CN106830479A - Using flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system and method - Google Patents

Using flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system and method Download PDF

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CN106830479A
CN106830479A CN201710021176.9A CN201710021176A CN106830479A CN 106830479 A CN106830479 A CN 106830479A CN 201710021176 A CN201710021176 A CN 201710021176A CN 106830479 A CN106830479 A CN 106830479A
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pond
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余智勇
闫巍
郜时旺
刘练波
卢峰
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Shanghai Shuang Jun Environmental Protection Technology Co Ltd
Huaneng Clean Energy Research Institute
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Abstract

利用烟道气和电渗析的脱硫废水零排放处理系统及方法,该系统包括化学沉淀絮凝单元、石灰‑烟道气软化单元、膜浓缩单元和蒸发结晶单元;基于上述系统,首先利用化学沉淀絮凝单元处理脱硫废水原水,然后利用石灰乳和电厂烟道气中的CO2高效脱除化学沉淀絮凝单元出水中的钙镁等硬度离子,同时实现二氧化碳减排;软化出水经过超滤处理后进入离子选择性电渗析单元进行高效浓缩,获得NaCl浓水,进一步通过蒸发结晶获得NaCl工业盐;电渗析淡水通过低压卷式反渗透膜,获得可回用淡水;反渗透浓水重新进入电渗析单元;本发明利用电厂烟道气中的CO2代替昂贵的纯碱,既降低了软化成本,又促进了CO2减排;引入电渗析法进行浓缩,使电渗析和反渗透均处在最佳处理条件下,降低了能耗。

A zero-discharge treatment system and method for desulfurization wastewater using flue gas and electrodialysis, the system includes a chemical precipitation flocculation unit, a lime-flue gas softening unit, a membrane concentration unit and an evaporation crystallization unit; based on the above system, the chemical precipitation flocculation is first used The unit treats the raw water of desulfurization wastewater, and then uses lime milk and CO2 in the flue gas of the power plant to efficiently remove hardness ions such as calcium and magnesium in the effluent of the chemical precipitation flocculation unit, and at the same time achieve carbon dioxide emission reduction; the softened effluent enters ions after ultrafiltration treatment The selective electrodialysis unit conducts high-efficiency concentration to obtain NaCl concentrated water, and further obtains NaCl industrial salt through evaporation and crystallization; the electrodialysis fresh water passes through the low-pressure roll-type reverse osmosis membrane to obtain reusable fresh water; the reverse osmosis concentrated water re-enters the electrodialysis unit; The present invention uses CO2 in the flue gas of the power plant to replace expensive soda ash, which not only reduces the cost of softening, but also promotes the reduction of CO2 emissions; introduces electrodialysis for concentration, and makes electrodialysis and reverse osmosis both in the best treatment conditions , reducing energy consumption.

Description

利用烟道气和电渗析的脱硫废水零排放处理系统及方法Zero-discharge treatment system and method for desulfurization wastewater using flue gas and electrodialysis

技术领域technical field

本发明涉及采用零排放技术处理脱硫废水的技术领域,具体涉及一种利用烟道气和电渗析的脱硫废水零排放处理系统及方法。The invention relates to the technical field of treating desulfurization wastewater by adopting zero-discharge technology, in particular to a zero-discharge treatment system and method for desulfurization wastewater using flue gas and electrodialysis.

背景技术Background technique

目前我国大部分燃煤电厂采用石灰石/石膏湿法脱硫技术(WFGD)进行烟气脱硫,脱硫过程中需定时排放一定量的脱硫废水。脱硫废水水质极差,具有含盐量高、固体悬浮物含量高、硬度高、腐蚀性强、水质随时间和工况变化大等特点。另外,脱硫废水中还含有微量重金属元素,如汞、铬、镉、铅等,其中很多为国家环保标准中要求严格控制的第一类污染物。国内电厂通常采用化学沉淀絮凝法对脱硫废水进行处理,可除去废水中大部分的重金属离子、化学需氧量(COD)、悬浮固体(SS)等物质。然而,经过化学沉淀絮凝法处理的出水中仍具有很高的含盐量。At present, most coal-fired power plants in my country use limestone/gypsum wet desulfurization technology (WFGD) for flue gas desulfurization, and a certain amount of desulfurization wastewater needs to be discharged regularly during the desulfurization process. The water quality of desulfurization wastewater is extremely poor, and it has the characteristics of high salt content, high content of suspended solids, high hardness, strong corrosion, and large changes in water quality with time and working conditions. In addition, desulfurization wastewater also contains trace heavy metal elements, such as mercury, chromium, cadmium, lead, etc., many of which are the first type of pollutants that are strictly controlled in the national environmental protection standards. Domestic power plants usually use chemical precipitation flocculation to treat desulfurization wastewater, which can remove most of the heavy metal ions, chemical oxygen demand (COD), suspended solids (SS) and other substances in the wastewater. However, the effluent treated by chemical precipitation and flocculation still has a high salt content.

随着环境保护问题日益突出,采用零排放技术处理脱硫废水受到越来越多的关注。2005年颁布的《中国节水技术政策大纲》明确要求企业发展外排废水回用和零排放技术。2015年颁布的国家《水污染防治行动计划》(水十条),鼓励节能减排先进企业、工业集聚区用水效率、排污强度等达到更高标准。因此,研究脱硫废水零排放工艺是火力发电厂实现可持续发展的必由之路。With the increasingly prominent environmental protection issues, the use of zero discharge technology to treat desulfurization wastewater has received more and more attention. The "China Water Conservation Technology Policy Outline" promulgated in 2005 clearly requires enterprises to develop waste water reuse and zero discharge technologies. The national "Water Pollution Prevention and Control Action Plan" (Water Ten Measures), promulgated in 2015, encourages advanced enterprises in energy conservation and emission reduction, and industrial clusters to achieve higher standards in terms of water efficiency and sewage discharge intensity. Therefore, research on the zero discharge process of desulfurization wastewater is the only way for thermal power plants to achieve sustainable development.

