherein, decorative panel 1 infiltration reinforce priming coat depth be 200 microns, seal coat with a thickness of 10 microns, it is white
Color seal coat with a thickness of 80 microns, first layer adhere to primer with a thickness of 12 microns, white closing coating layer is with a thickness of 90
Micron, the second layer adhere to primer with a thickness of 10 microns, light yellow coating with a thickness of 30 microns, the thickness 50 of top coat layer is micro-
Rice；
The preparation method of decorative panel 1, comprising the following steps:
Fixed thick sanding, dedusting are carried out to inorganic board, reinforce primary coat X1 in one layer of infiltration of surface roller coating of inorganic board, into line
The pipeline that 15 ms/min of speed conveys 1 minute, enters back into the native machine of benefit and mends soil X2, mono- into 15 ms/min of linear velocity, 7.2KW
The uv cure machine of mercury lamp, semi-solid preparation, then apply X3 in the one layer of closing of its external coating, into 15 ms/min of linear velocity,
The uv cure machine of the bis- gallium lamps of 9.6KW, solidification, sanding, dedusting, then adhere to primer X4 in its external coating first layer, enter
The mono- mercury lamp uv cure machine of 10 ms/min of linear velocity, 9.6KW, semi-solid preparation, then X3 is closed in its external coating white, enter
15 ms/min of linear velocity, 16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp uv cure machine, solidification, sanding, dedusting, then at it
The external coating second layer adheres to primer X4, solid into 15 ms/min of linear velocity, the uv cure machine of the bis- mercury lamps of 11.2KW, half
Change, then its external coating X5 (10 microns), into the uv cure machine of 15 ms/min of linear velocity, 11.2KW gallium lamp, gallium lamp,
Semi-solid preparation, then at its external coating X5 (10 microns), into 15 ms/min of linear velocity, 11.2KW gallium lamp, the UV light of gallium lamp
Change machine, semi-solid preparation, then at its external coating X5 (10 microns), into the purple of 15 ms/min of linear velocity, 11.2KW gallium lamp, gallium lamp
Outer photo solidification machine, semi-solid preparation, (three times total coating thickness: 30 microns) again in its external coating finishing coat X6, into 15 meters of linear velocity/
Minute, 16.8KW gallium lamp, gallium lamp, iron lamp, mercury lamp, mercury lamp uv cure machine, solidification, test, pasting protective film, i.e.,
Become: the aqueous lurid decorative panel of radiation curable coating.
In addition, the component and mass percentage of the radiation curing negative ion paint that decorative panel of the invention uses can also be with
It is indicated, is specifically included with the form of table:
In conclusion aqueous radiation curable coating decorative panel of the invention, has good pattern and color representation power, table
Face is smoothly fine and close, and manufacturing process is simple, is suitable for batch production, and good environmental protection.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row
His property includes, so that including the article of a series of elements or equipment not only includes those elements, but also including not having
There is the other element being expressly recited, or further includes for this article or the intrinsic element of equipment.Do not limiting more
In the case where system, the element that is limited by sentence " including ... ", it is not excluded that also deposited in the article or equipment for including element
In other identical element.
The above examples are only used to illustrate the technical scheme of the present invention and are not limiting, reference only to preferred embodiment to this hair
It is bright to be described in detail.Those skilled in the art should understand that can modify to technical solution of the present invention
Or equivalent replacement should all cover in claim model of the invention without departing from the spirit and scope of the technical solution of the present invention
In enclosing.
Claims (1)
1. aqueous radiation curable coating decorative panel, which is characterized in that including cement fibrolite plate and be successively painted on Cement fibre
The infiltration reinforcement primary coat of plate surface, seal coat, first layer attachment primer, white primary coat, second layer attachment primer, transfer film,
Third layer adheres to primer, finishing coat；
Wherein primary coat, seal coat, first layer attachment primer, white primary coat are reinforced in infiltration, and it is attached that the second layer adheres to primer, third layer
Primer, finishing coat include aqueous radiation curable coating；
It includes following components and content that the aqueous radiation curable coating that primary coat is included is reinforced in the infiltration:
Soluble epoxide acrylate 1wt%, DPGDA15wt%, aqueous polyurethane acrylate 25wt%, aqueous amino propylene
Acid esters 10wt%, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxide 8wt%, ethyl alcohol 21wt%, pure water 20wt%；
