CN107027770A - A kind of Herbicidal combinations with synergistic function - Google Patents
A kind of Herbicidal combinations with synergistic function Download PDFInfo
- Publication number
- CN107027770A CN107027770A CN201710183616.0A CN201710183616A CN107027770A CN 107027770 A CN107027770 A CN 107027770A CN 201710183616 A CN201710183616 A CN 201710183616A CN 107027770 A CN107027770 A CN 107027770A
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- CN
- China
- Prior art keywords
- fluroxypyr
- ester
- chlorine fluorine
- fluorine pyridine
- herbicidal combinations
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- HXELGNKCCDGMMN-UHFFFAOYSA-N [F].[Cl] Chemical compound [F].[Cl] HXELGNKCCDGMMN-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 108010064926 acyl-CoA carboxylase Proteins 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940125717 barbiturate Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 229920003064 carboxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- XFZUQTKDBCOXPP-UHFFFAOYSA-N florpyrauxifen Chemical compound COC1=C(Cl)C=CC(C=2C(=C(N)C(Cl)=C(C(O)=O)N=2)F)=C1F XFZUQTKDBCOXPP-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OLZQTUCTGLHFTQ-UHFFFAOYSA-N octan-2-yl 2-(4-amino-3,5-dichloro-6-fluoropyridin-2-yl)oxyacetate Chemical group CCCCCCC(C)OC(=O)COC1=NC(F)=C(Cl)C(N)=C1Cl OLZQTUCTGLHFTQ-UHFFFAOYSA-N 0.000 description 1
- 150000002916 oxazoles Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 238000000611 regression analysis Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Herbicidal combinations with synergistic function, it is 1~20 that active ingredient constitutes , metamifops, chlorine fluorine pyridine ester, the weight ratio of fluroxypyr (or its ester type compound) three in the composition You metamifop, chlorine fluorine pyridine ester, fluroxypyr (or its ester type compound):1:1~30.Herbicidal combinations of the present invention are mainly used in preventing and kill off for paddy field weed, be used alone with each single dose or mutually binary built significantly improves herbicidal effect compared with, expand herbicidal spectrum, the lasting period is long, to rice safety.There is significant synergistic function after metamifop, chlorine fluorine pyridine ester and fluroxypyr or the different monooctyl ester ternary built of fluroxypyr, effective usage amount of each single dose can be reduced, reduce use cost, mitigate the pollution to environment, delay the generation of herbicide resistance, increase the Pesticide use life-span.
Description
Technical field
The present invention relates to agricultural chemicals Herbicidal combinations and its application field, specifically Yi Zhong Yi metamifops, chlorine fluorine
Pyridine ester and the Herbicidal combinations that fluroxypyr (or its ester type compound) is effective active composition ternary built, mainly should
For preventing and kill off for paddy field weed.
Background technology
Metamifop (metamifop) is fragrant phenoxy phenoxy propionic acid inner-adsorption conduction-type herbicide, and its mechanism of action is second
Acyl coenzyme A carboxylase inhibitors, can suppress the synthesis of vegetable fatty acid, and barnyard grass, a thousand pieces of gold are prevented and kill off available for rice terrace cauline leaf process
A variety of grassy weeds such as son, rice Leersia Sw, lady's-grass, but its to broad leaved weed and sedge weed substantially without activity of weeding.
Chlorine fluorine pyridine ester (florpyrauxifen) is novel aromatic yl pyridines first acid herbicides, with wide spectrum, efficiently,
The low feature of quick-acting, consumption.Cauline leaf process after bud, grassy weed, broad leaved weed and nutgrass flatsedge are prevented and kill off available for rice terrace.
Fluroxypyr (fluroxypyr), the different monooctyl ester of fluroxypyr (fluroxypyr-meptyl) are interior
Conduction type herbicide after seedling is inhaled, the different monooctyl ester of fluroxypyr is that fluroxypyr reacts obtained esters product with alcohols.
The different monooctyl ester of fluroxypyr, fluroxypyr has good prevention effect to a variety of broad leaved weeds of rice terrace, still
It is poor to grassy weed and sedge weed prevention effect, and poisoning is also easy to produce to paddy rice.