目前国内对脱硫废水零排放工艺的研究处于起步阶段,基本思想是将脱硫废水经过一定的预处理,利用蒸汽加热对脱硫废水进行蒸发浓缩,产生的蒸汽冷凝回用,浓缩液结晶产品包装外运。然而,现有脱硫废水零排放工艺的投资运行成本较高。这主要是因为脱硫废水中的钙镁离子容易造成蒸发结晶系统的结垢和腐蚀,导致设备折旧费用提高;而且蒸发结晶过程能耗较高,导致运行成本增加。At present, domestic research on the zero-discharge process of desulfurization wastewater is in its infancy. The basic idea is to undergo certain pretreatment of desulfurization wastewater, use steam heating to evaporate and concentrate the desulfurization wastewater, and the generated steam is condensed for reuse, and the concentrated liquid crystallization product is packaged and shipped . However, the investment and operation cost of the existing desulfurization wastewater zero discharge process is relatively high. This is mainly because the calcium and magnesium ions in the desulfurization wastewater are likely to cause scaling and corrosion of the evaporative crystallization system, resulting in increased equipment depreciation costs; and the high energy consumption of the evaporative crystallization process leads to increased operating costs.

为了减少设备损害,需要对脱硫废水进行软化处理,脱除水中的钙镁离子。常规的软化工艺是石灰‐纯碱法,药剂费用较高。按脱硫废水中钙镁离子总量约为200mM计算,处理1吨废水约需加入碳酸22kg,按1500‐2000元/t的纯碱单价核算,仅纯碱的吨水药剂费用就高达40元左右,显著增加了零排放工艺的成本。In order to reduce equipment damage, desulfurization wastewater needs to be softened to remove calcium and magnesium ions in the water. The conventional softening process is the lime-soda ash method, and the cost of the agent is relatively high. Based on the calculation that the total amount of calcium and magnesium ions in desulfurization wastewater is about 200mM, about 22kg of carbonic acid needs to be added to treat 1 ton of wastewater. Calculated based on the unit price of soda ash of 1500-2000 yuan/t, the cost of soda ash alone is as high as about 40 yuan per ton of water, which is significant. Adds to the cost of the zero-emissions process.

为了降低运行能耗,需要对脱硫废水进行减量浓缩。反渗透法具有工艺简单、脱盐率高的优点,但是,反渗透工艺存在一些固有问题无法解决:产水回收率较低;对水质要求高;膜的污堵较为严重,膜清洗困难,寿命较低;高含盐量导致操作压力大和能耗增加。在处理水质较差的脱硫废水时,反渗透法的操作压力往往达到6MPa以上,投资和运行成本进一步提高。为了降低脱硫废水零排放的工艺成本,选择一种更加适合脱硫废水处理的浓缩工艺十分必要。In order to reduce operating energy consumption, it is necessary to reduce and concentrate desulfurization wastewater. The reverse osmosis method has the advantages of simple process and high desalination rate. However, there are some inherent problems in the reverse osmosis process that cannot be solved: the recovery rate of product water is low; Low; high salt content leads to high operating pressure and increased energy consumption. When treating desulfurization wastewater with poor water quality, the operating pressure of the reverse osmosis method often reaches above 6MPa, and the investment and operation costs are further increased. In order to reduce the process cost of zero discharge of desulfurization wastewater, it is necessary to choose a concentration process that is more suitable for desulfurization wastewater treatment.

发明内容Contents of the invention

为了解决上述问题,本发明的目的在于提供一种利用烟道气和电渗析的脱硫废水零排放处理系统及方法,通过各工艺环节的耦合和优化,降低零排放工艺的运行成本,实现资源回收利用和环境保护。In order to solve the above problems, the object of the present invention is to provide a zero-discharge treatment system and method for desulfurization wastewater using flue gas and electrodialysis, through the coupling and optimization of various process links, reduce the operating cost of the zero-discharge process, and realize resource recovery utilization and environmental protection.

本发明为实现上述目的,所采用的技术方案为:In order to achieve the above object, the present invention adopts the following technical solutions:

利用烟道气和电渗析的脱硫废水零排放处理系统,包括化学沉淀絮凝单元1、石灰-烟道气软化单元2、膜浓缩单元3和蒸发结晶单元4;A zero-discharge treatment system for desulfurization wastewater using flue gas and electrodialysis, including chemical precipitation flocculation unit 1, lime-flue gas softening unit 2, membrane concentration unit 3 and evaporation crystallization unit 4;

所述化学沉淀絮凝单元1由通过管道依次相连接的中和池、沉淀池、絮凝池、澄清池和1#清水池组成,中和池的进水口与脱硫废水的排放口相连;所述中和池中设置有石灰乳加药装置;所述沉淀池中设置有有机硫加药装置;所述絮凝池中设置有絮凝剂和助凝剂加药装置;所述澄清池下部有排泥口,排泥口通过管道与污泥脱水设备相连;The chemical precipitation flocculation unit 1 is composed of a neutralization tank, a sedimentation tank, a flocculation tank, a clarification tank and a 1# clear water tank connected in sequence through pipelines, and the water inlet of the neutralization tank is connected with the discharge port of the desulfurization wastewater; A lime milk dosing device is set in the mixing tank; an organic sulfur dosing device is set in the sedimentation tank; a flocculant and coagulant dosing device is set in the flocculation tank; a mud discharge port is provided at the lower part of the clarification tank , the sludge outlet is connected to the sludge dewatering equipment through pipelines;

所述石灰-烟道气软化单元2由通过管道依次相连接的苛化反应池、碳化反应池和2#清水池组成,苛化反应池与化学沉淀絮凝单元1中的1#清水池通过管道相连;所述苛化反应池中设置有石灰乳、硫酸钠、絮凝剂和助凝剂加药装置,苛化反应池底部有排泥口,排泥口通过管道与污泥脱水设备相连;所述碳化反应池的底部布置有气体分布器,气体分布器与烟道气压缩风机相连,碳化反应池中设置有絮凝剂、助凝剂加药装置,碳化反应池底部有排泥口,排泥口通过管道与污泥脱水设备相连;所述2#清水池中设置有稀盐酸加药装置;The lime-flue gas softening unit 2 is composed of a causticizing reaction tank, a carbonization reaction tank and a 2# clear water tank connected in sequence through pipelines, and the causticizing reaction tank and the 1# clear water tank in the chemical precipitation flocculation unit 1 pass through the pipeline connected; the causticization reaction tank is provided with lime milk, sodium sulfate, flocculant and coagulant dosing device, and there is a sludge discharge port at the bottom of the causticization reaction tank, and the sludge discharge port is connected with the sludge dewatering equipment through pipelines; A gas distributor is arranged at the bottom of the carbonization reaction tank, and the gas distributor is connected with the flue gas compressor fan. The carbonization reaction tank is provided with a flocculant and coagulant dosing device, and there is a mud discharge port at the bottom of the carbonization reaction tank. The port is connected to the sludge dewatering equipment through pipelines; the 2# clear water tank is provided with a dilute hydrochloric acid dosing device;