The aqueous radiation curable coating that the seal coat is included includes following components and content: water-soluble polyester acrylate
40wt%, soluble polyurethane acrylate 8wt%, soluble epoxide acrylate 10wt%, TMPTA7wt%, EO-
It is TMODA3wt%, HEMA2wt%, 2- hydroxy-2-methyl -1- acetone 5wt%, EFKA4010 3wt%, ethyl alcohol 1wt%, pure
Water 1wt%, PUR40 10wt%, talcum powder 5wt%, A80 5wt%；
The aqueous radiation curable coating that the first layer attachment primer, second layer attachment primer, third layer attachment primer are included
Including following components and content: soluble epoxide acrylate 20wt%, HMEA10wt%, PEG200DMA10wt%, it is water-soluble
Urethane acrylate 10wt%, water-soluble modified acrylate 5wt%, 1- hydroxy-cyclohexyl-phenyl ketone 5wt%, (2,
4,6- trimethylbenzene acyl groups) diphenyl phosphine oxide 5wt%, bis- (2.4.6- trimethylbenzoyl)-phenyl phosphine oxide 1wt%,
EFKA4010 1wt%, adhesion promoter 3wt%, pure water 30wt%；
The aqueous radiation curable coating that the white primary coat is included includes following components and content:
Soluble epoxide acrylate 15wt%, oil-in-water urethane acrylate 5wt%, water-soluble polyester acrylate
10wt%, PET5EO4A5wt%, PEG600DMA15wt%, white pearlescent powder 10wt%, titanium dioxide 2wt%, 1- hydroxy-cyclohexan
Base-phenyl ketone 2wt%, (2,4,6- trimethylbenzene acyl group) diphenyl phosphine oxide 2wt%, bis- (2.4.6- trimethylbenzoyls
Base)-phenyl phosphine oxide 1wt%, adhesion promoter 1wt%, TEGO450 1wt%, BYK028 1wt%, propylene glycol monomethyl ether
5wt%, pure water 25wt%；
The aqueous radiation curable coating that the finishing coat is included includes following components and content:
Fluosilicic modified soluble acrylate 15wt%, fluorine richness water-soluble acrylic ester copolymer 25wt%,
15wt%, 1- hydroxy-cyclohexyl-phenyl are starched in PEG600DMA15wt%, PHEA10wt%, flatting silica 3.5wt%, aqueous delustring
Ketone 3.2wt%, (2,4,6- trimethylbenzene acyl group) diphenyl phosphine oxide 2.5wt%, BYK190 0.3wt%, TEGO450
0.2wt%, BYK348 0.3wt%, ethyl alcohol 10wt%；
Wherein, it is 150 microns that the depth of priming coat is reinforced in the infiltration, the seal coat with a thickness of 50 microns, described the
One layer of attachment primer with a thickness of 0.001 micron, for the white bottom coating layer with a thickness of 50 microns, the second layer adheres to primer
With a thickness of 200 microns, third layer attachment primer with a thickness of 200 microns, 10 microns of the thickness of the top coat layer；
The preparation method of the decorative panel, comprising the following steps:
Fixed thick sanding, dedusting are carried out to inorganic board, reinforce primary coat in one layer of infiltration of surface roller coating of inorganic board, into linear velocity 10
M/min pipeline convey 1 minute, then in one layer of seal coat of its external coating, into 10 ms/min of linear velocity, 9.6kW
The uv cure machine of double mercury lamps, solidification, sanding, dedusting, then adhere to primer in its external coating first layer, into linear velocity 10
M/min, the mono- mercury lamp uv cure machine of 9.6kW, semi-solid preparation, then in its external coating white primary coat, into 10 meters of linear velocity/
Minute, 11.2kW gallium lamp, gallium lamp, mercury lamp, mercury lamp uv cure machine, solidification, sanding, dedusting, then in its external coating the
Two layers of attachment primer, into 10 ms/min of linear velocity, the uv cure machine of the bis- mercury lamps of 9.6kW, semi-solid preparation, then its surface benefit
The transfer film of walnut pattern is bonded with the transfer interpreter with gum, into 10 ms/min of linear velocity, 16.8kW gallium lamp, gallium lamp, iron
The uv cure machine of lamp, mercury lamp, solidification removes base load film, then adheres to primer layer in its external coating third, into linear velocity
10 ms/min, the uv cure machine of 11.2kW gallium lamp, gallium lamp, semi-solid preparation, then in its external coating finishing coat, into linear velocity
10 ms/min, 16.8kW gallium lamp, gallium lamp, iron lamp, mercury lamp, mercury lamp uv cure machine, solidification, testing, pasting protection
Film, are as follows: the decorative panel of aqueous radiation curable coating walnut pattern.
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| CN201610173345.6A CN105802482B (en) | 2016-03-23 | 2016-03-23 | Aqueous radiation curable coating decorative panel and preparation method thereof |
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| EP3875552A1 (en) * | 2020-03-04 | 2021-09-08 | Lambson Limited | Photoinitiator emulsions |
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| CN103774816B (en) * | 2014-01-08 | 2017-11-24 | 珠海市佳伟力环保科技有限公司 | A kind of radiation curing colored decorating plate |
| CN104989045B (en) * | 2014-12-29 | 2018-01-30 | 中关村人居环境工程与材料研究院 | A kind of ultra-violet curing transfer bloom decorative panel and its manufacture method |
| CN104927632A (en) * | 2015-07-01 | 2015-09-23 | 卓达新材料科技集团有限公司 | Xanthochromia-resistant UV paint for external wall sheet material and preparation method of xanthochromia-resistant UV paint |
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