CN110003785A - A kind of security door aqueous metallic paint - Google Patents
A kind of security door aqueous metallic paint Download PDFInfo
- Publication number
- CN110003785A CN110003785A CN201910383386.1A CN201910383386A CN110003785A CN 110003785 A CN110003785 A CN 110003785A CN 201910383386 A CN201910383386 A CN 201910383386A CN 110003785 A CN110003785 A CN 110003785A
- Authority
- CN
- China
- Prior art keywords
- metallic paint
- security door
- aqueous metallic
- aqueous
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000003973 paint Substances 0.000 title claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 15
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- -1 polypropylene glycerol Polymers 0.000 claims description 4
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- SGUQCKMQPFUEDZ-UHFFFAOYSA-N 6-butoxyhexyl acetate Chemical compound CCCCOCCCCCCOC(C)=O SGUQCKMQPFUEDZ-UHFFFAOYSA-N 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims description 3
- 229940063655 aluminum stearate Drugs 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 229920003180 amino resin Polymers 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 description 5
- 229920005749 polyurethane resin Polymers 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229960004279 formaldehyde Drugs 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/42—Gloss-reducing agents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of security door aqueous metallic paint, each component including following mass percent: water-base resin 50-90%, flatting silica 0.1-10%, defoaming agent 0.1-6%, moistening flatting agent 0.1-6%, thickener 0.1-6%, coalescing agent 0.6-10%, deionized water 2-20%.Security door aqueous metallic paint of the invention is free of amino resins, and the organic solvents such as containing benezene, formaldehydeless release, and aqueous polyurethane used do not have extremely low volatile organic content, and obtained aqueous metallic paint has very high environmental benefit；In addition, its adhesive force is good, glossiness is high, good weatherability.
Description
Technical field
The present invention relates to metallic paint technical field, in particular to a kind of security door aqueous metallic paint.
Background technique
In recent years, for security door coating with the growth that quickly grows of real-estate market, existing security door coating has amino
Coating, because its form of construction work is easy, quick, and film performance is excellent, can satisfy the requirement of various occasions, thus
Security door field of coating occupies larger share.But amido coatings volatile organic matter is more, and there are problems that Form aldehyde release,
It is difficult to meet environmental requirements.There are also waterborne epoxy coatings for existing security door metallic paint, and poor, flexibility that there is also weatherabilities is not
The problems such as sufficient.
Summary of the invention
The present invention in order to solve problems in the prior art, provides a kind of environmental protection, high durable, high performance security door water
Property metallic paint.
Specific technical solution is as follows: a kind of security door aqueous metallic paint, each component including following mass percent: water
Property resin 50-90%, flatting silica 0.1-10%, defoaming agent 0.1-6%, moistening flatting agent 0.1-6%, thickener 0.1-6%, at
Film auxiliary agent 0.6-10%, deionized water 2-20%.
The following are attached technical schemes of the invention.
Preferably, the water-base resin is in waterborne polyurethane resin or acrylic resin modified by aqueous polyaminoester
Any one or two kinds of mixed with arbitrary proportion.
Preferably, the flatting silica is superfine silicon dioxide, talcum powder, aluminum stearate, one in calcium stearate
Kind or several mixed with arbitrary proportion.
Preferably, the defoaming agent is silicone emulsion, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerol
One or more of ether is mixed with arbitrary proportion.
Preferably, the moistening flatting agent is any one of organic silicon, esters of acrylic acid or two kinds to appoint
The mixing of meaning ratio.
Preferably, the thickener is polyacrylic ester thickener, any in association type polyurethane thickener
It plants or two kinds is mixed with arbitrary proportion.
Preferably, the coalescing agent is alcohol ester-12, propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol list first
Any one or more of ether, Dipropylene glycol mono-n-butyl Ether, dimethyl ether, propylene glycol phenylate, hexylene glycol monobutyl ether acetate
It is mixed with arbitrary proportion.
Technical effect of the invention: security door aqueous metallic paint of the invention is free of amino resins, and containing benezene etc. does not have
Solvent, formaldehydeless release, and aqueous polyurethane used have extremely low volatile organic content, obtained water-based metal
Paint has very high environmental benefit；In addition, its adhesive force is good, glossiness is high, good weatherability.
Specific embodiment
In the following, in conjunction with example, property feature and advantage is further described for the essence of the present invention, but the present invention not office
It is limited to listed embodiment.
A kind of security door aqueous metallic paint of the present embodiment includes each component of following mass percent: water-base resin
50-90%, flatting silica 0.1-10%, defoaming agent 0.1-6%, moistening flatting agent 0.1-6%, thickener 0.1-6%, coalescing agent
0.6-10%, deionized water 2-20%.Using said ratio security door with aqueous metallic paint mainly by special water-base resin,
The composition such as functional aid, deionized water, is mono-component aqueous baking vanish, has the advantages that the organic solvents such as 1, not containing benezene,
Belong to environmentally friendly machine；2, adhesive force is good, glossiness is high, good weatherability；3, using advanced waterborne polyurethane resin, properties of product
It is superior.
In the present embodiment, the water-base resin is in waterborne polyurethane resin or acrylic resin modified by aqueous polyaminoester
It is any one or two kinds of to be mixed with arbitrary proportion, so that aqueous metallic paint has extremely low volatile organic content, so that aqueous
The feature of environmental protection of metallic paint is more preferable.
In the present embodiment, the flatting silica is one of superfine silicon dioxide, talcum powder, aluminum stearate, calcium stearate
Or it several is mixed with arbitrary proportion.
In the present embodiment, the defoaming agent is silicone emulsion, polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether
One or more of mixed with arbitrary proportion, to inhibit the foam of aqueous metallic paint.
In the present embodiment, the moistening flatting agent is any one of organic silicon, esters of acrylic acid or two kinds with any
Ratio mixing.
In the present embodiment, the thickener is any one of polyacrylic ester thickener, association type polyurethane thickener
Or two kinds mixed with arbitrary proportion.
In the present embodiment, the coalescing agent is alcohol ester-12, propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol list first
Any one or more of ether, Dipropylene glycol mono-n-butyl Ether, dimethyl ether, propylene glycol phenylate, hexylene glycol monobutyl ether acetate
It is mixed with arbitrary proportion.
Embodiment 1
Security door aqueous metallic paint of the invention includes following component in parts by mass: 72 parts of waterborne polyurethane resin,
3.2 parts of flatting silica, 1.1 parts of defoaming agent, 4 parts of moistening flatting agent, 2.5 parts of thickener, 5 parts of coalescing agent, 12.2 parts of deionized water.
According to GB/T1728-1979, GB/T1732-1993, GB/T9286-1998, GB/T9754-2007, GB/T1733-
1993, GB/T1771-2007 etc. is tested for the property the security door of the present embodiment with aqueous metallic paint paint film, meets security door
With metallic paint standard requirements, as a result such as following table.
Embodiment 2
The security door aqueous metallic paint of the present embodiment includes following component: waterborne polyurethane resin 50 in parts by mass
Part, 6.7 parts of flatting silica, 2.3 parts of defoaming agent, 6 parts of moistening flatting agent, 5 parts of thickener, 10 parts of coalescing agent, 20 parts of deionized water.
According to GB/T1728-1979, GB/T1732-1993, GB/T9286-1998, GB/T9754-2007, GB/T1733-
1993, GB/T1771-2007 etc. is tested for the property the security door of the present embodiment with aqueous metallic paint paint film, meets security door
With metallic paint standard requirements, as a result such as following table.
The security door aqueous metallic paint of the present embodiment is free of amino resins, formaldehydeless release, and aqueous polyurethane used
With extremely low volatile organic content, obtained aqueous metallic paint has very high environmental benefit.
It is pointed out that the technical concepts and features of above-mentioned preferred embodiment only to illustrate the invention, its object is to
Those skilled in the art can understand the contents of the present invention and implements accordingly, and protection of the invention can not be limited with this
Range.Any equivalent change or modification in accordance with the spirit of the invention should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of security door aqueous metallic paint, which is characterized in that each component including following mass percent: water-base resin
50-90%, flatting silica 0.1-10%, defoaming agent 0.1-6%, moistening flatting agent 0.1-6%, thickener 0.1-6%, coalescing agent
0.6-10%, deionized water 2-20%.
2. security door aqueous metallic paint according to claim 1, which is characterized in that the water-base resin is aqueous poly- ammonia
Any one of ester resin or acrylic resin modified by aqueous polyaminoester or two kinds are mixed with arbitrary proportion.
3. security door aqueous metallic paint according to claim 1, which is characterized in that the flatting silica is ultra-fine titanium dioxide
One or more of silicon, talcum powder, aluminum stearate, calcium stearate are mixed with arbitrary proportion.
4. security door aqueous metallic paint according to claim 1, which is characterized in that the defoaming agent be silicone emulsion,
One or more of polypropylene glycerol aether, polyoxyethylene polyoxypropylene glycerin ether are mixed with arbitrary proportion.
5. security door aqueous metallic paint according to claim 1, which is characterized in that the moistening flatting agent is organosilicon
Any one of class, esters of acrylic acid or two kinds are mixed with arbitrary proportion.
6. security door aqueous metallic paint according to claim 1, which is characterized in that the thickener is polyacrylate
Any one of thickener, association type polyurethane thickener or two kinds are mixed with arbitrary proportion.
7. security door aqueous metallic paint according to claim 1, which is characterized in that the coalescing agent be alcohol ester-12,
Propylene glycol monomethyl ether, propandiol butyl ether, dipropylene glycol monomethyl ether, Dipropylene glycol mono-n-butyl Ether, dimethyl ether, propylene glycol phenyl
Any one or more of ether, hexylene glycol monobutyl ether acetate are mixed with arbitrary proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910383386.1A CN110003785A (en) | 2019-05-09 | 2019-05-09 | A kind of security door aqueous metallic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910383386.1A CN110003785A (en) | 2019-05-09 | 2019-05-09 | A kind of security door aqueous metallic paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110003785A true CN110003785A (en) | 2019-07-12 |
Family
ID=67176342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910383386.1A Pending CN110003785A (en) | 2019-05-09 | 2019-05-09 | A kind of security door aqueous metallic paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110003785A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094554A (en) * | 2020-09-22 | 2020-12-18 | 卡秀万辉(无锡)高新材料有限公司 | Water-based bi-component coating, preparation method thereof and application thereof in anode aluminum substrate coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102363702A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Aqueous mono-component matte varnish and preparation method thereof |
| CN106147588A (en) * | 2016-07-22 | 2016-11-23 | 成都拜迪新材料有限公司 | One group is applied to the aqueous finish paint of 25 type passenger vehicles, varnish and preparation method thereof |
| CN106752825A (en) * | 2016-12-26 | 2017-05-31 | 大连佳秀百隆新材料股份有限公司 | A kind of one pack system dull finishing coat formula |
| CN109370411A (en) * | 2018-09-28 | 2019-02-22 | 合众（佛山）化工有限公司 | A kind of acrylic resin modified aqueous industrial coating of fluorine-silicon polyurethane |
-
2019
- 2019-05-09 CN CN201910383386.1A patent/CN110003785A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102363702A (en) * | 2011-06-30 | 2012-02-29 | 成都倍大涂料有限公司 | Aqueous mono-component matte varnish and preparation method thereof |
| CN106147588A (en) * | 2016-07-22 | 2016-11-23 | 成都拜迪新材料有限公司 | One group is applied to the aqueous finish paint of 25 type passenger vehicles, varnish and preparation method thereof |
| CN106752825A (en) * | 2016-12-26 | 2017-05-31 | 大连佳秀百隆新材料股份有限公司 | A kind of one pack system dull finishing coat formula |
| CN109370411A (en) * | 2018-09-28 | 2019-02-22 | 合众（佛山）化工有限公司 | A kind of acrylic resin modified aqueous industrial coating of fluorine-silicon polyurethane |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112094554A (en) * | 2020-09-22 | 2020-12-18 | 卡秀万辉(无锡)高新材料有限公司 | Water-based bi-component coating, preparation method thereof and application thereof in anode aluminum substrate coating |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20190712 |