所述膜浓缩单元3由通过管道依次相连接的超滤装置、电渗析装置和反渗透装置组成;所述超滤装置的进水口与石灰-烟道气软化单元2的2#清水池的出水口相连,超滤装置的出水口与电渗析装置的进水口相连,超滤装置的浓水回水口与化学沉淀絮凝单元1的中和池相连;电渗析装置的浓水排放口与蒸发结晶单元4相连,淡水排放口与反渗透装置的进水口相连;所述反渗透装置反渗透的浓水排放口与电渗析装置的进水口相连。The membrane concentration unit 3 is composed of an ultrafiltration device, an electrodialysis device and a reverse osmosis device connected in sequence through pipelines; The outlet of the ultrafiltration device is connected to the water inlet of the electrodialysis device, and the concentrated water return port of the ultrafiltration device is connected to the neutralization tank of the chemical precipitation flocculation unit 1; the concentrated water discharge port of the electrodialysis device is connected to the evaporation crystallization unit 4 connected, the fresh water discharge port is connected with the water inlet of the reverse osmosis device; the concentrated water discharge port of the reverse osmosis device is connected with the water inlet of the electrodialysis device.

所述电渗析装置为多级逆流倒极电渗析,采用了一价离子选择性膜,The electrodialysis device is a multi-stage countercurrent reverse electrode electrodialysis, using a monovalent ion selective membrane,

所述反渗透装置采用了卷式反渗透膜。The reverse osmosis device adopts a roll-type reverse osmosis membrane.

所述蒸发结晶单元4采用了机械式再压缩蒸发器。The evaporative crystallization unit 4 adopts a mechanical recompression evaporator.

利用烟道气和电渗析的脱硫废水零排放处理方法,该方法是利用所述系统实现的,所述方法包括如下步骤:A zero-discharge treatment method for desulfurization wastewater using flue gas and electrodialysis, the method is realized by using the system, and the method includes the following steps:

(1)将脱硫废水原水依次通入化学沉淀絮凝单元1的中和池、沉淀池、絮凝池和澄清池进行中和、沉淀、絮凝和澄清处理,澄清液最后进入1#清水池;(1) The raw water of desulfurization wastewater is passed into the neutralization tank, sedimentation tank, flocculation tank and clarification tank of the chemical precipitation flocculation unit 1 in sequence for neutralization, precipitation, flocculation and clarification, and the clarified liquid finally enters the 1# clear water tank;

(2)将上述步骤(1)中的澄清液依次通入石灰‐烟道气软化单元2中的苛化反应池和碳化反应池进行苛化、碳化处理,澄清液进入2#清水池;(2) The clarified liquid in the above step (1) is passed into the causticizing reaction tank and the carbonization reaction tank in the lime-flue gas softening unit 2 successively to carry out causticizing and carbonizing treatment, and the clarified liquid enters the 2# clear water tank;

(3)将上述步骤(2)获得的澄清液通入膜浓缩单元3,首先对该澄清液进行超滤处理,超滤的产水通入电渗析装置进行分盐和浓缩;电渗析产生的淡水通入反渗透装置进行纯化,同时产生含有NaCl的浓水;反渗透产生的淡水回用于生产,产生的浓水重新进入电渗析装置进行处理;(3) The clarified liquid that above-mentioned step (2) obtains is passed into membrane concentration unit 3, at first this clarified liquid is carried out ultrafiltration treatment, and the product water of ultrafiltration is passed into electrodialysis device and carries out salt separation and concentration; Electrodialysis produces The fresh water is passed into the reverse osmosis device for purification, and concentrated water containing NaCl is produced at the same time; the fresh water generated by reverse osmosis is reused for production, and the generated concentrated water enters the electrodialysis device for treatment;

(4)将上述步骤(3)电渗析装置产生的含有NaCl的浓水通入蒸发结晶单元4,获得到工业级NaCl结晶盐和冷凝水,冷凝水回用于生产;(4) Pass the concentrated water containing NaCl produced by the electrodialysis device in the above step (3) into the evaporation crystallization unit 4 to obtain industrial-grade NaCl crystalline salt and condensed water, and the condensed water is reused for production;

所述步骤(1)中,中和池中加入石灰乳,沉淀池中加入有机硫,石灰乳或有机硫与铁、铅、铬、铜、汞重金属离子反应产生氢氧化物或硫化物;In the described step (1), milk of lime is added in the neutralization tank, organic sulfur is added in the sedimentation tank, milk of lime or organic sulfur reacts with iron, lead, chromium, copper, mercury heavy metal ions to produce hydroxide or sulfide;

所述步骤(1)中,絮凝池中加入絮凝剂,使废水中的悬浮物产生沉淀,澄清池中加入助凝剂,使产生的沉淀物加速分离;In the step (1), a flocculant is added to the flocculation tank to cause the suspended matter in the waste water to precipitate, and a coagulant aid is added to the clarification tank to accelerate the separation of the produced sediment;

所述步骤(2)中,在苛化反应池加入石灰乳和硫酸钠,发生下述反应:In described step (2), milk of lime and sodium sulfate are added in the causticizing reaction tank, and following reaction takes place:

Ca(OH)2+MgSO4→CaSO4+Mg(OH)2Ca(OH) 2 +MgSO 4 →CaSO 4 +Mg(OH) 2

Ca(OH)2+Na2SO4→CaSO4+2NaOHCa(OH) 2 +Na 2 SO 4 →CaSO 4 +2NaOH

脱除废水中的Mg2+离子并产生氢氧化钠,然后向体系中加入一定的絮凝剂和助凝剂,充分絮凝澄清;Remove Mg 2+ ions in wastewater and generate sodium hydroxide, then add certain flocculants and coagulants to the system to fully flocculate and clarify;

