CN108913402B - Solid detergent for tableware and preparation method thereof - Google Patents

Solid detergent for tableware and preparation method thereof Download PDF

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Publication number
CN108913402B
CN108913402B CN201810676764.0A CN201810676764A CN108913402B CN 108913402 B CN108913402 B CN 108913402B CN 201810676764 A CN201810676764 A CN 201810676764A CN 108913402 B CN108913402 B CN 108913402B
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mass
parts
detergent
solid detergent
mixture
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CN108913402A (en
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于健强
于若水
李艳莉
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/008—Polymeric surface-active agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to a solid detergent suitable for tableware and a preparation method thereof, wherein the solid detergent comprises a washing mixture and a flexible framework, the washing mixture is fixedly connected to the flexible framework and fills gaps in the flexible framework, the washing mixture mainly comprises 100 parts by mass of sodium dodecyl benzene sulfonate, 25-35 parts by mass of sodium dodecyl sulfate, 20-30 parts by mass of saponin powder, 20-30 parts by mass of AEO-9, 80-110 parts by mass of bentonite powder and 40-60 parts by mass of zeolite powder, and the preparation method comprises the steps of putting the raw materials of the washing mixture into grinding and mixing equipment according to a proportion, grinding and mixing uniformly to form a semi-fluid washing mixture, injecting the semi-fluid washing mixture from an injection pipe extending into the middle part of a mould, and naturally drying in the shade to form a solid. The detergent is convenient to use, and is beneficial to reducing pollution caused by the detergent and reducing detergent residue.

Description

Solid detergent for tableware and preparation method thereof
Technical Field
The present invention relates to a solid detergent suitable for washing tableware and the like.
Background
The existing detergent suitable for tableware and food mostly adopts liquid state, which can be called detergent, etc., when in use, the detergent is firstly smeared on the wiping cloth or dissolved in water, and then the wiping cloth with the detergent is used for wiping the tableware, the mode is not only troublesome, but also the dosage of the added detergent is not easy to control, a large amount of detergent is actually soaked in the wiping cloth or dissolved in the water, the detergent is not utilized, not only is unnecessary waste caused, but also the pollution load of wastewater treatment is increased, when phosphate is used as a builder, the phosphorus content in the water is increased, and according to the existing research, the phosphorus discharged by the detergent is one of the main phosphorus sources for causing water eutrophication.
On the other hand, the impact of detergent on human health is a problem to be considered, and although the currently used surfactants and builders are considered as nontoxic or slightly toxic substances and harmless to human body, under the condition of increasing dosage of detergent, the long-term impact on human needs to be paid enough attention, and in the condition that the washing is not completely carried out each time in practice, the minimal amount of chemical substances remained in tableware is inevitable, so that the utilization of less-harmful substitutes and the reduction of dosage and residue of detergent through the improvement of detergent itself are effective ways for reducing the possible harm of detergent.
Disclosure of Invention
In order to solve the technical problems, the invention provides the solid detergent suitable for the tableware, which is convenient to use, and is beneficial to reducing pollution caused by the detergent and reducing detergent residues.
The technical scheme of the invention is as follows: a solid detergent composition suitable for dishwashing, comprising a cleaning mixture and a flexible backbone, said cleaning mixture being affixed to said flexible backbone.
The washing mixture mainly comprises 100 parts by mass of sodium dodecyl benzene sulfonate, 25-35 parts by mass of sodium dodecyl sulfate, 20-30 parts by mass of saponin powder, 20-30 parts by mass of AEO-9, 80-110 parts by mass of bentonite powder and 40-60 parts by mass of zeolite powder, and the washing mixture can comprise 5-10 parts by mass of sodium benzoate, 10-15 parts by mass of polyethylene glycol and/or 0-5 parts by mass of cold-pressed orange peel oil.
