CN108913402A - Solid abluent and preparation method thereof suitable for tableware - Google Patents
Solid abluent and preparation method thereof suitable for tableware Download PDFInfo
- Publication number
- CN108913402A CN108913402A CN201810676764.0A CN201810676764A CN108913402A CN 108913402 A CN108913402 A CN 108913402A CN 201810676764 A CN201810676764 A CN 201810676764A CN 108913402 A CN108913402 A CN 108913402A
- Authority
- CN
- China
- Prior art keywords
- solid
- mass parts
- abluent
- back bone
- flexible back
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007787 solid Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 51
- 210000000988 bone and bone Anatomy 0.000 claims abstract description 46
- 238000005406 washing Methods 0.000 claims abstract description 45
- 238000002347 injection Methods 0.000 claims abstract description 36
- 239000007924 injection Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 34
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 17
- 239000000440 bentonite Substances 0.000 claims abstract description 17
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 17
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 17
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010457 zeolite Substances 0.000 claims abstract description 17
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 15
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 239000001071 citrus reticulata blanco var. mandarin Substances 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 229920002994 synthetic fiber Polymers 0.000 claims description 6
- 239000012209 synthetic fiber Substances 0.000 claims description 6
- -1 Sodium alkyl benzene Chemical class 0.000 claims description 2
- 238000010348 incorporation Methods 0.000 claims description 2
- YFDKVXNMRLLVSL-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O YFDKVXNMRLLVSL-UHFFFAOYSA-N 0.000 claims 1
- 229940077388 benzenesulfonate Drugs 0.000 claims 1
- 239000003599 detergent Substances 0.000 abstract description 37
- 230000000116 mitigating effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000013042 solid detergent Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000004851 dishwashing Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000000447 pesticide residue Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- VMXUWOKSQNHOCA-UKTHLTGXSA-N ranitidine Chemical compound [O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 VMXUWOKSQNHOCA-UKTHLTGXSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The solid abluent and preparation method thereof that the present invention relates to a kind of suitable for tableware, the solid abluent includes washing mixture and flexible back bone, the washing mixture is fixedly arranged on the flexible back bone and the intraskeletal gap of filling flexible, the washing mixture mainly includes the neopelex of 100 mass parts, the lauryl sodium sulfate of 25-35 mass parts, the spaonin powder of 20-30 mass parts, the AEO-9 of 20-30 mass parts, the bentonite in powder of 80-110 mass parts and the zeolite powder of 40-60 mass parts, the preparation method is that each raw material for washing mixture is put in proportion into ground and mixed equipment, ground and mixed is uniform, form the washing mixture of half fluidised form, the washing mixture of half fluidised form is injected from the injection pipe extending into the middle part of mold, naturally it dries in the shade in solid.This detergent is easy to use, and is conducive to pollution caused by mitigating detergent, reduces detergent residual.
Description
Technical field
The present invention relates to a kind of solid abluents suitable for washings such as tablewares.
Background technique
It is existing to be adapted to tableware and the detergent of food mostly uses liquid, it can be described as dish washing liquid etc., when use is first applied to
It on wiper, or dissolves in water, then carries out tableware scrubbing with the wiper with detergent, this mode is not only troublesome, and puts into
Dosage of scour it is not easy to control, a large amount of detergent is actually to immerse in wiper or dissolve in water, is not utilized, no
Unnecessary waste is only caused, but also increases the pollutional load of wastewater treatment, when using phosphate as builder, is also increased
Added the phosphorus content in water, according to existing research, detergent discharge phosphorus be cause water eutrophication main phosphorus source it
One.
On the other hand, influence of the detergent to human health is also a problem in need of consideration, although currently used
Surfactant and builder are regarded as the substance of nontoxic or micro- poison, harmless, but constantly increase in dosage of scour
In the case where adding, the long-term influence of people is still needed to give enough attention, not can guarantee rinse every time in practice
In very thorough situation, tableware remains minimal amount of chemical substance and is inevitable, and therefore, replaces using harmfulness is lower
Dai Pin and the improvement reduction dosage of scour and residual for passing through detergent itself will reduce detergent harm that may be present
Effective way.
Summary of the invention
In order to solve the above technical problems, the present invention provides a kind of solid abluent suitable for tableware, this detergent makes
With convenient, and be conducive to pollution caused by mitigating detergent, reduce detergent residual.
The technical scheme is that:A kind of solid abluent suitable for tableware, it is characterised in that including washing mixture
And flexible back bone, the washing mixture are fixedly arranged on the flexible back bone.
The washing mixture mainly includes neopelex, lauryl sodium sulfate, spaonin powder, poly alkyl alcohol
Ethylene oxide ether AEO-9, bentonite in powder and zeolite powder, the neopelex are 100 mass parts, the dodecyl sulphur
Sour sodium is 25-35 mass parts, and the spaonin powder is 20-30 mass parts, and the AEO-9 is 20-30 mass parts, the bentonite in powder
For 80-110 mass parts, the zeolite powder is 40-60 mass parts, and may include the toluic acid sodium of 5-10 mass parts, 10-15 mass
The polyethylene glycol of part and/or the cold press mandarin oil of 0-5 mass parts.
It is disclosed by the invention any one be suitable for tableware solid detergent preparation method, each original of mixture will be washed
Material is put in proportion into ground and mixed equipment, and wherein all solids material is all made of the powder of -80 mesh, and 20-30 mass parts are added
Water, ground and mixed is uniform, forms the washing mixture of half fluidised form;The flexible back bone prepared is placed in mold, by injection pipe
The middle part for protruding into mold will be fixed on before injection pipe in the middle part of flexible back bone and close to injection pipe top;Pass through injection pipe injection half
The washing mixture of fluidised form is full of mold backed off after random input pipe, and washing mixture is dried in the shade naturally in solid, forms solid abluent
Product can be packed as needed.
The beneficial effects of the invention are as follows:Due to the flexible back bone using flexible porous material as detergent, formation is had
" wiper " or " cleaning ball " of detergent, therefore it is washed directly to clean tableware etc. when washing as wiper with this detergent
Object, unnecessary waste can be avoided, in turn with the dirt digestion on object by clipping the detergent on washed object
It also avoids discharging because a large amount of unemployed detergent enter in waste water, water pollution caused by alleviating because of detergent discharge;
Since each component is all made of the raw material to environment and human body close friend, and part composition can also be using more friendly to environment and human body
Good plant extracts material, and takes full advantage of the characteristic and its synergistic effect of a variety of materials, can obtain preferably washing effect
Fruit reduces the dosage of scour of effective use under conditions of meeting identical washing and requiring, alleviate detergent to environment and
The extent of injury of human body;Rationally due to the collocation of various components, it so that the soft or hard degree of detergent is suitable for, will not be needed because really up to the mark
Excessive wiping will not excessively be applied on washings due to excessively soft, and pass through the natural fiber as flexible back bone
The receiving and adsorption effect of equal porous materials, are beneficial to prevent excessive detergent and are coated on washed object;Due to various groups
The mutual cooperation divided the effects of playing mutually cleaning and adsorb, under identical flushing, helps to improve flushing effect, reduction institute
There is the residual of component.
Solid detergent of the invention is suitable for the washing of tableware, melon and fruit and other washable objects.
Specific embodiment
The present invention provides a kind of solid abluents suitable for tableware comprising washing mixture and flexible back bone, it is described
Flexible back bone described in flexible back bone preferably uses porous material or filiform, strip, netted(Including cloth-like of weaving)Material is made,
It can adhere to the flexible material of washing mixture using other, the washing mixture is fixedly arranged on the flexible back bone,
The all or part being generally filled in flexible back bone(It is usually most of)Gap.Block-like detergent is consequently formed, wherein containing
Flexible skeleton is equivalent to the surface that detergent is coated in wiper, can directly wipe as the wiper for being coated with detergent
The objects such as wash up, but the difference is that the detergent within/on flexible back bone is solid, only clip washed object table
The detergent in face is just detached from flexible back bone, and the detergent for not being coated in washed object surface will not waste, and flexible bone
Rubbing action possessed by frame assists in removing the dirt for being fixedly arranged at object surface.The hardness of the flexible back bone can foundation
Actual needs, for example, can be as the hardness of existing steel wire bowl-cleaning ball, it can also be as the hardness of existing plastics bath balls.
The flexible back bone is preferably made of natural fiber, can also be made of synthetic fibers, or be made of wire,
It is also possible to the mixing of a variety of different materials.When being made of natural fiber, it is possible thereby to which the hole using natural fiber is inhaled
Detergent is received, slow release, especially also contributes to consolidation strength of the detergent on flexible back bone if necessary,
It avoids removing with flexible back bone, water penetrates into inside along the gap on skeleton surface when also avoiding washing, and leads to the molten of detergent
Solution and detergent integrally softens in addition dissipate from, and after the detergent of outer layer is finished, compared to synthetic fibers, outside exposing
Natural fiber preferably can absorb water and control the burst size of detergent using its internal void in washing process, guarantee to wash
It washs effect and detergent is prevented excessively to be detached from.
