CN106242516A - The ceramic manufactured with hazardous waste, solid waste - Google Patents
The ceramic manufactured with hazardous waste, solid waste Download PDFInfo
- Publication number
- CN106242516A CN106242516A CN201610658194.3A CN201610658194A CN106242516A CN 106242516 A CN106242516 A CN 106242516A CN 201610658194 A CN201610658194 A CN 201610658194A CN 106242516 A CN106242516 A CN 106242516A
- Authority
- CN
- China
- Prior art keywords
- ceramic
- slag
- waste
- hazardous waste
- goods
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000919 ceramic Substances 0.000 title claims abstract description 137
- 239000002920 hazardous waste Substances 0.000 title claims abstract description 82
- 239000002910 solid waste Substances 0.000 title claims abstract description 39
- 239000011651 chromium Substances 0.000 claims abstract description 46
- 238000004519 manufacturing process Methods 0.000 claims abstract description 45
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 38
- 239000000126 substance Substances 0.000 claims abstract description 27
- 239000002689 soil Substances 0.000 claims abstract description 19
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 18
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 10
- 238000011049 filling Methods 0.000 claims abstract description 9
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 229910052785 arsenic Inorganic materials 0.000 claims abstract description 8
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052788 barium Inorganic materials 0.000 claims abstract description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 8
- 239000011572 manganese Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052572 stoneware Inorganic materials 0.000 claims abstract description 7
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- 239000011701 zinc Substances 0.000 claims abstract description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052790 beryllium Inorganic materials 0.000 claims abstract description 5
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 5
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 5
- 239000011669 selenium Substances 0.000 claims abstract description 5
- 239000002893 slag Substances 0.000 claims description 55
- 239000002994 raw material Substances 0.000 claims description 32
- 235000015895 biscuits Nutrition 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000011499 joint compound Substances 0.000 claims description 17
- 229910000831 Steel Inorganic materials 0.000 claims description 12
- 239000010959 steel Substances 0.000 claims description 12
- 229910052720 vanadium Inorganic materials 0.000 claims description 10
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 7
- 150000002894 organic compounds Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000002360 explosive Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052593 corundum Inorganic materials 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 239000010881 fly ash Substances 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010802 sludge Substances 0.000 claims description 5
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 5
- 241000700605 Viruses Species 0.000 claims description 4
- 230000007059 acute toxicity Effects 0.000 claims description 4
- 231100000403 acute toxicity Toxicity 0.000 claims description 4
- 208000015181 infectious disease Diseases 0.000 claims description 4
- 230000002458 infectious effect Effects 0.000 claims description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 4
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 4
- 230000000171 quenching effect Effects 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 claims description 3
- 239000002956 ash Substances 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 239000000428 dust Substances 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 2
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 2
- 229910000863 Ferronickel Inorganic materials 0.000 claims description 2
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 2
- 229910001145 Ferrotungsten Inorganic materials 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 2
- 108010038629 Molybdoferredoxin Proteins 0.000 claims description 2
- 229910000720 Silicomanganese Inorganic materials 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 claims description 2
- HBELESVMOSDEOV-UHFFFAOYSA-N [Fe].[Mo] Chemical compound [Fe].[Mo] HBELESVMOSDEOV-UHFFFAOYSA-N 0.000 claims description 2
- 230000009471 action Effects 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 claims description 2
- 238000001514 detection method Methods 0.000 claims description 2
- 239000003500 flue dust Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010985 leather Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- PYLLWONICXJARP-UHFFFAOYSA-N manganese silicon Chemical compound [Si].[Mn] PYLLWONICXJARP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 230000009257 reactivity Effects 0.000 claims description 2
- 229910052895 riebeckite Inorganic materials 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 238000001694 spray drying Methods 0.000 claims description 2
- 238000009628 steelmaking Methods 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims description 2
- 231100000419 toxicity Toxicity 0.000 claims description 2
- 230000001988 toxicity Effects 0.000 claims description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 description 11
- 239000004568 cement Substances 0.000 description 10
- 231100000614 poison Toxicity 0.000 description 10
- 229910052573 porcelain Inorganic materials 0.000 description 10
- 239000011449 brick Substances 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 229910052604 silicate mineral Inorganic materials 0.000 description 6