The invention discloses a preparation method of any solid detergent suitable for tableware, which comprises the steps of putting raw materials of a washing mixture into grinding and mixing equipment in proportion, wherein all solid materials are powder of-80 meshes, adding 20-30 parts by mass of water, grinding and mixing uniformly to form a semi-fluid washing mixture; placing the prepared flexible framework in a mold, extending an injection pipe into the middle part of the mold, and fixing the middle part of the flexible framework in front of the injection pipe and close to the top end of the injection pipe; injecting a semi-fluid washing mixture through the injection pipe, filling the mould, and then taking out the injection pipe, naturally drying the washing mixture in the shade to form a solid, forming a solid detergent product, and packaging the solid detergent product as required.
The invention has the beneficial effects that: because the flexible pore material is used as the flexible framework of the detergent to form the 'wiping cloth' or 'cleaning ball' with the detergent, the detergent is directly used for scrubbing washed objects such as tableware and the like as wiping cloth during washing, the detergent wiped on the washed objects can act with dirt on the objects, unnecessary waste is avoided, and further, the phenomenon that a large amount of unused detergent enters waste water to be discharged is avoided, and water pollution caused by the discharge of the detergent is reduced; because each component adopts environment-friendly and human-friendly raw materials, and part of the components can also adopt green plant extract materials which are more environment-friendly and human-friendly, and the characteristics and the synergistic effect of various materials are fully utilized, better washing effect can be obtained, the dosage of the effectively utilized detergent is reduced under the condition of meeting the same washing requirement, and the harm degree of the detergent to the environment and the human body is reduced; the detergent has proper hardness degree due to reasonable matching of various components, excessive wiping caused by excessive hardness is avoided, excessive smearing on the washed objects caused by excessive softness is avoided, and excessive detergent can be prevented from being smeared on the washed objects due to the containing and adsorbing effects of porous materials such as natural fibers serving as a flexible framework; due to the mutual matching of various components, the washing agent plays roles in mutual washing, adsorption and the like, and is beneficial to improving the washing effect and reducing the residues of all the components under the same washing.
The solid detergent of the present invention is suitable for washing tableware, melon and fruit and other articles capable of being scrubbed.
Detailed Description
The invention provides a solid detergent for tableware, which comprises a washing mixture and a flexible framework, wherein the flexible framework is preferably made of a porous material or a filamentous, strip-shaped or net-shaped (including a woven cloth-shaped) material, or other flexible materials capable of being attached with the washing mixture, and the washing mixture is fixed on the flexible framework and generally fills all or part (usually most) of gaps in the flexible framework. The detergent block is characterized in that the detergent material in/on the flexible framework is solid, only the detergent material which is wiped to the surface of the object to be washed is separated from the flexible framework, the detergent material which is not coated on the surface of the object to be washed is not wasted, and the friction effect of the flexible framework is helpful for removing dirt which is fixed on the surface of the object. The hardness of the flexible skeleton can be based on actual needs, for example, the hardness of the existing steel wire dish washing ball can be the same as that of the existing plastic bath ball.
The flexible skeleton is preferably made of natural fibres, but also synthetic fibres, or of metal wires, or a mixture of several different materials. When the washing material is made of natural fibers, the holes of the natural fibers can be used for absorbing the washing material and slowly releasing the washing material when necessary, the washing material is particularly favorable for improving the consolidation strength of the washing material on the flexible framework, the washing material is prevented from being stripped from the flexible framework, water is prevented from permeating into the washing material along the gaps on the surface of the framework during washing, the washing material is dissolved, the whole detergent is softened and even dispersed, and when the washing material on the outer layer is used up, the natural fibers exposed outside can better absorb water and control the release amount of the washing material by using the holes in the natural fibers in the washing process compared with synthetic fibers, so that the washing effect is ensured, and the washing material is prevented from being excessively separated.
The porosity of the flexible framework (the ratio of the voids between the metal wires, fiber yarns or meshes, without considering the internal porosity of the fibers) is preferably 20-50% to better adapt to the washing requirements.
