CN1089794C - 制备润滑基础油的方法 - Google Patents

制备润滑基础油的方法 Download PDF

Info

Publication number: CN1089794C
Authority: CN; China
Prior art keywords: dewaxing; fischer; weight; conversion catalyst; hydrogenation
Prior art date: 1995-11-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CN96121776A

Other languages

English (en)

Chinese (zh)

Other versions

CN1167811A (zh

Inventor

J-M·A·伯特奥特

G·R·B·格曼恩

A·霍克

M·M·P·让森

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Internationale Research Maatschappij BV

Original Assignee

Shell Internationale Research Maatschappij BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-11-28

Filing date

1996-11-27

Publication date

2002-08-28

1996-11-27 Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV

1997-12-17 Publication of CN1167811A publication Critical patent/CN1167811A/zh

2002-08-28 Application granted granted Critical

2002-08-28 Publication of CN1089794C publication Critical patent/CN1089794C/zh

2016-11-27 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 41
239000002199 base oil Substances 0.000 title claims abstract description 35
230000001050 lubricating effect Effects 0.000 title claims abstract description 19
239000003054 catalyst Substances 0.000 claims abstract description 43
238000009835 boiling Methods 0.000 claims abstract description 24
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 20
238000005984 hydrogenation reaction Methods 0.000 claims description 19
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
229910052697 platinum Inorganic materials 0.000 claims description 11
229910052763 palladium Inorganic materials 0.000 claims description 10
239000002904 solvent Substances 0.000 claims description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
229910052751 metal Inorganic materials 0.000 claims description 8
239000002184 metal Substances 0.000 claims description 8
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 8
238000006243 chemical reaction Methods 0.000 claims description 7
239000002808 molecular sieve Substances 0.000 claims description 6
239000011230 binding agent Substances 0.000 claims description 5
230000003197 catalytic effect Effects 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 4
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
239000000463 material Substances 0.000 claims description 3
238000004517 catalytic hydrocracking Methods 0.000 claims 2
239000002253 acid Substances 0.000 claims 1
239000010953 base metal Substances 0.000 claims 1
230000009849 deactivation Effects 0.000 claims 1
230000015572 biosynthetic process Effects 0.000 abstract description 8
238000003786 synthesis reaction Methods 0.000 abstract description 8
238000007710 freezing Methods 0.000 abstract description 5
230000008014 freezing Effects 0.000 abstract description 5
239000001993 wax Substances 0.000 description 55
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 18
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
150000001335 aliphatic alkanes Chemical class 0.000 description 8
239000000203 mixture Substances 0.000 description 8
239000010457 zeolite Substances 0.000 description 8
238000006317 isomerization reaction Methods 0.000 description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
239000011959 amorphous silica alumina Substances 0.000 description 6
229910052739 hydrogen Inorganic materials 0.000 description 6
239000001257 hydrogen Substances 0.000 description 6
239000010687 lubricating oil Substances 0.000 description 6
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
229910000510 noble metal Inorganic materials 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
229910001657 ferrierite group Inorganic materials 0.000 description 4
239000003921 oil Substances 0.000 description 4
238000004508 fractional distillation Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
229910017052 cobalt Inorganic materials 0.000 description 2
239000010941 cobalt Substances 0.000 description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000005194 fractionation Methods 0.000 description 2
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
229910052750 molybdenum Inorganic materials 0.000 description 2
239000011733 molybdenum Substances 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
239000011148 porous material Substances 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
-1 aluminum fluorosilicate Chemical compound 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000010292 electrical insulation Methods 0.000 description 1
239000002737 fuel gas Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000005457 optimization Methods 0.000 description 1
238000005057 refrigeration Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000001308 synthesis method Methods 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
238000005292 vacuum distillation Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/043—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)
Lubricants (AREA)

CN96121776A 1995-11-28 1996-11-27 制备润滑基础油的方法 Expired - Fee Related CN1089794C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP95402713.2		1995-11-28
EP95402713		1995-11-28

Publications (2)

Publication Number	Publication Date
CN1167811A CN1167811A (zh)	1997-12-17
CN1089794C true CN1089794C (zh)	2002-08-28

Family

ID=8221546

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN96121776A Expired - Fee Related CN1089794C (zh)	1995-11-28	1996-11-27	制备润滑基础油的方法

Country Status (11)

Country	Link
JP (1)	JP3986107B2 (fr)
KR (1)	KR100457182B1 (fr)
CN (1)	CN1089794C (fr)
AU (1)	AU705415B2 (fr)
CA (1)	CA2191290C (fr)
DE (2)	DE69633549T2 (fr)
DZ (1)	DZ2129A1 (fr)
MY (1)	MY114570A (fr)
SG (1)	SG74001A1 (fr)
TW (1)	TW416981B (fr)
ZA (1)	ZA969906B (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6103099A (en) *	1998-09-04	2000-08-15	Exxon Research And Engineering Company	Production of synthetic lubricant and lubricant base stock without dewaxing
ES2190303B1 (es) *	1999-04-29	2005-02-16	Institut Francais Du Petrole	Procedimiento flexible de produccion de bases de aceites y destilados para una conversion-hidroisomerizacion sobre un catalizador ligeramente disperso seguida de un desparafinado catalitico.
NL1015036C2 (nl) *	1999-04-29	2001-02-12	Inst Francais Du Petrole	Flexibel proces voor de productie van basisoliÙn en gemiddelde destillatieproducten met een omzetting-hydro-isomerisatie gevolgd door een katalytische ontparaffinering.
AR032941A1 (es)	2001-03-05	2003-12-03	Shell Int Research	Un procedimiento para preparar un aceite base lubricante y aceite base obtenido, con sus diversas utilizaciones
AR032930A1 (es) *	2001-03-05	2003-12-03	Shell Int Research	Procedimiento para preparar un aceite de base lubricante y gas oil
WO2004003113A1 (fr) *	2002-06-26	2004-01-08	Shell Internationale Research Maatschappij B.V.	Composition lubrifiante
EP1523536B1 (fr) *	2002-07-19	2019-08-21	Shell International Research Maatschappij B.V.	Caoutchouc de silicium comprenant une huile de dilution
US6703353B1 (en) *	2002-09-04	2004-03-09	Chevron U.S.A. Inc.	Blending of low viscosity Fischer-Tropsch base oils to produce high quality lubricating base oils
US7132042B2 (en) *	2002-10-08	2006-11-07	Exxonmobil Research And Engineering Company	Production of fuels and lube oils from fischer-tropsch wax
US7125818B2 (en) *	2002-10-08	2006-10-24	Exxonmobil Research & Engineering Co.	Catalyst for wax isomerate yield enhancement by oxygenate pretreatment
US20040129603A1 (en) *	2002-10-08	2004-07-08	Fyfe Kim Elizabeth	High viscosity-index base stocks, base oils and lubricant compositions and methods for their production and use
US7704379B2 (en) *	2002-10-08	2010-04-27	Exxonmobil Research And Engineering Company	Dual catalyst system for hydroisomerization of Fischer-Tropsch wax and waxy raffinate
US20040154958A1 (en) *	2002-12-11	2004-08-12	Alexander Albert Gordon	Functional fluids having low brookfield viscosity using high viscosity-index base stocks, base oils and lubricant compositions, and methods for their production and use
US6962651B2 (en) *	2003-03-10	2005-11-08	Chevron U.S.A. Inc.	Method for producing a plurality of lubricant base oils from paraffinic feedstock
US20050077208A1 (en) *	2003-10-14	2005-04-14	Miller Stephen J.	Lubricant base oils with optimized branching
US8137531B2 (en) *	2003-11-05	2012-03-20	Chevron U.S.A. Inc.	Integrated process for the production of lubricating base oils and liquid fuels from Fischer-Tropsch materials using split feed hydroprocessing
JP6080489B2 (ja) *	2005-01-07	2017-02-15	Ｊｘエネルギー株式会社	潤滑油基油
CN102911726B (zh) *	2011-08-01	2015-04-15	中国石油化工股份有限公司	高粘度指数润滑油基础油的生产方法
CN103102946B (zh) *	2011-11-10	2015-07-22	中国石油化工股份有限公司	一种生产轻质润滑油基础油和重质润滑油基础油的方法
CN103773466B (zh) *	2012-10-24	2015-06-17	中国石油化工股份有限公司	加氢裂化-异构脱蜡组合生产润滑油基础油方法
CN103773476B (zh) *	2012-10-24	2015-06-17	中国石油化工股份有限公司	一种加氢裂化-异构脱蜡生产高粘度指数润滑油基础油方法
CN103773465B (zh) *	2012-10-24	2015-04-15	中国石油化工股份有限公司	一种组合工艺生产高粘度指数润滑油基础油的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4943672A (en) *	1987-12-18	1990-07-24	Exxon Research And Engineering Company	Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403)
EP0515256A1 (fr) *	1991-05-21	1992-11-25	Institut Français du Pétrole	Procédé d'hydromérisation de paraffines issues du procédé Fischer-Tropsch à l'aide de catalyseurs à base de zéolithe H.Y

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5059299A (en) *	1987-12-18	1991-10-22	Exxon Research And Engineering Company	Method for isomerizing wax to lube base oils
AU610671B2 (en) *	1987-12-18	1991-05-23	Exxon Research And Engineering Company	Process for the hydroisomerization of fischer-tropsch wax to produce lubricating oil
US5379533A (en) *	1991-12-06	1995-01-10	Converse Inc.	Fluid filled amusement or attention attracting article for attachment to footwear
US5378348A (en) *	1993-07-22	1995-01-03	Exxon Research And Engineering Company	Distillate fuel production from Fischer-Tropsch wax
EP0668342B1 (fr) *	1994-02-08	1999-08-04	Shell Internationale Researchmaatschappij B.V.	Procédé de préparation d'une huile lubrifiante de base
FR2718145B1 (fr) *	1994-04-01	1996-05-31	Inst Francais Du Petrole	Procédé de traitement avec hydroisomérisation de charges issues du procédé fischer-tropsch.

1996
- 1996-11-25 DZ DZ960174A patent/DZ2129A1/fr active
- 1996-11-26 SG SG1996011445A patent/SG74001A1/en unknown
- 1996-11-26 JP JP32906696A patent/JP3986107B2/ja not_active Expired - Lifetime
- 1996-11-26 AU AU71988/96A patent/AU705415B2/en not_active Ceased
- 1996-11-26 KR KR1019960059633A patent/KR100457182B1/ko not_active Expired - Fee Related
- 1996-11-26 CA CA002191290A patent/CA2191290C/fr not_active Expired - Fee Related
- 1996-11-26 ZA ZA969906A patent/ZA969906B/xx unknown
- 1996-11-26 MY MYPI96004954A patent/MY114570A/en unknown
- 1996-11-27 CN CN96121776A patent/CN1089794C/zh not_active Expired - Fee Related
- 1996-11-28 DE DE69633549T patent/DE69633549T2/de not_active Expired - Fee Related
- 1996-11-28 DE DE69635320T patent/DE69635320T2/de not_active Expired - Fee Related
- 1996-12-24 TW TW085115965A patent/TW416981B/zh not_active IP Right Cessation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4943672A (en) *	1987-12-18	1990-07-24	Exxon Research And Engineering Company	Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403)
EP0515256A1 (fr) *	1991-05-21	1992-11-25	Institut Français du Pétrole	Procédé d'hydromérisation de paraffines issues du procédé Fischer-Tropsch à l'aide de catalyseurs à base de zéolithe H.Y

Also Published As

Publication number	Publication date
JPH09221685A (ja)	1997-08-26
DE69635320D1 (de)	2005-11-24
KR100457182B1 (ko)	2005-04-19
DE69633549D1 (de)	2004-11-11
DE69633549T2 (de)	2005-11-17
SG74001A1 (en)	2000-07-18
AU7198896A (en)	1997-06-05
CA2191290A1 (fr)	1997-05-29
DZ2129A1 (fr)	2002-07-23
JP3986107B2 (ja)	2007-10-03
DE69635320T2 (de)	2006-04-20
CN1167811A (zh)	1997-12-17
TW416981B (en)	2001-01-01
KR970027273A (ko)	1997-06-24
AU705415B2 (en)	1999-05-20
MY114570A (en)	2002-11-30
CA2191290C (fr)	2006-09-26
ZA969906B (en)	1997-05-28

Legal Events

Date	Code	Title	Description
1997-12-17	C06	Publication
1997-12-17	PB01	Publication
1999-02-17	C10	Entry into substantive examination
1999-02-17	SE01	Entry into force of request for substantive examination
2002-08-28	C14	Grant of patent or utility model
2002-08-28	GR01	Patent grant
2011-02-16	C17	Cessation of patent right
2011-02-16	CF01	Termination of patent right due to non-payment of annual fee	Granted publication date: 20020828 Termination date: 20091228

Publication	Publication Date	Title
CN1089794C (zh)	2002-08-28	制备润滑基础油的方法
EP0776959B1 (fr)	2004-10-06	Procédé pour la production d'huiles lubrifiantes
AU755963B2 (en)	2003-01-02	Catalytic dewaxing process and catalyst composition
JP4246496B2 (ja)	2009-04-02	ワックス状ラフィネートの製造方法
JP5000296B2 (ja)	2012-08-15	フィッシャー・トロプシュ合成生成物から基油を製造する方法
JP5570483B2 (ja)	2014-08-13	フィッシャー・トロプシュワックスからの基油の異性化／デヘイジング方法
JP5110759B2 (ja)	2012-12-26	ワックス質供給原料を低ヘーズ重質基油に転化する方法
JP2005506396A (ja)	2005-03-03	潤滑基油及びガス油の製造方法
US20080045614A1 (en)	2008-02-21	Process to Make a Base Oil
JP2008525607A (ja)	2008-07-17	フィッシャー・トロプシュ合成生成物から基油を製造する方法
KR100426263B1 (ko)	2004-05-31	윤활용 기재오일을 생성하는 방법
AU2005318135A1 (en)	2006-06-29	Process to prepare two iso paraffinic products from a Fisher-Tropsch derived feed
US7655134B2 (en)	2010-02-02	Process to prepare a base oil
EP2746367A1 (fr)	2014-06-25	Procédé pour préparer une huile de base et du gazole