所述步骤(2)中,在碳化反应池中通入烟道气,发生下述反应:In described step (2), pass into flue gas in carbonization reaction pool, following reaction takes place:

2NaOH+CO2→Na2CO3+H2O2NaOH+CO 2 →Na 2 CO 3 +H 2 O

Na2CO3+Ca2+→CaCO3↓+2Na+ Na 2 CO 3 +Ca 2+ →CaCO 3 ↓+2Na +

脱除废水中的Ca2+离子,然后向体系中加入一定的絮凝剂和助凝剂,充分絮凝澄清;Remove Ca 2+ ions in wastewater, and then add certain flocculants and coagulants to the system to fully flocculate and clarify;

所述步骤(2)中,苛化反应池中石灰乳和硫酸钠的加入量应控制产生氢氧化钠的量在0.05-0.2g/L之间;In described step (2), the add-on of milk of lime and sodium sulfate should control the amount that produces sodium hydroxide between 0.05-0.2g/L in the causticizing reaction tank;

所述步骤(2)中,碳化反应池中通入的烟道气为经过脱硝、除尘和脱硫的净烟气,在常温常压下缓慢通入,烟道气的通入量应使体系的pH在9-13之间;In the step (2), the flue gas introduced into the carbonization reaction tank is the net flue gas through denitrification, dust removal and desulfurization, which is slowly introduced at normal temperature and pressure, and the amount of flue gas introduced should make the system pH between 9-13;

所述步骤(3)中,超滤的目的是脱除水中的悬浮固体(SS),使出水满足后续膜处理和蒸发结晶处理的要求,超滤浓水回流至化学絮凝沉淀单元1的中和池;In the step (3), the purpose of ultrafiltration is to remove suspended solids (SS) in the water, so that the effluent meets the requirements of subsequent membrane treatment and evaporation crystallization treatment, and the ultrafiltration concentrated water is returned to the chemical flocculation precipitation unit 1 for neutralization pool;

所述步骤(3)中,电渗析离子交换膜采用一价离子选择性膜,使废水中的Cl-在浓水中富集,而SO4 2-留在淡水侧,提高后续结晶的纯度;In the step (3), the electrodialysis ion-exchange membrane adopts a monovalent ion-selective membrane, so that the Cl in the wastewater is enriched in the concentrated water, while the SO 4 2- is left on the fresh water side to improve the purity of subsequent crystallization;

所述步骤(3)中,反渗透装置产生的淡水中总溶解性固体(TDS)在0.05%以下,满足工业回用水的要求,膜浓缩单元淡水回收率不低于90%。In the step (3), the total dissolved solids (TDS) in the fresh water produced by the reverse osmosis device is less than 0.05%, meeting the requirements of industrial reuse water, and the fresh water recovery rate of the membrane concentration unit is not lower than 90%.

所述步骤(1)中,絮凝池中加入的絮凝剂为聚合氯化硫酸铁、聚合氯化铝、聚合硫酸铁中的一种或几种;澄清池中加入的助凝剂为聚丙烯酰胺、聚丙烯酸钠、壳聚糖中的一种或几种。In the step (1), the flocculant added in the flocculation tank is one or more of polyferric chloride sulfate, polyaluminum chloride, and polyferric sulfate; the coagulant aid added in the clarification tank is polyacrylamide , sodium polyacrylate, chitosan or one or more.

所述步骤(2)中,苛化反应池中加入的絮凝剂为聚合氯化硫酸铁、聚合氯化铝、聚合硫酸铁中的一种或几种;苛化反应池中加入的助凝剂为聚丙烯酰胺、聚丙烯酸钠、壳聚糖中的一种或几种;In the step (2), the flocculant added in the causticizing reaction tank is one or more of polyferric chloride sulfate, polyaluminum chloride, and polyferric sulfate; the coagulant added in the causticizing reaction tank One or more of polyacrylamide, sodium polyacrylate, and chitosan;

所述步骤(2)中,碳化反应池中加入的絮凝剂为聚合氯化硫酸铁、聚合氯化铝、聚合硫酸铁中的一种或几种;碳化反应池中加入的助凝剂为聚丙烯酰胺、聚丙烯酸钠、壳聚糖中的一种或几种。In the step (2), the flocculant added in the carbonization reaction tank is one or more of polymeric ferric sulfate chloride, polyaluminum chloride, and polyferric sulfate; the coagulation aid added in the carbonization reaction tank is poly One or more of acrylamide, sodium polyacrylate, and chitosan.

所述步骤(3)中,电渗析装置采用倒极操作,避免膜面的结垢。In the step (3), the electrodialysis device adopts pole-reversing operation to avoid scaling on the membrane surface.

与现有技术相比较,本发明具有如下优点:Compared with the prior art, the present invention has the following advantages:

1)利用燃煤电厂经过脱硝、除尘、脱硫的净烟道气对化学沉淀絮凝单元的出水进行软化,既能够代替昂贵的纯碱,降低软化成本,达到较高的软化效率,避免了后续设备的结垢和腐蚀,又促进了CO2减排。按脱硫废水中钙镁离子总量200mM计算,处理每吨脱硫废水的同时可减排约8.8g的二氧化碳。1) Use the clean flue gas of coal-fired power plants that has undergone denitrification, dust removal, and desulfurization to soften the effluent water of the chemical precipitation flocculation unit, which can replace expensive soda ash, reduce softening costs, achieve higher softening efficiency, and avoid follow-up equipment. Fouling and corrosion, in turn contribute to CO2 emission reductions. Calculated based on the total amount of calcium and magnesium ions in desulfurization wastewater being 200mM, about 8.8g of carbon dioxide can be reduced while treating each ton of desulfurization wastewater.