It can be seen that when , metamifops, chlorine fluorine pyridine ester, fluroxypyr or the different monooctyl ester of fluroxypyr are used alone
There is certain defect, such as preventing and treating spectrum is narrow, poisoning is also easy to produce to paddy rice, use cost is high and weeds are also easy to produce the resistance to the action of a drug
Problems；Mutually complicated, species is various for grass when occurring due to paddy field weed, such as grassy weed, sedge weed and broad-leaved
The mixing such as weeds occurs, even if Jiang metamifop, chlorine fluorine pyridine ester, fluroxypyr or the different monooctyl ester phase of fluroxypyr
Mutual binary built is used, and there is also the defect to part Weed-control effect difference, it is impossible to is thoroughly solved paddy field weed and is caused harm.
The present inventor is Jiang metamifop, chlorine fluorine pyridine ester and fluroxypyr or three kinds of the different monooctyl ester of fluroxypyr
Effective active composition is compounded together, in the range of certain compound proportion, with significant synergistic function, to rice terrace
A variety of broad leaved weeds, grassy weed and sedge weed are respectively provided with prominent prevention effect, expand herbicidal spectrum, and reducing makes
With cost, the generation of herbicide resistance is delayed, to rice safety, has efficiently solved each single dose exclusive use or mutually binary is answered
Various problems with presence described above when using.
The content of the invention
It is an object of the invention to provide a kind of component rationally, obvious synergy, herbicidal effect is protruded, herbicidal spectrum
Extensively, the lasting period is long, and drug cost is low, weeds can be delayed to develop immunity to drugs, and to the ternary built Herbicidal combinations of rice safety.
Another object of the present invention is to provide application of the above-mentioned Herbicidal combinations in paddy field weed is prevented and kill off.
Technical scheme：To achieve the above object, the present invention provides a kind of Herbicidal combination for having and acting synergistically
Thing, active ingredient constitutes , oxazoles acyl grass You metamifop, chlorine fluorine pyridine ester, fluroxypyr (or its ester type compound)
Amine, chlorine fluorine pyridine ester, the weight ratio of fluroxypyr (or its ester type compound) three in the composition are 1~20:1:1~
30, preferred weight ratio is 10:1:15 or 10:1:30.
Herbicidal combinations Zhong , metamifops of the present invention, chlorine fluorine pyridine ester and fluroxypyr (or its esters chemical combination
Thing) gross weight percentage composition in the composition is 1%~85%, preferably gross weight percentage composition is 10%~70%.
Herbicidal combinations of the present invention can be prepared into a variety of application forms used in suitable agricultural production, relatively good agent
Type has aqueous suspension agent, dispersible oil-suspending agent, missible oil, water dispersible granules, microemulsion, aqueous emulsion etc..
In various application forms prepared by Herbicidal combinations of the present invention, in addition to effective active composition, in addition in agricultural chemicals
Allow to use and the various auxiliary elements of acceptable.
Auxiliary element in aqueous suspension agent has：The optional freely double naphthalenesulfonate formaldehyde condensation compounds of dispersant, polycarboxylate, wood
Mahogany sulfonate, alkyl naphthalene formaldehyde condensate sulfonates, alkylphenol-polyethenoxy base ether phosphate, alkylphenol-polyethenoxy base ether
Sulfonate, phenethyl phenol polyoxyethylene groups ether phosphate, alkyl polyoxyethylene ether sulfonate, polyoxyethylene polyoxypropylene base ether are embedding
One or more of mixing in section copolymer, pull open powder, alkylpolyoxyethylene phosphate；Wetting agent is optional to be gathered freely
Ether modified polyorganosiloxanes, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkyl sulfate, alkylsulfonate,
Alkylnaphthalene sulfonate, alkyl phenol formaldehyde resin polyoxyethylene ether, triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer
In one or more of mixing；The optional Arabic gum freely of thickener, xanthans, carboxymethyl cellulose, polyvinyl alcohol, gaseous state
Silica, Magnesiumaluminumsilicate, carboxyethyl cellulose, carboxy-propyl cellulose, PAA, polyvinylpyrrolidone, polyacrylic acid
One or more of mixing in sodium, polyvinyl acetate, bentonite, white carbon, attapulgite, CMC；Preservative is optional freely
One or more of mixing in Kathon CG KF88, formaldehyde, benzoic acid, sodium benzoate, potassium sorbate, OIT；Defoamer
Optional silicone oil freely, silicone compound, C10- 20 saturated fat acids compounds, C8-10Aliphatic alcohols, hexanol, butanol, octanol
In one or more of mixing；The optional glycerine freely-ether diglycol of antifreezing agent, methyl propylene diglycol, ethylene glycol, third
One or more of mixing in glycol, glycerine, urea；Water is deionized water.
