CN106221663A - Marble energy-curable glue, surface process protection material and preparation method thereof - Google Patents
Marble energy-curable glue, surface process protection material and preparation method thereof Download PDFInfo
- Publication number
- CN106221663A CN106221663A CN201610774533.4A CN201610774533A CN106221663A CN 106221663 A CN106221663 A CN 106221663A CN 201610774533 A CN201610774533 A CN 201610774533A CN 106221663 A CN106221663 A CN 106221663A
- Authority
- CN
- China
- Prior art keywords
- marble
- energy
- poly
- curable glue
- surface process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 20
- 239000003292 glue Substances 0.000 title claims abstract description 15
- 239000004579 marble Substances 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 15
- 230000008569 process Effects 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 hexanediyl ester Chemical class 0.000 claims abstract description 26
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 150000002148 esters Chemical class 0.000 claims abstract description 22
- 239000002253 acid Substances 0.000 claims abstract description 21
- 150000001336 alkenes Chemical class 0.000 claims abstract description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 14
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 13
- UXWSUTBOOHDZIL-UHFFFAOYSA-N bis(1-hydroxycyclohexyl)methanone Chemical compound C1CCCCC1(O)C(=O)C1(O)CCCCC1 UXWSUTBOOHDZIL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000008859 change Effects 0.000 claims abstract description 13
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 13
- 239000011737 fluorine Substances 0.000 claims abstract description 13
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920003232 aliphatic polyester Polymers 0.000 claims abstract description 12
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 10
- 235000010290 biphenyl Nutrition 0.000 claims abstract description 8
- 239000004305 biphenyl Substances 0.000 claims abstract description 8
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- NXQNMWHBACKBIG-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCCC(O)(O)O Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCCC(O)(O)O NXQNMWHBACKBIG-UHFFFAOYSA-N 0.000 claims 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 229920005601 base polymer Polymers 0.000 claims 1
- 239000003999 initiator Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000004575 stone Substances 0.000 abstract description 5
- 230000003373 anti-fouling effect Effects 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- ZLXYJUZXHDRQMJ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol prop-1-ene Chemical group C=CC.C=CC.C=CC.C(O)C(CC)(CO)CO ZLXYJUZXHDRQMJ-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
- C09J183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
Marble energy-curable glue, surface process protection material and preparation method thereof, and it relates to building material technical field；It is made up of the raw material of following parts by weight: hexanediyl ester 10% 50%, tri (propylene glycol) diacrylate 10% 50%, trimethylolpropane trimethacrylate 10% 50%, trimethyl benzoyl diphenyl base phosphine oxide 1% 5%, hydroxy-cyclohexyl ketone 10% 50%, light trigger 10% 50%, the cruel acrylate of the poly-ammonia of high-ranking official 10% 50%, aliphatic polyester type 10% 50%, modified olefin(e) acid esters polymer defoamer 10% 50%, fluorine change domestic animal polysiloxane polymer 10% 50%.The present invention improves efficiency of construction, improves the density of stone material, glossiness and surface protection performance, reaches purpose waterproof, antifouling, corrosion resistant.
Description
Technical field
The present invention relates to building material technical field, be specifically related to marble energy-curable glue, surface process protection material
And preparation method thereof.
Background technology
Ornamental Stone Industry all uses resin and modified product thereof now, genus is from dry or hot dry type and still uses the most not environmentally
Auxiliary material and preparation method thereof.
Summary of the invention
Present invention aims to defect and the deficiency of prior art, it is provided that a kind of environment-friendly type, stone material can be improved
Density, glossiness and surface protection performance, reach the marble energy-curable glue of purpose waterproof, antifouling, corrosion resistant, table
Face processes protection material and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is: marble energy-curable glue and surface process protection
Material, it is made up of the raw material of following parts by weight: hexanediyl ester 10%-50%, tripropylene glycol two propylene
Acid esters 10%-50%, trimethylolpropane trimethacrylate 10%-50%, trimethyl benzoyl diphenyl base phosphine oxide 1%-
5%, hydroxy-cyclohexyl ketone 10%-50%, light trigger 10%-50%, the cruel acrylate of the poly-ammonia of high-ranking official 10%-50%, fat
Adoption ester type 10%-50%, modified olefin(e) acid esters polymer defoamer 10%-50%, fluorine change domestic animal polysiloxane polymer 10%-
50%。
Marble energy-curable glue, surface process the preparation method of protection material, and it comprises the steps of:
1, by hexanediyl ester 10%-50%, tri (propylene glycol) diacrylate 10%-50%, trihydroxy methyl third
Alkane triacrylate 10%-50%, trimethyl benzoyl diphenyl base phosphine oxide 1%-5%, hydroxy-cyclohexyl ketone 10%-
50%, light trigger 10%-50%, the cruel acrylate of the poly-ammonia of high-ranking official 10%-50%, aliphatic polyester type 10%-50%, modification
Olefin(e) acid esters polymer defoamer 10%-50%, fluorine change domestic animal polysiloxane polymer 10%-50% and get the raw materials ready；By above-mentioned group
Point hexanediyl ester, tri (propylene glycol) diacrylate, trimethylolpropane trimethacrylate mix
Stir 1-10 minute；
2, the solution toward above-mentioned steps 1 gained adds high-ranking official's cruel acrylate of poly-ammonia, aliphatic polyester type mixes stirring
5-20 minute；
3, be eventually adding light trigger, hydroxy-cyclohexyl ketone, modified olefin(e) acid esters polymer defoamer, fluorine change domestic animal polysiloxanes
Polymer mixed stirs 2-10 minute together,.
