CN106633588A - Cable material for electromobile charging piles and preparation method thereof - Google Patents
Cable material for electromobile charging piles and preparation method thereof Download PDFInfo
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- CN106633588A CN106633588A CN201611138158.0A CN201611138158A CN106633588A CN 106633588 A CN106633588 A CN 106633588A CN 201611138158 A CN201611138158 A CN 201611138158A CN 106633588 A CN106633588 A CN 106633588A
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- cable material
- charging pile
- electric automobile
- automobile charging
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- 239000000463 material Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 229920002725 thermoplastic elastomer Polymers 0.000 claims abstract description 51
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 29
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 29
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 24
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims abstract description 24
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 24
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 24
- 239000003963 antioxidant agent Substances 0.000 claims description 19
- 230000003078 antioxidant effect Effects 0.000 claims description 19
- 239000004642 Polyimide Substances 0.000 claims description 15
- 229920001721 polyimide Polymers 0.000 claims description 15
- 239000002245 particle Substances 0.000 claims description 14
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 11
- 230000036571 hydration Effects 0.000 claims description 9
- 238000006703 hydration reaction Methods 0.000 claims description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 8
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 8
- 238000001125 extrusion Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 5
- 125000005504 styryl group Chemical group 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000004898 kneading Methods 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000008188 pellet Substances 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 abstract description 23
- 239000000779 smoke Substances 0.000 abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 9
- 229920001971 elastomer Polymers 0.000 abstract description 8
- 239000000806 elastomer Substances 0.000 abstract description 7
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 abstract 2
- 230000002349 favourable effect Effects 0.000 abstract 1
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 11
- 230000000694 effects Effects 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 150000003440 styrenes Chemical class 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 3
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical group O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 230000000979 retarding effect Effects 0.000 description 2
- KHWQFISNNNRGLV-UHFFFAOYSA-N 2,4,6-tributylphenol Chemical compound CCCCC1=CC(CCCC)=C(O)C(CCCC)=C1 KHWQFISNNNRGLV-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical compound C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical class C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000012757 flame retardant agent Substances 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a cable material for electromobile charging piles and a preparation method thereof. The cable material for electromobile charging piles is composed of SEBS (styrene elastomer), nitrile-butadiene rubber, TPU (thermoplastic elastomer), high-density polyethylene, polypyromelliticimide, lower-hydrate zinc borate, a compatilizer and DMDPB (2,3-dimethyl-2,3-diphenyl butane). The cable material for electromobile charging piles has the advantages of favorable flame retardancy, low flame retardant addition amount, heat resistance, low smoke, mechanical properties and the like; and the flame retardant has the advantages of low toxicity and environment friendliness, and is cheap and accessible.
Description
Technical field
The present invention relates to a kind of cable material, and in particular to a kind of electric automobile charging pile cable material and preparation method.
Background technology
Thermoplastic elastomer (TPE), i.e. TPE, both processing characteristicies with thermoplastic, and with the physical of vulcanized rubber
Can, it is the advantageous combination of plastics and rubber advantage.Thermoplastic elastomer (TPE) is being captured and is being pertaining only to vulcanized rubber originally without restraint
Manor.In the recent decade, electronic apparatus, communication and the fast development of automobile industry has driven the high speed in thermoplastic elastomer (TPE) city
Development.Thermoplastic elastomer (TPE)（TPE）The performance of technical process of the physical and mechanical properties with vulcanized rubber and thermoplastic.By
In being not required to through heat cure, production can be completed using general device of plastic processing.
Because charging pile cable load electric current is larger, conductor easily generates heat, while charging pile cable is exposed to for a long time the external world
, there is the risk met naked light and burn in environment.So the insulating materials for needing charging pile cable has certain anti-flammability.It is complicated
External environment need cable to need more preferable weatherability, and using when there is the situation that cable circumnutates unavoidably, so phase
The cable answered should have the preferable resistance to performance that circumnutates.And conductor easily causes cable insulation material by the heat that high current is produced
Heating and aging, therefore, charging pile cable have higher wanting with the aspect such as fire-retardant to hot-air aging resistance, weatherability, resistance to circumnutating
Ask.