Auxiliary element in dispersible oil-suspending agent has：The optional block copolymers of EO-PO freely of dispersant, polycarboxylate,
(Huntsman Corporation of U.S. HUNTSMAN produces, alkylnaphthalene sulphur by lignosulfonates, alkylnaphthalene sulfonate, TERSPERSE 2020
Barbiturates) in one or more of mixing；Serial emulsifying agent (the BY- of the optional BY freely (castor oil polyoxyethylene ether) of emulsifying agent
110th, BY-125, BY-140), Nongru-700 # (common names：Alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201, this disk-
60# (common names：Sorbitan monostearate), Tween-60 # (common names：Sorbitan monostearate polyoxyethylene
Ether), agriculture breast 1601# (common names：Phenethyl phenol polyoxyethylene poly-oxygen propylene aether), TERSPERSE 4894 (U.S.'s Hensel step
Company produce) in one or more of mixing；Thickener may be selected from such as organobentonite, white carbon, polyvinyl alcohol, magnesium silicate
One or more of mixing in aluminium；One kind in the optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, sodium chloride
Or several mixing；The optional turpentine-based vegetable oil freely of decentralized medium, methyl oleate, soybean oil, peanut oil, mineral oil, solvent
Oily (the trade mark：S-150, S-180, S-200), one or more of mixing in formicester palm oil.
Auxiliary element in aqueous emulsion has：The optional ethylene oxide adduct freely of emulsifying agent, NPE phosphorus
Acid esters, triphenoethyl benzene phenol polyethenoxy ether phosphate, Nongru-700 # (common names：Alkyl phenol formaldehyde resin polyoxyethylene ether),
Agriculture breast 2201#, this disk -60# (common names：Span60), Tween-60 # (common names：Polyoxyethylene sorbitan mountain
Pears alcohol stearate), TX-10 (common names：Octyl phenol polyoxyethylene (10) ether), agriculture breast 1601# (common names：Triphenoethyl benzene
Phenol polyoxyethylene polyoxypropylene block polymer), agriculture breast 600#, one or more of mixing in agriculture breast 400#；Solvent is optional
Ethanol, normal propyl alcohol, isopropanol, butanol, isobutanol, sec-Butyl Acetate, ethylene glycol monoethyl ether, dimethylbenzene, trimethylbenzene, first freely
Benzene, cyclohexanone, the solvent naphtha (trade mark：S-150, S-180, S-200) in one or more of mixing；The optional ring freely of stabilizer
In oxygen soybean oil, epoxidized linseed oil, pentaerythrite, xylitol, 2,6- di-tert-butyl-4-methy phenols, butylated hydroxy anisole
One or more of mixing；The optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, one kind in sodium chloride or several
The mixing planted；The optional cellulose ether freely of thickener, xanthans, polyvinyl alcohol, organobentonite, one kind in aluminium-magnesium silicate or
Several mixing；The optional silicone oil freely of defoamer, silicone compound, C10-20 saturated fat acid compounds, C8-10 fat
One or more of mixing in alcohols, hexanol, butanol, octanol；In the optional formaldehyde freely of preservative, benzoic acid, sodium benzoate
One or more of mixing, water is deionized water.
Auxiliary element in microemulsion has：The optional calcium dodecyl benzene sulfonate freely (agriculture breast 500#) of emulsifying agent, agriculture breast
700#, agriculture breast 2201#, this disk-60#, polysorbate60-#, TX-10, agriculture breast 1601# (common names：Phenethyl phenol polyoxyethylene gathers
Oxypropylene ether), agriculture breast 600#, one or more of mixing in agriculture breast 400#；The optional methanol freely of assistant for emulsifying agent, isopropanol,
One or more of mixing in n-butanol, ethanol；The optional dimethylbenzene freely of solvent, cyclohexanone, the solvent naphtha (trade mark：S-150、
S-180, S-200), it is mineral oil, turpentine-based vegetable oil, turpentine oil, methyl oleate, one or more of mixed in sec-butyl acetate
Close；One or more of mixing in the optional ethylene glycol freely of antifreezing agent, propane diols, glycerine, urea, sodium chloride；Defoamer
Optional silicone oil freely, silicone compound, C10-20Saturated fat acids compound, C8-10Aliphatic alcohols, hexanol, butanol, octanol
In one or more of mixing；One kind in the optional epoxidized soybean oil freely of stabilizer, triphenyl phosphite, epoxychloropropane
Or several mixing；Water is deionized water.