The voidage of the flexible back bone(Gap accounting between wire, fiber yarn or twine, does not consider in fiber
Portion's hole)It is preferably 20-50%, to be better adapted to washing needs.
The flexible back bone is preferably the flexible back bone for being in bath ball shape or Washing ball shape, can also use scouring pad, wash the dishes
Towel, multilayer wash the dishes, and the shapes such as block are relatively-stationary to be similar to rectangle or the bulks such as spherical.
The flexible back bone made of natural fiber preferably uses natural fiber yarn, silk screen or cloth spiral system to form, from
The three-dimensional shape of any suitables such as spherical in shape, rectangle or oval shape under right state(According to the flexible certainly of flexible back bone material
There can be deformation under body gravity), can according to need and consume any setting of hobby, yarn(Yarn including net or cloth)
Between there are gaps, to accommodate detergent.
Alleged spiral system refer to by flexible material through part connection formed shape be spherical shape, rectangle, olive shape, etc. three-dimensional shapes
Flexible body(Closely knit and/or duromer is not become in a manner of compacting or closely knit bonding etc.), storeroom from center or edge stitch
It is integrated;Silk screen or cloth are wound and prick beam into bath ball shape;Natural fiber yarn or cloth are wound in or are woven into wash it is clean
It is spherical etc..
Incorporation accounts for the synthetic fibers of total fiber mass 20-30% in the natural fiber, for example, nylon yarn, to improve flexibility
The intensity of skeleton, specific adding mode can be made together in a manner of any suitable for example, synthetic staple is mixed into atural staple fibre
At yarn, perhaps by synthetic fiber yarn and natural fiber yarn it is blended for yarn or by synthetic yarns substitute part it is natural
Fiber yarn is woven into silk screen or is woven into cloth.
Preferably, the washing mixture mainly include neopelex, lauryl sodium sulfate, spaonin powder,
Fatty alcohol polyoxyethylene ether(It is preferred that AEO-9), bentonite in powder and zeolite powder, the neopelex is 100 mass parts,
The lauryl sodium sulfate is 25-35 mass parts, and the spaonin powder is 20-30 mass parts, and the AEO-9 is 20-30 mass
Part, the bentonite in powder is 80-110 mass parts, and the zeolite powder is 40-60 mass parts.The various originals used in above-mentioned formula
Material is the nontoxic or micro- toxogen material washed suitable for tableware and food, and the performance of each raw material complements each other, not only logical
There is good clean effect under the conditions of being often used, but also taken into account the washing effect under hard water and lower temperature, simultaneously
Necessary blistering and defoaming effect and good dispersion effect etc. have also been taken into account, has been taken into account to oily dirt and protein dirt
The removing of equal food and drink dirt, bentonite and zeolite powder not only act as filling effect, and friction when being adapted to dishwashing detergent is wanted
Ask, especially also have good adsorption effect, can effectively or Preferential adsorption Multiple Pesticides residual especially at present it is common
Various Organic pesticide residues.
It can according to need the ingredients such as addition foaming agent, defoaming agent, essence, filler and other builders, for example, described
Washing mixture can also include the toluic acid sodium of 5-10 mass parts and the polyethylene glycol of the mass parts containing 10-15, to improve anti-corrosion
Performance simultaneously obtains physically better character, is easy to use.
The washing mixture can also include the cold press mandarin oil of 0-5 mass parts, to inhibit or remove odors.
The various solid abluents suitable for tableware disclosed by the invention can be prepared using following method:Including following step
Suddenly:
Each raw material for washing mixture is put in proportion into ground and mixed equipment, wherein all solids material is all made of -80 purposes
Suitable water is added in powder, after ground and mixed is uniform, forms the washing mixture of half fluidised form, can according to actual needs and plus
Convenience amount of water in work, and then the flowable state of the washing mixture of half fluidised form is adjusted, for example, can be 10-100 mass
Part or 40-50 mass parts can be 20-30 mass parts to obtain better effect, and the water being added can be directly added into,
Can also first with part material formed aqueous solution again in the form of aqueous solution together be added.
The flexible back bone prepared is placed in mold, injection pipe is protruded into the middle part of mold, it will be solid in the middle part of flexible back bone
Before injection pipe and close to injection pipe top, consolidating in the middle part of the flexible back bone can be carried out by the way of rod-shaped scaffold
It is fixed, flexible back bone can also be directly bundled in the spout part of injection pipe, peripheral part position of flexible back bone can be fixed
On mold, can mold inner-cavity body and the size of flexible back bone under natural conditions determine according to actual needs, for example, can
So that the internal diameter of mold is slightly less than the corresponding size of flexible back bone in its natural state, thus formed on the surface of solid detergent
The material of one layer of flexible back bone.It will be fixed on before injection pipe in the middle part of flexible back bone and close to injection pipe top, and can use injection
Pipe injection half fluidised form material impact flow, flexible back bone is unfolded around, to avoid when being injected from side by flexible bone
Frame presses to the other side.
Preferably, the top of the injection pipe, which is equipped with, is respectively facing different directions outlet.For example, a kind of preferred injection pipe
Injection unit is cylindrical or Taper Pipe shape, top is hemispherical and is equipped with to be evenly distributed with and several makees along different radial through-holes
For injection hole, on the injection unit tube wall of the injection pipe also it is axially distributed have it is several along different radial through-holes as injection
Hole passes through the injection hole hole in the injection hole aperture on the top of moderate control injection pipe and quantity and the injection unit in addition to top
Diameter and quantity, and injection hole aperture and the quantity of axial upper different location, can make injecting material in all directions and each portion
The balanced injection of position, so that injecting material substantially squeezes the extruding of flexible back bone around from middle part, thereby guarantees that flexibility
Extended state of the skeleton in mold, the distribution of injection hole and aperture etc. optimize data can be according to hydrodynamics relevant calculation
And/or it is obtained by experiment.
The washing mixture of half fluidised form is injected by injection pipe, is full of mold backed off after random input pipe, be can be marginal not and enter side
It exits, fills the space occupied originally by injection pipe to exit the material injected in the process, can also directly exit, by material
Mobility fill the space that was occupied originally by injection pipe, can be in injection pipe and rod-shaped scaffold(If any)Exit mould
Molding is embossed etc. after tool space, at the same realize everywhere enrich and material is uniform.
The washing mixture for injecting mold is dried in the shade naturally in solid, solid abluent product is formed, can wrap as needed
Dress.
Several washing design of mixture are given below:
Formula 1:
100 grams of neopelex;
25 grams of lauryl sodium sulfate;
025 gram of spaonin powder;
AEO-9030 grams;
080 gram of bentonite in powder;
050 gram of zeolite powder.
Formula 2:
100 grams of neopelex;
30 grams of lauryl sodium sulfate;
030 gram of spaonin powder;
AEO-9020 grams;
095 gram of bentonite in powder;
060 gram of zeolite powder.
Formula 3:
100 grams of neopelex;
35 grams of lauryl sodium sulfate;
020 gram of spaonin powder;
AEO-9025 grams;
0110 gram of bentonite in powder;
040 gram of zeolite powder;
1 gram of cold press mandarin oil.
Formula 4:
100 grams of neopelex;
35 grams of lauryl sodium sulfate;
020 gram of spaonin powder;
AEO-9030 grams;
0110 gram of bentonite in powder;
040 gram of zeolite powder;
5 grams of toluic acid sodium;
15 grams of polyethylene glycol.
Formula 5:
100 grams of neopelex;
31 grams of lauryl sodium sulfate;
026 gram of spaonin powder;
AEO-9028 grams;
0100 gram of bentonite in powder;
053 gram of zeolite powder;
10 grams of toluic acid sodium;
10 grams of polyethylene glycol.
Formula 6:
100 grams of neopelex;
35 grams of lauryl sodium sulfate;
030 gram of spaonin powder;
AEO-9030 grams;
0110 gram of bentonite in powder;
060 gram of zeolite powder;
7.5 grams of toluic acid sodium;
12.5 grams of polyethylene glycol;
5 grams of cold press mandarin oil.
Formula 7:
100 grams of neopelex;
25 grams of lauryl sodium sulfate;
020 gram of spaonin powder;
AEO-9020 grams;
080 gram of bentonite in powder;
040 gram of zeolite powder;
7.5 grams of toluic acid sodium;
12.5 grams of polyethylene glycol;
3 grams of cold press mandarin oil.
Formula 8:
100 grams of neopelex;
28 grams of lauryl sodium sulfate;
022 gram of spaonin powder;
AEO-9024 grams;
0101 gram of bentonite in powder;
048 gram of zeolite powder;
15 grams of polyethylene glycol.
Formula 9:
100 grams of neopelex;
33 grams of lauryl sodium sulfate;
023 gram of spaonin powder;
AEO-9024 grams;
092 gram of bentonite in powder;
043 gram of zeolite powder;
7.5 grams of toluic acid sodium.
It is disclosed by the invention it is each preferably with optional technological means, unless otherwise indicated and one preferably or can selecting technology hand
Section is that further limiting for another technological means is outer, can form several different technical solutions in any combination.
Claims (10)
1. a kind of solid abluent suitable for tableware, it is characterised in that including washing mixture and flexible back bone, the washing is mixed
Object is closed to be fixedly arranged on the flexible back bone.
2. solid abluent as described in claim 1, it is characterised in that the flexible back bone is made of natural fiber, Huo Zheyou
Synthetic fibers are made, or are made of wire.
3. solid abluent as claimed in claim 2, it is characterised in that the flexible back bone is in bath ball shape or Washing ball shape
Flexible back bone.
4. solid abluent as claimed in claim 3, it is characterised in that the voidage of the flexible back bone is 20-50%.
5. solid abluent as claimed in claim 4, it is characterised in that the flexible back bone made of natural fiber uses
Natural fiber yarn, silk screen or cloth spiral system form, and there are gaps between yarn.
6. solid abluent as claimed in claim 5, it is characterised in that incorporation accounts for total fiber mass 20- in the natural fiber
30% synthetic fibers.
7. the solid abluent as described in claim 1-6 is any, it is characterised in that the washing mixture mainly includes 12
Sodium alkyl benzene sulfonate, lauryl sodium sulfate, spaonin powder, AEO-9, bentonite in powder and zeolite powder, the dodecyl benzene sulfonic acid
Sodium is 100 mass parts, and the lauryl sodium sulfate is 25-35 mass parts, and the spaonin powder is 20-30 mass parts, described
AEO-9 is 20-30 mass parts, and the bentonite in powder is 80-110 mass parts, and the zeolite powder is 40-60 mass parts.
8. solid abluent as claimed in claim 7, it is characterised in that the washing mixture further includes 5-10 mass parts
The polyethylene glycol of toluic acid sodium and the mass parts containing 10-15.
9. solid abluent as claimed in claim 7, it is characterised in that the washing mixture further includes the cold of 0-5 mass parts
Squeeze mandarin oil.
10. the preparation method of the solid abluent as claimed in claims 1-9 suitable for tableware, includes the following steps:
Each raw material for washing mixture is put in proportion into ground and mixed equipment, the water of 20-30 mass parts is added, ground and mixed is equal
It is even, form the washing mixture of half fluidised form;
The flexible back bone prepared is placed in mold, injection pipe is protruded into the middle part of mold, will be fixed in the middle part of flexible back bone
Before injection pipe and close to injection pipe top;
The washing mixture of half fluidised form is injected by injection pipe, is full of mold backed off after random input pipe, and washing mixture dries in the shade naturally
In solid, solid abluent product is formed.
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| CN201810676764.0A CN108913402B (en) | 2018-06-27 | 2018-06-27 | Solid detergent for tableware and preparation method thereof |
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| US4190549A (en) * | 1977-12-26 | 1980-02-26 | Kao Soap Co., Ltd. | Soap for scouring pad |
| CN2323733Y (en) * | 1998-02-09 | 1999-06-16 | 吕秀娟 | cleaning ball |
| CN1529564A (en) * | 2001-07-13 | 2004-09-15 | 3M | Scrubbing article for cleaning with scented scrubbing cloth |
| CN2912503Y (en) * | 2006-04-10 | 2007-06-20 | 吴頔杰 | Cleaning polishing steel wire cotton wool |
| CN101914417A (en) * | 2010-08-06 | 2010-12-15 | 李湘佩 | Novel household cleaning products and manufacturing method thereof |
| CN102018490A (en) * | 2010-04-19 | 2011-04-20 | 铜陵洁雅生物科技股份有限公司 | D-limonene contained cleaning moist wipe used in kitchens and production method thereof |
| CN103930535A (en) * | 2011-09-01 | 2014-07-16 | 宝洁公司 | Article and soil capture agent for cleaning surfaces |
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Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4190549A (en) * | 1977-12-26 | 1980-02-26 | Kao Soap Co., Ltd. | Soap for scouring pad |
| CN2323733Y (en) * | 1998-02-09 | 1999-06-16 | 吕秀娟 | cleaning ball |
| CN1529564A (en) * | 2001-07-13 | 2004-09-15 | 3M | Scrubbing article for cleaning with scented scrubbing cloth |
| CN2912503Y (en) * | 2006-04-10 | 2007-06-20 | 吴頔杰 | Cleaning polishing steel wire cotton wool |
| CN102018490A (en) * | 2010-04-19 | 2011-04-20 | 铜陵洁雅生物科技股份有限公司 | D-limonene contained cleaning moist wipe used in kitchens and production method thereof |
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| CN108913402B (en) | 2021-04-02 |
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