CN106830702A - A kind of safety glass prepares safety glass method with UV photocuring frosted glaze and using it - Google Patents
A kind of safety glass prepares safety glass method with UV photocuring frosted glaze and using it Download PDFInfo
- Publication number
- CN106830702A CN106830702A CN201710067401.2A CN201710067401A CN106830702A CN 106830702 A CN106830702 A CN 106830702A CN 201710067401 A CN201710067401 A CN 201710067401A CN 106830702 A CN106830702 A CN 106830702A
- Authority
- CN
- China
- Prior art keywords
- safety glass
- glaze
- frosted
- parts
- photocuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005336 safety glass Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000000016 photochemical curing Methods 0.000 title claims abstract description 12
- 239000011521 glass Substances 0.000 claims abstract description 17
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 4
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000005245 sintering Methods 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- RFJZMPMMBCKYGX-UHFFFAOYSA-N butyl prop-2-enoate;methyl prop-2-enoate Chemical compound COC(=O)C=C.CCCCOC(=O)C=C RFJZMPMMBCKYGX-UHFFFAOYSA-N 0.000 claims 1
- MZRQZJOUYWKDNH-UHFFFAOYSA-N diphenylphosphoryl-(2,3,4-trimethylphenyl)methanone Chemical compound CC1=C(C)C(C)=CC=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MZRQZJOUYWKDNH-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 238000005286 illumination Methods 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 description 2
- -1 Trimethylbenzoyl Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B27/00—Tempering or quenching glass products
- C03B27/02—Tempering or quenching glass products using liquid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2262—Oxides; Hydroxides of metals of manganese
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses a kind of safety glass safety glass method is prepared with UV photocuring frosted glaze and using it, glaze is using epoxy acrylate, first class methyl acrylate, butyl acrylate, manganese oxide, calcite, aluminum oxide, auxiliary agent as material, obtain safety glass UV photocuring frosted glaze, processed by pretreatment, light-initiated, heating, insulation, cleaning step afterwards, obtained safety glass.The present invention is doped in photocureable coating by by the frosted composition of frosted glaze, and because photocureable coating will produce polymerization to form coating in high temperature or illumination way, can directly adulterate frosted composition, reach frosted finish effect；In addition, glazing technology and steel process are carried out in the present invention simultaneously, so that can parameter bonding action between glaze and glass, it is to avoid glaze comes off in glass surface, influences using effect.
Description
Technical field
The present invention relates to glaze field, more particularly to a kind of safety glass is prepared with UV photocuring frosted glaze and using it
Safety glass method.
Background technology
In traditional safety glass production technology, in order to allow safety glass using the effect of surface frosted, most useizations
The mode for learning etching is processed, by that will be etched on the glass surface, to damage glass surface as cost, and undoubtedly efficiency
It is relatively low and serious to environmental pollution, fail to meet demand.
In addition, when there is the safety glass of production painting glaze on the market, general glass tempering process is divided with glaze handicraft is applied
Open operation, and its shortcoming to be glaze fail carries out generation with safety glass and be bonded, therefore often such that glaze is easily in glass
Surface comes off, and influences using effect.
The content of the invention
The technical problem to be solved in the present invention is：For above-mentioned the deficiencies in the prior art, there is provided a kind of safety glass UV
Photocuring frosted glaze and prepare safety glass method using it.
The present invention solve its technical problem solution be：A kind of safety glass UV photocuring frosted glaze, it is special
Levy and be, be formulated according to certain part by weight by following component：
Epoxy acrylate 30-100 parts
10-20 parts of first class methyl acrylate
Butyl acrylate 1-9 parts
Manganese oxide 1-3 parts
0.2-0.8 part of calcite
Aluminum oxide 1-3 parts
Auxiliary agent 1-3 parts.
A kind of method that safety glass is prepared using glaze described above, it is characterised in that comprise the following steps：
（1）Glass substrate is pre-processed, by Impurity removals such as dust；
（2）By the UV photocuring frosted glaze described in a surface smear claim 1 of glass substrate, and light trigger is added,
It is placed in ultraviolet sintering oven；
（3）By step（2）Temperature being lifted by ultraviolet light and mode of heating in described ultraviolet sintering oven
700-800 DEG C, be incubated 1-3h, after be cooled to room temperature；
（4）Glass surface soaks through water, obtains safety glass product.
As one of preferred technical scheme, it is characterised in that described light trigger is 2,4,6（Trimethylbenzoyl
Base）Diphenyl phosphine oxide.
The beneficial effects of the invention are as follows：The present invention is doped in photocureable coating by by the frosted composition of frosted glaze,
Because photocureable coating will produce polymerization to form coating in high temperature or illumination way, can directly adulterate frosted composition, reach frosted
Effect；In addition, glazing technology is carried out simultaneously with steel process in the present invention, so that can parameter between glaze and glass
Bonding action, it is to avoid glaze comes off in glass surface, influences using effect.
Specific embodiment
The technique effect of design of the invention, concrete structure and generation is carried out below with reference to embodiment clear, complete
Ground description, to be completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is of the invention one
Section Example, rather than whole embodiments, based on embodiments of the invention, those skilled in the art is not paying creativeness
The other embodiment obtained on the premise of work, belongs to the scope of protection of the invention.
Embodiment：A kind of safety glass UV photocuring frosted glaze, it is characterised in that by following component according to certain weight
Amount part is formulated：70 parts of epoxy acrylate；
20 parts of first class methyl acrylate；3 parts of butyl acrylate；2 parts of manganese oxide；0.8 part of calcite；2 parts of aluminum oxide；2 parts of auxiliary agent.
A kind of method that use above-described embodiment glaze prepares safety glass, it is characterised in that comprise the following steps：
（1）Glass substrate is pre-processed, by Impurity removals such as dust；
（2）By the UV photocuring frosted glaze of a surface smear embodiment glaze of glass substrate, and light trigger is added, placed
In ultraviolet sintering oven；
（3）By step（2）Temperature is lifted 800 by ultraviolet light and mode of heating in described ultraviolet sintering oven
DEG C, be incubated 3h, after be cooled to room temperature；
（4）Glass surface soaks through water, obtains safety glass product.
As one of preferred embodiment, it is characterised in that described light trigger is 2,4,6（Trimethylbenzoyl
Base）Diphenyl phosphine oxide.
Better embodiment of the invention is illustrated above, but the invention is not limited to the implementation
Example, those of ordinary skill in the art can also make a variety of equivalent modifications or replace on the premise of without prejudice to spirit of the invention
Change, these equivalent modifications or replacement are all contained in the application claim limited range.
Claims (3)
1. a kind of safety glass UV photocuring frosted glaze, it is characterised in that prepared according to certain part by weight by following component
Form：
Epoxy acrylate 30-100 parts
10-20 parts of first class methyl acrylate
Butyl acrylate 1-9 parts
Manganese oxide 1-3 parts
0.2-0.8 part of calcite
Aluminum oxide 1-3 parts
Auxiliary agent 1-3 parts.
2. the method that glaze described in a kind of usage right requirement 1 prepares safety glass, it is characterised in that comprise the following steps：
（1）Glass substrate is pre-processed, by Impurity removals such as dust；
（2）By the UV photocuring frosted glaze described in a surface smear claim 1 of glass substrate, and light trigger is added,
It is placed in ultraviolet sintering oven；
（3）By step（2）Temperature being lifted by ultraviolet light and mode of heating in described ultraviolet sintering oven
700-800 DEG C, be incubated 1-3h, after be cooled to room temperature；
（4）Glass surface soaks through water, obtains safety glass product.
3. the method for preparing safety glass according to claim 2, it is characterised in that described light trigger is 2,4,6
（Trimethylbenzoyl）Diphenyl phosphine oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067401.2A CN106830702A (en) | 2017-02-07 | 2017-02-07 | A kind of safety glass prepares safety glass method with UV photocuring frosted glaze and using it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710067401.2A CN106830702A (en) | 2017-02-07 | 2017-02-07 | A kind of safety glass prepares safety glass method with UV photocuring frosted glaze and using it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106830702A true CN106830702A (en) | 2017-06-13 |
Family
ID=59121458
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710067401.2A Pending CN106830702A (en) | 2017-02-07 | 2017-02-07 | A kind of safety glass prepares safety glass method with UV photocuring frosted glaze and using it |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106830702A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ308071B6 (en) * | 2018-09-19 | 2019-12-11 | Preciosa As | A method of matt glass surface treatment using a controlled thermal process |
| CN116265411A (en) * | 2021-12-17 | 2023-06-20 | 深圳南玻应用技术有限公司 | Glass processing method, pattern coated glass and insulating glass |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575173A (en) * | 2008-05-05 | 2009-11-11 | 王广武 | UV light- curable glue film glass and manufacture method thereof |
| CN104250472A (en) * | 2013-06-27 | 2014-12-31 | 罗小丰 | Glass UV frosted ink |
| CN105176351A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based frosted new material and preparing method thereof |
| CN106189504A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of environment-friendly type aqueous UV photocuring ceramic ink jet ink and preparation method thereof |
-
2017
- 2017-02-07 CN CN201710067401.2A patent/CN106830702A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575173A (en) * | 2008-05-05 | 2009-11-11 | 王广武 | UV light- curable glue film glass and manufacture method thereof |
| CN104250472A (en) * | 2013-06-27 | 2014-12-31 | 罗小丰 | Glass UV frosted ink |
| CN105176351A (en) * | 2015-10-10 | 2015-12-23 | 徐州市三为水性漆科技有限公司 | Water-based frosted new material and preparing method thereof |
| CN106189504A (en) * | 2016-08-29 | 2016-12-07 | 佛山市高明区海帝陶瓷原料有限公司 | A kind of environment-friendly type aqueous UV photocuring ceramic ink jet ink and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ308071B6 (en) * | 2018-09-19 | 2019-12-11 | Preciosa As | A method of matt glass surface treatment using a controlled thermal process |
| CN116265411A (en) * | 2021-12-17 | 2023-06-20 | 深圳南玻应用技术有限公司 | Glass processing method, pattern coated glass and insulating glass |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170613 |
|
| WD01 | Invention patent application deemed withdrawn after publication |