CN111139652A - Novel hydrophilic finishing agent for spinning - Google Patents
Novel hydrophilic finishing agent for spinning Download PDFInfo
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- CN111139652A CN111139652A CN202010016972.5A CN202010016972A CN111139652A CN 111139652 A CN111139652 A CN 111139652A CN 202010016972 A CN202010016972 A CN 202010016972A CN 111139652 A CN111139652 A CN 111139652A
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- polyether
- silicone oil
- finishing agent
- emulsifier
- hydrogen
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- 239000004900 Hydrophilic Finishing Agent Substances 0.000 title claims abstract description 22
- 238000009987 spinning Methods 0.000 title claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 50
- 229920000570 polyether Polymers 0.000 claims abstract description 50
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229920002545 silicone oil Polymers 0.000 claims abstract description 44
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 28
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 18
- 229920000728 polyester Polymers 0.000 claims abstract description 15
- 229960000583 acetic acid Drugs 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 14
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000001412 amines Chemical class 0.000 claims abstract description 12
- 239000004753 textile Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 238000006555 catalytic reaction Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012224 working solution Substances 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000007142 ring opening reaction Methods 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 150000003512 tertiary amines Chemical class 0.000 claims description 3
- -1 allyl ester Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 18
- 238000010521 absorption reaction Methods 0.000 abstract description 7
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 210000004243 sweat Anatomy 0.000 abstract description 3
- 239000004952 Polyamide Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 3
- 229920006052 Chinlon® Polymers 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Images
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention belongs to the technical field of auxiliaries for finishing and processing textile fabrics, and discloses a novel hydrophilic finishing agent for textile, which is characterized by comprising the following components: the hydrogen-terminated silicone oil, allyl polyether, isopropanol and polyether amine are used as raw materials, chloroplatinic acid is used as a catalyst, glacial acetic acid, polyester polyether and an emulsifier are used as post-treatment agents, and the following components are used in proportion: 200-400 parts of hydrogen-terminated silicone oil, 16-32 parts of allyl polyether, 120-300 parts of isopropanol and 20-40 parts of polyetheramine, wherein the addition amount of chloroplatinic acid is 0.3-0.6 part by weight, the addition amount of glacial acetic acid is 3-6% of the total amount of the components, the addition amount of emulsifier is 10-20% of the total amount of the components, and the addition amount of polyester polyether is 13-30% of the total amount of the components. The product using the hydrophilic finishing agent has hand feeling superior to that of common moisture-absorbing and sweat-releasing finishing agent, and the polyester, cotton, chemical fiber, blended fabric and polyamide fabric can reach instant water absorption or water absorption rate of 0-6 seconds.
Description
Technical Field
The invention belongs to the technical field of auxiliaries for finishing and processing textile fabrics, and particularly relates to a novel hydrophilic finishing agent for textile.
Background
The hydrophilic finishing agent is a commonly used auxiliary agent for printing and dyeing the fabric, the fabric dyed at first has rough hand feeling, poor water absorption and low resilience, and after the fabric is processed into clothes and underwear, the comfort level of the fabric can not meet the requirements of people, so that people develop softeners with different hand feeling styles according to different fabrics, such as fluffy type, smooth type and soft type, but the softeners do not have a hydrophilic function, and the textile finished by the softener still has rough hand feeling, poor resilience and no water absorption. For better product comfort, a better finish is needed.
Disclosure of Invention
The invention aims to overcome the defects that the hand feeling and the hydrophilicity of the existing fabric softener are incompatible and the hand feeling is not hydrophilic and hydrophilic but poor in hand feeling of common silicone oil, and provides a novel hydrophilic finishing agent for spinning, which has better hand feeling than the common moisture absorption and sweat release finishing agent for fabric fabrics after use and can achieve instant water absorption after polyester, cotton, chemical fiber and blended fabric are used.