Further, above-mentioned operation temperature in steps is between 20-50 degree.
What the present invention produced has the beneficial effect that marble energy-curable glue of the present invention, surface process protection material
And preparation method thereof, environmental protection, improve efficiency of construction, improve the density of stone material, glossiness and surface protection performance, reach anti-
Water, purpose antifouling, corrosion resistant, directly reduce production cost and save multinomial indirect cost.
Detailed description of the invention
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to above-mentioned technical side
Case is described in detail.
Embodiment 1
Marble energy-curable glue, surface process the preparation method of protection material, and it comprises the steps of:
1, by hexanediyl ester 15%, tri (propylene glycol) diacrylate 12%, trimethylolpropane trimethacrylate
10%, trimethyl benzoyl diphenyl base phosphine oxide 3%, hydroxy-cyclohexyl ketone 10%, light trigger 10%, the cruel propylene of the poly-ammonia of high-ranking official
Acid esters 10%, aliphatic polyester type 10%, modified olefin(e) acid esters polymer defoamer 10%, fluorine change domestic animal polysiloxane polymer 10% and enter
Row is got the raw materials ready；By the hexanediyl ester of said components, tri (propylene glycol) diacrylate, trimethylolpropane tris propylene
Acid esters mixes stirring 5 minutes；
2, the solution toward above-mentioned steps 1 gained adds high-ranking official's cruel acrylate of poly-ammonia, aliphatic polyester type mixes stirring
10 minutes；
3, be eventually adding light trigger, hydroxy-cyclohexyl ketone, modified olefin(e) acid esters polymer defoamer, fluorine change domestic animal polysiloxanes
Polymer mixed stirs 5 minutes together,.
In the present embodiment, above-mentioned operation temperature in steps is 20-50 degree Celsius.
Embodiment 2
Marble energy-curable glue, surface process the preparation method of protection material, and it comprises the steps of:
1, by hexanediyl ester 11%, tri (propylene glycol) diacrylate 11%, trimethylolpropane trimethacrylate
12%, trimethyl benzoyl diphenyl base phosphine oxide 2%, hydroxy-cyclohexyl ketone 11%, light trigger 11%, the cruel propylene of the poly-ammonia of high-ranking official
Acid esters 11%, aliphatic polyester type 11%, modified olefin(e) acid esters polymer defoamer 10%, fluorine change domestic animal polysiloxane polymer 10% and enter
Row is got the raw materials ready；By the hexanediyl ester of said components, tri (propylene glycol) diacrylate, trimethylolpropane tris propylene
Acid esters mixes stirring 8 minutes；
2, the solution toward above-mentioned steps 1 gained adds high-ranking official's cruel acrylate of poly-ammonia, aliphatic polyester type mixes stirring
15 minutes；
3, be eventually adding light trigger, hydroxy-cyclohexyl ketone, modified olefin(e) acid esters polymer defoamer, fluorine change domestic animal polysiloxanes
Polymer mixed stirs 8 minutes together,.
In the present embodiment, above-mentioned operation temperature in steps is 20-50 degree Celsius.
Embodiment 3
Marble energy-curable glue, surface process the preparation method of protection material, and it comprises the steps of:
1, by hexanediyl ester 10%, tri (propylene glycol) diacrylate 10%, trimethylolpropane trimethacrylate
11%, trimethyl benzoyl diphenyl base phosphine oxide 3%, hydroxy-cyclohexyl ketone 11%, light trigger 11%, the cruel propylene of the poly-ammonia of high-ranking official
Acid esters 11%, aliphatic polyester type 11%, modified olefin(e) acid esters polymer defoamer 11%, fluorine change domestic animal polysiloxane polymer 11% and enter
Row is got the raw materials ready；By the hexanediyl ester of said components, tri (propylene glycol) diacrylate, trimethylolpropane tris propylene
Acid esters mixes stirring 10 minutes；
2, the solution toward above-mentioned steps 1 gained adds high-ranking official's cruel acrylate of poly-ammonia, aliphatic polyester type mixes stirring
20 minutes；
3, be eventually adding light trigger, hydroxy-cyclohexyl ketone, modified olefin(e) acid esters polymer defoamer, fluorine change domestic animal polysiloxanes
Polymer mixed stirs 10 minutes together,.
