CN110128811A - 一种增强手套防切割性能的浸胶复合材料 - Google Patents
一种增强手套防切割性能的浸胶复合材料 Download PDFInfo
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- 239000002131 composite material Substances 0.000 title claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000002708 enhancing effect Effects 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- 239000000654 additive Substances 0.000 claims abstract description 8
- 239000003365 glass fiber Substances 0.000 claims abstract description 8
- 239000004816 latex Substances 0.000 claims abstract description 7
- 229920000126 latex Polymers 0.000 claims abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 7
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 7
- 229920002748 Basalt fiber Polymers 0.000 claims abstract description 6
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 229920000459 Nitrile rubber Polymers 0.000 claims description 6
- 229920002396 Polyurea Polymers 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 239000000741 silica gel Substances 0.000 claims description 2
- 229910002027 silica gel Inorganic materials 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims 6
- 239000002253 acid Substances 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 6
- 239000004760 aramid Substances 0.000 abstract description 3
- 238000007598 dipping method Methods 0.000 description 29
- 238000000034 method Methods 0.000 description 14
- 238000003756 stirring Methods 0.000 description 10
- 239000000843 powder Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 6
- 229920003225 polyurethane elastomer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000011521 glass Substances 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明公开了一种增强手套防切割性能的浸胶复合材料，其特征在于：在胶乳中添加有添加物，所述添加物为金属氧化物和/或二氧化硅和/或玻璃纤维和/或玄武岩纤维和/或芳纶纤维。本发明通过对浸胶层的配方进行改良，浸胶层具有防切割性能，其可明显提高手套的防切割等级。
Description
技术领域
本发明涉及一种手套浸胶层，具体地说，涉及一种增强手套防切割性能的浸胶复合材料。
背景技术
浸胶手套所用浸胶层常见的有PU、丁腈等，浸胶层的作用大多为增强手套的抓握力、耐磨性。而手套的防切割性能只能通过手套芯来提升，现有的浸胶层都不具有增强防切割的功能。因此，需要一种新的技术方案来解决上述技术问题。
发明内容
本发明的目的是提供一种增强手套防切割性能的浸胶复合材料，利用该浸胶复合材料制成的浸胶层能够明显增强手套的防切割等级。
本发明采用的技术方案是：
一种增强手套防切割性能的浸胶复合材料，在胶乳中添加有添加物，所述添加物为金属氧化物和/或二氧化硅和/或玻璃纤维和/或玄武岩纤维和/或芳纶纤维。
所述胶乳为天然橡胶、丁腈橡胶、氯丁橡胶、聚氨酯、聚脲、硅胶、丁苯橡胶、聚异戊二烯橡胶和丙烯酸中一种或几种任意比例的混合物。
所述金属氧化物为二氧化钛、氧化铁、氧化钙、氧化镁、氧化钠、氧化钾、氧化磷、氧化锰和氧化锆中的一种或几种任意比例的混合物。
所述金属氧化物的形态为晶须或是粉末状。
所述玻璃纤维、玄武岩纤维和芳纶纤维均为短纤或是浆粕。
所述添加物与胶乳的质量比为1-60:100。
本发明通过对浸胶层的配方进行改良，浸胶层具有防切割性能，其可明显提高手套的防切割等级。
具体实施方案
实施例1
一种增强手套防切割性能的浸胶复合材料，在10Kg聚氨酯胶料中添加0.05Kg二氧化钛细粉和0.05Kg二氧化硅细粉，搅拌均匀后制得浸胶复合料，采用普通不具有耐切割等级的手套芯，按照现有浸胶工艺浸胶制得手套。
实施例2
浸胶复合料由10Kg聚氨酯胶料中添加0.1Kg二氧化硅细粉搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例3
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例4
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例5
浸胶复合料由10Kg聚氨酯胶料中添加0.05Kg二氧化钛细粉、0.05Kg二氧化硅细粉和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例6
浸胶复合料由10Kg丁腈胶料中添加0.05Kg玄武岩纤维短纤和0.06Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例7
浸胶复合料由10Kg丁腈胶料中添加0.12Kg玻璃短纤搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例8
浸胶复合料由10Kg丁腈胶料中添加0.05Kg氧化镁、0.05K氧化钙、0.05Kg芳纶纤维浆搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例9
浸胶复合料由10Kg聚脲料中添加0.05Kg二氧化硅和0.05K氧化钙搅拌均匀制得，手套芯及浸胶工艺同实施例1。
实施例10
浸胶复合料由10Kg聚脲料中添加0.05Kg二氧化硅和0.05K玄武岩短纤维搅拌均匀制得，手套芯及浸胶工艺同实施例1。
对比例1
浸胶复合料仅由聚氨酯胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。
对比例2
浸胶复合料仅由丁腈胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。
对比例3
浸胶复合料仅由聚脲胶料组成，取实施例1同等的手套芯，采用相同的浸胶工艺制得手套。
上述实施例1-10以及对比例1-3中所制得手套的浸胶层厚度均相同，上述13组手套的切割等级经耐切割等级检测，所得数据如下：
Claims (6)
1.一种增强手套防切割性能的浸胶复合材料，其特征在于：在胶乳中添加有添加物，所述添加物为金属氧化物和/或二氧化硅和/或玻璃纤维和/或玄武岩纤维和/或芳纶纤维。
2.根据权利要求1所述的一种增强手套防切割性能的浸胶复合材料，其特征在于：所述胶乳为天然橡胶、丁腈橡胶、氯丁橡胶、聚氨酯、聚脲、硅胶、丁苯橡胶、聚异戊二烯橡胶和丙烯酸中一种或几种任意比例的混合物。
3.根据权利要求1所述的一种增强手套防切割性能的浸胶复合材料，其特征在于：所述金属氧化物为二氧化钛、氧化铁、氧化钙、氧化镁、氧化钠、氧化钾、氧化磷、氧化锰和氧化锆中的一种或几种任意比例的混合物。
4.根据权利要求1或3所述的一种增强手套防切割性能的浸胶复合材料，其特征在于：所述金属氧化物的形态为晶须或是粉末状。
5.根据权利要求1所述的一种增强手套防切割性能的浸胶复合材料，其特征在于：所述玻璃纤维、玄武岩纤维和芳纶纤维均为短纤或是浆粕。
6.根据权利要求1所述的一种增强手套防切割性能的浸胶复合材料，其特征在于：所述添加物与胶乳的质量比为1-60:100。
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111820510A (zh) * | 2020-07-24 | 2020-10-27 | 胡媛媛 | 一种丁腈耐磨浸胶手套 |
| CN113142721A (zh) * | 2021-05-28 | 2021-07-23 | 嘉鸿手套实业有限公司 | 一种耐切割、耐穿刺的工业防护手套 |
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| CN109454792A (zh) * | 2018-09-23 | 2019-03-12 | 南通嘉得利安全用品有限公司 | 一种水性聚氨酯浸胶手套及其生产方法 |
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| CN101469759A (zh) * | 2007-12-29 | 2009-07-01 | 柳州欧维姆机械股份有限公司 | 纤维增强橡胶隔振器及其制造方法 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111820510A (zh) * | 2020-07-24 | 2020-10-27 | 胡媛媛 | 一种丁腈耐磨浸胶手套 |
| CN113142721A (zh) * | 2021-05-28 | 2021-07-23 | 嘉鸿手套实业有限公司 | 一种耐切割、耐穿刺的工业防护手套 |
| CN113142721B (zh) * | 2021-05-28 | 2024-04-02 | 嘉鸿手套实业有限公司 | 一种耐切割、耐穿刺的工业防护手套 |
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