In order to achieve the purpose, the invention provides the following technical scheme: a novel hydrophilic finishing agent for spinning comprises the following components: the hydrogen-terminated silicone oil, allyl polyether, isopropanol and polyether amine are used as raw materials, chloroplatinic acid is used as a catalyst, glacial acetic acid, polyester polyether and an emulsifier are used as post-treatment agents, and the following components are used in proportion: 200-400 parts of hydrogen-terminated silicone oil, 16-32 parts of allyl polyether, 120-300 parts of isopropanol and 20-40 parts of polyetheramine, wherein the addition amount of chloroplatinic acid is 0.3-0.6 part, the addition amount of glacial acetic acid is 3-6% of the total amount of the components, the addition amount of emulsifier is 10-20% of the total amount of the components, and the addition amount of polyester polyether is 13-30% of the total amount of the components; adding hydrogen-terminated silicone oil, allyl polyether and isopropanol into a reaction kettle, mixing and stirring, heating, adding chloroplatinic acid for catalysis, heating, keeping the temperature, adding polyetheramine, keeping the temperature, cooling, adding glacial acetic acid, fully stirring, cooling to obtain hydrophilic silicone oil, diluting the obtained hydrophilic silicone oil and an emulsifier together with ionized water to obtain a working solution, adding polyester polyether, and compounding to obtain the hydrophilic finishing agent.
Preferably, the molecular weight of the hydrogen-terminated silicone oil is 8000-10000, and the hydrogen-terminated silicone oil can be replaced by the hydrogen-terminated silicone oil with the same molecular weight.
Preferably, the allyl ester polyether adopts allyl epoxy polyether with molecular weight of 1400.
Preferably, the isopropanol is a solvent, and ethylene glycol monobutyl ether or dipropylene glycol can be used to replace the isopropanol.
Preferably, AE-1000 is adopted as the polyether amine, and tertiary amine type polyether amine ER-700 can be selected.
Preferably, the emulsifier is a compound of an emulsifier TO5 and an emulsifier TO 7. The emulsifier TO5 and the emulsifier TO7 are common emulsifier types and can be mixed for use, and in addition, the emulsifier can also be selected from AEO series surfactants and TX series surfactants.
Preferably, the hydrogen-terminated silicone oil, the allyl polyether and the isopropanol are respectively put into a glass-lined anchor type reaction kettle according to the parts by weight, mixed and stirred for 5 minutes, a cover is covered, the mixture is heated to 60-65 ℃, chloroplatinic acid is added into pores for catalysis at one time, the temperature is raised to 83-90 ℃, the temperature is kept for 1.5-2 hours, the epoxy polyether terminated silicone oil at the end of the intermediate body is synthesized, the intermediate body is continuously subjected to ring-opening chain extension reaction with added polyetheramine, the temperature is kept for 5 hours at 83-90 ℃, glacial acetic acid is added into the mixture for full stirring after the temperature is lowered to 70 ℃, the mixture is cooled and discharged to obtain hydrophilic silicone oil, the obtained hydrophilic silicone oil and an emulsifier are diluted into working solution by using ionized water, then the polyester polyether is added, and the hydrophilic finishing.
The traditional hydrophilic silicone oil is mainly side chain polyether modified silicone oil and side chain polyether modified amino silicone oil. Such softeners are relatively hydrophilic, but the hand of the finished fabric is not ideal, which greatly limits further application. The invention especially develops a novel hydrophilic finishing agent which has soft and smooth hand feeling and instant hydrophilic perspiration, is suitable for finishing various novel textile fabrics, mainly comprises four categories, namely cotton fabrics, chinlon fabrics, terylene and chemical fibers, and underwear, socks, swimwear, yarns and the like which are frequently treated in the dyeing and finishing industry are in the use range; the invention takes epoxy-terminated silicone oil as an initiator, and carries out ammoniation reaction with hydrophilic polyether amine AE100 in the presence of a small amount of isopropanol to synthesize high-solid ternary hydrophilic silicone oil, and emulsifier is used to emulsify the ternary hydrophilic silicone oil to obtain the hydrophilic soft finishing agent.
Compared with the prior art, the invention has the beneficial effects that:
the product using the hydrophilic finishing agent has hand feeling superior to that of the common moisture-absorbing and sweat-releasing finishing agent, the terylene, the cotton, the chemical fiber and the blended fabric can absorb water instantly, and the water absorption rate of the chinlon fabric is between 0 and 6 seconds according to different colors and different hand feeling requirements.
Drawings
FIG. 1 is a schematic diagram of the preparation process of the present invention.