In the present embodiment, above-mentioned operation temperature in steps is 20-50 degree Celsius.
This detailed description of the invention produce have the beneficial effect that the marble energy-curable glue described in this detailed description of the invention,
Surface processes protection material and preparation method thereof, environmental protection, improves efficiency of construction, improves the density of stone material, glossiness and table
Face protective value, reaches purpose waterproof, antifouling, corrosion resistant, directly reduces production cost and saves multinomial indirect cost.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The skill of the industry
The art personnel simply explanation it should be appreciated that the present invention is not restricted to the described embodiments, described in above-described embodiment and description
The principle of the present invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these
Changes and improvements both fall within scope of the claimed invention.Claimed scope by appending claims and
Its equivalent defines.
Claims (3)
1. marble energy-curable glue and surface process protection material, it is characterised in that it is by the raw material group of following parts by weight
Become: hexanediyl ester 10%-50%, tri (propylene glycol) diacrylate 10%-50%, trimethylolpropane tris third
Olefin(e) acid ester 10%-50%, trimethyl benzoyl diphenyl base phosphine oxide 1%-5%, hydroxy-cyclohexyl ketone 10%-50%, light
Initiator 10%-50%, the cruel acrylate of the poly-ammonia of high-ranking official 10%-50%, aliphatic polyester type 10%-50%, modified olefin(e) acid ester
Base polymer defoamer 10%-50%, fluorine change domestic animal polysiloxane polymer 10%-50%.
2. marble energy-curable glue, surface process the preparation method protecting material, it is characterised in that:
(1), by hexanediyl ester 10%-50%, tri (propylene glycol) diacrylate 10%-50%, trihydroxy methyl
Propane triacrylate 10%-50%, trimethyl benzoyl diphenyl base phosphine oxide 1%-5%, hydroxy-cyclohexyl ketone 10%-
50%, light trigger 10%-50%, the cruel acrylate of the poly-ammonia of high-ranking official 10%-50%, aliphatic polyester type 10%-50%, modification
Olefin(e) acid esters polymer defoamer 10%-50%, fluorine change domestic animal polysiloxane polymer 10%-50% and get the raw materials ready；By above-mentioned group
Point hexanediyl ester, tri (propylene glycol) diacrylate, trimethylolpropane trimethacrylate mix
Stir 1-10 minute；
(2), the solution toward above-mentioned steps (1) gained adds high-ranking official's cruel acrylate of poly-ammonia, aliphatic polyester type mixes
Stir 5-20 minute；
(3), be eventually adding light trigger, hydroxy-cyclohexyl ketone, modified olefin(e) acid esters polymer defoamer, fluorine change the poly-silica of domestic animal
Alkane polymer mixed stirs 2-10 minute together,.
Marble energy-curable glue the most according to claim 2, surface process the preparation method of protection material, and its feature exists
In: above-mentioned operation temperature in steps is between 20-50 degree.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610774533.4A CN106221663A (en) | 2016-08-31 | 2016-08-31 | Marble energy-curable glue, surface process protection material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610774533.4A CN106221663A (en) | 2016-08-31 | 2016-08-31 | Marble energy-curable glue, surface process protection material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106221663A true CN106221663A (en) | 2016-12-14 |
Family
ID=58071916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610774533.4A Pending CN106221663A (en) | 2016-08-31 | 2016-08-31 | Marble energy-curable glue, surface process protection material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221663A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057554A (en) * | 2016-12-28 | 2017-08-18 | 广东理奥新材料科技有限公司 | Marble Energy curable surface handles protection materials and production technology |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103038299A (en) * | 2010-06-01 | 2013-04-10 | 理研科技株式会社 | Composition for use as coating material and adhesive, method for adhesive bonding, and laminated products |
-
2016
- 2016-08-31 CN CN201610774533.4A patent/CN106221663A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103038299A (en) * | 2010-06-01 | 2013-04-10 | 理研科技株式会社 | Composition for use as coating material and adhesive, method for adhesive bonding, and laminated products |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057554A (en) * | 2016-12-28 | 2017-08-18 | 广东理奥新材料科技有限公司 | Marble Energy curable surface handles protection materials and production technology |
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Application publication date: 20161214 |
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