The flexible framework is preferably a bath ball-shaped or cleaning ball-shaped flexible framework, and can also be a block-shaped structure which is relatively fixed in shape, such as a scouring pad, a dish towel, a multilayer dish washing block and the like, and is similar to a rectangle or a ball.
The flexible skeleton made of natural fiber is preferably made of natural fiber yarn, silk screen or cloth, and is in any suitable three-dimensional shape (which can be deformed under the action of self gravity according to the flexibility of the flexible skeleton material) such as spherical shape, rectangular shape or ellipsoidal shape in a natural state, and can be set in any way according to needs and consumer preferences, and gaps are left among the yarns (including the yarn of the silk screen or the cloth) so as to accommodate washing materials.
The plastic making is that flexible materials are locally connected to form a flexible body (which is not changed into a compact and/or hard body in a compaction or compact bonding mode) with a three-dimensional shape such as a sphere, a rectangle, an olive and the like, and the materials are sewn into a whole from the center or the edge; winding and bundling a silk screen or cloth strip into a bathtub shape; winding or weaving natural fiber yarns or cloth strips into cleaning balls and the like.
The natural fiber is mixed with synthetic fiber, such as nylon filament, accounting for 20-30% of the total mass of the fiber to improve the strength of the flexible skeleton, and the natural fiber can be mixed with the synthetic fiber to form yarn in any suitable mode, such as mixing the synthetic fiber with the natural fiber to form yarn, or blending the synthetic fiber yarn and the natural fiber yarn into yarn, or weaving the synthetic fiber yarn to replace part of the natural fiber yarn to form silk screen or woven cloth.
Preferably, the washing mixture mainly comprises 100 parts by mass of sodium dodecyl benzene sulfonate, 25-35 parts by mass of sodium dodecyl sulfate, 20-30 parts by mass of saponin powder, 20-30 parts by mass of AEO-9, 80-110 parts by mass of bentonite powder and 40-60 parts by mass of zeolite powder. The raw materials adopted in the formula are nontoxic or slightly toxic raw materials suitable for washing tableware and food, the performances of the raw materials supplement each other, the detergent has good decontamination effect under common use conditions, also has washing effect under hard water and lower temperature, also has necessary foaming and defoaming effects, good dispersion effect and the like, and also has removal of catering dirt such as oily dirt, protein dirt and the like, and the bentonite and the zeolite powder not only play a filling role, but also are suitable for friction requirements during tableware washing, especially have good adsorption effect, and can effectively or preferentially adsorb various pesticide residues, especially various common organic pesticide residues at present.
Foaming agent, defoaming agent, essence, filler and other builder can be added according to the requirement, for example, the washing mixture can also comprise 5-10 parts by mass of sodium benzoate and 10-15 parts by mass of polyethylene glycol, so as to improve the corrosion resistance and obtain better physical properties, and the washing mixture is convenient to use.
The washing mixture may also include 0-5 parts by mass of cold-pressed orange peel oil to suppress or remove off-flavors.
The various solid detergents suitable for tableware disclosed by the invention can be prepared by the following method: comprises the following steps:
the raw materials of the washing mixture are put into grinding and mixing equipment in proportion, wherein all solid materials adopt powder of minus 80 meshes, a proper amount of water is added, after grinding and mixing are carried out uniformly, a semi-fluid washing mixture is formed, the water addition amount can be adjusted according to actual needs and processing convenience, the flowable state of the semi-fluid washing mixture can be adjusted, for example, 10-100 parts by mass or 40-50 parts by mass to obtain better effects, the added water can be directly added, or the added water and part of the raw materials form an aqueous solution and then are added together in the form of the aqueous solution.