2)引入电渗析法改进传统的膜浓缩工艺,使电渗析和反渗透均处在最佳处理条件下,降低能耗和处理成本;电渗析离子交换膜可采用一价离子选择性膜,使废水中的SO4 2-留在淡水侧,Cl-离子在浓水中富集,进而通过蒸发结晶获得工业级NaCl结晶盐。2) Introduce electrodialysis to improve the traditional membrane concentration process, so that both electrodialysis and reverse osmosis are under the best treatment conditions, reducing energy consumption and treatment costs; electrodialysis ion exchange membranes can use monovalent ion-selective membranes, so that The SO 4 2- in the wastewater stays on the fresh water side, and the Cl - ions are enriched in the concentrated water, and then the industrial grade NaCl crystalline salt is obtained through evaporation and crystallization.

附图说明Description of drawings

图1为本发明系统及方法流程图。Fig. 1 is a flow chart of the system and method of the present invention.

具体实施方式detailed description

下面结合附图和具体实施例对本发明作更详细的说明。The present invention will be described in more detail below in conjunction with the accompanying drawings and specific embodiments.

脱硫废水原水主要成分如下:TDS 20000‐60000mg/L;SS 5000‐10000mg/L;SO4 2‐2000‐6000mg/L;Ca2+1500‐5000mg/L;Mg2+ 3000‐6000mg/L。如图1所示,将脱硫废水通入化学沉淀絮凝单元1进行中和、沉淀、絮凝、澄清处理,通过加入石灰乳、有机硫、聚合氯化硫酸铁和聚丙烯酰胺进行沉淀絮凝反应,获得满足《火电厂石灰石‐石膏湿法脱硫废水水质控制指标》(DL/T 997‐2006)的水质要求的澄清液;将获得的澄清液通入石灰‐烟道气软化单元2进行苛化、碳化和澄清处理,通过加入石灰乳和硫酸钠,使体系中的Mg2+沉降下来,同时硫酸钠和石灰乳反应生成硫酸钙沉淀和氢氧化钠;向体系中加入聚合氯化硫酸铁和聚丙烯酰胺,充分絮凝澄清。将所得澄清液通入碳化池,将经过脱硝、除尘和脱硫的净烟气通入碳化池中,烟道气中的二氧化碳被体系中的氢氧化钠吸收产生碳酸根,碳酸根与钙离子形成碳酸钙沉淀。该石灰‐烟道气软化单元2中,苛化反应氢氧化钠的积累量为0.1g/L,烟道气通入后体系pH变为10。向体系中加入聚合硫酸铁和聚丙烯酸钠,充分絮凝澄清。石灰‐烟道气软化单元2的出水钙镁离子总量不超过20mg/L。将石灰‐烟道气软化单元2获得的澄清液进行超滤处理,超滤产水率为95%,浓水回流到化学沉淀絮凝单元重新混凝沉淀;超滤产生的淡水中SS小于0.2mg/L,通入电渗析装置进行浓缩。电渗析装置采用频繁倒极操作,防止结垢;离子交换膜选用一价离子选择性交换膜,使废水中的Cl和SO4 2‐发生分离,使氯化钠在电渗析浓水中富集,提高后续结晶的纯度。电渗析采用5并2串连接方式,产生TDS为15%的浓水,经过蒸发结晶单元4蒸发结晶后获得工业级NaCl结晶盐。电渗析淡水TDS为0.5%,通过耐污染卷式反渗透膜进一步纯化,反渗透淡水TDS在0.05%以下,可作为工业回用水。反渗透浓水TDS为2%,经过一级电渗析浓缩至6%,经过蒸发结晶后获得工业级Na2SO4结晶盐,电渗析淡水回流至反渗透进水处。膜浓缩单元产水回收率为80%。本发明提出的脱硫废水零排放方法,可实现废物资源化利用,消除了废水和固废污染,具有良好的经济和环境效益。The main components of desulfurization wastewater raw water are as follows: TDS 20000‐60000mg/L; SS 5000‐10000mg/L; SO 4 2‐2000‐6000mg /L; Ca 2+ 1500‐5000mg/L; Mg 2+ 3000‐6000mg/L. As shown in Figure 1, the desulfurization wastewater is passed into the chemical precipitation flocculation unit 1 for neutralization, precipitation, flocculation, and clarification treatment, and the precipitation flocculation reaction is carried out by adding lime milk, organic sulfur, polyferric sulfate chloride and polyacrylamide to obtain Clarified liquid that meets the water quality requirements of "Water Quality Control Indicators for Limestone-Gypsum Wet Desulfurization Wastewater in Thermal Power Plants" (DL/T 997-2006); pass the obtained clarified liquid into lime-flue gas softening unit 2 for causticization and carbonization and clarification treatment, by adding milk of lime and sodium sulfate, the Mg 2+ in the system will settle down, and at the same time, sodium sulfate and milk of lime will react to form calcium sulfate precipitate and sodium hydroxide; add polyferric sulfate chloride and polypropylene to the system Amide, fully flocculated and clarified. The obtained clarified liquid is passed into the carbonization pool, and the clean flue gas that has undergone denitration, dust removal and desulfurization is passed into the carbonization pool. The carbon dioxide in the flue gas is absorbed by the sodium hydroxide in the system to produce carbonate, and the carbonate and calcium ions form Calcium carbonate precipitates. In the lime-flue gas softening unit 2, the accumulation of causticizing reaction sodium hydroxide is 0.1g/L, and the pH of the system becomes 10 after the flue gas is fed. Add polyferric sulfate and sodium polyacrylate to the system for full flocculation and clarification. The total amount of calcium and magnesium ions in the lime-flue gas softening unit 2 shall not exceed 20mg/L. The clarified liquid obtained from the lime-flue gas softening unit 2 is subjected to ultrafiltration treatment, and the ultrafiltration water production rate is 95%, and the concentrated water is returned to the chemical precipitation flocculation unit for re-coagulation and precipitation; the SS in the fresh water produced by ultrafiltration is less than 0.2mg /L, passed into the electrodialysis device for concentration. The electrodialysis device adopts frequent electrode reversal operation to prevent scaling; the ion exchange membrane uses a monovalent ion selective exchange membrane to separate Cl - and SO 4 2 - in the wastewater, so that sodium chloride can be enriched in the concentrated electrodialysis water , to improve the purity of subsequent crystallization. The electrodialysis adopts 5 parallel 2 series connections to produce concentrated water with a TDS of 15%. After evaporating and crystallizing unit 4, industrial grade NaCl crystalline salt is obtained. The TDS of electrodialysis fresh water is 0.5%, which is further purified through the anti-pollution roll-type reverse osmosis membrane. The TDS of reverse osmosis fresh water is below 0.05%, which can be used as industrial reuse water. The TDS of reverse osmosis concentrated water is 2%, which is concentrated to 6% after first-stage electrodialysis, and industrial grade Na 2 SO 4 crystalline salt is obtained after evaporation and crystallization, and the electrodialysis fresh water is returned to the reverse osmosis inlet. The water recovery rate of the membrane concentration unit is 80%. The zero-discharge method of desulfurization waste water proposed by the invention can realize waste resource utilization, eliminate waste water and solid waste pollution, and have good economic and environmental benefits.

Claims (9)

1. flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system are utilized, it is characterised in that:The system includes chemistry Precipitation flocculation unit (1), lime-flue gas pliable cell (2), film upgrading unit (3) and evaporative crystallization unit (4);
The chemical precipitation flocculation unit (1) is by being sequentially connected the neutralization pond for connecing, sedimentation basin, flocculation basin, depositing reservoir by pipeline Constituted with 1# clear water reserviors, the water inlet of neutralization pond is connected with the floss hole of desulfurization wastewater;Milk of lime is provided with the neutralization pond Chemicals dosing plant;Organic sulfur chemicals dosing plant is provided with the sedimentation basin;Flocculant is provided with the flocculation basin and flocculation aid adds Medicine device;Mud discharging mouth is arranged at the depositing reservoir bottom, and mud discharging mouth is connected by pipeline with device for dehydrating sladge waste;
The lime-flue gas pliable cell (2) is by being sequentially connected the causticizing reaction pond for connecing, carburizing reagent pond and 2# by pipeline Clear water reserviors are constituted, and causticizing reaction pond is connected with the 1# clear water reserviors in chemical precipitation flocculation unit (1) by pipeline;The causticization is anti- Ying Chizhong is provided with milk of lime, sodium sulphate, flocculant and flocculation aid chemicals dosing plant, and there are mud discharging mouth, spoil disposal in causticizing reaction bottom of pond portion Mouth is connected by pipeline with device for dehydrating sladge waste;The bottom in the carburizing reagent pond is disposed with gas distributor, gas distributor It is connected with flue gas compression fan, flocculant, flocculation aid chemicals dosing plant is provided with carburizing reagent pond, carburizing reagent bottom of pond portion has Mud discharging mouth, mud discharging mouth is connected by pipeline with device for dehydrating sladge waste;Watery hydrochloric acid chemicals dosing plant is provided with the 2# clear water reserviors;
The film upgrading unit (3) is by being sequentially connected the ultrafiltration apparatus for connecing, electrodialysis plant and reverse osmosis unit group by pipeline Into;The water inlet of the ultrafiltration apparatus is connected with the delivery port of the 2# clear water reserviors of lime-flue gas pliable cell (2), ultrafiltration dress The delivery port put is connected with the water inlet of electrodialysis plant, concentrated water water return outlet and the chemical precipitation flocculation unit (1) of ultrafiltration apparatus Neutralization pond be connected;The concentrated water discharge mouthful of electrodialysis plant is connected with evaporative crystallization unit (4), and fresh water floss hole is filled with counter-infiltration The water inlet put is connected;The concentrated water discharge mouthful of the reverse osmosis unit counter-infiltration is connected with the water inlet of electrodialysis plant.
2. utilization flue gas according to claim 1 and electrodialytic desulfurization wastewater zero-discharge treatment system, its feature exist In:The electrodialysis plant is multi-stage countercurrent pole-reversing electroosmosis, employs monovalent ion selective membrane.
3. utilization flue gas according to claim 1 and electrodialytic desulfurization wastewater zero-discharge treatment system, its feature exist In:The reverse osmosis unit employs coiled reverse osmosis membrane.
4. utilization flue gas according to claim 1 and electrodialytic desulfurization wastewater zero-discharge treatment system, its feature exist In:The evaporative crystallization unit (4) employs mechanical recompression evaporator.
5. flue gas and electrodialytic zero emission treatment of desulfured waste water are utilized, it is characterised in that:The method is to utilize right It is required that what system described in 1 to 4 any one was realized, methods described comprises the following steps:
(1) desulfurization wastewater raw water is passed through neutralization pond, sedimentation basin, flocculation basin and the clarification of chemical precipitation flocculation unit (1) successively Pond is neutralized, is precipitated, being flocculated and clarifying treatment, and clarified solution finally enters 1# clear water reserviors;
(2) by the clarified solution in above-mentioned steps (1) be passed through successively causticizing reaction pond in lime-flue gas pliable cell (2) and Carburizing reagent pond carries out causticization, carbonization treatment, and clarified solution enters 2# clear water reserviors;
(3) clarified solution that above-mentioned steps (2) are obtained is passed through film upgrading unit (3), hyperfiltration treatment is carried out to the clarified solution first, The product water of ultrafiltration is passed through electrodialysis plant and carries out point salt and concentration;Electrodialysis produce fresh water be passed through reverse osmosis unit carry out it is pure Change, while producing the concentrated water containing NaCl;The fresh water that counter-infiltration is produced is back to production, and the concentrated water of generation reenters electrodialysis Device is processed;
(4) concentrated water containing NaCl that above-mentioned steps (3) electrodialysis plant is produced is passed through evaporative crystallization unit (4), is acquired Technical grade NaCl crystal salts and condensed water, recycling condensing water is in production;
In the step (1), milk of lime is added in neutralization pond, add organic sulfur in sedimentation basin, milk of lime or organic sulfur and iron, Lead, chromium, copper, the reaction of mercury heavy metal ion produce hydroxide or sulfide;
In the step (1), flocculant is added in flocculation basin, the suspension in waste water is produced precipitation, added in depositing reservoir and helped Solidifying agent, makes the sediment of generation accelerate to separate;
In the step (2), milk of lime and sodium sulphate are added in causticizing reaction pond, following reactions occur:
Ca(OH)2+MgSO4→CaSO4+Mg(OH)2
Ca(OH)2+Na2SO4→CaSO4+2NaOH
Mg in removing waste water2+Ion simultaneously produces NaOH, then to certain flocculant and flocculation aid is added in system, fills Divide flocculation clarification;
In the step (2), flue gas is passed through in carburizing reagent pond, following reactions occur:
2NaOH+CO2→Na2CO3+H2O
Na2CO3+Ca2+→CaCO3↓+2Na+
Ca in removing waste water2+Ion, then to certain flocculant and flocculation aid is added in system, fully flocculation clarification;
In the step (2), the addition of milk of lime and sodium sulphate should control to produce the amount of NaOH to exist in causticizing reaction pond Between 0.05-0.2g/L;
In the step (2), the flue gas being passed through in carburizing reagent pond is the neat stress by denitration, dedusting and desulfurization, normal It is slowly introducing under normal temperature and pressure, the intake of flue gas should make the pH of system between 9-13;
In the step (3), the purpose of ultrafiltration is to remove the suspended solid (SS) in water, water outlet is met follow-up film process and steaming Send out the requirement of crystallization treatment, the neutralization pond of ultrafiltration concentrate recirculation to chemical flocculation precipitation unit (1);
In the step (3), electrodialysis-ion exchange film uses monovalent ion selective membrane, makes the Cl- in waste water in concentrated water Enrichment, and SO4 2-Dilute side is stayed in, the purity of later crystallization is improved;
In the step (3), total dissolved solid TDS meets industry below 0.05% in the fresh water that reverse osmosis unit is produced The requirement of recycle-water, film upgrading unit fresh-water recovery rate is not less than 90%.
6. method according to claim 5, it is characterised in that:In the step (1), the flocculant added in flocculation basin is One or more in poly-ferric sulfate chloride, aluminium polychloride, bodied ferric sulfate;The flocculation aid added in depositing reservoir is poly- third One or more in acrylamide, Sodium Polyacrylate, shitosan.
7. method according to claim 5, it is characterised in that:In the step (2), the flocculation added in causticizing reaction pond Agent is one or more in poly-ferric sulfate chloride, aluminium polychloride, bodied ferric sulfate;What is added in causticizing reaction pond helps solidifying Agent is one or more in polyacrylamide, Sodium Polyacrylate, shitosan.
8. method according to claim 5, it is characterised in that:In the step (2), the flocculation added in carburizing reagent pond Agent is one or more in poly-ferric sulfate chloride, aluminium polychloride, bodied ferric sulfate;What is added in carburizing reagent pond helps solidifying Agent is one or more in polyacrylamide, Sodium Polyacrylate, shitosan.
9. method according to claim 5, it is characterised in that:In the step (3), electrodialysis plant uses the behaviour of falling pole Make, it is to avoid the fouling of face.
CN201710021176.9A 2017-01-11 2017-01-11 Using flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system and method Pending CN106830479A (en)