- 210000004127 vitreous body Anatomy 0.000 description 6
- 239000013078 crystal Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 229910001385 heavy metal Inorganic materials 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000002574 poison Substances 0.000 description 5
- 230000007096 poisonous effect Effects 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- -1 gangue Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000002906 medical waste Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000003854 Surface Print Methods 0.000 description 2
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000003818 cinder Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 2
- 229910052683 pyrite Inorganic materials 0.000 description 2
- 239000011028 pyrite Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 229910001021 Ferroalloy Inorganic materials 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000222065 Lycoperdon Species 0.000 description 1
- 241000768494 Polymorphum Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000010171 animal model Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KMQAPZBMEMMKSS-UHFFFAOYSA-K calcium;magnesium;phosphate Chemical compound [Mg+2].[Ca+2].[O-]P([O-])([O-])=O KMQAPZBMEMMKSS-UHFFFAOYSA-K 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 231100000004 severe toxicity Toxicity 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000009270 solid waste treatment Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 238000009955 starching Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
- C04B33/1322—Red mud
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1325—Hazardous waste other than combustion residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1325—Hazardous waste other than combustion residues
- C04B33/1327—Hazardous waste other than combustion residues containing heavy metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
- C04B33/1352—Fuel ashes, e.g. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
" ceramic manufactured with hazardous waste, solid waste " relates to various hazardous wastes, solid waste, is used by the soil of Hazardous Wastes Management traditional ceramics production technology to manufacture ceramic, including the filling ceramic in art ceramic products, chemical stoneware goods, heat exchange or mixing or consersion unit, architectural pottery goods, sanitary ware, ceramic ware for daily use, ceramic solar slab products, infrared emitter ceramic；Total chromium ＜ 1.5mg/L, Cr VI ＜ 0.5mg/L, barium ＜ 10mg/L in the leachate of ceramic, nickel ＜ 0.3mg/L, copper ＜ 20mg/L, manganese ＜ 40mg/L, hydrargyrum ＜ 0.03mg/L, zinc ＜ 40mg/L, lead ＜ 0.15mg/L, cadmium ＜ 0.1mg/L, beryllium ＜ 0.012mg/L, arsenic ＜ 0.2mg/L, selenium ＜ 0.7mg/L.
Description
Technical field
The technical program relates to the improvement of various hazardous waste, solid waste treatment, Ceramic Production, particularly with various
Hazardous waste, solid waste produce various ceramics as one of raw material or raw material, eliminate during producing ceramic
Harmful substance, obtains safe ceramic.
Background technology
China's hazardous waste, solid waste, flying ash, residue often fill at Waste disposal center at present, but landfill
Field needs management, and standing cost is the highest, is also the major hidden danger of territory pollution, finally must all dig out as hazardous waste
Coming, again administer, we and descendant will pay great cost.China is industrial and population concentration is in eastern region, a large amount of work of output
More industry garbage, house refuse, flying dust of burning away the refuse, sludge of sewage treatment plant, carry out filling at present, take a large amount of soil, existing
It is being 0.5 meter of soil of covering on landfill yard, is planting tree greening, then after the several years, tree root enters harmful substance by half meter of soil,
Destroy waterproof layer, absorb harmful element, will occur now it is contemplated that and unimaginable negative consequence, should reduce now as far as possible
Landfill.
At present hazardous waste typically delivers to 3000 yuan to 4000 yuan per ton of Waste disposal center disposal costs, such as Jinan City and
Qingdao City charges 4000 yuan, and Yantai City charges 3800 yuan, the regional disposal costs having about 2000 yuan.
According to National Hazard refuse register and National Hazard refuse judging standard, a lot of industry output hazardous wastes, have
The thousand of ton of enterprise's year output, more than several ten thousand tons, with above-mentioned expenses standard, many performance of enterprisess are greatly affected, and are even difficult to
For continuing, some product price 1-2 per ton ten thousand yuan, often produce one ton of product output 0.5-5 ton refuse, environmental protection and economy development produces
Sharp contradiction.
Contradiction is not yet find that a kind of permanent secure, low cost, product can effectively digest the most pervasive at all
Property hazardous waste administering method and ripe production line, the even safety of administering method there is also problem, national
Treatment of chromate slag action there is certain representativeness.
China was worked out, by National Development and Reform Committee and State Environmental Protection Administration, " the chromium slag contaminated comprehensive improvement side promulgated in 2005
Case " require before the end of the year 2010, thoroughly eliminate the threat to environment of the chromium slag.But scheme is administered the method for chromium slag, technology, sets
Standby the most immature.
