CN1081204C - 具有改进的硫化性的热塑性弹性体 - Google Patents

具有改进的硫化性的热塑性弹性体 Download PDF

Info

Publication number
CN1081204C
CN1081204C CN96195416A CN96195416A CN1081204C CN 1081204 C CN1081204 C CN 1081204C CN 96195416 A CN96195416 A CN 96195416A CN 96195416 A CN96195416 A CN 96195416A CN 1081204 C CN1081204 C CN 1081204C
Authority
CN
China
Prior art keywords
elastomeric polymer
thermoplastic elastomer
polymer
alpha
vulcanizing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN96195416A
Other languages
English (en)
Chinese (zh)
Other versions
CN1190420A (zh
Inventor
M·D·艾鲁尔
D·R·哈泽尔顿
P·S·拉维尚卡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advanced Elastomer Systems LP
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Advanced Elastomer Systems LP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23948349&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1081204(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc, Advanced Elastomer Systems LP filed Critical Exxon Chemical Patents Inc
Publication of CN1190420A publication Critical patent/CN1190420A/zh
Application granted granted Critical
Publication of CN1081204C publication Critical patent/CN1081204C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CN96195416A 1995-06-14 1996-06-11 具有改进的硫化性的热塑性弹性体 Expired - Fee Related CN1081204C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/490,505 US5656693A (en) 1995-06-14 1995-06-14 Thermoplastic elastomers having improved cure
US08/490,505 1995-06-14

Publications (2)

Publication Number Publication Date
CN1190420A CN1190420A (zh) 1998-08-12
CN1081204C true CN1081204C (zh) 2002-03-20

Family

ID=23948349

Family Applications (1)

Application Number Title Priority Date Filing Date
CN96195416A Expired - Fee Related CN1081204C (zh) 1995-06-14 1996-06-11 具有改进的硫化性的热塑性弹性体

Country Status (13)

Country Link
US (1) US5656693A (2)
EP (1) EP0843698B1 (2)
JP (1) JPH11507696A (2)
KR (1) KR100411924B1 (2)
CN (1) CN1081204C (2)
AU (1) AU716677B2 (2)
BR (1) BR9608988A (2)
CA (1) CA2220668A1 (2)
DE (1) DE69603737T2 (2)
ES (1) ES2135904T3 (2)
IL (1) IL118531A0 (2)
TW (1) TW341586B (2)
WO (1) WO1997000288A1 (2)