Auxiliary element in water dispersible granules has：The optional sodium lignin sulfonate freely of dispersant, polycarboxylic acid salt, laruyl alcohol
Polyoxyethylene groups ether sodium sulfate, alkyl naphthalene formaldehyde condensate sulfonates, alkyl polyoxyethylene ether sulfonate, alkylphenol-polyethenoxy
One in base ether formaldehyde condensation products, polyoxyethylene polyoxypropylene base ether block copolymers, alkylpolyoxyethylene phosphate
Plant or several mixing；The optional neopelex freely of wetting agent, pull open powder, alkyl phenol formaldehyde resin polyoxyethylene ether
One or more of mixing in sulfate, alkylphenol-polyethenoxy base ether, Nonyl pheno base ether；Disintegrant may be selected from
Such as one or more of mixing in ammonium sulfate, sodium sulphate, polyvinylpyrrolidone, starch and its derivative, bentonite；Filler
Optional kaolin freely, diatomite, precipitated calcium carbonate, white carbon, attapulgite, cornstarch, sepiolite, calcite, silica,
One or more of mixing in pyrophyllite, xylitol, montmorillonite, clay.
Auxiliary element in missible oil has：The optional calcium dodecyl benzene sulfonate freely (agriculture breast 500#) of emulsifying agent, Nongru-700 #,
Agriculture breast 2201, this disk -60#, emulsifying agent T-60 (common names：Anhydrous sorbitol single-hard ester acid ester APEO), TX-10 it is (logical
With name：Octyl phenol polyoxyethylene (10) ether), agriculture breast 1601#, agriculture breast 600#, one or more of mixing in agriculture breast 400#；It is molten
The optional dimethylbenzene freely of agent, trimethylbenzene, methyl naphthalene, solvent naphtha (S-150, S-180, S-200), toluene, methyl oleate, aliphatic acid
One or more of mixing in methyl esters, loose base oil, soybean oil, biodiesel；The optional ethyl acetate freely of cosolvent, methanol,
One or more of mixing in dimethylformamide, cyclohexanone, acetone.
The production technology of the various application forms of Herbicidal combinations belongs to existing known technology, will not be repeated here.
Compared with prior art, the advantage of the invention is that：
1st, metamifop, chlorine fluorine pyridine ester and fluroxypyr or the different monooctyl ester ternary built of fluroxypyr, have
There is significant synergistic function, be used alone than each single dose or mutually binary built is prevented weeds using significantly improving
Effect is controlled, herbicidal spectrum is expanded.
2nd, metamifop, chlorine fluorine pyridine ester and fluroxypyr or the different monooctyl ester ternary built of fluroxypyr, make
Different with mechanism, action site increase can delay the generation of herbicide resistance, extend the Pesticide use life-span.
3rd, metamifop, chlorine fluorine pyridine ester and fluroxypyr or the different monooctyl ester ternary built of fluroxypyr, subtract
The effective usage amount of agricultural chemicals is lacked, has reduced use cost, alleviates pollution to environment.
Embodiment
Essence for a better understanding of the present invention, is described further with reference to embodiment to present disclosure,
But limitation of the present invention can not be considered as, it is as described below to be only used for explaining the present invention, for without departing from spirit of the invention and principle
Modification, replacement or the improvement made, belong to the scope of protection of present invention.
All percentages are weight percentage in following examples.
Embodiment 1:The 17% different monooctyl ester aqueous suspension agent of metamifop chlorine fluorine pyridine ester fluroxypyr.
Metamifop 1%, chlorine fluorine pyridine ester 1%, the different monooctyl ester 15% of fluroxypyr, phenethyl phenol polyoxyethylene groups
Ether phosphate 12%, alkylnaphthalene sulfonate 5%, xanthans 2%, OIT 0.3%, C10-20Saturated fat acids compound
0.2%th, methyl propylene diglycol 2%, deionized water supply 100%.Above-mentioned material is mixed in proportion, through high speed shear point
Dissipate after being sanded in uniform, sand mill, the 17% different monooctyl ester water of metamifop chlorine fluorine pyridine ester fluroxypyr is made and hangs
Floating agent.
Embodiment 2:The 26% dispersible oil-suspending agent of metamifop chlorine fluorine pyridine ester fluroxypyr.
Metamifop 10%, chlorine fluorine pyridine ester 1%, fluroxypyr 15%, EO-PO block copolymers 10%, castor
Sesame oil APEO 5%, alkyl phenol formaldehyde resin polyoxyethylene ether 8%, aluminium-magnesium silicate 1.5%, ethylene glycol 1.5%, rosin
Base vegetable oil supplies 100%.Above-mentioned material is mixed in proportion, after being uniformly dispersed, being sanded in sand mill through high speed shear, is made
The 26% dispersible oil-suspending agent of metamifop chlorine fluorine pyridine ester fluroxypyr.
Embodiment 3:The 51% different monooctyl ester water dispersible granules of metamifop chlorine fluorine pyridine ester fluroxypyr.
Metamifop 20%, chlorine fluorine pyridine ester 1%, the different monooctyl ester 30% of fluroxypyr, polyoxyethylene polyoxypropylene
Base ether block copolymers 15%, Nonyl pheno base ether 12%, ammonium sulfate 8%, diatomite supply 100%.By above-mentioned thing
Material is mixed in proportion, through air-flow crushing it is well mixed, mediate granulation, dry screening after, 51% metamifop chlorine fluorine is made
The different monooctyl ester water dispersible granules of pyridine ester fluroxypyr.
Embodiment 4:32% metamifop chlorine fluorine pyridine ester fluroxypyr microemulsion.
Metamifop 1%, chlorine fluorine pyridine ester 1%, fluroxypyr 30%, agriculture breast 2201#10%, methanol 1.5%,
Cyclohexanone 10%, sec-butyl acetate 5%, ethylene glycol 2%, C10-20Saturated fat acids compound 0.2%, epoxidized soybean oil
2.5%th, deionized water supplies 100%.Above-mentioned material is mixed in proportion, through high shear agitation it is uniform after, be made 32% Evil
Azole amide chlorine fluorine pyridine ester fluroxypyr microemulsion.
Embodiment 5:The 41% different monooctyl ester missible oil of metamifop chlorine fluorine pyridine ester fluroxypyr.
Metamifop 10%, chlorine fluorine pyridine ester 1%, the different monooctyl ester 30% of fluroxypyr, calcium dodecyl benzene sulfonate
5%th, anhydrous sorbitol single-hard ester acid ester APEO 5%, dimethylformamide 10%, loose base oil supply 100%.Will be above-mentioned
Material is mixed in proportion, after being stirred through dissolving, and 41% metamifop chlorine fluorine pyridine ester fluroxypyr is made
Different monooctyl ester missible oil.
Embodiment 6:36% metamifop chlorine fluorine pyridine ester fluroxypyr aqueous emulsion.
Metamifop 14%, chlorine fluorine pyridine ester 1%, fluroxypyr 21%, alkylphenol-formaldehyde resin polyoxyethylene
Ether 15%, sec-Butyl Acetate 10%, the solvent naphtha (trade mark：S-180) 5%, butylated hydroxy anisole 2%, ethylene glycol 1.5%, fine
The plain ether 1.5% of dimension, silicone oil 0.2%, sodium benzoate 0.5%, deionized water supply 100%.Above-mentioned material is mixed in proportion, passed through
After high shear agitation is uniform, 36% metamifop chlorine fluorine pyridine ester fluroxypyr aqueous emulsion is made.
Embodiment 7：Indoor biological determination of activity.
Test method：With reference to《Farm-chemical indoor determination test rule herbicide NY/T1155.4-2006》, using cauline leaf
Spray-on process.Test method：, will be for 15~20, target weeds seed of examination in the built-in quantitative soil of high 6cm, diameter 9cm polypots
Sowing is placed in greenhouse after fine earth thick 0.5~1cm of lid and cultivated, treat that weeds length to the 2-3 leaf phases are carried out at spraying in polypots
Reason, per alms bowl spraying liquid 1mL, often processing is repeated 4 times, and sets the processing without medicament as control.Material is tried after processing to be placed in greenhouse
Range estimation target damage symptoms and growth inhibition situation after culture, the growing state of routine observation target weeds, 21d, and claim on the ground
Part fresh weight, calculates fresh weight preventive effect.
Regression analysis is carried out to the logarithm value of drug dose and the probability system of fresh weight preventive effect with DPS statistical analysis softwares, counted
Calculate the ED of each medicament50, and according to the co-toxicity coefficient (CTC values) of the abundant method calculating mixtures of Sun Yun.
Co-toxicity coefficient (CTC) >=120 shows as synergistic effect；CTC≤80 show as antagonism；The tables of 80 ＜ CTC ＜ 120
It is now summation action.
The metamifop of table 1, chlorine fluorine pyridine ester and fluroxypyr ternary built
To the Toxicity Determination result of rice Leersia Sw
| Medicament title and proportioning (weight ratio) | ED50(g a.i./ha) | ATI | TTI | CTC |
| Metamifop | 43.65 | |||
| Chlorine fluorine pyridine ester | 7.34 | |||
| Fluroxypyr | 764.71 | |||
| Metamifop:Chlorine fluorine pyridine ester (1:1) | 13.89 | 314.25 | 347.35 | 90.47 |
| Metamifop:Chlorine fluorine pyridine ester (10:1) | 27.23 | 160.30 | 144.97 | 110.57 |
| Metamifop:Chlorine fluorine pyridine ester (20:1) | 35.14 | 124.22 | 123.56 | 100.53 |
| Metamifop:Fluroxypyr (20:1) | 39.46 | 110.62 | 95.51 | 115.82 |
| Metamifop:Fluroxypyr (10:1) | 57.83 | 75.48 | 91.43 | 82.55 |
| Metamifop:Fluroxypyr (1:1) | 74.12 | 58.89 | 52.86 | 111.41 |
| Metamifop:Fluroxypyr (1:15) | 389.36 | 11.21 | 11.60 | 96.64 |
| Metamifop:Fluroxypyr (1:30) | 554.75 | 7.87 | 8.75 | 89.94 |
| Chlorine fluorine pyridine ester:Fluroxypyr (1:1) | 16.58 | 44.27 | 50.48 | 87.70 |
| Chlorine fluorine pyridine ester:Fluroxypyr (1:15) | 98.16 | 7.48 | 7.15 | 104.62 |
| Chlorine fluorine pyridine ester:Fluroxypyr (1:30) | 161.63 | 4.54 | 4.15 | 109.40 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (1:1:1) | 6.89 | 633.53 | 233.46 | 271.36 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (1:1:15) | 41.32 | 105.64 | 45.90 | 230.15 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (1:1:30) | 64.84 | 67.32 | 27.06 | 248.78 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (10:1:1) | 15.05 | 290.03 | 133.37 | 217.47 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (10:1:15) | 19.67 | 221.91 | 64.63 | 343.37 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (10:1:30) | 36.98 | 118.04 | 43.07 | 274.05 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (20:1:1) | 17.71 | 246.47 | 118.20 | 208.52 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (20:1:15) | 24.02 | 181.72 | 74.45 | 244.08 |
| Metamifop:Chlorine fluorine pyridine ester:Fluroxypyr (20:1:30) | 35.26 | 123.79 | 54.23 | 228.26 |
It is equal to rice Leersia Sw by the visible , metamifops of table 1, chlorine fluorine pyridine ester, the mutual binary built of fluroxypyr
Simple summation action is showed only as, and shows synergistic function after ternary built to rice Leersia Sw, Te other Shi oxazole acyls
Careless amine, chlorine fluorine pyridine ester and fluroxypyr are with 10:1:15 (by weight) compoundings, synergistic function is the most notable, altogether poison
Coefficient (CTC) reaches maximum, is 343.37.It can be seen that , metamifops, chlorine fluorine pyridine ester and fluroxypyr ternary built tool
There are reasonability and feasibility.
The interior poison of the metamifop of table 2, chlorine fluorine pyridine ester and the different monooctyl ester ternary built of fluroxypyr to bald barnyard
Power measurement result
By the visible , metamifops of table 2, chlorine fluorine pyridine ester, the mutual binary built of the different monooctyl ester of fluroxypyr, to shaven head
Barnyard grass is showed only as simple summation action, and shows synergistic function after ternary built to bald barnyard, Te other Shi oxazoles
Acyl grass amine, chlorine fluorine pyridine ester and the different monooctyl ester of fluroxypyr are with 10:1:30 (by weight) compoundings, synergistic function shows the most
Write, co-toxicity coefficient (CTC) reaches maximum, is 365.35.It can be seen that , metamifops, chlorine fluorine pyridine ester and fluroxypyr are different
Monooctyl ester ternary built has reasonability and feasibility.
