CN110128811A - A rubber-dipped composite material that enhances the cut resistance of gloves - Google Patents
A rubber-dipped composite material that enhances the cut resistance of gloves Download PDFInfo
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- CN110128811A CN110128811A CN201910364057.2A CN201910364057A CN110128811A CN 110128811 A CN110128811 A CN 110128811A CN 201910364057 A CN201910364057 A CN 201910364057A CN 110128811 A CN110128811 A CN 110128811A
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- rubber
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- 239000002131 composite material Substances 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000002708 enhancing effect Effects 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000003365 glass fiber Substances 0.000 claims abstract description 8
- 239000004816 latex Substances 0.000 claims abstract description 7
- 229920000126 latex Polymers 0.000 claims abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 7
- 229920002748 Basalt fiber Polymers 0.000 claims abstract description 6
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 229920000459 Nitrile rubber Polymers 0.000 claims description 6
- 229920002396 Polyurea Polymers 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims 6
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 6
- 239000004760 aramid Substances 0.000 abstract description 3
- 238000007598 dipping method Methods 0.000 description 29
- 238000000034 method Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 6
- 229920003225 polyurethane elastomer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011521 glass Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种增强手套防切割性能的浸胶复合材料，其特征在于：在胶乳中添加有添加物，所述添加物为金属氧化物和/或二氧化硅和/或玻璃纤维和/或玄武岩纤维和/或芳纶纤维。本发明通过对浸胶层的配方进行改良，浸胶层具有防切割性能，其可明显提高手套的防切割等级。The invention discloses a dipped composite material for enhancing the anti-cut performance of gloves, which is characterized in that: additives are added to the latex, and the additives are metal oxides and/or silicon dioxide and/or glass fibers and/or or basalt fibers and/or aramid fibers. The invention improves the formula of the dipped layer, so that the dipped layer has anti-cutting performance, which can obviously improve the anti-cutting grade of the glove.
Description
技术领域technical field
本发明涉及一种手套浸胶层，具体地说，涉及一种增强手套防切割性能的浸胶复合材料。The invention relates to a rubber-dipped layer of gloves, in particular to a rubber-dipped composite material for enhancing the anti-cutting performance of gloves.
背景技术Background technique
浸胶手套所用浸胶层常见的有PU、丁腈等，浸胶层的作用大多为增强手套的抓握力、耐磨性。而手套的防切割性能只能通过手套芯来提升，现有的浸胶层都不具有增强防切割的功能。因此，需要一种新的技术方案来解决上述技术问题。Common dipping layers used in dipped gloves are PU, nitrile, etc., and the role of the dipping layer is mostly to enhance the grip and wear resistance of the gloves. And the anti-cutting performance of gloves can only be improved by the glove core, and the existing dipping layer does not have the function of enhancing the anti-cutting. Therefore, a new technical solution is needed to solve the above technical problems.
发明内容Contents of the invention
本发明的目的是提供一种增强手套防切割性能的浸胶复合材料，利用该浸胶复合材料制成的浸胶层能够明显增强手套的防切割等级。The object of the present invention is to provide a dipped composite material that enhances the cut resistance performance of gloves, and the dipped layer made of the dipped composite material can obviously enhance the cut resistance level of gloves.
本发明采用的技术方案是：The technical scheme adopted in the present invention is:
一种增强手套防切割性能的浸胶复合材料，在胶乳中添加有添加物，所述添加物为金属氧化物和/或二氧化硅和/或玻璃纤维和/或玄武岩纤维和/或芳纶纤维。A rubber-dipping composite material for enhancing the cut resistance of gloves, in which additives are added to the latex, and the additives are metal oxides and/or silicon dioxide and/or glass fibers and/or basalt fibers and/or aramid fibers fiber.
所述胶乳为天然橡胶、丁腈橡胶、氯丁橡胶、聚氨酯、聚脲、硅胶、丁苯橡胶、聚异戊二烯橡胶和丙烯酸中一种或几种任意比例的混合物。The latex is a mixture of one or more of natural rubber, nitrile rubber, neoprene, polyurethane, polyurea, silica gel, styrene-butadiene rubber, polyisoprene rubber and acrylic acid in any proportion.
所述金属氧化物为二氧化钛、氧化铁、氧化钙、氧化镁、氧化钠、氧化钾、氧化磷、氧化锰和氧化锆中的一种或几种任意比例的混合物。The metal oxide is one or a mixture of several of titanium dioxide, iron oxide, calcium oxide, magnesium oxide, sodium oxide, potassium oxide, phosphorus oxide, manganese oxide and zirconium oxide in any proportion.
所述金属氧化物的形态为晶须或是粉末状。The form of the metal oxide is whisker or powder.
所述玻璃纤维、玄武岩纤维和芳纶纤维均为短纤或是浆粕。The glass fibers, basalt fibers and aramid fibers are all short fibers or pulp.
所述添加物与胶乳的质量比为1-60:100。The mass ratio of the additive to the latex is 1-60:100.
本发明通过对浸胶层的配方进行改良，浸胶层具有防切割性能，其可明显提高手套的防切割等级。The invention improves the formula of the dipped layer, so that the dipped layer has anti-cutting performance, which can obviously improve the anti-cutting grade of the glove.
具体实施方案specific implementation plan
实施例1Example 1
一种增强手套防切割性能的浸胶复合材料，在10Kg聚氨酯胶料中添加0.05Kg二氧化钛细粉和0.05Kg二氧化硅细粉，搅拌均匀后制得浸胶复合料，采用普通不具有耐切割等级的手套芯，按照现有浸胶工艺浸胶制得手套。A dipped composite material that enhances the cut resistance of gloves. Add 0.05Kg of titanium dioxide fine powder and 0.05Kg of silicon dioxide fine powder to 10Kg of polyurethane rubber, and stir evenly to obtain a dipped composite material. Grade glove cores are dipped into gloves according to the existing dipping process.