Scheme proposes 8 kinds of administering method, and " dry reduction, wet reducing, chromium slag for comprehensive utilizes brickmaking, calcium magnesium phosphate, casting
Stone, cement additire, glass colorant, sintering deposit are smelted iron ".
But, redox reaction is reversible reaction, and the chromium slag after reduction finds again to return poison；Rhizoma Begoniae Willsonii sintering temperature 1000
About DEG C or following, it is impossible to destroy poisonous solid solution and molecular structure in chromium slag, be formed without new nontoxic mineral, the most enough
Vitreous body, except poison is thorough, use dangerous, intensity is low, will thoroughly disintegrate in natural environment between decades to centuries,
Return soil.
And mineralogy is pointed out, under high temperature, silico-calcium ratio is more than 2, and Cr VI is changed into trivalent chromium, and less than 2, then trivalent chromium changes
For Cr VI, this is one of mineralogy ultimate principle.Chromium slag produces cement and violates mineralogy principle, and in manufacture of cement, silico-calcium ratio is remote
Less than 2, being poisonous Cr VI by the nontoxic oxidation of chromite of the 1-2% of remaining original in chromium slag, chromium slag produces cement and increases
Add, spread polluter, leave the future trouble that cannot reclaim, remedy；A lot of danger are useless, solid waste contains chromium, it should forbid that all contain
Chromium refuse enters cement kiln and produces cement.
Although 2007 national environmental standard " chromium slag contaminated Environment control resist technology specification " list in chromium slag produce aggregate,
National standard in 2013 " cement kiln synergic processing solid waste pollution controls standard " forbids that chromium slag enters cement kiln and works in coordination with
Dispose.But " chromium slag contaminated comprehensive improvement scheme " that 2006-2012 implements uses on a large scale, and chromium slag produces cement, chromium slag is made
Fill after brick, chromium slag reduction.
420,000 tons of chromium slags of Changsha in November, 2010 reduction improvement now are still deposited in the obvious brightness reversion in Xiang River limit and return poison.
A large amount of reduction filled are administered chromium slag and are left substantial pollution hidden danger to territory, subsoil water, and up to ten million ton cements are
It is distributed to all parts of the country, leaves irremediable future trouble, except malicious halfway chromium slag brick is lasting hexavalent chromium polluted source.
" chromium slag contaminated comprehensive improvement scheme " and ten announcements of soil in the recent period that 2006-2012 cost 10,000,000,000 is implemented on a large scale
Some is launched rashly except poison administering method the most thorough, unabiding afterwards, illustrates that one or more permanent secure, low one-tenth are badly in need of in China
Originally, the danger that product can effectively digest is useless, solid waste is administered, Application way.
Summary of the invention
China's hazardous waste, solid waste quantum of output are very big, need multiple method to administer, utilize, produce permanent secure, one-tenth
This is cheap, the product that market capacity is big.
Use hazardous waste and/or solid waste and/or manufactured with conventional ceramic raw material by the soil of Hazardous Wastes Management
Ceramic, described ceramic is referred to as green ceramic goods；Hazardous waste and/or solid waste and/or by hazardous waste
In contaminated soil, dry gross weight accounts for the 1-100% of green ceramic goods raw material dry gross weight, green ceramic goods
(SiO in formula2+Al2O3+Fe2O3)/(CaO+MgO) ＞ 2；Hazardous waste refers to the National Hazard refuse of national publication in 2016
Listed by register, there is corrosivity, toxicity, inflammability, the refuse of one or several hazard properties such as reactive or infectious
With the refuse that is managed according to hazardous waste of needs, including containing cadmium, lead, hydrargyrum, beryllium, cobalt, nickel, chromium, zinc, barium, copper, antimony,
Thallium, arsenic, selenium, fluorine, cyanogen, the various hazardous wastes of asbestos；Detect according to harmful components detection method in the leachate of national regulation,
In the leachate of green ceramic goods, each harmful substance contents is simultaneously less than following each limits of harmful substances: total chromium ＜ 1.5mg/L,
Cr VI ＜ 0.5mg/L, barium ＜ 10mg/L, nickel ＜ 0.3mg/L, copper ＜ 20mg/L, manganese ＜ 40mg/L, hydrargyrum ＜ 0.03mg/L, zinc
＜ 40mg/L, lead ＜ 0.15mg/L, cadmium ＜ 0.1mg/L, beryllium ＜ 0.012mg/L, arsenic ＜ 0.2mg/L, selenium ＜ 0.7mg/L；Use
Hazardous waste and/or solid waste and/or used traditional ceramics to produce by the soil of Hazardous Wastes Management and conventional ceramic raw material
Technique manufactures green ceramic goods and is used as in art ceramic products, chemical stoneware goods, heat exchange or mixing or consersion unit
Fill ceramic, architectural pottery goods, sanitary ware, ceramic ware for daily use, ceramic solar plate, infrared ceramic transmitting
Body；Green ceramic goods firing temperature ＞ 1100 DEG C.