The Toxicity Determination knot of the metamifop of table 3, chlorine fluorine pyridine ester and fluroxypyr ternary built to Eclipta prostrata
Really
By the visible , metamifops of table 3, chlorine fluorine pyridine ester, the mutual binary built of fluroxypyr, to Eclipta prostrata only table
Be now simple summation action, and show synergistic function after ternary built to Eclipta prostrata, Te Bie Shi metamifops, chlorine fluorine
Pyridine ester and fluroxypyr are with 10:1:15 (by weight) compoundings, synergistic function is the most notable, co-toxicity coefficient (CTC)
Maximum is reached, is 395.58.It can be seen that , metamifops, chlorine fluorine pyridine ester and fluroxypyr ternary built have reasonability
And feasibility.
The interior poison of the metamifop of table 4, chlorine fluorine pyridine ester and the different monooctyl ester ternary built of fluroxypyr to bog pondweed
Power measurement result
By the visible , metamifops of table 4, chlorine fluorine pyridine ester, the mutual binary built of the different monooctyl ester of fluroxypyr, to eye
Dish is showed only as simple summation action, and shows synergistic function after ternary built to bog pondweed, Te other Shi oxazoles
Acyl grass amine, chlorine fluorine pyridine ester and the different monooctyl ester of fluroxypyr are with 10:1:30 (by weight) compoundings, synergistic function shows the most
Write, co-toxicity coefficient (CTC) reaches maximum, is 302.34.It can be seen that , metamifops, chlorine fluorine pyridine ester and fluroxypyr are different
Monooctyl ester ternary built has reasonability and feasibility.
The Toxicity Determination of the metamifop of table 5, chlorine fluorine pyridine ester and fluroxypyr ternary built to wild water chestnut
As a result
By the visible , metamifops of table 5, chlorine fluorine pyridine ester, the mutual binary built of fluroxypyr, to wild water chestnut only
Simple summation action is shown as, and shows synergistic function after ternary built to wild water chestnut, Te other Shi metamifops,
Chlorine fluorine pyridine ester and fluroxypyr are with 10:1:15 (by weight) compoundings, synergistic function is the most notable, co-toxicity coefficient
(CTC) maximum is reached, is 375.81.Closed it can be seen that , metamifops, chlorine fluorine pyridine ester and fluroxypyr ternary built have
Rationality and feasibility.
The room of the metamifop of table 6, chlorine fluorine pyridine ester and the different monooctyl ester ternary built counterglow dichotomous fimbristylis herb of fluroxypyr
Interior virulence measurement result
By the visible , metamifops of table 6, chlorine fluorine pyridine ester, the mutual binary built of the different monooctyl ester of fluroxypyr, counterglow
Dichotomous fimbristylis herb is showed only as simple summation action, and counterglow dichotomous fimbristylis herb shows synergistic function after ternary built, special
Other Shi metamifops, chlorine fluorine pyridine ester and the different monooctyl ester of fluroxypyr are with 10:1:30 (by weight) compoundings, Synergistic is made
With significantly, co-toxicity coefficient (CTC) reaches maximum, is 413.77.It can be seen that , metamifops, chlorine fluorine pyridine ester and chlorine fluorine pyrrole
The different monooctyl ester ternary built of fluoroacetic acid has reasonability and feasibility.
Embodiment 8：Field control effectiveness test
Experimental field selection rice terrace is carried out, and often processing, which is set, observes each processing weeds death condition for 30 days after 3 repetitions, medicine simultaneously
Calculate preventive effect.