实施例2Example 2
浸胶复合料由10Kg聚氨酯胶料中添加0.1Kg二氧化硅细粉搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping composite material is prepared by adding 0.1 kg of silicon dioxide fine powder to 10 kg of polyurethane rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例3Example 3
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping compound is prepared by adding 0.05Kg of silica fine powder and 0.06Kg of short glass fiber to 10Kg of polyurethane rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例4Example 4
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping compound is prepared by adding 0.05Kg of silica fine powder and 0.06Kg of short glass fiber to 10Kg of polyurethane rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例5Example 5
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化钛细粉、0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping composite material is prepared by adding 0.05Kg titanium dioxide fine powder, 0.05Kg silica fine powder and 0.06Kg glass short fiber to 10Kg polyurethane rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例6Example 6
浸胶复合料由10Kg丁腈胶料中添加0.05Kg玄武岩纤维短纤和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping compound is prepared by adding 0.05Kg of basalt fiber short fibers and 0.06Kg of glass short fibers to 10Kg of nitrile rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例7Example 7
浸胶复合料由10Kg丁腈胶料中添加0.12Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping composite material is prepared by adding 0.12 kg of short glass fibers to 10 kg of nitrile rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例8Example 8
浸胶复合料由10Kg丁腈胶料中添加0.05Kg氧化镁、0.05K氧化钙、0.05Kg芳纶纤维浆搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping composite material is prepared by adding 0.05Kg magnesium oxide, 0.05K calcium oxide, and 0.05Kg aramid fiber slurry to 10Kg of nitrile rubber and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例9Example 9
浸胶复合料由10Kg聚脲料中添加0.05Kg二氧化硅和0.05K氧化钙搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping compound is prepared by adding 0.05Kg of silicon dioxide and 0.05K of calcium oxide to 10Kg of polyurea material and stirring evenly. The glove core and dipping process are the same as in Example 1.
实施例10Example 10
浸胶复合料由10Kg聚脲料中添加0.05Kg二氧化硅和0.05K玄武岩短纤维搅拌均匀制得，手套芯及浸胶工艺同实施例1。The dipping composite material is prepared by adding 0.05Kg of silicon dioxide and 0.05K basalt short fiber to 10Kg of polyurea material and stirring evenly. The glove core and dipping process are the same as in Example 1.
对比例1Comparative example 1
浸胶复合料仅由聚氨酯胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。The dipping composite material is only composed of polyurethane rubber, and the same glove core as in Example 1 is used to prepare gloves by the same dipping process.
对比例2Comparative example 2
浸胶复合料仅由丁腈胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。The dipping composite material is only composed of nitrile rubber, and the same glove core as in Example 1 is taken, and the gloves are prepared by the same dipping process.
对比例3Comparative example 3
浸胶复合料仅由聚脲胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。The dipping composite material is only composed of polyurea rubber, and the same glove core as in Example 1 is taken, and the same dipping process is used to prepare gloves.
上述实施例1-10以及对比例1-3中所制得手套的浸胶层厚度均相同，上述13组手套的切割等级经耐切割等级检测，所得数据如下：The thickness of the dipped layer of the gloves prepared in the above-mentioned Examples 1-10 and Comparative Examples 1-3 is the same, and the cutting grade of the above-mentioned 13 groups of gloves is tested by the cutting-resistant grade, and the obtained data are as follows:
Claims (6)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910364057.2A CN110128811A (en) | 2019-04-30 | 2019-04-30 | A rubber-dipped composite material that enhances the cut resistance of gloves |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910364057.2A CN110128811A (en) | 2019-04-30 | 2019-04-30 | A rubber-dipped composite material that enhances the cut resistance of gloves |
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| CN110128811A true CN110128811A (en) | 2019-08-16 |
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| CN201910364057.2A Pending CN110128811A (en) | 2019-04-30 | 2019-04-30 | A rubber-dipped composite material that enhances the cut resistance of gloves |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111820510A (en) * | 2020-07-24 | 2020-10-27 | 胡媛媛 | Butyronitrile wear-resistant impregnated glove |
| CN113142721A (en) * | 2021-05-28 | 2021-07-23 | 嘉鸿手套实业有限公司 | Cutting-resistant and puncture-resistant industrial protective glove |
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| CN102079825A (en) * | 2009-11-27 | 2011-06-01 | 东台百地医用制品有限公司 | Heat conduction thigmonasty latex product as well as preparation method and application thereof |
| CN107775854A (en) * | 2017-12-12 | 2018-03-09 | 段书霞 | A kind of heat resistant rubber gloves |
| CN109454792A (en) * | 2018-09-23 | 2019-03-12 | 南通嘉得利安全用品有限公司 | A kind of aqueous polyurethane dipped gloves and its production method |
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2019
- 2019-04-30 CN CN201910364057.2A patent/CN110128811A/en active Pending
Patent Citations (4)
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|---|---|---|---|---|
| CN101469759A (en) * | 2007-12-29 | 2009-07-01 | 柳州欧维姆机械股份有限公司 | Fiber reinforced rubber vibration isolator and method of producing the same |
| CN102079825A (en) * | 2009-11-27 | 2011-06-01 | 东台百地医用制品有限公司 | Heat conduction thigmonasty latex product as well as preparation method and application thereof |
| CN107775854A (en) * | 2017-12-12 | 2018-03-09 | 段书霞 | A kind of heat resistant rubber gloves |
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Application publication date: 20190816 |