The prepared flexible framework is placed in a mold, an injection pipe extends into the middle of the mold, the middle of the flexible framework is fixed in front of the injection pipe and is close to the top end of the injection pipe, the middle of the flexible framework can be fixed in a rod-shaped support mode, the flexible framework can also be directly bound at a pipe opening of the injection pipe, the position of the peripheral part of the flexible framework can be fixed on the mold, the size ratio of a cavity in the mold to the flexible framework in a natural state can be determined according to actual needs, for example, the inner diameter of the mold can be slightly smaller than the corresponding size of the flexible framework in the natural state, and a layer of flexible framework material is formed on the surface of the solid detergent. Before being fixed in the injection pipe with flexible skeleton middle part and pressing close to the injection pipe top, can utilize the flow impact of the half fluid material that the injection pipe injected into, make flexible skeleton expand to all around to extrude the opposite side with flexible skeleton when avoiding injecting from one side.
Preferably, the top end of the injection pipe is provided with outlets facing different directions respectively. For example, an injection portion of a preferred injection pipe is in a circular pipe shape or a conical pipe shape, the top end of the injection pipe is in a hemispherical shape and is provided with a plurality of through holes which are uniformly distributed along different radial directions as injection holes, the pipe wall of the injection portion of the injection pipe is also distributed with a plurality of through holes which are uniformly distributed along different radial directions as injection holes, the hole diameter and the number of the injection holes at the top end of the injection pipe, the hole diameter and the number of the injection holes of the injection portion except the top end, and the hole diameter and the number of the injection holes at different positions in the axial direction are properly controlled, so that injection materials can be injected uniformly in all directions and all positions, the injection materials can extrude the flexible framework basically from the middle to the periphery, the extension state of the flexible framework in the mold is ensured, and optimized data such as the distribution and the hole diameter of the.
The semi-fluid washing mixture is injected through the injection pipe, the mold is filled with the washing mixture, the input pipe is withdrawn after the washing mixture is filled, the washing mixture can be injected while being withdrawn, the injected material fills the space occupied by the injection pipe in the withdrawal process, the washing mixture can also be directly withdrawn, the space occupied by the injection pipe is filled by the fluidity of the material, embossing and other mold pressing can be carried out after the injection pipe and the rod-shaped bracket (if any) are withdrawn from the mold space, and simultaneously the filling of all parts and the uniformity of the material are realized.
And naturally drying the washing mixture injected into the mould in the shade to form a solid detergent product, and packaging the solid detergent product according to the requirement.
Several wash mixture formulations are given below:
formula 1:
100 g of sodium dodecyl benzene sulfonate;
25 g of sodium dodecyl sulfate;
025 g of Chinese honey locust powder;
AEO-9030 g;
080 g of bentonite powder;
050 g of zeolite powder.
And (2) formula:
100 g of sodium dodecyl benzene sulfonate;
30 g of sodium dodecyl sulfate;
030 g of Chinese honey locust powder;
AEO-9020 g;
095 g of bentonite powder;
060 g of zeolite powder.
And (3) formula:
100 g of sodium dodecyl benzene sulfonate;
35 g of sodium dodecyl sulfate;
020 g of Chinese honey locust powder;
AEO-9025 g;
0110 g of bentonite powder;
040 g of zeolite powder;
1 g of cold pressed orange peel oil.
And (4) formula:
100 g of sodium dodecyl benzene sulfonate;
35 g of sodium dodecyl sulfate;
020 g of Chinese honey locust powder;
AEO-9030 g;
0110 g of bentonite powder;
040 g of zeolite powder;
5 g of sodium benzoate;
15 g of polyethylene glycol.
And (5) formula:
100 g of sodium dodecyl benzene sulfonate;
31 g of sodium dodecyl sulfate;
026 g of Chinese honey locust powder;
AEO-9028 g;
0100 g of bentonite powder;
053 g of zeolite powder;
10 g of sodium benzoate;
10 g of polyethylene glycol.
And (6) formula:
100 g of sodium dodecyl benzene sulfonate;
35 g of sodium dodecyl sulfate;
030 g of Chinese honey locust powder;
AEO-9030 g;
0110 g of bentonite powder;
060 g of zeolite powder;
7.5 g of sodium benzoate;
12.5 g of polyethylene glycol;
5 g of cold pressed orange peel oil.
And (3) formula 7:
100 g of sodium dodecyl benzene sulfonate;
25 g of sodium dodecyl sulfate;
020 g of Chinese honey locust powder;
AEO-9020 g;
080 g of bentonite powder;
040 g of zeolite powder;
7.5 g of sodium benzoate;
12.5 g of polyethylene glycol;
3 g of cold-pressed orange peel oil.
And (4) formula 8:
100 g of sodium dodecyl benzene sulfonate;
28 g of sodium dodecyl sulfate;
022 grams of Chinese honeylocust fruit powder;
AEO-9024 g;
0101 g of bentonite powder;
048 g of zeolite powder;
15 g of polyethylene glycol.
Formula 9:
100 g of sodium dodecyl benzene sulfonate;
33 g of sodium dodecyl sulfate;
023 g of gleditsia sinensis lam powder;
AEO-9024 g;
092 g of bentonite powder;
043 g of zeolite powder;
sodium benzoate 7.5 g.
The technical means disclosed by the invention can be combined arbitrarily to form a plurality of different technical schemes except for special description and the further limitation that one technical means is another technical means.

Claims (10)

1. A solid dishwashing detergent for use in connection with the cleaning of a scrubbable article comprising a cleaning mixture and a flexible matrix, said cleaning mixture being affixed to said flexible matrix to fill substantially all voids within said flexible matrix.
2. A solid detergent composition according to claim 1 wherein said flexible matrix is made of natural fibers, or synthetic fibers, or metal wire.
3. A solid detergent composition according to claim 2 wherein said flexible matrix is a bath or detergent ball shaped flexible matrix.
4. A solid detergent composition according to claim 3 wherein said flexible matrix has a void volume of from 20% to 50%.
5. The solid detergent according to claim 4 wherein said flexible skeleton made of natural fibers is formed by yarns, nets or cloths of natural fibers with voids left between the yarns.
6. A solid detergent according to claim 5 wherein said natural fibres incorporate synthetic fibres in an amount of from 20 to 30% by weight of the total mass of the fibres.
7. The solid detergent according to any one of claims 1 to 6, wherein said washing mixture mainly comprises 100 parts by mass of sodium dodecylbenzenesulfonate, 25 to 35 parts by mass of sodium dodecylsulfate, 20 to 30 parts by mass of saponin powder, 20 to 30 parts by mass of AEO-9, 80 to 110 parts by mass of bentonite powder and 40 to 60 parts by mass of zeolite powder, sodium dodecylbenzenesulfonate, sodium dodecylsulfate, saponin powder, AEO-9, bentonite powder and zeolite powder.
8. The solid detergent according to claim 7, wherein said detergent mixture further comprises 5 to 10 parts by mass of sodium benzoate and 10 to 15 parts by mass of polyethylene glycol.
9. A solid detergent composition according to claim 7 wherein the detergent mixture further comprises 0 to 5 parts by mass of cold pressed citrus peel oil.
10. A process for the preparation of a solid detergent composition for dishes according to claims 1-9, comprising the steps of:
putting the raw materials of the washing mixture into grinding and mixing equipment in proportion, adding 20-30 parts by mass of water, and grinding and mixing uniformly to form a semi-fluid washing mixture;
placing the prepared flexible framework in a mold, extending an injection pipe into the middle part of the mold, and fixing the middle part of the flexible framework in front of the injection pipe and close to the top end of the injection pipe;
injecting a semi-fluid washing mixture through the injection pipe, filling the mould, and then taking out the injection pipe, wherein the washing mixture is naturally dried in the shade to be solid, and a solid detergent product is formed.
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