CN106830999A - A kind of noble metal preparation of resistance to dish-washing machine - Google Patents
A kind of noble metal preparation of resistance to dish-washing machine Download PDFInfo
- Publication number
- CN106830999A CN106830999A CN201710015896.4A CN201710015896A CN106830999A CN 106830999 A CN106830999 A CN 106830999A CN 201710015896 A CN201710015896 A CN 201710015896A CN 106830999 A CN106830999 A CN 106830999A
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- China
- Prior art keywords
- dish
- washing machine
- resistance
- noble metal
- metallo
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000004851 dishwashing Methods 0.000 title claims abstract description 43
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000002904 solvent Substances 0.000 claims abstract description 20
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 13
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 13
- 239000011651 chromium Substances 0.000 claims abstract description 13
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 13
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 12
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000010931 gold Substances 0.000 claims abstract description 12
- 229910052737 gold Inorganic materials 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 12
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 11
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 9
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 5
- 150000007942 carboxylates Chemical class 0.000 claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052718 tin Inorganic materials 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- -1 zirconium Carboxylate Chemical class 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 125000002524 organometallic group Chemical group 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 239000013008 thixotropic agent Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 229910052573 porcelain Inorganic materials 0.000 description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 238000012360 testing method Methods 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 3
- 235000019795 sodium metasilicate Nutrition 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 229910052911 sodium silicate Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229910000897 Babbitt (metal) Inorganic materials 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 241001085205 Prenanthella exigua Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940111120 gold preparations Drugs 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003791 organic solvent mixture Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000010668 rosemary oil Substances 0.000 description 1
- 229940058206 rosemary oil Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000010938 white gold Substances 0.000 description 1
- 229910000832 white gold Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/515—Other specific metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/515—Other specific metals
- C04B41/5161—Tin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Chemically Coating (AREA)
Abstract
The invention provides a kind of noble metal preparation of resistance to dish-washing machine, the noble metal preparation of the resistance to dish-washing machine includes：The metallo-organic compound of the metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the metallo-organic compound of the vanadium being dissolved in solvent, the metallo-organic compound of the zirconium being dissolved in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, the chromium being dissolved in solvent.Using technical scheme, the noble metal preparation of the resistance to dish-washing machine keeps the color of light using the product after fired on the silicate base material, and with mechanical resistant abrasion and chemical resistance corrosion higher, anti- dish-washing machine excellent performance, still keeps the light of the noble metal decorative layer on silicate base material after being tested through resistance to dish-washing machine.
Description
Technical field
The invention belongs to Inorganic Non-metallic Materials decoration technique field, more particularly to a kind of noble metal system of resistance to dish-washing machine
Agent.
Background technology
The noble metal preparation of light is with organic basic compound shape by soluble organic precious metal compounds and one kind
Soluble fluxes and a kind of organic vehicle composition that formula is presented.As a kind of flux, the number of organo-metallic compound
Amount is 0.25-1mol, and every mole of noble metal can use underlying metal.These preparations are employed for the noble metal film on ceramics
Production, sintering temperature is 1140 DEG C.Although but these external coatings can battle line light noble metal speciality, be not resistant to wash
Bowl machine.
Made referrals in patent DE-AS 22 08 915, the polished bright-gold preparations containing Solid non-metallic oxide, higher than Huang
1063 DEG C of the fusing point of gold, it is adaptable to silicate material.Although the golden thin film that it is fired into has relatively highly dense coating, can also show
Show the characteristic of bright golden color, but their mechanical resistant abrasion and chemical resistance corrode poor, it is impossible to anti-dish-washing machine.
The content of the invention
For above technical problem, the invention discloses a kind of noble metal preparation of resistance to dish-washing machine, it is using in silicate
On base material it is fired after product keep the color of light, and with mechanical resistant abrasion higher and chemical resistance corrosion.
In this regard, the technical scheme is that：
A kind of noble metal preparation of resistance to dish-washing machine, the noble metal preparation of the resistance to dish-washing machine includes：
The metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the Organometallic of the vanadium being dissolved in solvent are closed
Thing, the metallo-organic compound of the zirconium being dissolved in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, it is dissolved in solvent
In chromium metallo-organic compound.
Preferably, the noble metal preparation includes the underlying metal flux being dissolved in solvent.
Preferably, the metallo-organic compound of the gold, platinum or palladium is the resinate of gold, platinum or palladium.
Wherein, the selection of the constituent of the solvent of bearing metal organic compound can come from various suitable organic molten
Agent, wherein essential oil can be selected.For example, the composition of solvent can be any suitable simple organic solvent or two kinds or two kinds
More than organic solvent mixture, such as toluene, nitrobenzene, butanol, phenmethylol, cellosolve, butyl cellosolve, acetone, butanone,
Cyclohexanone, ethyl acetate, butyl acetate, ether, turpentine oil, terpineol, dimethylbenzene, various note alkenes such as firpene, cinene etc..
Essential oil can include lavender oil, rosemary oil, lavender spike oil and/or camphorated oil.The noble metal preparation can also include viscous
Mixture, described adhesive is synthetic resin, preferably phenolic resin.
Using this technical scheme, it is fired on the silicate base material after product keep the color of light, with very strong
Mechanical resistant is worn and torn, anti-dish-washing machine performance, through dish-washing machine after, remain to keep the noble metal on silicate base material such as ceramic whiteware, ceramics
The light of decorative layer.
As a further improvement on the present invention, the content of the vanadium accounts for the 0.016~0.1% of component gross weight.
As a further improvement on the present invention, the noble metal preparation of the resistance to dish-washing machine also includes the tin being dissolved in solvent
Metallo-organic compound.
As a further improvement on the present invention, the content of the tin accounts for the 0.08-0.1% of component gross weight.
As a further improvement on the present invention, the metallo-organic compound of the tin is the carboxylate of tin.
As a further improvement on the present invention, the total content of bismuth, zirconium and chromium accounts for the 0.5-1% of component gross weight.
As a further improvement on the present invention, the content of the bismuth accounts for the 0.4-0.8% of component gross weight, and the chromium contains
Amount accounts for the 0.08-0.2% of component gross weight, and the content of the zirconium accounts for the 0.05-0.1% of component gross weight.
As a further improvement on the present invention, the metallo-organic compound of the bismuth is the carboxylate of bismuth, the gold of the vanadium
Category organic compound is the carboxylate of vanadium, and the metallo-organic compound of the zirconium is the carboxylate of zirconium, and the metal of the chromium is organic
Compound is the carboxylate of chromium.
As a further improvement on the present invention, the carboxylate of the bismuth, the carboxylate of vanadium, the carboxylate of zirconium, the carboxylic acid of chromium
The carboxylate of salt and tin is what is extracted from bismuth, zirconium, vanadium, chromium, tin and its mixture.
As a further improvement on the present invention, the roasting that the noble metal preparation of the resistance to dish-washing machine is used on silicate base material
Temperature is 780~820 DEG C.
As a further improvement on the present invention, the noble metal preparation of the resistance to dish-washing machine also includes auxiliary agent, the auxiliary agent bag
Include rosin and flexible resin, the flexible resin such as polyamide.
Using this technical scheme, the flexible resin dissolves as carrier in organo-metallic compound, beneficial to carrying out silk
Wire mark brush.
As a further improvement on the present invention, the auxiliary agent also includes defoamer and thixotropic agent.Using this technical scheme, have
Beneficial to preferably carrying out silk-screen printing.
It is the noble metal using above-mentioned resistance to dish-washing machine the invention also discloses a kind of noble metal decorating film of resistance to dish-washing machine
Preparation is transferred on silicate base material, is calcined at 780~820 DEG C.
Compared with prior art, beneficial effects of the present invention are：
Using technical scheme, the noble metal preparation of the resistance to dish-washing machine uses fired on silicate base material
Product afterwards keeps the color of light, and with mechanical resistant abrasion and chemical resistance corrosion higher, anti-dish-washing machine performance is excellent
It is different, the light of the noble metal decorative layer on silicate base material is still kept after being tested through dish-washing machine.
Specific embodiment
Preferably embodiment of the invention is described in further detail below.
Embodiment 1
Formula table according to table 1 weighs each component, and be mixed it is uniform after, heated 1.5 hours in 75 DEG C of constant temperature,
It is brushed on the region of hard porcelain 0.5cm*4cm, has after then being fired 90 minutes in 820 DEG C of constant temperature, on hard porcelain surface resistance to
The bright gold external coating of dish-washing machine.
By the bright gold external coating on this hard porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into 95 DEG C
In dissolved with the water of 0.5% sodium carbonate, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, hard porcelain table in addition, the hard porcelain with bright gold external coating of this example being put into dish-washing machine and carrying out completion
The bright gold external coating in face does not wear and tear.
The formula table of the embodiment 1 of table 1
Embodiment 2
A kind of noble metal silk-screen printing preparation of light, weighs each component, by above-mentioned substance 90 according to the formula table of table 2
DEG C to stirring between 120 DEG C, it is allowed to homogenize and colloidization reaction.Then, matter is printed on as applique
On the very hard porcelain in ground, printing area size is 5 × 5cm, after being calcined through 820 DEG C, forms one layer of golden layer of light, and it is entered
Row dish-washing machine is tested.
The formula table of the embodiment 2 of table 2
% in upper table is weight percentage.
By the bright golden layer on above-mentioned porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into 95
In DEG C dissolved with the water of 0.5% sodium carbonate in, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, porcelain table in addition, golden layer porcelain of this example with light being put into dish-washing machine and carrying out completion
The bright golden layer in face does not wear and tear.
Embodiment 3
A kind of is the bright white gold preparation (7% gold medal) of silk-screen printing preparation, and formula table is as shown in table 3.According to table 3
Formula table weighs each component, and above-mentioned substance is stirred at 75 DEG C, is allowed to homogenize and thixotropy.Then, as patch
Spend and be equally printed on the very hard porcelain of quality, printing area size is 5x5cm, after being calcined through 820 DEG C, form one layer of light
Bright platinum chromatograph, dish-washing machine test is carried out to it.
The formula table of the embodiment 3 of table 3
% in upper table is weight percentage.
By the bright platinum chromatograph on above-mentioned porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into
In 95 DEG C dissolved with the water of 0.5% sodium carbonate in, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, porcelain in addition, the porcelain of platinum chromatograph of this example with light being put into dish-washing machine and carrying out completion
The bright platinum chromatograph on device surface does not wear and tear.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert
Specific implementation of the invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should be all considered as belonging to of the invention
Protection domain.
Claims (10)
1. a kind of noble metal preparation of resistance to dish-washing machine, it is characterised in that：The noble metal preparation of the resistance to dish-washing machine includes：
It is the metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the metallo-organic compound of the vanadium being dissolved in solvent, molten
The metallo-organic compound of the zirconium in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, it is dissolved in solvent
The metallo-organic compound of chromium.
2. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：It is total that the content of the vanadium accounts for component
The 0.016 ~ 0.1% of weight.
3. the noble metal preparation of resistance to dish-washing machine according to claim 1 and 2, it is characterised in that：The resistance to dish-washing machine it is expensive
Metal preparation also includes the metallo-organic compound of the tin being dissolved in solvent.
4. the noble metal preparation of resistance to dish-washing machine according to claim 3, it is characterised in that：It is total that the content of the tin accounts for component
The 0.08-0.1% of weight, the metallo-organic compound of the tin is the carboxylate of tin.
5. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The total content of bismuth, zirconium and chromium is accounted for
The 0.5-1% of component gross weight.
6. the noble metal preparation of resistance to dish-washing machine according to claim 5, it is characterised in that：It is total that the content of the bismuth accounts for component
The 0.4-0.8% of weight, the content of the chromium accounts for the 0.08-0.2% of component gross weight, and the content of the zirconium accounts for component gross weight
0.05-0.1%。
7. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The Organometallic of the bismuth is closed
Thing is the carboxylate of bismuth, and the metallo-organic compound of the vanadium is the carboxylate of vanadium, and the metallo-organic compound of the zirconium is zirconium
Carboxylate, the metallo-organic compound of the chromium is the carboxylate of chromium.
8. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The noble metal of the resistance to dish-washing machine
Preparation also includes auxiliary agent, and the auxiliary agent includes rosin and flexible resin, and the flexible resin is polyamide；The auxiliary agent also includes
Defoamer and thixotropic agent.
9. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The noble metal of the resistance to dish-washing machine
The sintering temperature that preparation is used on silicate base material is 780 ~ 820 DEG C.
10. a kind of noble metal decorating film of resistance to dish-washing machine, is using the resistance to dish-washing machine as described in claim 1 ~ 9 any one
Noble metal preparation is transferred on silicate base material, is calcined at 780 ~ 820 DEG C.
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| CN201710015896.4A CN106830999B (en) | 2017-01-10 | 2017-01-10 | Precious metal preparation resistant to dish washing machine |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710015896.4A CN106830999B (en) | 2017-01-10 | 2017-01-10 | Precious metal preparation resistant to dish washing machine |
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| CN106830999A true CN106830999A (en) | 2017-06-13 |
| CN106830999B CN106830999B (en) | 2022-09-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116535242A (en) * | 2023-05-06 | 2023-08-04 | 湖北新亚多联新材料有限公司 | Porcelain gold paste suitable for microwave oven and application method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4418099A (en) * | 1982-02-05 | 1983-11-29 | Engelhard Corporation | Non-burnished precious metal composition |
| CN1346339A (en) * | 1999-04-09 | 2002-04-24 | W.C.贺利氏股份有限及两合公司 | Bright noble metal preparation |
| CN1637096A (en) * | 2003-12-17 | 2005-07-13 | W.C.贺利氏有限公司 | Noble metal preparations and lustring preparations for direct and indirect screen printing |
| CN101555163A (en) * | 2009-05-13 | 2009-10-14 | 深圳市永丰源实业有限公司 | Noble metal preparation or luster preparation for direct or indirect silk screen printing |
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2017
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4418099A (en) * | 1982-02-05 | 1983-11-29 | Engelhard Corporation | Non-burnished precious metal composition |
| CN1346339A (en) * | 1999-04-09 | 2002-04-24 | W.C.贺利氏股份有限及两合公司 | Bright noble metal preparation |
| CN1637096A (en) * | 2003-12-17 | 2005-07-13 | W.C.贺利氏有限公司 | Noble metal preparations and lustring preparations for direct and indirect screen printing |
| CN101555163A (en) * | 2009-05-13 | 2009-10-14 | 深圳市永丰源实业有限公司 | Noble metal preparation or luster preparation for direct or indirect silk screen printing |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116535242A (en) * | 2023-05-06 | 2023-08-04 | 湖北新亚多联新材料有限公司 | Porcelain gold paste suitable for microwave oven and application method thereof |
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| CN106830999B (en) | 2022-09-30 |
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