Each chemicals treatment of table 7 prevents and kill off the field control effectiveness test result of paddy field weed
30 Tian metamifops, chlorine fluorine pyridine ester and chlorine fluorine pyrrole oxygen second after medicine it can be seen from the field test results of table 7
Rice Leersia Sw, shaven head of each example composition preparation of acid or the different monooctyl ester ternary built of fluroxypyr to rice terrace
The weeds such as barnyard grass, Eclipta prostrata, bog pondweed, wild water chestnut, miliary fimbristylis herb have excellent prevention effect, and preventive effect is bright up to more than 80%
It is powerful and influential to be better than that each single dose is used alone or mutually binary built is used, wherein (the 26% metamifop chlorine fluorine pyridine of embodiment 2
The dispersible oil-suspending agent of ester fluroxypyr) and (the 41% metamifop chlorine fluorine pyridine ester chlorine fluorine pyrrole oxygen of embodiment 5
2-ethyl hexyl ethanoate missible oil) preventive effect more protrude, preventive effect is up to more than 90%.Simultaneously during pilot survey non-Fa Xian oxazoles
Each example composition system of acyl grass amine, chlorine fluorine pyridine ester and fluroxypyr or the different monooctyl ester ternary built of fluroxypyr
Agent produces poisoning to paddy rice.
In summary, a kind of Herbicidal combinations with synergy of the present invention, obvious synergy, phase
It is used alone than each single dose or mutually binary built is using herbicidal spectrum is expanded, is improved preventive effect, can effectively prevent and kill off rice terrace wealthy
A variety of weeds such as leaf weeds, grassy weed and sedge weed, the lasting period is long, and use cost is low, to rice safety, is worth
Popularization and application in agricultural production.
Claims (7)
1. a kind of Herbicidal combinations with synergistic function, it is characterised in that：Active ingredient You metamifops, chlorine fluorine pyrrole
Pyridine ester, fluroxypyr or the different monooctyl ester composition , metamifops of fluroxypyr, chlorine fluorine pyridine ester, fluroxypyr
Or the weight ratio of the different monooctyl ester three of fluroxypyr in the composition is 1~20:1:1~30.
2. a kind of Herbicidal combinations with synergistic function according to claim 1, it is characterised in that：Oxazole acyl grass
Amine, chlorine fluorine pyridine ester, the weight ratio of fluroxypyr or the different monooctyl ester three of fluroxypyr in the composition are 10:1:
15。
3. a kind of Herbicidal combinations with synergistic function according to claim 1, it is characterised in that：Oxazole acyl grass
Amine, chlorine fluorine pyridine ester, the weight ratio of fluroxypyr or the different monooctyl ester three of fluroxypyr in the composition are 10:1:
30。
4. a kind of Herbicidal combinations with synergistic function according to claim 1, it is characterised in that：Oxazole acyl grass
Amine, chlorine fluorine pyridine ester, the gross weight percentage composition of fluroxypyr or the different monooctyl ester three of fluroxypyr in the composition
For 1%~85%.
5. a kind of Herbicidal combinations with synergy according to claim 1, it is characterised in that：The Herbicidal combination
The formulation of thing is aqueous suspension agent, dispersible oil-suspending agent, missible oil, water dispersible granules, microemulsion or aqueous emulsion.
6. a kind of purposes that there are the Herbicidal combinations of synergy in paddy field weed is prevented and kill off described in claim 1.
7. a kind of use that there are the Herbicidal combinations of synergy in paddy field weed is prevented and kill off according to claim 6
On the way, it is characterised in that：The paddy field weed is rice Leersia Sw, bald barnyard, Eclipta prostrata, bog pondweed, wild water chestnut, miliary fimbristylis herb.
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| CN109042668A (en) * | 2018-08-07 | 2018-12-21 | 安徽省银山药业有限公司 | A kind of mixed herbicide and its application of containing chlorine fluorine pyridine ester and fluroxypyr |
| CN113575593A (en) * | 2021-09-06 | 2021-11-02 | 安徽沙隆达生物科技有限公司 | Compound preparation containing fluroxypyr-meptyl and metamifop and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104661524A (en) * | 2012-07-24 | 2015-05-27 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid |
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2017
- 2017-03-24 CN CN201710183616.0A patent/CN107027770A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104661524A (en) * | 2012-07-24 | 2015-05-27 | 美国陶氏益农公司 | Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109042668A (en) * | 2018-08-07 | 2018-12-21 | 安徽省银山药业有限公司 | A kind of mixed herbicide and its application of containing chlorine fluorine pyridine ester and fluroxypyr |
| CN109042668B (en) * | 2018-08-07 | 2021-04-02 | 安徽辉隆集团银山药业有限责任公司 | Mixed herbicide containing fluroxypyridine ester and fluroxypyr and application thereof |
| CN113575593A (en) * | 2021-09-06 | 2021-11-02 | 安徽沙隆达生物科技有限公司 | Compound preparation containing fluroxypyr-meptyl and metamifop and application thereof |
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