Described hazardous waste includes containing hydrion, the corrosivity hazardous waste of hydroxyl ion, containing having acute toxicity and leaching
Going out toxic inorganic element and compound, the hazardous waste of organic compound, the flammability hazard refuse containing combustibles, containing blast
The reactivity hazard refuse of thing, containing the infectious hazardous waste infecting virus；Described hazardous waste and solid waste include chromium slag,
Tailings in vanadium extraction, pyrite cinder, leather mud, electroplating sludge, acid-washing stainless steel mud, red mud, boron mud, gangue, flyash,
Ettle, the stone-like pulse of output of opening a mine, ferromanganese slag, silicochromium slag, carbon ferrochrome slag, ferro-silicon slag, ferrotungsten slag, molybdenum iron slag, crome metal
Metallurgical slag, electrolytic manganese residues, silicon manganese slag, silicomanganese flue dust, ferronickel slag, slag, steel rolling iron scale, vanadium titano-magnetite ironmaking slag,
In vanadium titano-magnetite steelmaking slag, copper ashes, blast furnace Water Quenching Slag, wet type copper smelting leached mud, lead fuming furnace Water Quenching Slag, electrolytic manganese production
The chromium-bearing sludge of passivation electrolytic manganese board.
The gross weight of the combustible material in hazardous waste is less than the 1% of green ceramic goods raw material gross weight, with not shadow
The quality standard ringing the requirement of green ceramic goods is as the criterion, such as the porosity, microcrack quantity and the restriction of length.
The gross weight of the explosive substance in hazardous waste is less than the 0.1% of green ceramic goods raw material gross weight, with not
The quality standard affecting the requirement of green ceramic goods is as the criterion, such as the porosity, microcrack quantity and the restriction of length.
Hazardous waste and/or solid waste and/or be sufficiently mixed with traditional ceramics raw material by the soil of Hazardous Wastes Management,
With traditional ceramics production technology manufacture green ceramic goods, with traditional ceramics production technology be shaped to biscuit of ceramics, be dried,
Glazing, burn till as green building ceramic, sanitary ware, ceramic ware for daily use, chemical stoneware goods, heat exchange or mixed
Filling ceramic in conjunction or consersion unit.
During traditional ceramics produces, raw material needs through adding spray drying after water for ball milling is mud in ball mill, compressing
For biscuit manufacture architectural pottery goods or by mud through filter pressing, pugging, be shaped to biscuit manufacture architectural pottery goods, daily pottery
Filling ceramic in ceramic products, chemical stoneware goods, heat exchange or mixing or consersion unit, or directly with mud through stone
Cream is molded into starching the filling ceramic being shaped in biscuit manufacture sanitary ware or heat exchange or mixing or consersion unit；Green
Water content in amount of water hazardous waste to be deducted, the slag of solid waste, mud, liquid in ball mill in color Ceramic Production.
During the ceramic manufactured with hazardous waste, solid waste, mud through pressure filter filter pressing water out,
The water added during ball milling in ball mill as raw material.
Green ceramic production of articles produces than traditional ceramics and improves mechanization degree, increase robot and mechanical hand behaviour
Make operation, strengthen protection, make human body be reduced to bottom line with raw material or contacting of raw material dust.
Method described above manufactures green ceramic goods.
The above-mentioned harmful substance contents being had by the soil of hazardous waste or solid waste pollution or severe contamination alreadys more than
National Hazard refuse judging standard, is the hazardous waste of standard, is the refuse that must administer of national regulation.
(SiO in green ceramic article formulations2+Al2O3+Fe2O3)/(CaO+MgO) ＞ 2 be achieved in that above-mentioned a lot
In hazardous waste or solid waste, itself is containing SiO2、Al2O3、Fe2O3, and gangue, flyash, ettle, output of opening a mine
Stone-like pulse, contaminated soil, conventional ceramic raw material has substantial amounts of SiO2, reach (SiO when organizing formula2+Al2O3+Fe2O3)
/ (CaO+MgO) ＞ 2, or ＞ 2 is easily to realize far away.
Make green ceramic goods reach permanent secure, innoxious according to being: whole listed by National Hazard refuse register
Heavy metal hazardous waste harmful element is consistent with ceramic colorant, and heavy metal ion colour generation is that ceramic produces color
Basis, the heavy metal basic compound forming hazardous waste can find in the dangerous goods store of ceramics factory, exists including arsenic
Also functioning in Production of Ceramics make high-temperature liquid-phase clarification, hazardous compound is completely converted into harmless useful in Production of Ceramics
Material, heavy metal ion enters in the lattice of various newborn stable crystal, and is wrapped by vitreous body, produces and have shades of colour
Ceramic.
Hazardous chemical can produce thousands of kinds of hazardous wastes, and ceramic colorant also has thousands of kinds of formula, pottery
The safety of goods is confirmed by the large-scale production of centuries, use, global trade customs inspection.
Manufacturing ceramic with hazardous waste, solid waste and meet ceramics principle, green ceramic goods are porcelain class potteries
Ceramic products, soluble substance is few, and harmful substance stripping quantity can reach above-mentioned requirements.
Above-mentioned green ceramic goods firing temperature ＞ 1100 DEG C, is made up of the vitreous body of crystalline silicates and covering crystal grain,
When firing temperature ＞ 1100 DEG C, have acid, alkalescence hydrion, hydroxyl ion cannot individualism, formed hydrone gasification,
Thus Production of Ceramics process can eliminate corrosivity hazardous waste.
Acute toxicity material be instigate experimental animal in 14 days the material of dead half, acute toxicity and Leaching without
The hazardous waste of machine element and compound, organic compound include cyanide, arsenic, poisonous inorganic elements and compound thereof,
The poisonous organic compound of ad hoc structure, above-mentioned green ceramic goods firing temperature ＞ 1100 DEG C, silicate is main component,
1100 DEG C can be destroyed cyanide, arsenic quasi-molecule structure, it is possible to destroy the structure of all of organic compound；1100 DEG C of high temperature
Synergy with silicate can destroy nearly all inorganic elements and the molecule of compound, ionic structure, ultimately forms
Harmless mineral and cover the vitreous body of mineral grains, 1100 DEG C can to kill all viral and biological, including infectious virus.
When the gross weight of the combustible material in hazardous waste is less than the 1% of green ceramic goods raw material gross weight,
When less than 1100 DEG C, combustible material has burnouted, and does not typically interfere with the quality of common green ceramic goods requirement.
When the gross weight of the explosive substance in hazardous waste is less than the 1% of green ceramic goods raw material gross weight, when
When explosive substance is in dispersity, its character is suitable with combustibles, and time below 1100 DEG C, explosive substance has burnouted, typically
Do not interfere with the quality of common green ceramic goods requirement.
When the soil of severe contamination wherein harmful substance contents has exceeded the limit value that National Hazard refuse standard specifies, also it is
Hazardous waste, but the soil of severe contamination remains soil, and main component is silicate mineral, at green ceramic goods raw material
In be the hazardous waste that must be administered, be also the supplier of silicate mineral.
Green ceramic goods use a large amount of harmful substances, heavy metal present-color material etc. to be one of raw material or raw material, its physics
Performance is also no less than conventional ceramic, but general body color is in light gray, Lycoperdon polymorphum Vitt, dark color, even black, is suitable for manufacturing needs
The goods of this type of color, it is possible to use the glaze layer that covering power is stronger manufactures green ceramic product.
One of the technical program principle: in hazardous waste, mostly harmful metal ion is high-valence cationic, has in haydite biscuit
Evil metal ion typically constitute from biscuit gross weight ten thousand/several to one of percentage left and right, the having in haydite biscuit when pyroreaction
Acidic oxide meeting that under silicate mineral under machine thing, carbon and high temperature, high temperature, silicate mineral produces and harmful metal ion
React, make harmful metal ion become harmless low price ion or become molecule, and react formation with silicate mineral
Harmless new silicate mineral crystal grain, and fully wrapped by vitreous body, become safe ceramic.
China's hazardous waste being administered, being utilized technology to be in the starting stage, if can not find cost effective method for a long time at present
Or be difficult to hazardous waste low cost and administer and utilize, it not that environmental requirement considerable part of crushing relates to useless basic industries, just
It is that country is forced to revise limit of harmful substance standard.
The contradiction of the environmental policy produced in the recent period and economic development, can only in the way of finding safety, cheap, digestion solution
Certainly, landfill is not outlet.
The high temperature of green ceramic article manufacturing process, silicate, interior reducing environment destroy whole molecules in raw material, ion knot
Structure, forms safe crystal grain, wraps the vitreous body of crystal grain, manufacturing process is simple, low production cost, as ordinary pottery products.
Ceramic is most stable of culture, and pottery is the remnants of Ancient people, including the pottery of green ceramic goods
Porcelain is the remnants that modern humans is last, permanent secure.Said method may be used for most useless, solid waste of endangering, China's traditional ceramics
Product yield accounts for the whole world more than 50%.
Green ceramic goods permanent secure, low cost, entirely digest, have mineralogy, ceramics theoretical foundation, have and grind for a long time
Study carefully, product that actual production line and centuries produce, equipment, the basis of production line, have obvious technology, industry, region,
Raw material, the market advantage.
Detailed description of the invention:
1, the ferroalloy works in somewhere, chemical plant, Electroplate Factory, insecticide factory, mine, hospital etc. produce containing chromium, barium, nickel, copper, manganese,
The hazardous wastes such as hydrargyrum, zinc, lead, agricultural residue, medical waste.Above-mentioned hazardous waste is pressed and is worked as by locality green ceramic production of articles factory
The ratio of ground quantum of output is mixed into the Large Steel ball mill of steel lining, steel abrading-ball, adds suitable quantity of water, and ball milling becomes refuse mud
Slurry, all becomes Waste Slurry including the gauze in medical waste, packing material, vial.Another Large Steel ball mill will be dried
Conventional ceramic raw material wear into the Ceramic Material powder that fineness is 80 mesh.Calculate according to dry, Waste Slurry: Ceramic Material powder:
Flyash 30:65:5, stirs in biaxial rneader, enters vacuum deairing machine, and its extrusion extrusion pug is cylinder
Shape biscuit, tubular biscuit Automatic-expanding after the cutting knife of top is flat board biscuit, and flat board biscuit becomes through roll squeezer, bead cutter
Dense, smooth, neat flat board biscuit, flat board biscuit is through being dried, and surface printing glaze, 1180 DEG C are sintered into green
Ceramic wall and floor bricks.In green ceramic Wall or floor tile leachate: total chromium 0.3mg/L, Cr VI 0.02mg/L, barium 3mg/L, nickel
0.01mg/L, copper 4mg/L, manganese 3.5mg/L, hydrargyrum 0.002mg/L, zinc 6mg/L, lead 0.05mg/L.The poisonous organic compound such as pesticide
Thing is made up of elements such as carbon, hydrogen, oxygen, nitrogen phosphate and sulfur, chlorine, and insecticide factory special equipment, production technology form it into specifically
Molecular structure, the organic compound of this specific molecular structure has severe toxicity, is used for killing various insect, Production of Ceramics mistake
The high temperature of journey thoroughly destroys this specific molecular structure, forms the oxide of the elements such as carbon, hydrogen, nitrogen phosphate and sulfur, chlorine, loses poison
Property.The various viruses in medical waste have been killed simultaneously.
2, by hazardous waste electroplating sludge, acid-washing stainless steel mud, solid waste red mud, boron mud enter steel lining, steel mill
The Large Steel ball mill of ball, adds suitable quantity of water, and ball milling becomes hazardous waste mud.By solid waste gangue, flyash dry grinding
Become 100 mesh solid waste powder.Calculating according to dry, hazardous waste mud: solid waste powder 40:60, at twin shaft
Stirring in blender, enter vacuum deairing machine, its extrusion extrusion pug is tubular biscuit, and tubular biscuit is through upper
After side's cutting knife, Automatic-expanding is flat board biscuit, and flat board biscuit becomes dense, smooth, neat through roll squeezer, bead cutter
Flat board biscuit, flat board biscuit is through being dried, and surface printing glaze, 1230 DEG C are sintered into green ceramic Wall or floor tile.Green ceramic
In Wall or floor tile leachate: total chromium 0.2mg/L, Cr VI 0.01mg/L, barium 2mg/L, nickel 0.02mg/L, copper 5mg/L.
3, calculate according to dry, chromium slag: tailings in vanadium extraction: pyrite cinder: by the clay of hazardous waste severe contamination
20:20:20:40, enters steel lining, the Large Steel ball mill of steel abrading-ball, adds suitable quantity of water, and ball milling becomes Waste Slurry, injects
Plaster mold is shaped to annular biscuit, and through being dried, glaze is applied on surface, and 1210 DEG C are sintered into ring-type green ceramic goods, are used as
Chemical plant Organic substance mixing and the filling ceramic in consersion unit.
4, manufacturing V-Ti black porcelain with hazardous waste tailings in vanadium extraction with conventional ceramic raw material, wherein tailings in vanadium extraction accounts for 30-70%,
Declining more than 90% than traditional black porcelain cost, traditional black porcelain uses the metal-oxides such as cobalt, chromium, nickel, vanadium, titanium, manganese, ferrum with strictly
Processing conditions manufactures ceramic black coloring agent, cost intensive.V-Ti black porcelain can manufacture various products, now tens works in the whole nation
Factory produces, the black polished bricks of global marketing is all V-Ti black porcelain polished bricks, squeezes into black polished bricks or V-Ti black porcelain on the net
Polished bricks is it can be seen that tens factories；The most special national building materials row of ceramic solar energy heat-collection plate that V-Ti black porcelain manufactures
Industry standard JC/T2194-2013 " ceramic solar energy heat-collection plate "；The infrared radiation heater of V-Ti black porcelain manufacture has been listed in red
External heat device standard GB/T/T4654-2008 " nonmetal basal body infrared radiation heater general technical specifications ".
Claims (9)
1. the ceramic manufactured with hazardous waste, solid waste, it is characterised in that use hazardous waste and/or solid waste
And/or the ceramic by the soil of Hazardous Wastes Management with the manufacture of conventional ceramic raw material, described ceramic is referred to as green pottery
Ceramic products；Hazardous waste and/or solid waste and/or accounted for green ceramic by dry gross weight in the soil of Hazardous Wastes Management
The 1-100%, (SiO in green ceramic article formulations of goods raw material dry gross weight2+Al2O3+Fe2O3)/(CaO+MgO) ＞
2；Hazardous waste refers to have corrosivity, toxicity, inflammability, anti-listed by the National Hazard refuse register of national publication in 2016
The refuse that the refuse of one or several hazard properties such as answering property or infectivity and needs are managed according to hazardous waste, its
Include containing cadmium, lead, hydrargyrum, beryllium, cobalt, nickel, chromium, zinc, barium, copper, antimony, thallium, arsenic, selenium, fluorine, cyanogen, the various hazardous wastes of asbestos；Root
Detect according to harmful components detection method in the leachate of national regulation, each harmful substance contents in the leachate of green ceramic goods
Simultaneously less than following each limits of harmful substances: total chromium ＜ 1.5mg/L, Cr VI ＜ 0.5mg/L, barium ＜ 10mg/L, nickel ＜
0.3mg/L, copper ＜ 20mg/L, manganese ＜ 40mg/L, hydrargyrum ＜ 0.03mg/L, zinc ＜ 40mg/L, lead ＜ 0.15mg/L, cadmium ＜
0.1mg/L, beryllium ＜ 0.012mg/L, arsenic ＜ 0.2mg/L, selenium ＜ 0.7mg/L；Use hazardous waste and/or solid waste and/or
Traditional ceramics production technology is used to manufacture green ceramic goods with performing by the soil of Hazardous Wastes Management and conventional ceramic raw material
Filling ceramic in art ceramic, chemical stoneware goods, heat exchange or mixing or consersion unit, architectural pottery goods,
Sanitary ware, ceramic ware for daily use, ceramic solar slab products, infrared ceramic emitter goods；Green ceramic goods burn
Become temperature ＞ 1100 DEG C.
The ceramic that hazardous waste the most according to claim 1, solid waste manufacture, it is characterised in that described danger
Refuse includes containing hydrion, the corrosivity hazardous waste of hydroxyl ion, containing have acute toxicity and Leaching inorganic elements and
Its compound, the hazardous waste of organic compound, the flammability hazard refuse containing combustibles, the reactivity hazard containing explosive gives up
Thing, containing the infectious hazardous waste infecting virus；Described hazardous waste and solid waste include chromium slag, tailings in vanadium extraction, troilite
Slag, leather mud, electroplating sludge, acid-washing stainless steel mud, red mud, boron mud, gangue, flyash, ettle, output of opening a mine
Stone-like pulse, ferromanganese slag, silicochromium slag, carbon ferrochrome slag, ferro-silicon slag, ferrotungsten slag, molybdenum iron slag, crome metal metallurgical slag, electrolytic manganese residues,
Silicon manganese slag, silicomanganese flue dust, ferronickel slag, slag, steel rolling iron scale, vanadium titano-magnetite ironmaking slag, vanadium titano-magnetite steelmaking slag,
Copper ashes, blast furnace Water Quenching Slag, wet type copper smelting leached mud, lead fuming furnace Water Quenching Slag, electrolytic manganese production are passivated containing of electrolytic manganese board
Chromium mud.
The ceramic that hazardous waste the most according to claim 1, solid waste manufacture, it is characterised in that hazardous waste
In combustible material gross weight less than green ceramic goods raw material gross weight 1%.
The ceramic that hazardous waste the most according to claim 1, solid waste manufacture, it is characterised in that hazardous waste
In explosive substance gross weight less than green ceramic goods raw material gross weight 0.1%.
The ceramic that hazardous waste the most according to claim 1, solid waste manufacture, it is characterised in that hazardous waste
And/or solid waste and/or be sufficiently mixed with traditional ceramics raw material by the soil of Hazardous Wastes Management, produce work with traditional ceramics
Skill is shaped to biscuit of ceramics, is dried, glazing, burns till as green building ceramic, sanitary ware, domestic ceramics system
Filling ceramic in product, chemical stoneware goods, heat exchange or mixing or consersion unit.
The ceramic that hazardous waste the most according to claim 5, solid waste manufacture, it is characterised in that traditional ceramics
In production, raw material needs through adding spray drying after water for ball milling is mud in ball mill, compressing for biscuit manufacture building pottery
Ceramic products or by mud through filter pressing, pugging, be shaped to biscuit manufacture architectural pottery goods, ceramic ware for daily use, chemical stoneware
Filling ceramic or direct mud in goods, heat exchange or mixing or consersion unit are shaped to element through gypsum mould grouting
Base manufactures sanitary ware；Amount of water hazardous waste to be deducted, solid waste in ball mill in green ceramic production of articles
Slag, mud, water content in liquid.
7. according to the ceramic manufactured with hazardous waste, solid waste described in claim 5,6, it is characterised in that mud warp
Pressure filter filter pressing water out, the water added during ball milling in ball mill as raw material.
The ceramic that hazardous waste the most according to claim 1, solid waste manufacture, it is characterised in that make pottery in green
Ceramic products improves mechanization degree than traditional ceramics production in producing, and increases robot and Robot actions operation, strengthens
Protection, makes human body be reduced to bottom line with raw material or contacting of raw material dust.
9. the green ceramic goods manufactured according to claim 1,2,3,4,5,6,7,8.
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| CN107265855A (en) * | 2017-05-25 | 2017-10-20 | 浙江工商大学 | The formula and method of a kind of hydrometallurgy slag and coal solid waste coprocessing |
| CN108435757A (en) * | 2018-03-16 | 2018-08-24 | 广州大学 | A method of stablizing cadmium using oxide containing silicon |
| CN109231959A (en) * | 2018-08-15 | 2019-01-18 | 陕西科技大学 | A kind of preparation method using leather sludge production exterior wall tile |
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| CN106927651B (en) * | 2017-05-17 | 2020-03-20 | 姜艳 | Treatment method of heavy metal-containing industrial sludge |
| CN107265855A (en) * | 2017-05-25 | 2017-10-20 | 浙江工商大学 | The formula and method of a kind of hydrometallurgy slag and coal solid waste coprocessing |
| CN107265855B (en) * | 2017-05-25 | 2020-06-02 | 浙江工商大学 | A formula and method for co-processing hydrometallurgical slag and coal-based solid waste |
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| CN111675549A (en) * | 2020-06-22 | 2020-09-18 | 山东洛尔环保科技有限公司 | Resource utilization method of hexavalent chromium contaminated soil |
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| CN112645700A (en) * | 2020-12-28 | 2021-04-13 | 内蒙古华宸再生资源科技有限公司 | Selenium-rich ceramic wine bottle and preparation method thereof |
| CN112645700B (en) * | 2020-12-28 | 2023-02-07 | 内蒙古华宸再生资源科技有限公司 | Selenium-rich ceramic wine bottle and preparation method thereof |
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