Families Citing this family (91)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2219052A1 (en) * 1996-10-28 1998-04-28 Mitsui Chemicals, Incorporated Olefin thermoplastic elastomer composition
US5952427A (en) * 1996-12-10 1999-09-14 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5763533A (en) 1996-12-10 1998-06-09 Exxon Chemical Patents Inc. Electrical devices including ethylene, α-olefin, vinyl norbornene elastomers and ethylene α-olefin polymers
US5965077A (en) * 1997-10-16 1999-10-12 Mercury Plastics, Inc. Method of making an overmolded flexible valve
ES2213297T3 (es) 1997-11-20 2004-08-16 Advanced Elastomer Systems, L.P. Modificacion de vulcanizados termoplasticos con un copolimero termoplastico al azar de etileno.
AR018359A1 (es) * 1998-05-18 2001-11-14 Dow Global Technologies Inc Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano
US6288171B2 (en) * 1998-07-01 2001-09-11 Advanced Elastomer Systems, L.P. Modification of thermoplastic vulcanizates using random propylene copolymers
DE50007779D1 (de) * 1999-02-15 2004-10-21 Polyone Corp Thermoplastisches vulkanisat und verfahren zur herstellung
US6281316B1 (en) 1999-03-22 2001-08-28 Union Carbide Chemicals & Plastics Technology Corporation Enhanced crosslinking terpolymer
PT1192624E (pt) * 1999-06-21 2005-02-28 Pirelli & C Spa Cabo, em particular para transporte ou distribuicao de energia electrica
US6815062B2 (en) 1999-06-21 2004-11-09 Pirelli Cavi E Sistemi S.P.A. Cable, in particular for electric energy transportation or distribution, and an insulating composition used therein
CA2292387A1 (en) 1999-12-17 2001-06-17 Bayer Inc. Process for producing olefin polymer with long chain branching
US20020018958A1 (en) * 2000-06-20 2002-02-14 Jsr Corporation Polymeric material for laser processing and a laminated body for laser processing thereof, flexographic printing plate and the method of producing the same, and a seal material
US6667364B2 (en) * 2000-12-29 2003-12-23 Advanced Elastomer Systems Lp Processable polyethylene/EPDM thermoplastic vulcanizates
US6451915B1 (en) 2000-12-29 2002-09-17 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved processing and physical property balance
US6433090B1 (en) 2001-01-26 2002-08-13 Advanced Elastomer Systems, L.P. Thermoplastic elastomers having improved set foams made therefrom
US7021633B2 (en) * 2001-09-11 2006-04-04 Gorman Company, Inc. Low friction fluid seal device with additive to rubber compound
EP1591458B8 (en) * 2002-01-15 2010-06-02 Advanced Elastomer Systems, L.P. Thermoplastic Elastomers
CN1308357C (zh) * 2002-01-15 2007-04-04 高级弹性体系统两合公司 热塑性弹性体及其制备方法
EP1474477B1 (en) * 2002-02-11 2006-01-11 DSM IP Assets B.V. Thermoplastic elastomer composition
JP4945080B2 (ja) 2002-06-19 2012-06-06 エクソンモービル・ケミカル・パテンツ・インク エチレン、より高級なα−オレフィンコモノマー及びジエン、特にビニルノルボルネン、並びにそのような方法を用いて製造されるポリマー
US6790911B2 (en) * 2002-12-26 2004-09-14 Advanvced Elastomer Systems, L.P. Thermoplastic elastomers having improved adhesive proterties
US7737205B2 (en) * 2003-07-28 2010-06-15 Dow Global Technologies Inc Thermoplastic vulcanizates and process to prepare them
EP1664189B1 (en) * 2003-09-17 2009-11-18 ExxonMobil Chemical Patents Inc. Improved thermoplastic vulcanizates and processes for making the same
US7605217B2 (en) * 2003-11-14 2009-10-20 Exxonmobil Chemical Patents Inc. High strength propylene-based elastomers and uses thereof
US20060014903A1 (en) 2004-07-14 2006-01-19 Thierry Vromman Thermoplastic vulcanizates with enhanced cooling and articles made therefrom
US20060052540A1 (en) * 2004-09-09 2006-03-09 Maria Ellul Thermoplastic vulcanizates
US7193018B2 (en) * 2004-09-15 2007-03-20 Advanced Elastomer Systems, Lp. Slip-coat compositions and polymeric laminates
US7829623B2 (en) * 2004-11-05 2010-11-09 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates having improved fabricability
US8076416B2 (en) 2005-02-04 2011-12-13 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and their use
US7655728B2 (en) * 2005-06-27 2010-02-02 Exxonmobil Chemical Patents Inc. Preparation of thermoplastic elastomers by dynamic vulcanization in multi-screw extruders
US20070021564A1 (en) * 2005-07-13 2007-01-25 Ellul Maria D Peroxide-cured thermoplastic vulcanizates
US7872075B2 (en) 2005-10-07 2011-01-18 Exxonmobil Chemical Patents Inc. Peroxide-cured thermoplastic vulcanizates and process for making the same
US20070112139A1 (en) * 2005-11-14 2007-05-17 Ellul Maria D Peroxide-cured thermoplastic vulcanizates and process for making the same
WO2007067307A1 (en) * 2005-12-06 2007-06-14 Exxonmobil Chemical Patents Inc. Ethylene elastomer compositions
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
US7812093B2 (en) * 2005-12-19 2010-10-12 Exxonmobil Chemical Patents Inc. Peroxide-cured thermoplastic vulcanizates and medical devices made therewith
DE102006003194A1 (de) * 2006-01-24 2007-08-02 Elringklinger Ag Radialdichtung
US7504458B2 (en) * 2006-04-12 2009-03-17 Advanced Elastomer Systems, Llp Method for improving compression set in thermoplastic vulcanizates
US20070244263A1 (en) * 2006-04-13 2007-10-18 Burrowes Thomas G Elastomeric composition for transmission belt
US7985804B2 (en) 2006-11-06 2011-07-26 Exxonmobil Chemical Patents Inc. Rubber toughened compositions, articles, films, and methods of making the same
US7955540B2 (en) * 2007-01-19 2011-06-07 Exxonmobil Chemical Patents Inc. Extrusion of thermoplastic elastomers
WO2008134173A1 (en) * 2007-05-01 2008-11-06 Advanced Elastomer Systems, L.P. Method for preparing thermoplastic vulcanizates
WO2009020720A1 (en) * 2007-08-06 2009-02-12 Advance Elastomer Systems, L.P. Peroxide-cured thermoplastic vulcanizates prepared with ultrahigh molecular weight plastics
WO2009123609A1 (en) * 2008-03-31 2009-10-08 Advanced Elastomer Systems, L.P. Thermoplastic vulcanizates
US8877867B2 (en) * 2008-11-06 2014-11-04 Exxonmobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates and extruded articles therefrom
US20100119855A1 (en) * 2008-11-10 2010-05-13 Trazollah Ouhadi Thermoplastic Elastomer with Excellent Adhesion to EPDM Thermoset Rubber and Low Coefficient of Friction
US8829349B2 (en) * 2008-12-18 2014-09-09 Exxonmobil Chemical Patents Inc. Oxides for protection against electrochemical oxidation and ionic contamination in medium-voltage power-cable insulation
WO2010071718A1 (en) * 2008-12-18 2010-06-24 Exxonmobil Chemical Patents Inc. Peroxide cured tpv
KR101741857B1 (ko) 2009-07-15 2017-05-30 다우 글로벌 테크놀로지스 엘엘씨 중합체 조성물, 그의 제조 방법 및 그로부터 제조된 용품
EP2519581B1 (en) 2009-12-30 2015-03-04 ExxonMobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates
US8557906B2 (en) 2010-09-03 2013-10-15 Exxonmobil Chemical Patents Inc. Flame resistant polyolefin compositions and methods for making the same
EP2658920B1 (en) * 2010-12-30 2020-02-12 Dow Global Technologies LLC Compositions, methods of making the same, and articles prepared from the same
BR112013027872B1 (pt) 2011-04-29 2021-08-10 American Biltrite (Canada) Ltd Material para pavimentação, produto para pavimentação curado de composição para pavimentação e método para produção de produto para pavimentação
EP2574635A1 (en) 2011-09-28 2013-04-03 Lanxess Inc. Process for continuous production of halogen-free thermoplastic elastomer compositions
JP5966220B2 (ja) 2012-05-10 2016-08-10 エクソンモービル ケミカル パテンツ インコーポレイテッド 組成物及びそれらの製造方法
US8962761B2 (en) 2012-08-16 2015-02-24 Exxonmobil Chemical Patents Inc. Long chain branched EPDM compositions and processes for production thereof
KR20160119079A (ko) * 2014-02-07 2016-10-12 제너럴 케이블 테크놀로지즈 코오포레이션 개선된 외피를 가지는 케이블 형성방법
US10414881B2 (en) 2014-11-25 2019-09-17 Exxonmobil Chemical Patents Inc. Method of making thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom
WO2016088844A1 (ja) * 2014-12-05 2016-06-09 横浜ゴム株式会社 接着方法およびコンベヤベルト
US10730206B2 (en) 2015-02-26 2020-08-04 Exxonmobil Chemical Patents Inc. Process for forming thermoplastic vulcanizates and thermoplastic vulcanizates made therefrom
JP2019513307A (ja) 2016-03-30 2019-05-23 エクソンモービル・ケミカル・パテンツ・インク 太陽電池用途向けの熱可塑性加硫物組成物
CN110291143B (zh) 2016-12-29 2022-05-10 埃克森美孚化学专利公司 用于发泡应用的热塑性硫化橡胶
WO2018160300A1 (en) 2017-02-28 2018-09-07 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized epdm
EP3676068A1 (en) 2017-08-31 2020-07-08 ExxonMobil Chemical Patents Inc. Methods of making thermoplastic vulcanizates (tpv)
US11203677B2 (en) 2017-11-03 2021-12-21 American Biltrite (Canada) Ltd. Resilient surface coverings and methods of making and using thereof
CN111615535A (zh) 2017-12-06 2020-09-01 埃克森美孚化学专利公司 低密度发泡热塑性硫化橡胶组合物
EP3740532B1 (en) 2018-01-18 2024-02-21 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizates
EP3740531B1 (en) 2018-01-18 2024-03-20 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizates
EP3774256A4 (en) 2018-04-05 2022-03-09 ExxonMobil Chemical Patents Inc. IMPROVEMENT OF CROSSLINKED RUBBER DISPERSION IN THERMOPLASTIC VULCANIZATE
WO2019199486A1 (en) 2018-04-10 2019-10-17 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizale compositions
JP7216184B2 (ja) 2018-07-23 2023-01-31 エクソンモービル・ケミカル・パテンツ・インク バイモーダルゴム、熱可塑性加硫物の調製およびそれから作られた物品
EP3849791A1 (en) 2018-09-14 2021-07-21 ExxonMobil Chemical Patents Inc. Thermoplastic vulcanizate compositions in polymeric inner / pressure sheaths of flexible pipes for oil & gas applications
WO2020068409A1 (en) 2018-09-24 2020-04-02 Exxonmobil Chemical Patents Inc. Crosslinked elastomer-polymer blends
US20210355255A1 (en) * 2019-01-30 2021-11-18 Sumitomo Chemical Company, Limited Rubber composition
EP3941976A1 (en) 2019-03-21 2022-01-26 ExxonMobil Chemical Patents Inc. Pipe including a thermoplastic vulcanizate composition
JP2020164700A (ja) * 2019-03-29 2020-10-08 三井化学株式会社 エチレン・α−オレフィン・ビニルノルボルネン共重合体組成物およびその架橋物
US11413800B2 (en) 2019-05-20 2022-08-16 Kraton Polymers Llc Molding compositions and articles made thereof
US12371556B2 (en) 2019-06-13 2025-07-29 Celanese International Corporation Automotive weather seals formed with thermoplastic vulcanizate compositions
US12545777B2 (en) 2019-06-21 2026-02-10 Celanese International Corporation Thermoplastic vulcanizate compositions
US20220299154A1 (en) 2019-08-26 2022-09-22 Celanese International Corporation Thermoplastic Vulcanizate Compositions and Thermoplastic Olefinic Compositions as Insulating Layers in Non-Flexible Pipes
CN114846074A (zh) 2019-10-22 2022-08-02 国际人造丝公司 热塑性硫化橡胶组合物及其生产工艺
WO2021188361A1 (en) 2020-03-20 2021-09-23 Exxonmobil Chemical Patents Inc. Linear alpha-olefin copolymers and impact copolymers thereof
EP4146735A1 (en) 2020-05-05 2023-03-15 Celanese International Corporation Pipe including a polymethylpentene thermoplastic polymer
EP4157813A1 (en) 2020-05-29 2023-04-05 ExxonMobil Chemical Patents Inc. Processes for producing cyclic olefins from polymers and re-polymerization thereof
US11674024B2 (en) 2020-05-29 2023-06-13 Exxonmobil Chemical Patents Inc. Sequential, double elastomer vulcanization system, method and composition
EP4176005A1 (en) 2020-07-02 2023-05-10 Celanese International Corporation Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same
JP2022047722A (ja) * 2020-09-14 2022-03-25 豊田合成株式会社 架橋ゴム組成物及びその製造方法
WO2022093448A1 (en) 2020-10-30 2022-05-05 Celanese International Corporation Thermoplastic vulcanizate compositions and articles containing the same
CN116847969A (zh) 2020-12-16 2023-10-03 国际人造丝公司 挤出成型的热塑性硫化橡胶垫和制造这种垫的方法
WO2023225203A1 (en) 2022-05-18 2023-11-23 Mcpp Innovation Llc Split-proof automotive corner molding compound

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6454010A (en) * 1987-08-26 1989-03-01 Mitsui Petrochemical Ind Random ethylene copolymer and its use

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1018778A (en) * 1962-08-09 1966-02-02 Montedison Spa Olefin copolymers
DE1595440B2 (de) * 1966-08-18 1973-05-24 Chemische Werke Hüls AG, 4370 Mari Verfahren zur herstellung von vulkanisierbaren, ungesaettigten copolymeren
CA920742A (en) * 1969-01-15 1973-02-06 Du Pont Of Canada Limited Copolymers of ethylene and bicyclo-(2,2,1)-2-heptenes with improved physical properties
GB1311946A (en) * 1969-09-05 1973-03-28 Montedison Spa Ethylene propylene copolymers
US3637617A (en) * 1969-09-08 1972-01-25 Copolymer Rubber & Chem Corp Minimizing compression set of curable rubbers
US3806558A (en) * 1971-08-12 1974-04-23 Uniroyal Inc Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic
GB1402049A (en) * 1972-12-22 1975-08-06 Stamicarbon Polypropylene compositions having mechanical properties
US4130535A (en) * 1975-07-21 1978-12-19 Monsanto Company Thermoplastic vulcanizates of olefin rubber and polyolefin resin
US4031169A (en) * 1975-09-11 1977-06-21 Uniroyal Inc. Thermoplastic elastomeric polymer blend
GB1597833A (en) * 1977-03-05 1981-09-09 Treacy T P Shoring assembly for a trench or hole
DE2822815C2 (de) * 1977-05-26 1994-02-17 Mitsui Petrochemical Ind Verfahren zur Herstellung einer teilweise vulkanisierten thermoplastischen Masse
US4311628A (en) * 1977-11-09 1982-01-19 Monsanto Company Thermoplastic elastomeric blends of olefin rubber and polyolefin resin
US4220579A (en) * 1978-04-17 1980-09-02 Uniroyal, Inc. Thermoplastic elastomeric blend of monoolefin copolymer rubber, amorphous polypropylene resin and crystalline polyolefin resin
JPS58191705A (ja) * 1982-05-06 1983-11-09 Mitsui Petrochem Ind Ltd エチレン共重合ゴム
JPS6040141A (ja) * 1983-08-16 1985-03-02 Mitsui Petrochem Ind Ltd 硫黄加硫可能な低比重ゴム組成物
JPS61151758A (ja) * 1984-12-26 1986-07-10 Nec Corp メモリバツクアツプ方式
JPH0627129B2 (ja) * 1985-10-31 1994-04-13 三井石油化学工業株式会社 塩素化ゴム
US5177147A (en) * 1986-03-03 1993-01-05 Advanced Elastomer Systems, Lp Elastomer-plastic blends
JPS62210169A (ja) * 1986-03-10 1987-09-16 Nissan Motor Co Ltd 車両用実舵角制御装置
JPH0730217B2 (ja) * 1986-05-08 1995-04-05 住友化学工業株式会社 熱可塑性エラストマ−組成物
IN167956B (2) * 1986-05-23 1991-01-12 Uniroyal Chem Co Inc
EP0275925B1 (en) * 1987-01-19 1995-04-05 Sumitomo Chemical Company, Limited Rubbery copolymers of ethylene, propylene and a nonconjugated polyene and their use
JPS63265940A (ja) * 1987-04-24 1988-11-02 Nippon Oil Co Ltd 熱可塑性エラストマ−組成物
EP0366411A3 (en) * 1988-10-28 1991-04-24 Exxon Chemical Patents Inc. Graft polymers of ethylene-propylene-diene monomer polymers with propylene, means of preparation, and use of polypropylene compositions
US5292811A (en) * 1988-11-21 1994-03-08 Mitsui Petrochemical Industries, Ltd. Process for preparing thermoplastic elastomers
US4985502A (en) * 1988-12-23 1991-01-15 Showa Denko K.K. Thermoplastic elastomer
US5157081A (en) * 1989-05-26 1992-10-20 Advanced Elastomer Systems, L.P. Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix
JP3031022B2 (ja) * 1991-12-19 2000-04-10 住友化学工業株式会社 熱可塑性エラストマー組成物の製造方法
US5288806A (en) * 1992-09-22 1994-02-22 Exxon Chemical Patents Inc. Thermoplastic olefins with low viscosity

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6454010A (en) * 1987-08-26 1989-03-01 Mitsui Petrochemical Ind Random ethylene copolymer and its use

Also Published As

Publication number Publication date
CN1190420A (zh) 1998-08-12
WO1997000288A1 (en) 1997-01-03
KR100411924B1 (ko) 2004-02-18
DE69603737T2 (de) 2000-03-16
EP0843698A1 (en) 1998-05-27
JPH11507696A (ja) 1999-07-06
DE69603737D1 (de) 1999-09-16
US5656693A (en) 1997-08-12
EP0843698B1 (en) 1999-08-11
ES2135904T3 (es) 1999-11-01
CA2220668A1 (en) 1997-01-03
AU716677B2 (en) 2000-03-02
IL118531A0 (en) 1996-10-16
BR9608988A (pt) 1999-06-29
AU6109596A (en) 1997-01-15
KR19990022926A (ko) 1999-03-25
TW341586B (en) 1998-10-01

Similar Documents

Publication Publication Date Title
CN1081204C (zh) 具有改进的硫化性的热塑性弹性体
US9296885B2 (en) Thermoplastic vulcanizates and processes for making the same
US6121383A (en) Thermosplastic vulcanizates from blends of a polypropylene and elastic α-olefin/cyclic olefin copolymers
EP1219679B1 (en) Thermoplastic elastomers having improved processing and physical property balance
EP1419183B2 (en) Thermoplastic elastomers and process for making the same
US9234093B2 (en) Thermoplastic vulcanizates
CN1092687C (zh) 可动态硫化的聚烯烃组合物
EP1633791B1 (en) Co-agents for the preparation of thermoplastic elastomeric blends of rubber and polyolefins
EP1940945B1 (en) Peroxide-cured thermoplastic vulcanizates and process for making the same
US6939918B2 (en) Thermoplastic elastomers having improved low temperature properties
US20060052540A1 (en) Thermoplastic vulcanizates
US20070021564A1 (en) Peroxide-cured thermoplastic vulcanizates
KR100405102B1 (ko) 차량용엘라스토머성호스
US10508179B2 (en) Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM
WO2022005634A1 (en) Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same
US20070112139A1 (en) Peroxide-cured thermoplastic vulcanizates and process for making the same
JP3240589B2 (ja) プロピレンエチレンブロック共重合体組成物
EP1591458B1 (en) Thermoplastic Elastomers
JP2909196B2 (ja) エチレン系共重合体およびその製造方法
US20060155069A1 (en) Process for making lightly cross-linked thermoplastic polyolefin elastomers
HK1087136A (en) Co-agents for the preparation of thermoplastic elastomeric blends of rubber and polyolefins

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: EXXON.MOBIL CHEMICAL PATENTS CORP.; HIGH BRAND ELA

Free format text: FORMER NAME OR ADDRESS: EXXON CHEMICAL PATENTS INC.; HIGH BRAND ELASTIC BODY SYSTEM PARTENERSHIP CO.,LTD.

CP01 Change in the name or title of a patent holder

Patentee after: Exxon Chemical Patents Inc.

Patentee after: Advanced Elastomer Systems, L.P.

Patentee before: Exxon Chemical Patents Inc.

Patentee before: Advanced Elastomer Systems, L.P.

C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee