CN1099781A - Multi-polymerizing blend resin varnish - Google Patents
Multi-polymerizing blend resin varnish Download PDFInfo
- Publication number
- CN1099781A CN1099781A CN 93109988 CN93109988A CN1099781A CN 1099781 A CN1099781 A CN 1099781A CN 93109988 CN93109988 CN 93109988 CN 93109988 A CN93109988 A CN 93109988A CN 1099781 A CN1099781 A CN 1099781A
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- CN
- China
- Prior art keywords
- kilogram
- resin
- component
- add
- urethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011347 resin Substances 0.000 title claims abstract description 24
- 229920005989 resin Polymers 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims description 5
- 239000002966 varnish Substances 0.000 title description 3
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 229920003180 amino resin Polymers 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 18
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 18
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004922 lacquer Substances 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 7
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims 2
- 230000000996 additive effect Effects 0.000 claims 2
- 235000004443 Ricinus communis Nutrition 0.000 claims 1
- 240000000528 Ricinus communis Species 0.000 claims 1
- 239000000470 constituent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000003973 paint Substances 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000007812 deficiency Effects 0.000 abstract description 3
- 238000005282 brightening Methods 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 229920005749 polyurethane resin Polymers 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 4
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 3
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- 239000012972 dimethylethanolamine Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SCRYTJBWFYOLEF-UHFFFAOYSA-N butanoic acid;tin Chemical compound [Sn].CCCC(O)=O SCRYTJBWFYOLEF-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- -1 diethyleneglycolamin Chemical compound 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
Abstract
This invention is aimed at some defects and deficiency in current recipe and technology, and adopts a multiple resin mixing technology to research and develop <<W9269 series resin paint>> (i.e. multipolymerized mixed resin paint) by employing "mutual crossing net polymerization" theory. It uses polyurethane resin, epoxy resin, acrylic resin and amino resin as main materials, combining with such auxiliaries as brightening agent. The said product has dual components A and B to be mixed under normal temp., and can be used after stirred uniformly. This series product may be compounded into different colours, and is suitable for building, communication and household electric appliances.
Description
The invention belongs to polycomponent polyurethane resin coating field.
Bicomponent polyurethane paint is subjected to human consumer's welcome with the performance of excellence and application widely.But, at present because prescription and technology have some defectives and deficiency, there are many problems on the quality product, crosslinked insufficient as the resene membrane-forming agent, linking agent is undesirable, problems such as indexs such as paint film appearance, sticking power, intensity are not good, range of application is narrow, thereby has limited the production and the popularization of this kind.In order to overcome above-mentioned deficiency, the present invention takes the various kinds of resin blending technology, and utilization " latex interpenetrating polymerization " theory is developed " multi-polymerizing blend resin varnish ".Poly resin lacquer mainly comprises: urethane resin, Resins, epoxy, acrylic resin, aminoresin are major ingredient, are compounded with multiple compositions such as brightening agent, ripening agent, stearic agent, thinner.This product is divided into the two components of A, B, promptly joins promptly and uses.
A component prescription is: in polymeric kettle, add urethane resin 130-160 kilogram, ring ethyl ketone 15-20 kilogram, dimethylbenzene 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, add acrylic resin 10-15 kilogram, Resins, epoxy 15-20 kilogram, aminoresin 15-20 kilogram down at 50 ℃, be warming up to 90-100 ℃, be incubated two hours, be cooled to 50 ℃, add 50 milliliters of a small amount of Viscotrol C, HDI biurets, titanium dioxide 20-30 kilogram, after being ground to 500 orders, reduce to normal temperature, add a spot of sodium stearate, dibutyl phthalate, soluble cotton, silicone oil again.
B component prescription is: 0.7 kilogram of urethane 120-150 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, dimethylbenzene 15-20 kilogram, dimethylethanolamine add a little biuret, diethyleneglycolamin, quadrol, two bay dibutyl acid tin, silicone oil etc. again.Heat 80 ℃, it is standby to stir.
The A, the B two component normal temperature that make are mixed down, stir and to use.
The series product that the present invention produces comprise: decorated resin lacquer, waterproof resin lacquer, inferior photopolymer resin lacquer, anti-corrosion resin lacquer, anti-electrostatic resin paint, fluorescence resin lacquer.Can be mixed with shades of colour, be coated with brush finish indoor and outdoor wall wall, replace ceramic tile; Various warehouse floor protection against the tide, the roof seepage replaces by " three oily three felts "; Office's cement, wood floors brushing have that inferior light is anti-skidding, characteristics such as damp proof insulation, wear-resisting, insulation; The coating of metallic conduit inside and outside wall, the spraying of vehicle and household electrical appliance, the spraying of oil depot can resist electric shock; Be used for brushing highway boundary line, road upright stone tablet etc.
Easy construction of the present invention sprays all suitable.
The key technical indexes of the present invention is as follows:
1, gloss (%) 105
2, hardness 0.66
3, sticking power (level) is not more than 2
4, disruptive strength (normality, KV/mm) 89.7
5, petrol-resistance (25 ℃, 120h) no change
6, thermotolerance (120 ℃, 120h) no change
7, oil-proofness (25 ℃, 120h) no change
8, acid resistance (25 ℃, 40% sulfuric acid, 120h) no change
9, alkali resistance (25 ℃, 36% sodium hydroxide, 120h) no change
10, resistance to salt water (25 ℃, 20% sodium-chlor, 120h) no change
11, temperature-change resistance (40～60 ℃, 10 circulations) no change
Embodiment 1:
The preparation of A component: in reactor, add urethane resin 130-160 kilogram, add thinner dimethylbenzene 15-20 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram again, under 50 ℃, add Resins, epoxy 15-20 kilogram, acrylic resin 10-15 kilogram again, be warmed up to 90-100 ℃, be incubated two hours, drop to 50 ℃, add 50 milliliters of a little Viscotrol C, HDI biurets, titanium dioxide 20-30 kilogram, after being ground to 500 orders, drop to normal temperature, add a little sodium stearate, dibutyl phthalate, soluble cotton, silicone oil again, stir half an hour.
The preparation of B component: add urethane resin 120-150 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, dimethylbenzene 15-20 kilogram, dimethylethanolamine 0.7-1 kilogram in the reactor, reach a little biuret, diethanolamine, quadrol, two bay dibutyl acid tin, silicone oil, heat to 80 ℃, stirring, it is standby to be cooled to normal temperature.
Promptly become product with mixing under A, the B two component normal temperature.
The smooth smooth of this product paint film appearance is plentiful, and texture is like enamel, viscosity 24.4(25 ℃, S), time of drying: surface drying＜3h does solid work＜12h, solid content 56.22%, 10 microns of fineness, opacifying power white 120 meters squared per gram, gloss 105%, hardness 0.66, disruptive strength 89.7KV/MM(normality), sticking power＜2 grade, 72.4 ℃ of thermal degradation temperature amounts, water tolerance, oil-proofness, resistance to acids and bases, salt tolerance, thermotolerance are all good.
Embodiment 2:
The preparation of A component: in reactor, add urethane 120-150 kilogram, add dimethylbenzene 15-20 kilogram again, N-BUTYL ACETATE 15-20 kilogram, ring ethyl ketone 15-20 kilogram adds acrylic resin 1-5 kilogram, Resins, epoxy (664,601) 15-20 kilogram again under 50 ℃, be warming up to 90-100 ℃, be incubated two hours, drop to 50 ℃, add a little biuret 5-10 milliliter, titanium dioxide 20-30 kilogram, be ground to 500 orders after, drop to normal temperature, add a small amount of silicone oil, sodium stearate again, stir half an hour.
The preparation of B component: in reactor, add urethane 120-150 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, dimethylbenzene 15-20 kilogram adds two bays, two butyric acid tin, quadrol, biuret and silicone oil again, is heated to 80 ℃, stir, be cooled to normal temperature, standby.
The coating that A, B two set of dispense are made, except that fineness, brightness do not reach requirement, sticking power poor slightly, other performances are with embodiment 1.
Embodiment 3:
The preparation of A component: add polymeric amide 8-10 kilogram in reactor, Resins, epoxy 5-10 kilogram is warmed up to 80 ℃, adds urethane 120-150 kilogram again, acrylic resin 10-15 kilogram cools to 50 ℃, adds titanium dioxide 20-30 kilogram, be warmed up to 90 ℃, stir, do not grind.
The preparation of B component: in reactor, add urethane 120-150 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, dimethylbenzene 15-20 kilogram, a little two bay dibutyl acid tin and quadrol.
The coating that A, B two set of dispense are made, hardness, brightness all do not reach requirement, and dry slow, lacquer bubbles, other performances such as embodiment 1.
Claims (3)
1, a kind of two-pack blending resin lacquer is characterized in that A component main component is that urethane resin, acrylic resin, Resins, epoxy, aminoresin and corresponding additive are formed; The B component is that urethane resin and silicone oil, castor-oil plant wet goods corresponding additive are formed.
2, two-pack blending resin lacquer according to claim 1 is characterized in that the composition of each material of A component is: urethane resin 130-160 kilogram, acrylic resin 10-15 kilogram, Resins, epoxy 15-20 kilogram, aminoresin 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, ring ethyl ketone 15-20 kilogram, dimethylbenzene 15-20 kilogram, titanium dioxide 20-30 kilogram.
3, two-pack blending resin lacquer according to claim 1, the batching that it is characterized in that each constituent of B component are urethane 120-150 kilogram, ring ethyl ketone 15-20 kilogram, N-BUTYL ACETATE 15-20 kilogram, dimethylbenzene 15-20 kilogram.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93109988 CN1099781A (en) | 1993-08-25 | 1993-08-25 | Multi-polymerizing blend resin varnish |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93109988 CN1099781A (en) | 1993-08-25 | 1993-08-25 | Multi-polymerizing blend resin varnish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1099781A true CN1099781A (en) | 1995-03-08 |
Family
ID=4987898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93109988 Pending CN1099781A (en) | 1993-08-25 | 1993-08-25 | Multi-polymerizing blend resin varnish |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1099781A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100369993C (en) * | 2006-03-20 | 2008-02-20 | 王新成 | Epoxy polyurethane-alkene polymer interpenetrating network anti-corrosion paint |
| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN118271915A (en) * | 2024-03-01 | 2024-07-02 | 广西南宁维一防腐科技有限公司 | A kind of environmentally friendly thermosetting acrylic paint for building |
-
1993
- 1993-08-25 CN CN 93109988 patent/CN1099781A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100369993C (en) * | 2006-03-20 | 2008-02-20 | 王新成 | Epoxy polyurethane-alkene polymer interpenetrating network anti-corrosion paint |
| CN103146278A (en) * | 2013-03-25 | 2013-06-12 | 扬州大学 | Preparation method of low-temperature curing water-based acrylic amino baking coating |
| CN118271915A (en) * | 2024-03-01 | 2024-07-02 | 广西南宁维一防腐科技有限公司 | A kind of environmentally friendly thermosetting acrylic paint for building |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |