CN108047842A - A kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof - Google Patents
A kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof Download PDFInfo
- Publication number
- CN108047842A CN108047842A CN201711310430.3A CN201711310430A CN108047842A CN 108047842 A CN108047842 A CN 108047842A CN 201711310430 A CN201711310430 A CN 201711310430A CN 108047842 A CN108047842 A CN 108047842A
- Authority
- CN
- China
- Prior art keywords
- water drilling
- aqueous
- acrylic resin
- present
- resin
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 238000005553 drilling Methods 0.000 title claims abstract description 29
- 239000002966 varnish Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000004593 Epoxy Substances 0.000 claims abstract description 23
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 22
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 22
- 229920003180 amino resin Polymers 0.000 claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000008878 coupling Effects 0.000 claims abstract description 11
- 238000010168 coupling process Methods 0.000 claims abstract description 11
- 238000005859 coupling reaction Methods 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000003085 diluting agent Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims 1
- -1 epoxy group silicon Alkane Chemical class 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052709 silver Inorganic materials 0.000 abstract description 7
- 239000004332 silver Substances 0.000 abstract description 7
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 239000003973 paint Substances 0.000 abstract description 5
- 239000003431 cross linking reagent Substances 0.000 abstract description 4
- 239000002519 antifouling agent Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 230000004888 barrier function Effects 0.000 abstract description 2
- 239000003995 emulsifying agent Substances 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract description 2
- 238000007711 solidification Methods 0.000 abstract description 2
- 230000008023 solidification Effects 0.000 abstract description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 230000003260 anti-sepsis Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/085—Copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof, including 55 60g of aqueous thermosetting acrylic resin, 10 15g of full Amino resin, 10 15g of waterborne epoxy modified acrylic resin, 0.4 0.5g of epoxy silane coupling, 15 20g of 6 8g of copper powder, 10 15g of filler, 15 25g of pigment and diluent.Using aqueous thermosetting acrylic resin and waterborne epoxy modified acrylic resin as film forming matter, full Amino resin as crosslinking agent, make after dry solidification of the present invention will not residual emulsifying agents, greatly improve water resistance of the present invention.The present invention also using epoxy silane coupling, makes pigment improve the service life of the present invention well with film forming matter, the compatibility of crosslinking agent.Copper powder and filler provide decoration and barrier propterty.The present invention is used using three kinds of water-base resin collocation so that paint film uses suitable for the outer painting protective paint in water drilling field with good adhesive force and toughness, can be good at protecting the silver coating on water drilling, be a kind of baking vanish of high comprehensive performance.
Description
Technical field
This application involves aqueous amino-stoving varnish technical field, be related to a kind of aqueous amino-stoving varnish applied to water drilling field and
Its preparation method.
Background technology
Water drilling is being commonly called as simulated diamond.Water drilling uses because the flash of light with similar diamond frequently as ornament, such as first
In decorations or dress ornament.Water drilling is the silver coating on the base material in diamond face is cut into, and the persistence and integrality of the silver coating can influence
The appearance and light-gathering of water drilling.In order to protect the silver coating, meeting coating protection paint outside silver coating in the production of water drilling promotes water
The use value of brill.
Water drilling product after application belongs to daily necessities, meeting and direct body contact, therefore to the ring of its protective paint used
Guarantor property also proposed higher requirement.It is more environmentally friendly the most commonly used is aqueous amino-stoving varnish.But the requirement of application water drilling is good outer
Sight and performance.The factors such as the resistance to flavescence of aqueous amino-stoving varnish common at present, water resistance, corrosion-resistant and transparency can shadow
The quality that Xiangshui County is bored.
The content of the invention
It is existing to solve this application provides a kind of no-solvent type high-solid lower-viscosity ring hydrogen heavy antisepsis priming paint and preparation method thereof
Water-based epoxy zinc-rich primer zinc powder in use easy deposit clumps the problem of.
In a first aspect, the embodiment of the present application discloses a kind of aqueous amino-stoving varnish applied to water drilling field, by quality point
Number scale, including aqueous thermosetting acrylic resin 55-60g, full Amino resin 10-15g, waterborne epoxy modified acrylic
Resin 10-15g, epoxy silane coupling 0.4-0.5g, copper powder 6-8g, filler 10-15g, pigment 15-25g and diluent 15-
20g。
Preferably, in aqueous amino-stoving varnish of the above application in water drilling field, the filler is talcum powder.
Preferably, in aqueous amino-stoving varnish of the above application in water drilling field, the diluent is deionized water.
Second aspect, the embodiment of the present application disclose a kind of preparation side of the aqueous amino-stoving varnish applied to water drilling field
Method comprises the following steps：
Aqueous thermosetting acrylic resin, full Amino resin, waterborne epoxy modified is sequentially added into reaction kettle
Acrylic resin, epoxy silane coupling and diluent stir evenly, and it is spare to obtain slurry；
In the slurry after stirring evenly add in copper powder, filler, pigment stir viscosity to 80 ± 5ku to obtain the final product.
Compared with prior art, the application has the beneficial effect that：
The present invention using aqueous thermosetting acrylic resin and waterborne epoxy modified acrylic resin as film forming matter, entirely
Amino resin is as crosslinking agent.Since full Amino resin itself carries hydrophilic radical, can be directly dissolved in water,
Make after dry solidification of the present invention will not residual emulsifying agents, greatly improve water resistance of the present invention；The present invention also uses epoxy radicals silicone hydride
Coupling agent makes pigment improve the service life of the present invention well with film forming matter, the compatibility of crosslinking agent.Copper powder and filler provide
Decoration and barrier propterty.The present invention use using the collocation of three kinds of water-base resins so that paint film is with good adhesive force and toughness,
It is used suitable for the outer painting protective paint in water drilling field, can be good at protecting the silver coating on water drilling.It is provided by the invention to have
Excellent adhesive force, weatherability, impact resistance, chemicals-resistant, high rigidity, resistance to flavescence, clarity, high glaze.And the present invention is dry
Dry cured speed is fast, and dry required temperature is low, is a kind of baking vanish of high comprehensive performance.
Specific embodiment
Technical solution of the present invention is described in detail below, but protection scope of the present invention is not limited to following implementations
Example.
Embodiment 1
A kind of aqueous amino-stoving varnish applied to water drilling field is remembered by mass fraction, including aqueous thermosetting acrylic acid tree
Fat 55g, full Amino resin 10g, waterborne epoxy modified acrylic resin 10g, epoxy silane coupling 0.4g, copper powder
6g, talcum powder 10g, pigment 15g and deionized water 15g.
Preparation method is as follows：
Aqueous thermosetting acrylic resin 55g, full Amino resin 10g, aqueous ring are sequentially added into reaction kettle
The acrylic resin modified 10g of oxygen, epoxy silane coupling 0.4g and water 15g are stirred evenly, and it is spare to obtain slurry；
Copper powder 6g, talcum powder 10g, pigment 15g are added in the slurry after stirring evenly and stirs viscosity to 80 ± 5ku i.e.
.
According to relevant national standard, following performance detection is done to the baking vanish of embodiment 1：
| Test event | Test result |
| Fineness um | ≤35 |
| Storage stability (30 DEG C, 10d) | It is without exception, no caking |
| Adhesive force | 1 grade |
| Hardness | H |
| Viscosity (applies -4 glasss, 25 DEG C) | 140-180 |
| Suppleness | 1mm |
As it can be seen that baking vanish provided by the invention, adhesive force is preferable, and suppleness is preferable, is applicable in the protection as application outside water drilling
Paint uses, and can be good at protecting the silver coating of water drilling so that water drilling keeps good light-gathering.Moreover, the whole of the baking vanish
Using water-base resin, using water as solvent, there is excellent environmental-protecting performance.
Embodiment 2
A kind of aqueous amino-stoving varnish applied to water drilling field is remembered by mass fraction, including aqueous thermosetting acrylic acid tree
Fat 60g, full Amino resin 15g, waterborne epoxy modified acrylic resin 15g, epoxy silane coupling 0.5g, copper powder
8g, talcum powder 15g, pigment 15g and deionized water 15g.
Preparation method is as follows：
Aqueous thermosetting acrylic resin 55g, full Amino resin 10g, aqueous ring are sequentially added into reaction kettle
The acrylic resin modified 10g of oxygen, epoxy silane coupling 0.4g and water 15g are stirred evenly, and it is spare to obtain slurry；
Copper powder 6g, talcum powder 10g, pigment 15g are added in the slurry after stirring evenly and stirs viscosity to 80 ± 5ku i.e.
.
Embodiment 3
A kind of aqueous amino-stoving varnish applied to water drilling field is remembered by mass fraction, including aqueous thermosetting acrylic acid tree
Fat 58g, full Amino resin 10g, waterborne epoxy modified acrylic resin 10g, epoxy silane coupling 0.4g, copper powder
6g, talcum powder 10g, pigment 25g and deionized water 20g.
Preparation method is as follows：
Aqueous thermosetting acrylic resin 55g, full Amino resin 10g, aqueous ring are sequentially added into reaction kettle
The acrylic resin modified 10g of oxygen, epoxy silane coupling 0.4g and water 15g are stirred evenly, and it is spare to obtain slurry；
Copper powder 6g, talcum powder 10g, pigment 15g are added in the slurry after stirring evenly and stirs viscosity to 80 ± 5ku i.e.
.
It should be noted that in the present specification, the relational terms of such as " first " and " second " or the like are used merely to
It distinguishes one entity or operation from another entity or operation, and not necessarily requires or imply these entities or operation
Between there are any this actual relations or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Cover non-exclusive inclusion, so that circuit structure, article or equipment including a series of elements not only include those
Element, but also including other elements that are not explicitly listed or further include as this circuit structure, article or equipment
Intrinsic element.In the absence of more restrictions, there is the element that sentence "including a ..." limits, it is not excluded that
Also there are other identical elements in circuit structure, article or equipment including the element.
Those skilled in the art will readily occur to the application its after considering specification and putting into practice the disclosure invented here
His embodiment.This application is intended to cover the present invention any variations, uses, or adaptations, these modifications, purposes or
Person's adaptive change follows the general principle of the application and including the undocumented common knowledge in the art of the application
Or conventional techniques.Description and embodiments are considered only as illustratively, and the true scope and spirit of the application will by right
The content asked is pointed out.
Above-described the application embodiment does not form the restriction to the application protection domain.
Claims (4)
1. a kind of aqueous amino-stoving varnish applied to water drilling field, which is characterized in that remember by mass fraction, including aqueous thermosetting
Acrylic resin 55-60g, full Amino resin 10-15g, waterborne epoxy modified acrylic resin 10-15g, epoxy group silicon
Alkane coupling agent 0.4-0.5g, copper powder 6-8g, filler 10-15g, pigment 15-25g and diluent 15-20g.
2. the aqueous amino-stoving varnish according to claim 1 applied to water drilling field, which is characterized in that the filler is cunning
Mountain flour.
3. the aqueous amino-stoving varnish according to claim 1 applied to water drilling field, which is characterized in that the diluent is
Deionized water.
4. the preparation method of a kind of aqueous amino-stoving varnish applied to water drilling field, which is characterized in that comprise the following steps：
Aqueous thermosetting acrylic resin, full Amino resin, waterborne epoxy modified propylene are sequentially added into reaction kettle
Acid resin, epoxy silane coupling and diluent stir evenly, and it is spare to obtain slurry；
In the slurry after stirring evenly add in copper powder, filler, pigment stir viscosity to 80 ± 5ku to obtain the final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711310430.3A CN108047842A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711310430.3A CN108047842A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108047842A true CN108047842A (en) | 2018-05-18 |
Family
ID=62124018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711310430.3A Pending CN108047842A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous amino-stoving varnish applied to water drilling field and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108047842A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119463696A (en) * | 2024-10-08 | 2025-02-18 | 北新嘉宝莉涂料(广东)有限公司 | Epoxy inner wall baking varnish and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN105153847A (en) * | 2015-10-14 | 2015-12-16 | 芜湖春风新材料有限公司 | Water-based glass high-temperature baking varnish and preparation method thereof |
| CN106433383A (en) * | 2016-11-11 | 2017-02-22 | 青岛益群漆业集团有限公司 | Amino baking paint special for water-based oil drum |
-
2017
- 2017-12-11 CN CN201711310430.3A patent/CN108047842A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN105153847A (en) * | 2015-10-14 | 2015-12-16 | 芜湖春风新材料有限公司 | Water-based glass high-temperature baking varnish and preparation method thereof |
| CN106433383A (en) * | 2016-11-11 | 2017-02-22 | 青岛益群漆业集团有限公司 | Amino baking paint special for water-based oil drum |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119463696A (en) * | 2024-10-08 | 2025-02-18 | 北新嘉宝莉涂料(广东)有限公司 | Epoxy inner wall baking varnish and preparation method and application thereof |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180518 |
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