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Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619137A (en) * 2017-10-10 2018-01-23 华北电力大学(保定) The apparatus and method of calcium and magnesium in a kind of carbonizatin method recovery desulfurization wastewater
CN107892427A (en) * 2017-12-29 2018-04-10 中国能源建设集团浙江省电力设计院有限公司 A kind of Desulphurization for Coal-fired Power Plant Wastewater zero-discharge treatment system and method
CN107902826A (en) * 2017-11-06 2018-04-13 新疆环境工程技术有限责任公司 A kind of power plant desulfurization wastewater zero-discharge treatment system and method
CN108383308A (en) * 2018-02-11 2018-08-10 浙江天蓝环保技术股份有限公司 A kind of low energy consumption desulfurization wastewater technique of zero discharge and device
CN108623055A (en) * 2018-07-18 2018-10-09 南京工业大学 Pulping and papermaking wastewater zero-discharge softening process and device
CN108821407A (en) * 2018-06-26 2018-11-16 广州发展集团股份有限公司 The processing method of desulfurization wastewater
CN108975570A (en) * 2018-09-19 2018-12-11 南京友智科技有限公司 A kind of device and method handling industrially desulfurized waste water using stack gases
CN109912103A (en) * 2019-04-24 2019-06-21 盐城工学院 A zero-discharge system for desulfurization wastewater in a coal-fired plant
CN110590072A (en) * 2019-10-08 2019-12-20 南京霄祥工程技术有限公司 Zero-emission treatment process and system for power plant desulfurization wastewater
CN110921948A (en) * 2018-09-19 2020-03-27 杭州水处理技术研究开发中心有限公司 Treatment device and treatment method for high-salinity industrial wastewater
CN112794541A (en) * 2021-03-12 2021-05-14 中冶北方(大连)工程技术有限公司 Metallurgical wet desulfurization wastewater zero discharge treatment system
CN112897730A (en) * 2021-01-07 2021-06-04 易门铜业有限公司 System and method for treating and recycling high-arsenic high-fluorine waste acid
CN113292188A (en) * 2021-03-17 2021-08-24 华电水务工程有限公司 Non-softening concentrated high-salinity wastewater treatment process based on precipitated salt recovery
CN114735874A (en) * 2022-04-08 2022-07-12 中国石油化工股份有限公司 Method and device for continuously treating high-salinity desulfurization wastewater
CN114933384A (en) * 2022-05-25 2022-08-23 上海电站辅机厂有限公司 Selective electrodialysis concentration salt separation recycling system and method for power plant desulfurization wastewater treatment
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
CN115490387A (en) * 2021-06-18 2022-12-20 新特能源股份有限公司 Comprehensive treatment method and device for various tail gas treatment recovery liquids
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump
US12040517B2 (en) 2022-11-15 2024-07-16 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
US12341228B2 (en) 2022-11-15 2025-06-24 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104355473A (en) * 2014-10-28 2015-02-18 中国科学院过程工程研究所 Method for carrying out desalination and zero-discharge processing of power plant desulphurization wastewater by adopting electrodialysis technology
CN105347592A (en) * 2015-10-28 2016-02-24 北京国电富通科技发展有限责任公司 Recycling zero-emission treatment process for desulfurization wastewater
CN105481157A (en) * 2015-12-18 2016-04-13 王辛平 Method for zero emission treatment of desulfurization waste water based on flue gas waste heat evaporation
CN105540960A (en) * 2016-03-02 2016-05-04 北京新源国能科技集团股份有限公司 Treatment method and treatment system for wastewater produced during flue gas desulfurization adopting limestone/lime-gypsum method
CN205575837U (en) * 2016-03-02 2016-09-14 北京新源国能科技集团股份有限公司 Processing system of lime stone / lime - gypsum method flue gas desulfurization waste water
US20160367936A1 (en) * 2015-02-19 2016-12-22 Mitsubishi Heavy Industries, Ltd. Water treatment system and method
CN206521361U (en) * 2017-01-11 2017-09-26 中国华能集团清洁能源技术研究院有限公司 Utilize flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104355473A (en) * 2014-10-28 2015-02-18 中国科学院过程工程研究所 Method for carrying out desalination and zero-discharge processing of power plant desulphurization wastewater by adopting electrodialysis technology
US20160367936A1 (en) * 2015-02-19 2016-12-22 Mitsubishi Heavy Industries, Ltd. Water treatment system and method
CN105347592A (en) * 2015-10-28 2016-02-24 北京国电富通科技发展有限责任公司 Recycling zero-emission treatment process for desulfurization wastewater
CN105481157A (en) * 2015-12-18 2016-04-13 王辛平 Method for zero emission treatment of desulfurization waste water based on flue gas waste heat evaporation
CN105540960A (en) * 2016-03-02 2016-05-04 北京新源国能科技集团股份有限公司 Treatment method and treatment system for wastewater produced during flue gas desulfurization adopting limestone/lime-gypsum method
CN205575837U (en) * 2016-03-02 2016-09-14 北京新源国能科技集团股份有限公司 Processing system of lime stone / lime - gypsum method flue gas desulfurization waste water
CN206521361U (en) * 2017-01-11 2017-09-26 中国华能集团清洁能源技术研究院有限公司 Utilize flue gas and electrodialytic desulfurization wastewater zero-discharge treatment system