CN103554814 discloses a kind of good TPE material of resistance to elevated temperatures, it by following weight portion each component system
Into：Hydrogenated styrene-butadiene-styrene block copolymers 80-100 parts, hydrogenation naphthenic oil 80-100 parts, polypropylene 15-20
Part, Propylene-ethylene random copolymer 15-20 part, calcium carbonate 100-120 parts, calcium stearate 0.5-1 parts, the 2- tert-butyl groups -4,6- two
Methylphenol 0.1-0.2 parts, 2,4,6- tri-butyl-phenol 0.4-0.8 parts.The TPE material heat resistance is good, compressive deformation, bullet
Property the physical property such as recover and will not be remarkably decreased because temperature is too high, but its fire resistance is poor.
CN201410390759 discloses a kind of modified TPE mixing materials and its system of electric automobile charging pile cable
Preparation Method, the TPE mixing materials include by weight following component：50～70 parts of thermoplastic elastomer (TPE), reinforcing agent 10～20
Part, 25～55 parts of fire retardant, 0.2～0.5 part of lubricant, 0.1～0.3 part of coupling agent, 0.1～0.3 part of antioxidant, the material because
Fire retardant addition is larger and intensity is relatively low, and oil resistivity, heat resistance and scratch resistance are poor, limit it and fill in electric automobile
Application on electric stake cable.
Electric automobile charging pile cable material will unavoidably use fire retardant because of the particularity of its use environment, and China is
Jing becomes fire retardant big producing country, remains leading in many field halogen system flame retardants, although halogen fire proofing has superior
Anti-flammability, but they burning when produce more smog and poisonous, mordant gas (hydrogen halides).These are poisonous
Gas has serious harm to human respiratory tract and other organs, hinders the carrying out of disaster relief work, and their diffusion velocity is remote
It is factor most dangerous in fire more than the diffusion velocity of flame.In the consideration of environmental protection, these years, phosphorus flame retardant is gradually
Halogen system flame retardant is substituted, but phosphorus flame retardant still suffers from some shortcomings, such as poor heat resistance, volatility be big, compatibility is undesirable, and
And have dropping to produce when burning etc..Nitrogenated flame retardant is related to melamine, melamine cyanurate, melamine methyl alcohol
Condensation product, polyamide, polyimides, guanidinesalt, guanidine condensation product etc., and based on melamine and melamine cyanurate.
At present, generally speaking, the fire resistance of nitrogenated flame retardant is not fine, is needed and other fire retardant compound uses.Three oxidations two
Antimony because usage amount is low, synergy is widely used in fire retarding synergist fortunately, but the technique of antimony oxide have it is special
Property, the heavy metals such as cadmium are inevitably introduced, there is harmful effect to environment, so, exploitation environmental protection, combination property are preferably fire-retardant
Synergist is also following focus.
The content of the invention
The electric automobile charging pile private cable material of the present invention, with fire resistance is good, fire retardant addition is low, resistance to
The advantages of heat, fire retardant low toxic and environment-friendly and cheap and easy to get, low cigarette, good mechanical property.
A kind of electric automobile charging pile cable material, the material composition is calculated by weight, and raw material includes：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
Low hydration zinc borate：10-15 parts,
Compatilizer：4 parts,
DMDPB：2-3 parts,
Wherein：
（1）The compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the maleic anhydride
The weight ratio that Maleated SEBS is grafted PE with maleic anhydride is 1:2；
（2）The styrene series elastomer is each based block copolymer containing styryl structures unit of hub-and-spoke configuration, and
The styrene contained in the styrene series elastomer is 3 with the weight ratio of butadiene:1.
Preferably, the low hydration zinc borate is 2ZnO3B2O35H2O.
Preferably, Li Jing≤2 μm of described 2ZnO3B2O35H2O.
Preferably, the particle diameter of described 2ZnO3B2O35H2O is 75nm.
Preferably, the nitrile rubber is nitrile rubber of the hydrogenation degree more than 99%.
Preferably, the TPU thermoplastic elastomer (TPE)s are polyester-type TPU.
Preferably, also including the antioxidant of 0.1-1 parts in material.
Preferably, the antioxidant is the mixture of antioxidant 1010 and irgasfos 168, wherein antioxidant 1010 and antioxygen
The weight ratio of agent 168 is 1:2.
The method for preparing the electric automobile charging pile cable material, comprises the steps：
（1）Weighing：It is standby various materials accurately to be weighed according to composition；
（2）The SEBS, nitrile rubber, TPU thermoplastic elastomer (TPE)s, high density polyethylene (HDPE), equal benzene are added in high-speed mixer
Polyimides, is stirred 5 minutes at 80 DEG C with 900 revs/min of rotating speed, adds low hydration zinc borate, compatilizer, DMDPB,
Mixed material is obtained under conditions of mixing with 1000 revs/min at 100 DEG C；
（3）The mixed material obtained in step 2 is put into double screw extruder to carry out melt kneading and extrudes, extrusion temperature
For 220 DEG C, screw speed is 550rpm；Again water cooling is carried out to the melting output of extruder die head extrusion, after making pellet
Packaging is completed.
Specific embodiment
With reference to embodiment, the invention will be further described, and the mode of the present invention includes but are not limited to following examples.
Embodiment 1, the composition and weight of the electric automobile charging pile cable material of the present embodiment is as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：10 parts,
Compatilizer：4 parts,
DMDPB：1 part,
Antioxidant：0.2 part,
Wherein：
（1）The compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the maleic anhydride
The weight ratio that Maleated SEBS is grafted PE with maleic anhydride is 1:2；
（2）It is mixture of the antioxidant 1010 with irgasfos 168, wherein antioxidant 1010 and irgasfos 168 that the antioxidant is
Weight ratio be 1:2.
（3）The styrene series elastomer（SEBS）All kinds of blocks containing styryl structures unit for hub-and-spoke configuration are total to
The styrene contained in polymers, and the styrene series elastomer is 3 with the weight ratio of butadiene:1.
（4）The nitrile rubber is nitrile rubber of the hydrogenation degree more than 99%, and the TPU thermoplastic elastomer (TPE)s are polyester-type
TPU。
The method for preparing electric automobile charging pile cable material using above-mentioned material, comprises the steps：
（1）Weighing：It is standby various materials accurately to be weighed according to composition；
（2）The SEBS, nitrile rubber, TPU thermoplastic elastomer (TPE)s, high density polyethylene (HDPE), equal benzene are added in high-speed mixer
Polyimides, is stirred 5 minutes at 80 DEG C with 900 revs/min of rotating speed, adds low hydration zinc borate, compatilizer, DMDPB,
Antioxidant, under conditions of mixing with 1000 revs/min at 100 DEG C mixed material is obtained；
（3）The mixed material obtained in step 2 is put into double screw extruder to carry out melt kneading and extrudes, extrusion temperature
For 220 DEG C, screw speed is 550rpm；Again water cooling is carried out to the melting output of extruder die head extrusion, after making pellet
Packaging is completed.
Embodiment 2, the preparation method such as embodiment 1 of the electric automobile charging pile cable material of the present embodiment is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：10 parts,
Compatilizer：4 parts,
DMDPB：2 parts,
Antioxidant：0.2 part.
Embodiment 3, the preparation method such as embodiment 1 of the electric automobile charging pile cable material of the present embodiment is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：10 parts,
Compatilizer：4 parts,
DMDPB：3 parts,
Antioxidant：0.2 part.
Embodiment 4, the preparation method such as embodiment 1 of the electric automobile charging pile cable material of the present embodiment is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：5 parts,
Compatilizer：4 parts,
DMDPB：3 parts,
Antioxidant：0.2 part.
The preparation method of the electric automobile charging pile cable material of embodiment 5, the present embodiment such as embodiment 1 is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：15 parts,
Compatilizer：4 parts,
DMDPB：2 parts,
Antioxidant：0.2 part.
The preparation method of the electric automobile charging pile cable material of embodiment 6, the present embodiment such as embodiment 1 is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：15 parts,
Compatilizer：4 parts,
DMDPB：1 part,
Antioxidant：0.2 part.
The preparation method of the electric automobile charging pile cable material of comparative example 1, this comparative example such as embodiment 1 is different
It is that its composition and weight are as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
The mixture of poly cyanamid cyanurate and diethyl hypophosphites（1:1）：40 parts,
Silicone master batch:3 parts,
Compatilizer：4 parts,
Antioxidant：0.2 part,
Smoke suppressant：4 parts.
（1）Described smoke suppressant is Firebrake ZB.
The preparation method of the electric automobile charging pile cable material of comparative example 2, this comparative example such as embodiment 1, its composition
And weight is as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 2 μm)：10 parts,
Compatilizer：4 parts,
DMDPB：2 parts,
Antioxidant：0.2 part.
The preparation method of the electric automobile charging pile cable material of comparative example 3, this comparative example such as embodiment 1, its composition
And weight is as follows：
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
2ZnO3B2O35H2O (particle diameter, 75nm)：10 parts,
Compatilizer：4 parts,
Sb2O3：2 parts,
Antioxidant：1 part.
The composition of table 1, embodiment 1-6 and comparative example 1-3
| SEBS | Nitrile rubber | TPU | High density is gathered Ethene | Benzene gathers Acid amides | 2ZnO· 3B2O3· 5H2O（Particle diameter, 75nm） | Compatilizer | DMDPB | Antioxidant | Poly cyanamid cyanurate and two The mixing of ethyl hypophosphites Thing（1：1） | 2ZnO· 3B2O3·5H2O （Particle diameter, 2 μm） | Silicone master batch | Smoke suppressant | Sb2O3 | |
| Embodiment 1 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 1 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 2 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 2 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 3 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 3 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 4 | 20 | 10 | 15 | 15 | 15 | 5 | 4 | 3 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 5 | 20 | 10 | 15 | 15 | 15 | 15 | 4 | 2 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Embodiment 6 | 20 | 10 | 15 | 15 | 15 | 15 | 4 | 1 | 0.2 | 0 | 0 | 0 | 0 | 0 |
| Comparative example 1 | 20 | 10 | 15 | 15 | 15 | 0 | 4 | 0 | 0.2 | 40 | 0 | 3 | 4 | 0 |
| Comparative example 2 | 20 | 10 | 15 | 15 | 15 | 0 | 4 | 2 | 0.2 | 0 | 10 | 0 | 0 | 0 |
| Comparative example 3 | 20 | 10 | 15 | 15 | 15 | 10 | 4 | 0 | 1 | 0 | 0 | 0 | 0 | 2 |
The explanation of a part of content of table：
（1）Compatilizer described in table is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein the Malaysia
The weight ratio that acid anhydrides Maleated SEBS is grafted PE with maleic anhydride is 1:2；
（2）It is mixture of the antioxidant 1010 with irgasfos 168, wherein antioxidant 1010 and antioxidant that antioxidant described in table is
168 weight ratio is 1:2.
（3）Styrene series elastomer described in table（SEBS）For hub-and-spoke configuration containing all kinds of embedding of styryl structures unit
The styrene contained in section copolymer, and the styrene series elastomer is 3 with the weight ratio of butadiene:1.
（4）Nitrile rubber described in table is nitrile rubber of the hydrogenation degree more than 99%, and the TPU thermoplastic elastomer (TPE)s are poly-
Ester type TPU.
（5）Smoke suppressant described in table is Firebrake ZB.
The indices and comparing result of table 2, embodiment 1-6 and comparative example 1-3
Relative to immediate documents CN201510516682, the invention has the beneficial effects as follows:
Documents are using phosphorus flame retardant diethyl hypophosphites and nitrogen system as composite flame-retardant agent, diethyl hypophosphites category
In small molecule phosphorus flame retardant, its is volatile, not only makes processing environment be deteriorated, and easily separates out, and pollutes mould, and price also compares
Costly.The present invention is using low hydration zinc borate as fire retardant, especially 2ZnOB2O3H2O, it is only necessary to which addition is lower
Amount can just reach the flame retardant effect of CN201510516682 preferred embodiments.
Fire retarding synergist is 2,3- dimethyl -2,3- diphenyl butanes（DMDPB）, with fire retardant in certain proportion
Interior combination, can effectively reduce the consumption of fire retardant, very little to cable material mechanical impact, and overcome existing height
The high shortcoming of effect synergist Sb2O3 lifes smoke.
Hydration zinc borate and DMDPB do not only have fire retardation, while there is suppression cigarette effect, the cable material of the present invention does not add yet
Plus smoke suppressant, just reach the smoke suppressing effect of CN201510516682 preferred embodiments.Composition is relatively easy, reduces technique step
Suddenly.Within the specific limits, we compared for the different impacts to smoke suppressing effect and other indexs of 2ZnOB2O3H2O particle diameters.
It was found that selecting the little 2ZnOB2O3H2O smoke suppressing effects of particle diameter more preferable.
Claims (9)
1. a kind of electric automobile charging pile cable material, it is characterised in that by weight, the material each component includes:
SEBS：20 parts,
Nitrile rubber：10 parts,
TPU thermoplastic elastomer (TPE)s：15 parts,
High density polyethylene (HDPE)：15 parts,
Equal benzene polyimides：15 parts,
Low hydration zinc borate：10-15 parts,
Compatilizer：4 parts,
DMDPB：2-3 parts,
Wherein：
The compatilizer is the mixture that maleic anhydride-g-SBS and maleic anhydride are grafted PE, wherein maleic anhydride grafting
The weight ratio that SEBS is grafted PE with maleic anhydride is 1:2；
（2）Described SEBS for hub-and-spoke configuration each based block copolymer containing styryl structures unit, and the SEBS
In the styrene that contains and the weight ratio of butadiene be 3:1.
2. electric automobile charging pile cable material as claimed in claim 1, it is characterised in that：Described low hydration zinc borate
For 2ZnO3B2O35H2O.
3. electric automobile charging pile cable material as claimed in claim 2, it is characterised in that：Described 2ZnO
Li Jing≤2 μm of 3B2O35H2O.
4. electric automobile charging pile cable material as claimed in claim 3, it is characterised in that：Described 2ZnO
The particle diameter of 3B2O35H2O is 75nm.
5. electric automobile charging pile cable material as claimed in claim 4, it is characterised in that：The nitrile rubber is hydrogenation
Nitrile rubber of the degree more than 99%.
6. electric automobile charging pile cable material as claimed in claim 5, it is characterised in that：The TPU thermoplastic elastics
Body is polyester-type TPU.
7. electric automobile charging pile cable material as claimed in claim 6, it is characterised in that：Also include 0.1-1 in material
The antioxidant of part.
8. electric automobile charging pile cable material as claimed in claim 7, it is characterised in that：The antioxidant is antioxidant
1010 with the mixture of irgasfos 168, wherein antioxidant 1010 and the weight ratio of irgasfos 168 are 1:2.
9. the method for preparing the electric automobile charging pile cable material as described in claim 1-8, it is characterised in that including as follows
Step：
（1）Weighing：It is standby various materials accurately to be weighed according to composition；
（2）The SEBS, nitrile rubber, TPU thermoplastic elastomer (TPE)s, high density polyethylene (HDPE), equal benzene are added in high-speed mixer
Polyimides, is stirred 5 minutes at 80 DEG C with 900 revs/min of rotating speed, adds low hydration zinc borate, compatilizer, DMDPB,
Mixed material is obtained under conditions of mixing with 1000 revs/min at 100 DEG C；
（3）The mixed material obtained in step 2 is put into double screw extruder to carry out melt kneading and extrudes, extrusion temperature
For 220 DEG C, screw speed is 550rpm；Again water cooling is carried out to the melting output of extruder die head extrusion, after making pellet
Packaging is completed.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102356123A (en) * | 2009-04-28 | 2012-02-15 | 第一工业制药株式会社 | Flame-retardant expandable styrene resin composition |
| CN105038088A (en) * | 2015-08-21 | 2015-11-11 | 中广核三角洲（苏州）高聚物有限公司 | Elastomer cable material for oil-resistant cold-resistant high-temperature-resistant electric automobile charge piles and preparation method thereof |
| CN105556028A (en) * | 2013-09-12 | 2016-05-04 | 溴化合物有限公司 | Brominated epoxy polymers as textile-finishing flame retardant formulations |
| CN105980467A (en) * | 2013-12-16 | 2016-09-28 | 科莱恩国际有限公司 | Polymeric Foam |
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2016
- 2016-12-12 CN CN201611138158.0A patent/CN106633588B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102356123A (en) * | 2009-04-28 | 2012-02-15 | 第一工业制药株式会社 | Flame-retardant expandable styrene resin composition |
| CN105556028A (en) * | 2013-09-12 | 2016-05-04 | 溴化合物有限公司 | Brominated epoxy polymers as textile-finishing flame retardant formulations |
| CN105980467A (en) * | 2013-12-16 | 2016-09-28 | 科莱恩国际有限公司 | Polymeric Foam |
| CN105038088A (en) * | 2015-08-21 | 2015-11-11 | 中广核三角洲（苏州）高聚物有限公司 | Elastomer cable material for oil-resistant cold-resistant high-temperature-resistant electric automobile charge piles and preparation method thereof |
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