Detailed Description
The technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides the following technical scheme: a novel hydrophilic finishing agent for spinning comprises the following components: the hydrogen-terminated silicone oil, allyl polyether, isopropanol and polyether amine are used as raw materials, chloroplatinic acid is used as a catalyst, glacial acetic acid, polyester polyether and an emulsifier are used as post-treatment agents, and the following components are used in proportion: 200-400 parts of hydrogen-terminated silicone oil, 16-32 parts of allyl polyether, 120-300 parts of isopropanol and 20-40 parts of polyetheramine, wherein the addition amount of chloroplatinic acid is 0.3-0.6 part, the addition amount of glacial acetic acid is 3-6% of the total amount of the components, the addition amount of emulsifier is 10-20% of the total amount of the components, and the addition amount of polyester polyether is 13-30% of the total amount of the components; adding hydrogen-terminated silicone oil, allyl polyether and isopropanol into a reaction kettle, mixing and stirring, heating, adding chloroplatinic acid for catalysis, heating, keeping the temperature, adding polyetheramine, keeping the temperature, cooling, adding glacial acetic acid, fully stirring, cooling to obtain hydrophilic silicone oil, diluting the obtained hydrophilic silicone oil and an emulsifier together with ionized water to obtain a working solution, adding polyester polyether, and compounding to obtain the hydrophilic finishing agent.
Furthermore, the molecular weight of the hydrogen-terminated silicone oil is 8000-10000, and the hydrogen-terminated silicone oil can be replaced by the end-terminated silicone oil with the same molecular weight.
Further, allyl polyether is allyl epoxy polyether with molecular weight of 1400.
Furthermore, isopropanol is used as a solvent, and ethylene glycol monobutyl ether or dipropylene glycol can be used to replace the isopropanol.
Further, AE-1000 is adopted as the polyether amine, and tertiary amine type polyether amine ER-700 can be selected.
Further, the emulsifier is a compound of emulsifier TO5 and emulsifier TO7, and the dosage of the emulsifier TO5 and the emulsifier TO7 is 1: 1.
The specific using process is as follows: as shown in figure 1, 200 kg of hydrogen-terminated silicone oil, 15.8 kg of allyl polyether and 120 kg of isopropanol are respectively put into a glass-lined anchor type reaction kettle to be mixed and stirred for 5 minutes, a cover is covered, the reaction kettle is heated to 60-65 ℃, then 0.3 kg of chloroplatinic acid is added into pores for catalysis at one time, the temperature is raised to 83-90 ℃, the temperature is kept for 1.5-2 hours, the epoxy-terminated polyether silicone oil at the end of an intermediate body is synthesized, the intermediate body is continuously subjected to ring-opening chain extension reaction with 20 kg of added polyether amine and kept at 83-90 ℃ for 5 hours, the temperature is lowered to 70 ℃, glacial acetic acid is added into the reaction kettle for 12 kg and sufficient stirring, the temperature is lowered, cooling and discharging are carried out to obtain hydrophilic silicone oil, the obtained hydrophilic silicone oil and 50 kg of emulsifier are diluted into working solution by ionized water, then 60 kg.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. A novel hydrophilic finishing agent for spinning is characterized by comprising the following components: the hydrogen-terminated silicone oil, allyl polyether, isopropanol and polyether amine are used as raw materials, chloroplatinic acid is used as a catalyst, glacial acetic acid, polyester polyether and an emulsifier are used as post-treatment agents, and the following components are used in proportion: 200-400 parts of hydrogen-terminated silicone oil, 16-32 parts of allyl polyether, 120-300 parts of isopropanol and 20-40 parts of polyetheramine, wherein the addition amount of chloroplatinic acid is 0.3-0.6 part, the addition amount of glacial acetic acid is 3-6% of the total amount of the components, the addition amount of emulsifier is 10-20% of the total amount of the components, and the addition amount of polyester polyether is 13-30% of the total amount of the components;
adding hydrogen-terminated silicone oil, allyl polyether and isopropanol into a reaction kettle, mixing and stirring, heating, adding chloroplatinic acid for catalysis, heating, keeping the temperature, adding polyetheramine, keeping the temperature, cooling, adding glacial acetic acid, fully stirring, cooling to obtain hydrophilic silicone oil, diluting the obtained hydrophilic silicone oil and an emulsifier together with ionized water to obtain a working solution, adding polyester polyether, and compounding to obtain the hydrophilic finishing agent.
2. The novel hydrophilic finishing agent for textile as claimed in claim 1, wherein the molecular weight of the hydrogen-terminated silicone oil is 8000-10000, and the hydrogen-terminated silicone oil can be replaced by the same molecular weight of the hydrogen-terminated silicone oil.
3. The novel hydrophilic finishing agent for textile as claimed in claim 1, wherein allyl ester polyether is allyl epoxy polyether with molecular weight of 1400.
4. The novel hydrophilic finishing agent for textile use as claimed in claim 1, wherein the isopropyl alcohol is a solvent, and ethylene glycol monobutyl ether or dipropylene glycol can be used instead of isopropyl alcohol.
5. The novel hydrophilic finishing agent for textile as claimed in claim 1, wherein AE-1000 is adopted as the polyether amine, and ER-700 is adopted as the tertiary amine type polyether amine.
6. The novel hydrophilic finishing agent for textiles as claimed in claim 1, wherein the emulsifier is a compound of emulsifier TO5 and emulsifier TO 7.
7. The novel textile hydrophilic finishing agent as claimed in claim 1, wherein the hydrogen-terminated silicone oil, allyl polyether and isopropyl alcohol are respectively put into a glass-lined anchor reactor according to parts by weight, mixed and stirred for 5 minutes, covered by a cover, heated to 60-65 ℃, and then added with chloroplatinic acid for catalysis at a time from a small hole, heated to 83-90 ℃ and insulated for 1.5-2 hours to synthesize intermediate-end epoxy polyether terminated silicone oil, the intermediate is continuously subjected to ring-opening chain extension reaction with added polyetheramine and insulated for 5 hours at 83-90 ℃, cooled to 70 ℃, added with glacial acetic acid for sufficient stirring, cooled and discharged to obtain hydrophilic silicone oil, the obtained hydrophilic silicone oil and an emulsifier are diluted into working solution by ionized water, and then added with polyester polyether to compound the hydrophilic finishing agent.
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| CN202010016972.5A CN111139652A (en) | 2020-01-08 | 2020-01-08 | Novel hydrophilic finishing agent for spinning |
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| CN202010016972.5A CN111139652A (en) | 2020-01-08 | 2020-01-08 | Novel hydrophilic finishing agent for spinning |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111945434A (en) * | 2020-09-01 | 2020-11-17 | 浙江汉邦新材料股份有限公司 | Hydrophilic ice feeling special-effect silicone oil |
| CN112482031A (en) * | 2020-11-27 | 2021-03-12 | 苏州联胜化学有限公司 | Fluffy elastic silicone oil for terylene and preparation method thereof |
| CN113004530A (en) * | 2021-04-12 | 2021-06-22 | 江苏尼美达科技有限公司 | Multi-component copolymer block silicone oil and preparation method thereof |
| CN113235301A (en) * | 2021-06-18 | 2021-08-10 | 广东宏昊化工有限公司 | Moisture-absorbing quick-drying finishing agent for textiles and preparation method thereof |
| CN113529425A (en) * | 2021-07-29 | 2021-10-22 | 广东新翔星科技股份有限公司 | Hydrophilic fluffy organic silicon softening agent and preparation method thereof |
| CN115717335A (en) * | 2022-11-28 | 2023-02-28 | 浙江理工大学桐乡研究院有限公司 | A moisture-absorbing and sweat-wicking finishing agent for cotton and its preparation method |
| CN115926173A (en) * | 2022-12-26 | 2023-04-07 | 广东宏昊化工有限公司 | Low-ring silicone oil and preparation method thereof |
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| 曹华: "亲水型聚醚胺AE-1000的性能及应用", 《海云花杯《印染助剂》暨江苏省印染助剂情报站第33届年会》 * |
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| CN115717335A (en) * | 2022-11-28 | 2023-02-28 | 浙江理工大学桐乡研究院有限公司 | A moisture-absorbing and sweat-wicking finishing agent for cotton and its preparation method |
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