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619137A (en) * 2017-10-10 2018-01-23 华北电力大学(保定) The apparatus and method of calcium and magnesium in a kind of carbonizatin method recovery desulfurization wastewater
CN107619137B (en) * 2017-10-10 2020-07-14 华北电力大学(保定) A method for recovering calcium and magnesium in desulfurization wastewater by carbonization
CN107902826A (en) * 2017-11-06 2018-04-13 新疆环境工程技术有限责任公司 A kind of power plant desulfurization wastewater zero-discharge treatment system and method
CN107892427A (en) * 2017-12-29 2018-04-10 中国能源建设集团浙江省电力设计院有限公司 A kind of Desulphurization for Coal-fired Power Plant Wastewater zero-discharge treatment system and method
CN108383308A (en) * 2018-02-11 2018-08-10 浙江天蓝环保技术股份有限公司 A kind of low energy consumption desulfurization wastewater technique of zero discharge and device
CN108821407A (en) * 2018-06-26 2018-11-16 广州发展集团股份有限公司 The processing method of desulfurization wastewater
CN108623055A (en) * 2018-07-18 2018-10-09 南京工业大学 Pulping and papermaking wastewater zero-discharge softening process and device
CN108623055B (en) * 2018-07-18 2024-05-10 南京工业大学 Zero-discharge softening process and device for pulping and papermaking wastewater
CN108975570A (en) * 2018-09-19 2018-12-11 南京友智科技有限公司 A kind of device and method handling industrially desulfurized waste water using stack gases
CN110921948A (en) * 2018-09-19 2020-03-27 杭州水处理技术研究开发中心有限公司 Treatment device and treatment method for high-salinity industrial wastewater
CN109912103A (en) * 2019-04-24 2019-06-21 盐城工学院 A zero-discharge system for desulfurization wastewater in a coal-fired plant
CN110590072B (en) * 2019-10-08 2022-02-22 广东山美环境科技有限公司 Zero-emission treatment process and system for power plant desulfurization wastewater
CN110590072A (en) * 2019-10-08 2019-12-20 南京霄祥工程技术有限公司 Zero-emission treatment process and system for power plant desulfurization wastewater
CN112897730A (en) * 2021-01-07 2021-06-04 易门铜业有限公司 System and method for treating and recycling high-arsenic high-fluorine waste acid
CN112897730B (en) * 2021-01-07 2023-01-06 易门铜业有限公司 System and method for treating and recycling high-arsenic high-fluorine waste acid
CN112794541A (en) * 2021-03-12 2021-05-14 中冶北方(大连)工程技术有限公司 Metallurgical wet desulfurization wastewater zero discharge treatment system
CN113292188A (en) * 2021-03-17 2021-08-24 华电水务工程有限公司 Non-softening concentrated high-salinity wastewater treatment process based on precipitated salt recovery
CN115490387A (en) * 2021-06-18 2022-12-20 新特能源股份有限公司 Comprehensive treatment method and device for various tail gas treatment recovery liquids
CN114735874A (en) * 2022-04-08 2022-07-12 中国石油化工股份有限公司 Method and device for continuously treating high-salinity desulfurization wastewater
US11502323B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11502322B1 (en) 2022-05-09 2022-11-15 Rahul S Nana Reverse electrodialysis cell with heat pump
US11563229B1 (en) 2022-05-09 2023-01-24 Rahul S Nana Reverse electrodialysis cell with heat pump
US11611099B1 (en) 2022-05-09 2023-03-21 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
US11699803B1 (en) 2022-05-09 2023-07-11 Rahul S Nana Reverse electrodialysis cell with heat pump
US12107308B2 (en) 2022-05-09 2024-10-01 Rahul S Nana Reverse electrodialysis cell and methods of use thereof
CN114933384A (en) * 2022-05-25 2022-08-23 上海电站辅机厂有限公司 Selective electrodialysis concentration salt separation recycling system and method for power plant desulfurization wastewater treatment
US12040517B2 (en) 2022-11-15 2024-07-16 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
US11855324B1 (en) 2022-11-15 2023-12-26 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump
US12341228B2 (en) 2022-11-15 2025-06-24 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell and methods of use thereof
US12374711B2 (en) 2022-11-15 2025-07-29 Rahul S. Nana Reverse electrodialysis or pressure-retarded osmosis cell with heat pump

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